The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterost...The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.展开更多
Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to t...Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.展开更多
Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriou...Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.展开更多
Offshore carbon capture, utilization, and storage(OCCUS) is regarded as a crucial technology for mitigating greenhouse gas emissions.Quantitative monitoring maps of sealed carbon dioxide are necessary in a comprehensi...Offshore carbon capture, utilization, and storage(OCCUS) is regarded as a crucial technology for mitigating greenhouse gas emissions.Quantitative monitoring maps of sealed carbon dioxide are necessary in a comprehensive OCCUS project. A potential high-resolution method for the aforementioned purpose lies in the full-waveform inversion(FWI) of time-lapse seismic data. However, practical applications of FWI are severely restricted by the well-known cycle-skipping problem. A new time-lapse FWI method using cross-correlation-based dynamic time warping(CDTW) is proposed to detect changes in the subsurface property due to carbon dioxide(CO_(2)) injection and address the aforementioned issue. The proposed method, namely CDTW, which combines the advantages of cross-correlation and dynamic time warping, is employed in the automatic estimation of the discrepancy between the seismic signals simulated using the baseline/initial model and those acquired. The proposed FWI method can then back-project the estimated discrepancy to the subsurface space domain, thereby facilitating retrieval of the induced subsurface property change by taking the difference between the inverted baseline and monitor models. Numerical results on pairs of signals prove that CDTW can obtain reliable shifts under amplitude modulation and noise contamination conditions. The performance of CDTW substantially outperforms that of the conventional dynamic time warping method. The proposed time-lapse fullwaveform inversion(FWI) method is applied to the Frio-2 CO_(2) storage model. The baseline and monitor models are inverted from the corresponding time-lapse seismic data. The changes in velocity due to CO_(2) injection are reconstructed by the difference between the baseline and the monitor models.展开更多
Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and u...Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.展开更多
In this paper, we deal with isommetric immersions of globally null warped product manifolds into Lorentzian manifolds with constant curvature c in codimension k≥3. Under the assumptions that the globally null warped ...In this paper, we deal with isommetric immersions of globally null warped product manifolds into Lorentzian manifolds with constant curvature c in codimension k≥3. Under the assumptions that the globally null warped product manifold has no points with the same constant sectional curvature c as the Lorentzian ambient, we show that such isometric immersion splits into warped product of isometric immersions.展开更多
Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also ch...Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.展开更多
Crealet is the world leader in sophisticated warp feeding technology and tailored solutions.Controlled warp tension stands also for controlled fabric quality.The Swiss firm presents its latest developments for technic...Crealet is the world leader in sophisticated warp feeding technology and tailored solutions.Controlled warp tension stands also for controlled fabric quality.The Swiss firm presents its latest developments for technical textile applications at Techtextil 2024 in Frankfurt,Germany.展开更多
The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior ele...The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior electronic conductivity and high electrocatalytic activity,e.g.,heterostructures,is a promising strategy to solve the above obstacles.Herein,a binary metal sulfide MnS-MoS_(2) heterojunction electrocatalyst is first designed for the construction of high-sulfur-loaded and durable Li-S batteries.The MnS-MoS_(2) p-n heterojunction shows a unique structure of MoS_(2) nanosheets decorated with ample MnS nanodots,which contributes to the formation of a strong built-in electric field at the two-phase interface.The MnS-MoS_(2) hybrid host shows strong soluble polysulfide affinity,enhanced electronic conductivity,and exceptional catalytic effect on sulfur reduction.Benefiting from the synergistic effect,the as-derived S/MnS-MoS_(2) cathode delivers a superb rate capability(643 m A h g^(-1)at 6 C)and a durable cyclability(0.048%decay per cycle over 1000 cycles).More impressively,an areal capacity of 9.9 m A h cm^(-2)can be achieved even under an extremely high sulfur loading of 14.7 mg cm^(-2)and a low electrolyte to sulfur ratio of 2.9μL mg^(-1).This work provides an in-depth understanding of the interfacial catalytic effect of binary metal compound heterojunctions on sulfur reaction kinetics.展开更多
To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a st...To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals sulfides.However,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed rationally.Herein,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox kinetics.Owing to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first time.The superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.展开更多
