Modulating charge separation and transfer for high-performance photoelectrodes via built-in electric field

Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.

VSe_(2)/V_(2)C heterocatalyst with built-in electric field for efficient lithium-sulfur batteries:Remedies polysulfide shuttle and conversion kinetics

Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.

Bimetallic selenide heterostructure with directional built-in electricfield confined in N-doped carbon nanofibers for superior sodium storage with ultralong lifespan

Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.

Interfacial built-in electric field and crosslinking pathways enabling WS_(2)/Ti_(3)C_(2)T_(x) heterojunction with robust sodium storage at low temperature

Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.

Crealet presents its innovative warp tension solutions at Techtextil 2024

Crealet is the world leader in sophisticated warp feeding technology and tailored solutions.Controlled warp tension stands also for controlled fabric quality.The Swiss firm presents its latest developments for technical textile applications at Techtextil 2024 in Frankfurt,Germany.

MRI去金属伪影WARP序列在关节假体周围感染中的应用

MRI去金属伪影WARP序列在关节假体周围感染中的应用。方法 选取2021年1月-2022年12月本院收治的关节假体周围感染患者62例为观察对象,62例患者均接受常规序列、WARP序列检查。分析62例患者的诊断效果。结果 WARP序列检查最大层面伪影平均面积优于常规序列(P〈0.05);WARP序列检查 图像清晰度、手术指导作用、信噪比优于常规序列(P〈0.05)。结论 MRI去金属伪影WARP序列可以在关节假体周围感染的诊断、评估中起到积极作用。

基于代数结构视角对轻量分组密码WARP的积分分析

在融合了物联网、5G网络等新一代信息技术的工业互联网中,底层终端设备产生海量数据.数据安全传输的需求使得针对资源受限环境所设计的轻量级密码得到广泛应用.对新提出的轻量级密码进行安全性评估对于保障工业互联网的安全运行至关重要.发现了某种特定结构加密算法基于多变量多项式的积分性质,利用该性质得到了更长积分区分器,改进了基于代数结构的分析方法.提出了基于代数结构构造SPN(substitution permutation network)和Feistel-SP结构分组密码积分区分器的框架,并将其应用于SAC 2020会议上提出的轻量分组密码WARP的分析上,构造了2个复杂度为2^(116)的22轮积分区分器,比设计者给出的区分器多了2轮,并且复杂度更低.利用该积分区分器,实现26轮密钥恢复攻击,比设计者给出的密钥恢复攻击增加了5轮,这是目前在单密钥情境下对WARP最好的攻击结果.此外,还对18轮积分区分器进行了实验验证,运算复杂度为2^(32).

Construction of strong built-in electric field in binary metal sulfide heterojunction to propel high-loading lithium-sulfur batteries

The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior electronic conductivity and high electrocatalytic activity,e.g.,heterostructures,is a promising strategy to solve the above obstacles.Herein,a binary metal sulfide MnS-MoS_(2) heterojunction electrocatalyst is first designed for the construction of high-sulfur-loaded and durable Li-S batteries.The MnS-MoS_(2) p-n heterojunction shows a unique structure of MoS_(2) nanosheets decorated with ample MnS nanodots,which contributes to the formation of a strong built-in electric field at the two-phase interface.The MnS-MoS_(2) hybrid host shows strong soluble polysulfide affinity,enhanced electronic conductivity,and exceptional catalytic effect on sulfur reduction.Benefiting from the synergistic effect,the as-derived S/MnS-MoS_(2) cathode delivers a superb rate capability(643 m A h g^(-1)at 6 C)and a durable cyclability(0.048%decay per cycle over 1000 cycles).More impressively,an areal capacity of 9.9 m A h cm^(-2)can be achieved even under an extremely high sulfur loading of 14.7 mg cm^(-2)and a low electrolyte to sulfur ratio of 2.9μL mg^(-1).This work provides an in-depth understanding of the interfacial catalytic effect of binary metal compound heterojunctions on sulfur reaction kinetics.

Optimally arranged TiO_(2)@MoS_(2) heterostructures with effectively induced built-in electric field for high-performance lithium-sulfur batteries

To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals sulfides.However,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed rationally.Herein,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox kinetics.Owing to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first time.The superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.

