Time-of-flight(TOF) mass spectra of molecular butanone clusters were measured under the irradiation of photons at 355 and 118 nm. Butanone molecular parent ion and several series of butanone cluster fragments such ...Time-of-flight(TOF) mass spectra of molecular butanone clusters were measured under the irradiation of photons at 355 and 118 nm. Butanone molecular parent ion and several series of butanone cluster fragments such as (CH3COC2H5)nH+, (CH3COC2H5)nC2H5+, (CH3COC2H5)nCH3CO+ and (CH3COC2H5)nC2H5CO+ were observed. Odd-even variation pattern in the intensity of (CH3COC2H5)nCH3CO+ is obvious from n=4 to 8. A connection is es-tablished between the fragment clusters (CH3COC2H5)nCH3CO+ and the neutral clusters (CH3COC2H5)n+1 based on the consideration of butanone cluster dissociation mainly by losing a radical C2H5?. The stability variation of the neutral clusters calculated via the HF-B3LYP method based on DFT is in agreement with the observed phenomena experimentally, indicating (CH3COC2H5)n+1(n+1=5,7) with a ring structure are with higher stability over the adjacent even-number clusters.展开更多
The isobaric vapor-liquid equilibrium data of butanone1-N, N-dimethylformamide DMF2 at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene1-DMF2 at 100.92kPa were measured using a modified Rose–Williams still. The above...The isobaric vapor-liquid equilibrium data of butanone1-N, N-dimethylformamide DMF2 at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene1-DMF2 at 100.92kPa were measured using a modified Rose–Williams still. The above data met the thermodynamic consistency test and were correlated with the Wilson, NRTL, and UNIQUAC equations. These data can be used in the analysis and design of the process that involves separating DMF from butanone and toluene in the leather synthesis industry.展开更多
The title compound, [t-BuCOCH(C2H2N3)(C6H4N3)], has been prepared and characterized by elemental analysis, IR spectrum and X-ray studies. It crystallizes in mono-clinic, space group C2/c with a = 11.563(3), b = 10.906...The title compound, [t-BuCOCH(C2H2N3)(C6H4N3)], has been prepared and characterized by elemental analysis, IR spectrum and X-ray studies. It crystallizes in mono-clinic, space group C2/c with a = 11.563(3), b = 10.906(3), c = 23.602(5) ? b = 98.35(3)? C14H16N6O, Mr = 284.33, V = 2944.8(13) 3, Z = 8, Dc = 1.283 g/cm3, F(000) = 1200, = 0.087 mm-1, R = 0.0535 and wR = 0.1046. The crystal structure consists of discrete 2,2-dimethyl-4-[1H-(1,2,4-triazolyl)]-4-[1H-benzotriazolyl]-3-butanones. The planes of carbonyl group and benzotriazole ring form the dihedral angle of 89.14(1). The molecules of the title compound are connected to each other through extensive hydrogen bonds to form hydrogen networks. Elemen- tal analysis and IR spectra are in good agreement with the structural data.展开更多
Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper.Spectral variation of n-π^*transition b...Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper.Spectral variation of n-π^*transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra.Experimental results indicate that Ca^2+ and Al^3+ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π-*transition band,which is manifested by cross peaks in 2D asynchronous spectra.展开更多
The isobaric vapor-liquid equilibrium data of butanone(1)-N, N-dimethylformamide (DMF)(2) at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene(1)-DMF(2) at 100.92kPa were measured using a modified Rose-Williams still. ...The isobaric vapor-liquid equilibrium data of butanone(1)-N, N-dimethylformamide (DMF)(2) at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene(1)-DMF(2) at 100.92kPa were measured using a modified Rose-Williams still. The above data met the thermodynamic consistency test and were correlated with the Wilson,NRTL, and UNIQUAC equations. These data can be used in the analysis and design of the process that involves separating DMF from butanone and toluene in the leather synthesis industry.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.10404008, 10774056 and 10974070)Doctoral Fund of Ministry of Education of China
文摘Time-of-flight(TOF) mass spectra of molecular butanone clusters were measured under the irradiation of photons at 355 and 118 nm. Butanone molecular parent ion and several series of butanone cluster fragments such as (CH3COC2H5)nH+, (CH3COC2H5)nC2H5+, (CH3COC2H5)nCH3CO+ and (CH3COC2H5)nC2H5CO+ were observed. Odd-even variation pattern in the intensity of (CH3COC2H5)nCH3CO+ is obvious from n=4 to 8. A connection is es-tablished between the fragment clusters (CH3COC2H5)nCH3CO+ and the neutral clusters (CH3COC2H5)n+1 based on the consideration of butanone cluster dissociation mainly by losing a radical C2H5?. The stability variation of the neutral clusters calculated via the HF-B3LYP method based on DFT is in agreement with the observed phenomena experimentally, indicating (CH3COC2H5)n+1(n+1=5,7) with a ring structure are with higher stability over the adjacent even-number clusters.
基金the National Natural Science Foundation of China (No.20376073)
文摘The isobaric vapor-liquid equilibrium data of butanone1-N, N-dimethylformamide DMF2 at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene1-DMF2 at 100.92kPa were measured using a modified Rose–Williams still. The above data met the thermodynamic consistency test and were correlated with the Wilson, NRTL, and UNIQUAC equations. These data can be used in the analysis and design of the process that involves separating DMF from butanone and toluene in the leather synthesis industry.
基金Natural Science Foundation of Shandong Province (No. Y2002B06)
文摘The title compound, [t-BuCOCH(C2H2N3)(C6H4N3)], has been prepared and characterized by elemental analysis, IR spectrum and X-ray studies. It crystallizes in mono-clinic, space group C2/c with a = 11.563(3), b = 10.906(3), c = 23.602(5) ? b = 98.35(3)? C14H16N6O, Mr = 284.33, V = 2944.8(13) 3, Z = 8, Dc = 1.283 g/cm3, F(000) = 1200, = 0.087 mm-1, R = 0.0535 and wR = 0.1046. The crystal structure consists of discrete 2,2-dimethyl-4-[1H-(1,2,4-triazolyl)]-4-[1H-benzotriazolyl]-3-butanones. The planes of carbonyl group and benzotriazole ring form the dihedral angle of 89.14(1). The molecules of the title compound are connected to each other through extensive hydrogen bonds to form hydrogen networks. Elemen- tal analysis and IR spectra are in good agreement with the structural data.
基金financially supported by the National Natural Science Foundation of China(No.51373003)Beijing Natural Science Foundation(No.2122059)
文摘Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper.Spectral variation of n-π^*transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra.Experimental results indicate that Ca^2+ and Al^3+ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π-*transition band,which is manifested by cross peaks in 2D asynchronous spectra.
基金Supported by the National Natural Science Foundation of China (No.20376073).
文摘The isobaric vapor-liquid equilibrium data of butanone(1)-N, N-dimethylformamide (DMF)(2) at 100.92kPa, 93.32kPa, and 79.99kPa and of toluene(1)-DMF(2) at 100.92kPa were measured using a modified Rose-Williams still. The above data met the thermodynamic consistency test and were correlated with the Wilson,NRTL, and UNIQUAC equations. These data can be used in the analysis and design of the process that involves separating DMF from butanone and toluene in the leather synthesis industry.