Surface nanopatterning of semiconductor optoelectronic devices is a powerful way to improve their quality and performance.However,photoelectric devices’inherent stress sensitivity and inevitable warpage pose a huge c...Surface nanopatterning of semiconductor optoelectronic devices is a powerful way to improve their quality and performance.However,photoelectric devices’inherent stress sensitivity and inevitable warpage pose a huge challenge on fabricating nanostructures large-scale.Electric-driven flexible-roller nanoimprint lithography for nanopatterning the optoelectronic wafer is proposed in this study.The flexible nanoimprint template twining around a roller is continuously released and recovered,controlled by the roller’s simple motion.The electric field applied to the template and substrate provides the driving force.The contact line of the template and the substrate gradually moves with the roller to enable scanning and adapting to the entire warped substrate,under the electric field.In addition,the driving force generated from electric field is applied to the surface of substrate,so that the substrate is free from external pressure.Furthermore,liquid resist completely fills in microcavities on the template by powerful electric field force,to ensure the fidelity of the nanostructures.The proposed nanoimprint technology is validated on the prototype.Finally,nano-grating structures are fabricated on a gallium nitride light-emitting diode chip adopting the solution,achieving polarization of the light source.展开更多
The warping may become an important factor for the precise transverse vibrations of curved beams.Thus,the first aim of this study is to specify the structural design parameters where the influence of cross-sectional w...The warping may become an important factor for the precise transverse vibrations of curved beams.Thus,the first aim of this study is to specify the structural design parameters where the influence of cross-sectional warping becomes great and the first-order shear deformation theory lacks the precision necessary.The outof-plane vibrations of the first-order shear deformation theory are compared with the warping-included vibrations as the curvature and/or thickness increase for symmetric and asymmetric transversely-functionally graded(TFG)curved beams.The second aim is to determine the influence of design parameters on the vibrations.The circular/exact elliptical beams are formed via curved mixed finite elements(MFEs)based on the exact curvature and length.The stress-free conditions are satisfied on three-dimensional(3D)constitutive equations.The variation of functionally graded(FG)material constituents is considered based on the power-law dependence.The cross-sectional warping deformations are defined over a displacement-type FE formulation.The warping-included MFEs(W-MFEs)provide satisfactory 3D structural characteristics with smaller degrees of freedom(DOFs)compared with the brick FEs.The Newmark method is used for the forced vibrations.展开更多
In this paper,a 20kW vehicle built-in permanent magnet synchronous motor is taken as an example,and a magnetic barrier structure is added to the rotor of the motor to solve the uneven saturation problem of the rotor s...In this paper,a 20kW vehicle built-in permanent magnet synchronous motor is taken as an example,and a magnetic barrier structure is added to the rotor of the motor to solve the uneven saturation problem of the rotor side magnetic bridge.This structure improves the air-gap flux density waveform of the motor by influencing the internal magnetic flux path of the motor rotor,thus improving the sine of the no-load back EMF waveform of the motor and reducing the torque ripple of the motor.At the same time,Taguchi method is used to optimize the structural parameters of the added magnetic barrier.In order to facilitate the analysis of its uneven saturation phenomenon and improve the optimization effect,a simple equivalent magnetic network(EMN)model considering the uneven saturation of rotor magnetic bridge is established in this paper,and the initial values of optimization factors are selected based on this model.Finally,the no-load back EMF waveform distortion rate,torque ripple and output torque of the optimized motor are compared and analyzed,and the influence of magnetic barrier structure parameters on the electromagnetic performance of the motor is also analyzed.The results show that the optimized motor can not change the output torque of the motor as much as possible on the basis of reducing the waveform distortion rate of no-load back EMF and torque ripple.展开更多
In this paper, we delve into the intrinsic nature of mass and gravity, as per the amplitude modulation interpretation of the quantum theory. We explore the idea that the elementary constituent is an electromagnetic co...In this paper, we delve into the intrinsic nature of mass and gravity, as per the amplitude modulation interpretation of the quantum theory. We explore the idea that the elementary constituent is an electromagnetic configuration that interacts with the quantum field, leading to the emergence of inertia and gravity as a reaction to the exchange with the quantum field. While these two phenomena have a common origin, they are distinct. Our proposal suggests manipulating the connection between the quantum field and the particle using high-frequency electromagnetic fields, thereby making a warp drive possible.展开更多
Based on artificial intelligence technology,HawkVision intelligent image pattern/weft straightening machine of Changzhou Hongda Wisdom Technology Co.,Ltd.pioneered the internationally advanced"fullwidth scanning ...Based on artificial intelligence technology,HawkVision intelligent image pattern/weft straightening machine of Changzhou Hongda Wisdom Technology Co.,Ltd.pioneered the internationally advanced"fullwidth scanning warping and weft straightening technology",which completely solved the problems of textile pattern deformation,weft skew and weft bending that cannot be corrected and recognized by photoelectric weft straightening.展开更多
基金supported by the National Natural Science Foundation of China(No.22269010,52231007,12327804,T2321003,22088101)the Jiangxi Provincial Natural Science Foundation(No.20224BAB214021)+1 种基金the Major Research Program of Jingdezhen Ceramic Industry(No.2023ZDGG002)the Ministry of Science and Technology of China(973 Project No.2021YFA1200600).
