Renewable Diesel Fuel from Processing of Vegetable Oil in Hydrotreatment Units: Theoretical Compliance with European Directive 2009/28/EC and Ongoing Projects in Spain

Oil hydrotreating units in refineries are aimed at reducing the sulfur content of fuels to accomplish standard par-ticular specifications. However, this process is currently one of the best available technologies to produce biofuels from vegetable oil in a refinery. Vegetable oils can be processed or co-processed in these units if several adaptations are performed, so some properties could be improved in comparison with conventional fuel such as density and cetane number. This study highlights the theoretical greenhouse gases (GHG) emissions (using a life cycle assessment–LCA-approach) of a hydrotreated vegetable oil (HVO) from bibliographical data. Results were compared with other biofuel production processes, such as those obtained by transesterification of vegetable oil (FAME, fatty acid methyl ester). It has also been included the comparison with conventional fossil diesel as a benchmark in order to assess the theoretical compliance with GHG savings proposed in European Directive 2009/28/EC. Finally, ongoing projects and future perspectives in Spain are mentioned.

Microscopic and macroscopic atomization characteristics of a pressure-swirl atomizer, injecting a viscous fuel oil

Combustion of heavy fuels is one of the main sources of greenhouse gases, particulate emissions, ashes, NOxand SOx. Gasification is an advanced and environmentally friendly process that generates combustible and clean gas products such as hydrogen. Some entrained flow gasifiers operate with Heavy Fuel Oil(HFO) feedstock. In this application, HFO atomization is very important in determining the performance and efficiency of the gasifiers.The atomization characteristics of HFO(Mazut) discharging from a pressure-swirl atomizer(PSA) are studied for different pressures difference(Δp) and temperatures in the atmospheric ambient. The investigated parameters include atomizer mass flow rate( _m), discharge coefficient(CD), spray cone angle(θ), breakup length(Lb), the unstable wavelength of undulations on the liquid sheet(λs), global and local SMD(sauter mean diameter) and size distribution of droplets. The characteristics of Mazut sheet breakup are deduced from the shadowgraph technique. The experiments on Mazut film breakup were compared with the predictions obtained from the liquid film breakup model. Validity of the theory for predicting maximum unstable wavelength was investigated for HFO(as a highly viscous liquid). A modification on the formulation of maximum unstable wavelength was presented for HFO. SMD decreases by getting far from the atomizer. The measurement for SMD and θ were compared with the available correlations. The comparisons of the available correlations with the measurements of SMD andθ show a good agreement for Ballester and Varde correlations, respectively. The results show that the experimental sizing data could be presented by Rosin-Rammler distributions very well at different pressure difference and temperatures.

Removal of Hexavalent Chromium from Aqueous Solution by Adsorption on Palm Oil Fuel Ash (POFA)

This study investigated the removal of hexavalent chromium, Cr(VI) from aqueous solution by adsorption using palm oil fuel ash (POFA), an agricultural waste from the palm oil industry. POFA adsorbent was characterized by X-ray diffraction (XRD) analysis. Batch adsorption study revealed that the optimum conditions for the removal were as follows: pH 2, adsorbent dosage 80 g/L and contact time of 6 min, which resulted in 92% removal and 0.464 mg/g maximum adsorption capacity. Adsorption isotherm and kinetic studies showed that Freundlich isotherm and pseudo-second-order kinetic models fitted best to the experimental data. Column adsorption study at 5 mL/min of flow rate showed that 90% removal was obtained at 2 min of contact time which represented its breakthrough point. The column reached saturation at 30 min and the maximum column adsorption capacity recorded was 0.412 mg/g. The column adsorption behavior showed good fit with both Thomas and Yoon-Nelson kinetic models. These findings suggested that the utilization of POFA as a low-cost adsorbent to remove Cr(VI) from wastewater, either in batch or fixed bed adsorption system is not only effective, but concurrently will help to reduce wastes from the palm oil industry.

Biodiesel from Palm Vegetable Oil

Energy obtained from a variety of non-renewable sources is considered unsustainable. Various fossil fuels, such as petroleum, coal, and natural gas, are among these sources. The combustion of fossil fuels resulted in the generation of greenhouse gases, which increased the amount of carbon dioxide in the atmosphere. Global warming and ozone layer degradation are the negative consequences. In a country like India, where consumable oils are still imported, it is sense to look at the possibility of using such unpalatable oils in CI engines that aren’t often utilized as cooking oil. Palm oil is a vegetable oil obtained from the monocarp of the oil palm’s crop. The main goal is to provide a low-cost, high-performance alternative to diesel. The possibility of palm oil as a realistic, modest, and effective hotspot for the generation of biodiesel is investigated in this research. The article is focused on the comparison of palm oil and diesel in terms of characteristics.

