The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on...The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on the preparation of a directional vertical array of micro-porous transport networks on LTO electrodes using a femtosecond laser processing strategy,enabling directional ion rapid transport and achieving good electrochemical performance in thick film electrodes.Various three-dimensional(3D)vertically aligned micro-pore networks are innovatively designed,and the structure,kinetics characteristics,and electrochemical performance of the prepared ion transport channels are analyzed and discussed by multiple characterization and testing methods.Furthermore,the rational mechanisms of electrode performance improvement are studied experimentally and simulated from two aspects of structural mechanics and transmission kinetics.The ion diffusion coefficient,rate performance at 60 C,and electrode interface area of the laser-optimized 60-15%micro-porous transport network electrodes increase by 25.2 times,2.2 times,and 2.15 times,respectively than those of untreated electrodes.Therefore,the preparation of 3D micro-porous transport networks by femtosecond laser on ultra-thick electrodes is a feasible way to develop high-energy batteries.In addition,the unique micro-porous transport network structure can be widely extended to design and explore other high-performance energy materials.展开更多
Non-penetration laser welding of lap joints in austenitic stainless steel sheets is commonly preferred in fields where the surface quality is of utmost importance.However,the application of non-penetration welded aust...Non-penetration laser welding of lap joints in austenitic stainless steel sheets is commonly preferred in fields where the surface quality is of utmost importance.However,the application of non-penetration welded austenitic stainless steel parts is limited owing to the micro bulging distortion that occurs on the back surface of the partial penetration side.In this paper,non-penetration lap laser welding experiments,were conducted on galvanized and SUS304 austenitic stainless steel plates using a fiber laser,to investigate the mechanism of bulging distortion.A comparative experiment of DC01 galvanized steel-Q235 carbon steel lap laser welding was carried out,and the deflection and distortion profile of partially penetrated side of the sheets were measured using a noncontact laser interferometer.In addition,the cold-rolled SUS304 was subjected to heat holding at different temperatures and water quenching after bending to characterize its microstructure under tensile and compressive stress.The results show that,during the heating stage of the thermal cycle of laser lap welding,the partial penetration side of the SUS304 steel sheet generates compressive stress,which extrudes the material in the heat-affected zone to the outside of the back of the SUS304 steel sheet,thereby forming a bulge.The findings of these experiments can be of great value for controlling the distortion of the partial penetrated side of austenitic stainless steel sheet during laser non-penetration lap welding.展开更多
Based on scanning electron microscopy and nitrogen adsorption experiment at low temperature, the pore types and structures of the Longmaxi Formation shale in the Dianqianbei area, SW China were analyzed, and a molecul...Based on scanning electron microscopy and nitrogen adsorption experiment at low temperature, the pore types and structures of the Longmaxi Formation shale in the Dianqianbei area, SW China were analyzed, and a molecular model was built. According to mathematical statistics, the validation of the model was solved by converting it into a mathematical formula. It is found by SEM that the pores in clay mineral layers and organic pores occupy most of the pores in shale; the nitrogen adsorption experiment at low temperature reveals that groove pores formed by flaky particles and micro-pores are the main types of pores, and the results of the two are in good agreement. A molecular model was established by illite and graphene molecular structures. Moreover, based on the fractal theory and the Frenkel-Halsey-Hill formula, a modified Frenkel-Halsey-Hill formula was proposed. The reliability of the molecular model was verified to some extent by obtaining parameters such as the fractal dimension, replacement rate and fractal coefficients of correction, and mathematical calculation. This study provides the theoretical basis for quantitative study of shale reservoirs.展开更多
The DD33 superalloy with ultra-low nitrogen (N) content was prepared by vacuum induced melting, and the effect of N on micro-pores in the DD33 single crystal nickel-base superalloy during solidification and homogeniza...The DD33 superalloy with ultra-low nitrogen (N) content was prepared by vacuum induced melting, and the effect of N on micro-pores in the DD33 single crystal nickel-base superalloy during solidification and homogenization was investigated by in-situ X-ray computed tomography (XCT). Results indicate that the volume fraction of micro-pores, including shrinkage pores and gas pores, increases from 0.08% to 0.11% with increasing N content from 5 ppm to 45 ppm during solidification. Correspondingly, the level of micro-pores in the sample with high N content is higher than that in the sample with low N content during homogenization at 1,330 °C for different time periods. However, the evolution behaviors of gas pores is different from that of shrinkage pores during solidification and homogenization. The number of gas pores is obviously larger in the high N sample during solidification, while the number of shrinkage pores and gas pores is almost the same in both samples after 1 h homogenization. Quantitative results show that the annihilation of micro-pores is associated with bubble diffusion, while the growth behavior of micro-pores during further exposure is dominated by Kirkendall-Frenkel effect.展开更多