文摘The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.
基金financially supported by the Industrial Technology Innovation Program of IMAST(No.2023JSYD 01003)the National Natural Science Foundation of China(Nos.52104292 and U2341209)。
文摘Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.
基金supported by the National Natural Science Foundation of China(No.52072099)the Joint Guidance Project of the Natural Science Foundation of Heilongjiang Province,China(No.LH2022E093)the Team Program of the Natural Science Foundation of Heilongjiang Province,China(No.TD2021E005)。
文摘Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.
文摘Offshore carbon capture, utilization, and storage(OCCUS) is regarded as a crucial technology for mitigating greenhouse gas emissions.Quantitative monitoring maps of sealed carbon dioxide are necessary in a comprehensive OCCUS project. A potential high-resolution method for the aforementioned purpose lies in the full-waveform inversion(FWI) of time-lapse seismic data. However, practical applications of FWI are severely restricted by the well-known cycle-skipping problem. A new time-lapse FWI method using cross-correlation-based dynamic time warping(CDTW) is proposed to detect changes in the subsurface property due to carbon dioxide(CO_(2)) injection and address the aforementioned issue. The proposed method, namely CDTW, which combines the advantages of cross-correlation and dynamic time warping, is employed in the automatic estimation of the discrepancy between the seismic signals simulated using the baseline/initial model and those acquired. The proposed FWI method can then back-project the estimated discrepancy to the subsurface space domain, thereby facilitating retrieval of the induced subsurface property change by taking the difference between the inverted baseline and monitor models. Numerical results on pairs of signals prove that CDTW can obtain reliable shifts under amplitude modulation and noise contamination conditions. The performance of CDTW substantially outperforms that of the conventional dynamic time warping method. The proposed time-lapse fullwaveform inversion(FWI) method is applied to the Frio-2 CO_(2) storage model. The baseline and monitor models are inverted from the corresponding time-lapse seismic data. The changes in velocity due to CO_(2) injection are reconstructed by the difference between the baseline and the monitor models.
基金financially supported by the Natural Science Foundation of Shandong Province(ZR2021QB055,ZR2023MB017,ZR2022JQ10)the National Natural Science Foundation of China(21901146,220781792,22274083)。
文摘Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.
文摘In this paper, we deal with isommetric immersions of globally null warped product manifolds into Lorentzian manifolds with constant curvature c in codimension k≥3. Under the assumptions that the globally null warped product manifold has no points with the same constant sectional curvature c as the Lorentzian ambient, we show that such isometric immersion splits into warped product of isometric immersions.
基金supported by the faculty startup funds from the Yangzhou Universitythe Natural Science Foundation of Jiangsu Province(BK20210821)+1 种基金the National Natural Science Foundation of China(22102141)the Lvyangjinfeng Talent Program of Yangzhou。
文摘Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.
文摘Crealet is the world leader in sophisticated warp feeding technology and tailored solutions.Controlled warp tension stands also for controlled fabric quality.The Swiss firm presents its latest developments for technical textile applications at Techtextil 2024 in Frankfurt,Germany.
基金financial support from the National Natural Science Foundation of China (NSFC,21875155,22032004)the support of the National Key Research and Development Program of China (2021YFA1201502)the support of the Nanqiang Young Top-notch Talent Fellowship in Xiamen University。
文摘The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior electronic conductivity and high electrocatalytic activity,e.g.,heterostructures,is a promising strategy to solve the above obstacles.Herein,a binary metal sulfide MnS-MoS_(2) heterojunction electrocatalyst is first designed for the construction of high-sulfur-loaded and durable Li-S batteries.The MnS-MoS_(2) p-n heterojunction shows a unique structure of MoS_(2) nanosheets decorated with ample MnS nanodots,which contributes to the formation of a strong built-in electric field at the two-phase interface.The MnS-MoS_(2) hybrid host shows strong soluble polysulfide affinity,enhanced electronic conductivity,and exceptional catalytic effect on sulfur reduction.Benefiting from the synergistic effect,the as-derived S/MnS-MoS_(2) cathode delivers a superb rate capability(643 m A h g^(-1)at 6 C)and a durable cyclability(0.048%decay per cycle over 1000 cycles).More impressively,an areal capacity of 9.9 m A h cm^(-2)can be achieved even under an extremely high sulfur loading of 14.7 mg cm^(-2)and a low electrolyte to sulfur ratio of 2.9μL mg^(-1).This work provides an in-depth understanding of the interfacial catalytic effect of binary metal compound heterojunctions on sulfur reaction kinetics.