Conversion of lignin oil and hemicellulose derivative into high-density jet fuel

Synthesizing high-density fuel from lignocellulose can not only achieve green and low-carbon development,but also expand the feedstock source of hydrocarbon fuel.Here,we reported a route of producing high-density fuel from lignin oil and hemicellulose derivative cyclopentanol through alkylation and hydrodeoxygenation,HY with SiO_(2)/Al_(2)O_(3) molar ratio of 5.3 was screened as the alkylation catalyst in the reaction of model phenolic compounds and mixtures,and the reaction conditions were optimized to achieve conversion of phenolic compounds higher than 87%and selectivity of bicyclic and tricyclic products higher than 99%.Then two phenolic pools simulating the composition of two typic lignin oils were studied to validate the alkylation and analyze the competition mechanism of phenolic compounds in mixture system.Finally,real lignin oil from depolymerized of beech powder was tested,and notably80%of phenolic monomers in the oil were converted into fuel precursor.After hydrodeoxygenation,the alkylated product was converted to fuel blend with a density of 0.91 g/mL at 20℃and a freezing point lower than-60℃,very promising as high density fuel.This work provides a facile and energyefficient way of synthesizing high-performance jet fuel directly from lignocellulosic derivatives,which decreases processing energy consumption and improve the utilization rate of feedstock.

Evaluation of a Pulse Width Modulated Bypass Nozzle for the Development of a Variable Load Residential Oil Burner

Due to the need for energy conservation in buildings and the simultaneous benefit of cost savings, the development of a low firing rate load modulating residential oil burner is very desirable. One of the two main requirements of such a burner is the development of a burner nozzle that is able to maintain the particle size distribution of the fuel spray in the desirable (small) size range for efficient and stable combustion. The other being the ability to vary the air flow rate and air distribution around the fuel nozzle in the burner for optimal combustion at the current fuel firing rate. In this paper, which deals with the first requirement, we show that by using pulse width modulation in the bypass channel of a commercial off-the-shelf bypass nozzle, this objective can be met. Here we present results of spray patterns and particle size distribution for a range of fuel firing rates. The results show that a desirable fuel spray pattern can be maintained over a fuel firing rate turndown ratio (Maximum Fuel Flow Rate/Minimum Fuel Flow Rate) of 3.7. Thus here we successfully demonstrate the ability to electronically vary the fuel firing rate by more than a factor of 3 while simultaneously maintaining good atomization.

Biodiesel from Plant Resources—Sustainable Solution to Ever Increasing Fuel Oil Demands

The demand for fuel oil is ever increasing with the advance of the modern world, whereas worldwide reserves of fossil oils are diminishing at an alarming rate. However, there exist large stockpiles of vegetable oil feedstocks that could be exploited to produce fuel oil, called biodiesel with the aid of biotechnology. Initially, the biodiesel produced from vegetable oil did not attract much attention because of its high cost. However, the recent increase in petroleum prices and the uncertainties of petroleum availability led to the renewal of interest in biodiesel production from such sustainable resources (i.e., vegetable oil feedstocks). This research focuses on the production of biodiesel from plant resources, and further investigates the influences of key process parameters, such as the molar ratio of methanol to oil, catalyst concentration, reaction temperature, reaction period and stirring speed on the biodiesel yield. This investigation is to determine the optimum process parameters for maximum biodiesel yield. The biodiesel was produced from three vegetable oil feedstocks, namely palm, soybean and sunflower oil via a transesterification process. It was observed that all the process parameters significantly influenced the biodiesel yield. The maximum biodiesel yields for palm, sunflower and soybean oil feedstocks were found to be 87.5%, 83.6% and 80.2%, respectively at optimum condition. The results suggest that through proper optimization of the process parameters the biodiesel yields could be maximized. In conclusion, the production of biodiesel from plant resources would be regarded as a sustainable solution to the ever increasing demand of fuel oils.

Chemical and Thermal Characterization of Cement Mortar Containing Ground Palm Oil Fuel Ash as a Partial Cement Replacement

This study investigates the influence of using ground palm oil fuel ash(G-POFA) from 10%-30% as cement replacement(by weight) on the cement mortar's pH under various curing conditions. These findings were supplemented by thermal gravimetric analysis(TGA). Moreover, the resistance of G-POFA blended cement mortars to water absorption and sorptivity was determined. Further, the k-value test was carried out to explain the pozzolanic and filler behavior of G-POFA and to support the results obtained from TGA. It was found that there was no significant impact of several curing conditions on the pH of mortars. The mortar with 10% G-POFA in replacement of cement(G-POFA-10) exhibited the best resistance against water absorption and sorptivity.