Electric-driven flexible-roller nanoimprint lithography on the stress-sensitive warped wafer

Surface nanopatterning of semiconductor optoelectronic devices is a powerful way to improve their quality and performance.However,photoelectric devices’inherent stress sensitivity and inevitable warpage pose a huge challenge on fabricating nanostructures large-scale.Electric-driven flexible-roller nanoimprint lithography for nanopatterning the optoelectronic wafer is proposed in this study.The flexible nanoimprint template twining around a roller is continuously released and recovered,controlled by the roller’s simple motion.The electric field applied to the template and substrate provides the driving force.The contact line of the template and the substrate gradually moves with the roller to enable scanning and adapting to the entire warped substrate,under the electric field.In addition,the driving force generated from electric field is applied to the surface of substrate,so that the substrate is free from external pressure.Furthermore,liquid resist completely fills in microcavities on the template by powerful electric field force,to ensure the fidelity of the nanostructures.The proposed nanoimprint technology is validated on the prototype.Finally,nano-grating structures are fabricated on a gallium nitride light-emitting diode chip adopting the solution,achieving polarization of the light source.

WARP序列在腰椎金属植入物术后去金属伪影的应用

目的探讨去金属伪影序列(WARP)在腰椎金属植入物术后磁共振成像的临床价值。方法比较1.5T MRI syngo扫描仪上WARP序列和常规快速自旋回波(TSE)序列在纳入研究标准的39例腰椎金属植入物术后患者的金属植入物伪影面积、各序列图像质量评分的差异。结果与常规TSE序列相比,WARP序列的金属伪影的面积减少28%~34%,图像质量评分更高;同序列评分中,T_(1)加权像(T_(1)WI)>T_(2)加权象(T_(2)WI)>短时翻转恢复序列(STIR),差异均具有统计学意义(P<0.05)。结论WARP序列可有效降低金属植入物的伪影,更清晰显示金属植入物周围解剖细节,有助于腰椎金属植入物术后患者的随访。

Cross-sectional warping and precision of the first-order shear deformation theory for vibrations of transversely functionally graded curved beams

The warping may become an important factor for the precise transverse vibrations of curved beams.Thus,the first aim of this study is to specify the structural design parameters where the influence of cross-sectional warping becomes great and the first-order shear deformation theory lacks the precision necessary.The outof-plane vibrations of the first-order shear deformation theory are compared with the warping-included vibrations as the curvature and/or thickness increase for symmetric and asymmetric transversely-functionally graded(TFG)curved beams.The second aim is to determine the influence of design parameters on the vibrations.The circular/exact elliptical beams are formed via curved mixed finite elements(MFEs)based on the exact curvature and length.The stress-free conditions are satisfied on three-dimensional(3D)constitutive equations.The variation of functionally graded(FG)material constituents is considered based on the power-law dependence.The cross-sectional warping deformations are defined over a displacement-type FE formulation.The warping-included MFEs(W-MFEs)provide satisfactory 3D structural characteristics with smaller degrees of freedom(DOFs)compared with the brick FEs.The Newmark method is used for the forced vibrations.

Design of Rotor Magnetic Barrier Structure of Built-in Permanent Magnet Motor Based on Taguchi Method

In this paper,a 20kW vehicle built-in permanent magnet synchronous motor is taken as an example,and a magnetic barrier structure is added to the rotor of the motor to solve the uneven saturation problem of the rotor side magnetic bridge.This structure improves the air-gap flux density waveform of the motor by influencing the internal magnetic flux path of the motor rotor,thus improving the sine of the no-load back EMF waveform of the motor and reducing the torque ripple of the motor.At the same time,Taguchi method is used to optimize the structural parameters of the added magnetic barrier.In order to facilitate the analysis of its uneven saturation phenomenon and improve the optimization effect,a simple equivalent magnetic network(EMN)model considering the uneven saturation of rotor magnetic bridge is established in this paper,and the initial values of optimization factors are selected based on this model.Finally,the no-load back EMF waveform distortion rate,torque ripple and output torque of the optimized motor are compared and analyzed,and the influence of magnetic barrier structure parameters on the electromagnetic performance of the motor is also analyzed.The results show that the optimized motor can not change the output torque of the motor as much as possible on the basis of reducing the waveform distortion rate of no-load back EMF and torque ripple.

How to Achieve a Warp Drive

In this paper, we delve into the intrinsic nature of mass and gravity, as per the amplitude modulation interpretation of the quantum theory. We explore the idea that the elementary constituent is an electromagnetic configuration that interacts with the quantum field, leading to the emergence of inertia and gravity as a reaction to the exchange with the quantum field. While these two phenomena have a common origin, they are distinct. Our proposal suggests manipulating the connection between the quantum field and the particle using high-frequency electromagnetic fields, thereby making a warp drive possible.