In this paper we explore the formation of bars and present the bulge and bar properties and their correlations for a sample of lenticular barred(SB0)and lenticular unbarred(S0)galaxies in the central region of the Com...In this paper we explore the formation of bars and present the bulge and bar properties and their correlations for a sample of lenticular barred(SB0)and lenticular unbarred(S0)galaxies in the central region of the Coma Cluster using HST/ACS data.In our sample,we identified bar features using the luminosity profile decomposition software GALFIT.We classified the bulges based on Sérsic index and Kormendy relation.We found that the average mass of the bulge in SB0 galaxies is 1.48×10^(10)M☉whereas the average mass of the bulge in S0 galaxies is 4.3×10^(10)M☉.We observe that SB0 galaxies show lower bulge concentration,low mass and also smaller B/T values compared to S0 galaxies.Using the Kormendy relation,we found that among the lenticular barred galaxies,82%have classical bulges and 18%have pseudo bulges.These classical bulges have low masses compared to the classical bulges of unbarred galaxies.S0,galaxies with massive classical bulges do not host bars.We also found that for all SB0s the bulge effective radius is less than the bar effective radius.SB0 galaxies with classical bulges suggest that the bar may have formed by mergers.展开更多
为研究辊形电磁调控技术(roll profile electromagnetic control technology,RPECT)的热力胀形行为,采用有限元方法分析了不同电流密度及频率下综合辊凸度、热力贡献辊凸度以及力凸度占比等随接触区热量的变化规律,探究了接触区热量与...为研究辊形电磁调控技术(roll profile electromagnetic control technology,RPECT)的热力胀形行为,采用有限元方法分析了不同电流密度及频率下综合辊凸度、热力贡献辊凸度以及力凸度占比等随接触区热量的变化规律,探究了接触区热量与热力胀形能力的映射关系及其成立条件.结果表明,在接触区热量的中低取值范围内,同一接触区热量所对应的热力调控能力不会受磁参数影响,故提出将接触区热量作为输入参数与调控能力之间桥梁的RPECT高效控制策略.该策略通过提升磁参数来快速达到接触区的目标温升效果,进而获取目标调控能力.以20μm的辊缝凸度需求为例,经原始与高效控制策略间的对比发现,新策略的调控时间可有效地缩短至原调控时间的19.57%.展开更多
基金supported by the National Natural Science Foundation of China(52275463,51772240)the National Key Research and Development Program of China(2021YFB3302000)the Key Research and Development Projects of Shaanxi Province,China(2018ZDXM-GY-135)。
文摘The development of energy storage devices with high energy density relies heavily on thick film electrodes,but it is challenging due to the limited ion transport kinetics inherent in thick electrodes.Here,we report on the preparation of a directional vertical array of micro-porous transport networks on LTO electrodes using a femtosecond laser processing strategy,enabling directional ion rapid transport and achieving good electrochemical performance in thick film electrodes.Various three-dimensional(3D)vertically aligned micro-pore networks are innovatively designed,and the structure,kinetics characteristics,and electrochemical performance of the prepared ion transport channels are analyzed and discussed by multiple characterization and testing methods.Furthermore,the rational mechanisms of electrode performance improvement are studied experimentally and simulated from two aspects of structural mechanics and transmission kinetics.The ion diffusion coefficient,rate performance at 60 C,and electrode interface area of the laser-optimized 60-15%micro-porous transport network electrodes increase by 25.2 times,2.2 times,and 2.15 times,respectively than those of untreated electrodes.Therefore,the preparation of 3D micro-porous transport networks by femtosecond laser on ultra-thick electrodes is a feasible way to develop high-energy batteries.In addition,the unique micro-porous transport network structure can be widely extended to design and explore other high-performance energy materials.
文摘Non-penetration laser welding of lap joints in austenitic stainless steel sheets is commonly preferred in fields where the surface quality is of utmost importance.However,the application of non-penetration welded austenitic stainless steel parts is limited owing to the micro bulging distortion that occurs on the back surface of the partial penetration side.In this paper,non-penetration lap laser welding experiments,were conducted on galvanized and SUS304 austenitic stainless steel plates using a fiber laser,to investigate the mechanism of bulging distortion.A comparative experiment of DC01 galvanized steel-Q235 carbon steel lap laser welding was carried out,and the deflection and distortion profile of partially penetrated side of the sheets were measured using a noncontact laser interferometer.In addition,the cold-rolled SUS304 was subjected to heat holding at different temperatures and water quenching after bending to characterize its microstructure under tensile and compressive stress.The results show that,during the heating stage of the thermal cycle of laser lap welding,the partial penetration side of the SUS304 steel sheet generates compressive stress,which extrudes the material in the heat-affected zone to the outside of the back of the SUS304 steel sheet,thereby forming a bulge.The findings of these experiments can be of great value for controlling the distortion of the partial penetrated side of austenitic stainless steel sheet during laser non-penetration lap welding.