Thermomechanical and Hydrous Effect of Heavy Fuel Oil in a Building Material Based on Silty Clayey Soil

This study focuses on the use of heavy fuel oil in construction in Burkina Faso.Mixed with silty and/or clay soil,it is used as a coating to reinforce the walls of raw soil constructions which are very sensitive to water.The interest of this paper is to shed light on the thermomechanical and above all water effects of heavy fuel oil on a sample of silty clayey soil.To achieve this,we used heavy fuel oil added in different proportions to silty clayey soil,to make sample of bricks on which tests were carried out.At the end of the experimental tests carried out on materials made(bricks)with our soil sample,it appears that heavy fuel oil moderately reduces the mechanical resistance of bricks and slightly increases thermal diffusion through them.On the contrary,we note a very good water resistance of the bricks thanks to the heavy fuel oil,in particular their water absorption by capillarity.This confirms that the mixture of heavy fuel oil and a silty-clayey soil used as a coating makes it possible to prevent the infiltration of water into the walls of raw soil constructions.However,its use as a construction material does not guarantee very good mechanical resistance,and slightly increases thermal diffusion.

Oil and Gas Policies in the World’s Major Countries

Revolutionary adjustments were made to the global energy structure in 2017.For the first time,OPEC cooperated with non-OPEC countries to reach an agreement on production curtailment in order to stabilize the oil and gas market.On the one hand,host countries have introduced various fiscal and tax incentive policies to attract investment in the oil and gas industry;on the other,the lack of fiscal revenue has been made up for and the low-carbon environmental protection policy supported by imposing a value-added tax and environmental protection tax.Major consumers have introduced a timetable for the sales prohibition of fuel vehicles and supported the development of new energy vehicles with fiscal and taxation policies.However,from the perspective of the full life cycle,the promotion of electric vehicles is only conducive to partially improving the environment and is not the optimal choice for national energy structure optimization.Electric vehicles will have real significance for environmental protection only after clean electric power is solved.As such,implementing the sales prohibition of fuel vehicles with administrative power goes against market discipline.

The Effect of Reaction Temperature, Catalyst Concentration and Alcohol Ratio in the Production of Biodiesel from Raw and Purified Castor Oil

In this study, a homogeneous alkaline catalyst was used in the production of biodiesel from raw and refined castor oil feedstock. The effect of potassium hydroxide (KOH) as a catalyst between the two feedstocks, raw and refined castor oil was compared. The transesterification technique was utilized in this study, aiming to investigate the effect of different parameters, which include the reaction temperature, methanol-to-oil mole ratio, and catalyst concentration at a constant period of 90 minutes. The result revealed the performance of the KOH catalyst on raw castor oil yielded 98.49% FAME, which was higher than the refined castor oil which yielded 97.9% FAME. The optimal conditions obtained from refined castor oil were applied to raw castor oil because of the same properties. The fuel quality of castor oil and produced biodiesel were tested for physicochemical properties.

Improving Winter Traction and Fuel Economy of Car Tires Using Naphthenic Tire Oils

Naphthenic tire oils were used in winter tire tread compounding. Properties of compounds were compared with similar compounds made of other safe tire oils. Retreaded passenger car winter tires were prepared using the compounds. Traction and rolling resistance of the tires were determined in different weather conditions.It was shown that naphthenie oils may lead to improvement of winter traction and rolling resistance without compromising other tire properties.

Numerical simulation of heavy fuel oil atomization using a pulsed pressure-swirl injector

It is known that increasing the injection pressure reduces the breakup length and the droplet size.Adding pulses,on the other hand,helps to atomize the liquid into finer droplets,similar to airassisted injectors but without altering the airtofuel concentration.To further reduce the droplet size and breakup length,a novel injector type,called''Pulsed PressureSwirl"(PPS),is introduced in this work,which is a combination of pressureswirl and ultrasonic pulsed injectors.A pressureswirl atomizer was designed and fabricated specifically for Mazut HFO(Heavy Fuel Oil).The droplet formation process and droplet size distribution have been studied experimentally(by shadowgraphy high speed imaging)and numerically(with the opensource VolumeofFluid code Gerris).Changing liquid injection pressure effect on the spray angle and film thickness has been quantified.These simulations have been used to study the primary breakup process and quantify the droplet size distributions,using different injection pulse frequencies and pressures.The numerical results have revealed that the new injector concept successfully produces finer droplets and results in a decrease in the breakup length,especially when applying high pulse frequencies,with no significant changes in the spray angle.