Changzhou Hongda:The first internationally advanced full-width scanning and warping technology

Based on artificial intelligence technology,HawkVision intelligent image pattern/weft straightening machine of Changzhou Hongda Wisdom Technology Co.,Ltd.pioneered the internationally advanced"fullwidth scanning warping and weft straightening technology",which completely solved the problems of textile pattern deformation,weft skew and weft bending that cannot be corrected and recognized by photoelectric weft straightening.

考虑翘曲应力的半潜平台扭转极限强度计算方法研究

半潜平台由于结构和受力复杂,目前主要采用非线性有限元整体模型计算其扭转极限承载力,存在建模和计算时间较长、精度较差和不易收敛等问题。一方面进行半潜平台的整体有限元模型的简化研究,提高其计算效率和收敛性;另一方面基于薄壁杆件理论,将该半潜平台截面简化为单壁室截面计算其翘曲应力,提出了基于一跨模型且考虑翘曲应力影响的半潜平台约束扭转极限强度计算的简化增量迭代方法,并编制了相应的计算程序。计算结果表明,所提简化增量迭代方法计算精度较高,能很好地反应翘曲应力对半潜平台约束扭转极限强度的影响,大幅减少了计算约束扭转极限强度的时间,可用于半潜平台的设计。

基于TCN和迁移学习的混凝土坝变形预测方法

混凝土坝变形测点数据丢失或者新增测点测量时间太短都会导致这部分测点的数据量不足,使得变形预测精度受到影响。为了提高这些小数据量测点的变形预测精度,提出了将时域卷积网络(TCN)与迁移学习相结合的变形预测方法。以数据量充足的测点为源域,以缺少数据的测点为目标域,将在源域上训练好的TCN模型的结构和参数迁移到目标域模型中,固定其中的冻结层参数,利用目标域中的数据对目标域模型可调层参数进行调整。同时,采用动态时间规整选择与目标域数据序列相似度最高的监测数据作为最佳源域数据,提升迁移学习效果。工程实例分析表明:迁移学习后的目标域模型的均方根误差和平均绝对误差与利用足量数据训练的TCN模型的预测误差相比,差异仅分别为1.73%和8.09%,小数据量情况下TCN预测模型的精度得到了提高。

基于PCA-ShapeDTW-QWGRU的分布式光伏集群短期功率预测

针对分布式光伏短期功率预测建立基于主成分分析、改进的动态时间规整算法与量子加权门控循环单元(PCAShapeDTW-QWGRU)的集群功率预测模型。针对集群划分不够精细、光伏电站数据蕴含的信息难以捕捉的问题,提出基于主成分分析结合密度聚类算法(PCA-OPTICS)的集群划分方法;针对目前选取代表电站与集群相似性较低的问题,提出基于改进的动态时间规整算法(ShapeDTW)的代表电站的选取方法,利用ShapeDTW度量相似性距离,选取最小值作为代表电站,并利用基于均方根传播梯度下降法优化的量子加权门控循环单元(RMSprop-QWGRU)模型进行预测;为了解决代表电站与集群功率的变换系数转换差异较大的问题,采用实时变换系数对代表电站进行集群功率值预测计算。实验结果表明,所提方法能有效提升光伏集群功率预测的精度。

“新农科”背景下“卓越农林经管人才”实践能力经纬耦合模块化培养模式探究

教育部提出的“新农科”建设和“卓越农林人才教育培养计划”均对新时期全国农林高校人才培养提出了新的要求和标准。在提出农林经济管理专业实践能力培养中存在的主要问题的基础上,根据以往实践教学经验,构建了微观、中观与宏观有机结合,横向与纵向经纬耦合的多层面设计、多主体参与的实践能力培养架构,最后提出了“卓越农林经管人才”实践能力培养模式的具体实施措施。

基于 Moldflow 的汽车中控台框架翘曲变形分析及优化

以某汽车中控台框架为研究对象,测量试模样品发现其翘曲变形量超过了装配要求。通过Moldflow软件模拟了该塑件实际的注塑过程,翘曲变形量的模拟值与实测平均值的最大误差为5.98%,发现该塑件翘曲变形的主要因素为冷却不均和收缩不均。本文在原物料中添加质量分数为25%的玻璃纤维以及优化工艺参数后,翘曲变形量的模拟值与初始方案相比降低了86.22%。试模验证表明,优化后的翘曲变形量模拟值与实测平均值的最大误差为4.35%,证明了Moldflow软件模拟分析的准确性。试模后各检测点的最大翘曲变形量降到了1.6 mm以下,较优化之前降低了80%以上,为类似大型复杂注塑件的翘曲变形分析及优化提供了思路。