基金Supported by the China National Science and Technology Major Project(2017ZX05063002-009)the National Natural Science Foundation of China(41772150)
文摘Based on scanning electron microscopy and nitrogen adsorption experiment at low temperature, the pore types and structures of the Longmaxi Formation shale in the Dianqianbei area, SW China were analyzed, and a molecular model was built. According to mathematical statistics, the validation of the model was solved by converting it into a mathematical formula. It is found by SEM that the pores in clay mineral layers and organic pores occupy most of the pores in shale; the nitrogen adsorption experiment at low temperature reveals that groove pores formed by flaky particles and micro-pores are the main types of pores, and the results of the two are in good agreement. A molecular model was established by illite and graphene molecular structures. Moreover, based on the fractal theory and the Frenkel-Halsey-Hill formula, a modified Frenkel-Halsey-Hill formula was proposed. The reliability of the molecular model was verified to some extent by obtaining parameters such as the fractal dimension, replacement rate and fractal coefficients of correction, and mathematical calculation. This study provides the theoretical basis for quantitative study of shale reservoirs.
基金This work was financially supported by the Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030001)the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2016ZT06G025).
文摘The DD33 superalloy with ultra-low nitrogen (N) content was prepared by vacuum induced melting, and the effect of N on micro-pores in the DD33 single crystal nickel-base superalloy during solidification and homogenization was investigated by in-situ X-ray computed tomography (XCT). Results indicate that the volume fraction of micro-pores, including shrinkage pores and gas pores, increases from 0.08% to 0.11% with increasing N content from 5 ppm to 45 ppm during solidification. Correspondingly, the level of micro-pores in the sample with high N content is higher than that in the sample with low N content during homogenization at 1,330 °C for different time periods. However, the evolution behaviors of gas pores is different from that of shrinkage pores during solidification and homogenization. The number of gas pores is obviously larger in the high N sample during solidification, while the number of shrinkage pores and gas pores is almost the same in both samples after 1 h homogenization. Quantitative results show that the annihilation of micro-pores is associated with bubble diffusion, while the growth behavior of micro-pores during further exposure is dominated by Kirkendall-Frenkel effect.
文摘In this paper we explore the formation of bars and present the bulge and bar properties and their correlations for a sample of lenticular barred(SB0)and lenticular unbarred(S0)galaxies in the central region of the Coma Cluster using HST/ACS data.In our sample,we identified bar features using the luminosity profile decomposition software GALFIT.We classified the bulges based on Sérsic index and Kormendy relation.We found that the average mass of the bulge in SB0 galaxies is 1.48×10^(10)M☉whereas the average mass of the bulge in S0 galaxies is 4.3×10^(10)M☉.We observe that SB0 galaxies show lower bulge concentration,low mass and also smaller B/T values compared to S0 galaxies.Using the Kormendy relation,we found that among the lenticular barred galaxies,82%have classical bulges and 18%have pseudo bulges.These classical bulges have low masses compared to the classical bulges of unbarred galaxies.S0,galaxies with massive classical bulges do not host bars.We also found that for all SB0s the bulge effective radius is less than the bar effective radius.SB0 galaxies with classical bulges suggest that the bar may have formed by mergers.
基金Supported jointly by the Internal Medicine Research Program of Tianjin Seismological Bureau (Zd202108 and Zd202204)the Seismological Science and Technology Spark Program (XH20003Y)+3 种基金the Three Combination Program of Monitoring,Forecasting and Scientific Research of China Seismological Bureau (3JH-202201040)the Scientific Research and Development Program of Hebei University of Economics and Trade (2021ZD06)the Higher Education Teaching Reform Research and Practice Program of Hebei Province (2021GJJG175)the Teaching Research Program of Hebei University of Economics and Trade (2021JYQ05)。
基金supported by the National Key Research and Development Program of China(No.2018YFA0707300)the National Natural Science Foundation of China(Nos.51901151,51905372,52275362,52171122)China Postdoctoral Science Foundation(Nos.2020M680918,2021T140503)。
基金supported by the National Natural Science Foundation of China (No. 51505323)the Applied Basic Research Program of Shanxi Province,China (Nos. 20210302123117, 20210302124658)。
文摘为研究辊形电磁调控技术(roll profile electromagnetic control technology,RPECT)的热力胀形行为,采用有限元方法分析了不同电流密度及频率下综合辊凸度、热力贡献辊凸度以及力凸度占比等随接触区热量的变化规律,探究了接触区热量与热力胀形能力的映射关系及其成立条件.结果表明,在接触区热量的中低取值范围内,同一接触区热量所对应的热力调控能力不会受磁参数影响,故提出将接触区热量作为输入参数与调控能力之间桥梁的RPECT高效控制策略.该策略通过提升磁参数来快速达到接触区的目标温升效果,进而获取目标调控能力.以20μm的辊缝凸度需求为例,经原始与高效控制策略间的对比发现,新策略的调控时间可有效地缩短至原调控时间的19.57%.