增压条件下活塞的动压润滑分析

根据流体动力润滑理论与活塞动力学方程建立的分析模型,依据发动机燃气压力的变化,计算了增压前后的活塞裙部最小润滑油膜厚度和摩擦力。结果表明,发动机增压后,主推力边和次推力边的最小润滑油膜厚度分别变小,裙部的摩擦力和摩擦功耗增大。因增压后活塞润滑能力降低,并且摩擦功耗增加,会对整机的可靠性产生影响,这些都应当在增压改进设计时予以重视。

Application of Non-Fuel Power Generation Technology in Steel Industry

Through continuous equipment technology transformation and full utilization of Ma Steel's abundant gas,the boiler no longer relies on fuel oil for stable combustion during boiler startup,sliding parameter shutdown,and RB,thus achieving safe and stable operation of the boiler under any abnormal working conditions,and achieving good economic and social benefits.

A STUDY ON' SYNCHRONOUS-HI GH-DERIVATIVE SPECTFLUOR—THE DI FFERENTI ATI ON OF CRUDE OIL AND FUEL OIL POLLUTION

A method of synchronous-high-derivative spectfluor for identification of crude oil and fuel oil pollution is studied. The best operation conditions for the 2nd and 4th deriv, are set. To differentiate oil-spill at river and sea, this method is rapid and simple, and the spectra have high resolution power as 'fingerprint'.

Engine performance and combustion characteristics of a direct injection compression ignition engine fueled waste cooking oil synthetic diesel

Biodiesels produced from various feedstocks have been considered as alternative fuels used in internal combustion engines without major modifications.This research focuses on producing biodiesel from waste cooking oil(WCOSD)by the catalytic cracking method using MgO as the catalyst and comparing the engine operating characteristics of the test engine when using WCOSD and traditional diesel(CD)as test fuels.As a result,the brake power of the test engine fueled WCOSD,and traditional diesel is similar.However,the engine fuel consumption in the case of using WCOSD is slight increases in some operating conditions.Also,the nitrogen oxides emissions of the test engine fueled WCOSD are higher than those of CD at all tested conditions.The trend is opposite for hydrocarbon emission as the HC emission of the engine fueled by WCOSD reduces 26.3%on average.The smoke emission of the test engine in case of using WCOSD is lower 17%on average than that of CD.However,the carbon monoxide emissions are lower at the low and medium loads and higher at the full loads.These results show that the new biodiesel has the same characteristics as those of commercial biodiesel and can be used as fuel for diesel engines.

Waste Frying Oils-Based Biodiesel: Process and Fuel Properties

The conversion of waste frying oil into a valuable methyl ester (biodiesel) has been successfully conducted and also the acid pre-treatment process was carried out prior to the main biodiesel production process for lowering waste frying oil free fatty acid (FFA) content below 1%. The physicochemical properties of biodiesel were analyzed to ensure the product could meet the standards of fuel properties. The methanolysis was selected as the biodiesel production technique under various mixing speeds namely 350, 400 and 450 rpm, while the other parameters are maintained at the optimum process conditions such as methanol to oil molar ratio is 6:1, percentage of catalyst loading is 1.0% wt, reaction temperature is 60℃, and reaction time is 50 min. Also, the investigation on the kinematic viscosity, density and flash point of biodiesel was performed against a number of rpm. The standards of ASTM D 6751 were applied to measure the entire prescribed properties of biodiesel. The highest yield of biodiesel obtained was 99%. The values of flash point, kinematic viscosity and density were in the range of specified limitations. Other biodiesel properties fulfilled the diesel engine application requirements.

高压油泵阻尼孔对燃油系统压力特性的影响研究

为实现更高的热效率和更优的排放,柴油机的喷射压力不断提高。阻尼孔作为高压油泵等压出油阀的关键结构,对燃油系统的压力特性有重要影响。本文研究了阻尼孔大小对喷油器的喷射特性以及高压油管压力波动特性的影响,结果表明:随着阻尼孔由0.1 mm增大至2.0 mm,喷油器喷油持续期相对缩短,循环喷油量减小,这是不同阻尼孔对应的高压油管残余压力大小不同,以及不同阻尼孔大小对系统压力调节的速度不同的结果;此外,阻尼孔较小(0.1 mm)时,燃油系统存在二次喷射现象,而阻尼孔过大(3 mm)时,系统内还会存在零压区,即存在穴蚀的风险;对高压油管残余压力的频谱分析发现,阻尼孔较小时,高压油管内压力脉动与出油阀的运动存在较强的相关性,而阻尼孔较大时,压力脉动与回油阀的运动相关,即供油系统中多种阀件的运动是高压油管压力脉动的主要原因。