基金supported by the National R&D Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2018M3D1A1058793 and 2021R1A3B1068920)supported by the Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2018M3D1A1058744)the Yonsei Signature Research Cluster Program of 2021 (2021-22-0002)。
文摘To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals sulfides.However,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed rationally.Herein,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox kinetics.Owing to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first time.The superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.
基金financed by the National Natural Science Foundation of China(Nos.52025055 and 5227050783)。
文摘Surface nanopatterning of semiconductor optoelectronic devices is a powerful way to improve their quality and performance.However,photoelectric devices’inherent stress sensitivity and inevitable warpage pose a huge challenge on fabricating nanostructures large-scale.Electric-driven flexible-roller nanoimprint lithography for nanopatterning the optoelectronic wafer is proposed in this study.The flexible nanoimprint template twining around a roller is continuously released and recovered,controlled by the roller’s simple motion.The electric field applied to the template and substrate provides the driving force.The contact line of the template and the substrate gradually moves with the roller to enable scanning and adapting to the entire warped substrate,under the electric field.In addition,the driving force generated from electric field is applied to the surface of substrate,so that the substrate is free from external pressure.Furthermore,liquid resist completely fills in microcavities on the template by powerful electric field force,to ensure the fidelity of the nanostructures.The proposed nanoimprint technology is validated on the prototype.Finally,nano-grating structures are fabricated on a gallium nitride light-emitting diode chip adopting the solution,achieving polarization of the light source.
基金Project supported by the Scientific and Technological Research Council of Turkey(TUBITAK)via 2209-A Programme。
文摘The warping may become an important factor for the precise transverse vibrations of curved beams.Thus,the first aim of this study is to specify the structural design parameters where the influence of cross-sectional warping becomes great and the first-order shear deformation theory lacks the precision necessary.The outof-plane vibrations of the first-order shear deformation theory are compared with the warping-included vibrations as the curvature and/or thickness increase for symmetric and asymmetric transversely-functionally graded(TFG)curved beams.The second aim is to determine the influence of design parameters on the vibrations.The circular/exact elliptical beams are formed via curved mixed finite elements(MFEs)based on the exact curvature and length.The stress-free conditions are satisfied on three-dimensional(3D)constitutive equations.The variation of functionally graded(FG)material constituents is considered based on the power-law dependence.The cross-sectional warping deformations are defined over a displacement-type FE formulation.The warping-included MFEs(W-MFEs)provide satisfactory 3D structural characteristics with smaller degrees of freedom(DOFs)compared with the brick FEs.The Newmark method is used for the forced vibrations.
基金supported by the National Natural Science Funds of China No.51907129Technology program of Liaoning province No.2021-MS-236。
文摘In this paper,a 20kW vehicle built-in permanent magnet synchronous motor is taken as an example,and a magnetic barrier structure is added to the rotor of the motor to solve the uneven saturation problem of the rotor side magnetic bridge.This structure improves the air-gap flux density waveform of the motor by influencing the internal magnetic flux path of the motor rotor,thus improving the sine of the no-load back EMF waveform of the motor and reducing the torque ripple of the motor.At the same time,Taguchi method is used to optimize the structural parameters of the added magnetic barrier.In order to facilitate the analysis of its uneven saturation phenomenon and improve the optimization effect,a simple equivalent magnetic network(EMN)model considering the uneven saturation of rotor magnetic bridge is established in this paper,and the initial values of optimization factors are selected based on this model.Finally,the no-load back EMF waveform distortion rate,torque ripple and output torque of the optimized motor are compared and analyzed,and the influence of magnetic barrier structure parameters on the electromagnetic performance of the motor is also analyzed.The results show that the optimized motor can not change the output torque of the motor as much as possible on the basis of reducing the waveform distortion rate of no-load back EMF and torque ripple.
文摘In this paper, we delve into the intrinsic nature of mass and gravity, as per the amplitude modulation interpretation of the quantum theory. We explore the idea that the elementary constituent is an electromagnetic configuration that interacts with the quantum field, leading to the emergence of inertia and gravity as a reaction to the exchange with the quantum field. While these two phenomena have a common origin, they are distinct. Our proposal suggests manipulating the connection between the quantum field and the particle using high-frequency electromagnetic fields, thereby making a warp drive possible.
文摘Based on artificial intelligence technology,HawkVision intelligent image pattern/weft straightening machine of Changzhou Hongda Wisdom Technology Co.,Ltd.pioneered the internationally advanced"fullwidth scanning warping and weft straightening technology",which completely solved the problems of textile pattern deformation,weft skew and weft bending that cannot be corrected and recognized by photoelectric weft straightening.