Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the info...Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the information of geophysical field was divided into two parts: deep and sh allow focus fields. And then, the information of two different fields was c ombined with that of deep seated geology and ore deposit features. The syntheti c result was adopted to analyze three dimension structure, to probe into crust mantle coupling effects of mineralization and dynamics of ore formation system .展开更多
To investigate the effects of biochar addition(1 or 3%)to the soil of a China fir plantation with or without litter,we conducted a 90-day incubation experiment.We also studied the C and N dynamics and the microbial co...To investigate the effects of biochar addition(1 or 3%)to the soil of a China fir plantation with or without litter,we conducted a 90-day incubation experiment.We also studied the C and N dynamics and the microbial community structure of the soil.In soil without litter,the application of biochar at a rate of 3%significantly decreased CO2 emissions,while addition of 1%biochar had no effect.Biochar application did not affect the net N mineralization rate but significantly reduced the NH4?concentration after 90 days.In litter-enriched soil,biochar application had no significant effect on total CO2 emissions;however,application of 3%biochar significantly reduced the net N mineralization rate.Biochar application to soil with or without litter immediately reduced the dissolved organic carbon(DOC)concentration independent of the application rate,which was primarily due to sorption of DOC by the biochar.Phospholipid fatty acid analysis demonstrated that both concentrations of added biochar to soil(with or without litter)altered the soil microbial community structure at the end of incubation,although the effect of biochar was not as strong as the effect of time or litter application.The effect of biochar addition alone on microbial community structure was inconsistent over time.Litter added to soil significantly increased fungi and reduced Gram-positive bacteria.In the presence of litter,biochar applied at both 1%and 3%significantly increased(p<0.05)the proportion of actinomycete only at day 90.Our results indicate biochar as a potentially effective measure for C sequestration in the test soil of a China fir plantation,even in the presence of litter.展开更多
By adding small amount of TiO2, aluminum slag could be used to synthesize cor- dierite. α-Al2O3, TiO2 and dehydrated talc could generate solid solution to accelerate the solid-state reaction to form cordierite. The e...By adding small amount of TiO2, aluminum slag could be used to synthesize cor- dierite. α-Al2O3, TiO2 and dehydrated talc could generate solid solution to accelerate the solid-state reaction to form cordierite. The experimental results show that the content of cordierite increases with the increase of TiO2 added. 3.0% of TiO2 is determined to be the best amount, because all crystalline substances are converted into cordierite at this content. Philips X’pert plus software analysis shows that when the content of TiO2 is from 0 to 1.0%, cordierite has the same hexagonal structure as the single crystal and the lattice parameters change slightly; when the content of TiO2 is from 1.0 to 2.0%, the cordierite still keeps hexagonal structure but the lattice parameters change greatly; when the content of TiO2 is from 2.0 to 3.5%, the cordierite is converted from hexagonal into rhombic and the lattice parameters change accordingly.展开更多
The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It co...The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It could be concluded that the fixation capacity is determined by the total amount of interlayer charge originating from both octahedral and tetrahedral sheets. The relationship between interlayer cation fixation and octahedral structure of the secondary minerals may be different from that of the primary minerals. The oxidation and reduction of cations with variable valence can greatly influence the cation-fixation capacity.展开更多
A new mineral,jichengite ideally 3CuIr_2S_4·(Ni,Fe)_9S_8,was found as a constituent of placer concentrates at a branch of the Luanhe River,about 220 km NNE of Beijing.Its associated minerals are chromite,magnetit...A new mineral,jichengite ideally 3CuIr_2S_4·(Ni,Fe)_9S_8,was found as a constituent of placer concentrates at a branch of the Luanhe River,about 220 km NNE of Beijing.Its associated minerals are chromite,magnetite,ilmenite,zircon,native gold,iridium,ferrian platinum and osmium.The placer is distributed at places around ultrabasic rock,which hosts chromite orebodies,from which PGM originated.Jichengite occurs commonly as massive or granular aggregates.No perfect morphology of jichengite was observed.It is steel gray and opaque with metallic luster and black streak.It has a Mohs hardness of 5,VHN(d) urn 21.65,H_m 4.465,Hv = 268.1 N/um^2.It is brittle and weakly magnetic. Cleavage {010} is rarely observed.No fracture was observed.Density could not be measured because of its too small grain size.Density(calc.) is 7.003 g/cm^3.Reflect light is reddish-brown,without internal reflections.Anisotropism is distinct with grayish or yellowish white in crossed nicols and bluish violetcopper red in uncrossed nicols.Jichengite shows weak pleochroism and strong bireflectance.The reflectance values in air at the Standard Commission on Ore Mineralogy wavelengths are:38.9,34.3 at 470 nm,38.9,34.5 at 546 nm,39.1,35.3 at 590 nm,39.2,36.8 at 650 nm,parallel-axial extinction.The six strongest lines in the X-ray powder-diffraction pattern[d in A,(I),(hkl)]are:3.00(100)(116),2.80(50) (205),2.48.(50)(208),1.916(40)(2,1,10),1.765(60)(220),1.753(50)(2,0,16).Five chemical analyses carried out,yielding the following results:S 25.76(25.49-5.97),Fe 10.03(9.78-10.31),Co 0.78 (0.75-0.81),Ni 12.48(12.32-12.85),Cu 4.77(4.69-4.83),Ir 46.98(46.14-47.89),sum 100.80wt%,which produced a formula(Cu_(1.556)Fe_(0.976))_(2.532)(Ir_(5.063)S_(10.126))·(Fe_(2.7451)Ni_(4.404)Co_(0.273))_(7.422)S_(6.517).The ideal formula is X_(10)Ir_5S_(17.5),which was calculated by single crystal structure analyses,where X=Cu(Ⅱ)+Fe(Ⅱ)+Ni(Ⅱ) +Co(Ⅱ).The single crystal data were collected using a diffractometer with Mo Kαradiation and a graphite monochromate.The crystal system is trigonal with space group R3m and unit cell parameters a=7.0745(14) A,c=34.267(10) A(The superstructure not found),and the final R Indices[with 564 observed reflections,I>2sigma(Ⅰ)]are R_1=0.0495,wR_2=0.1349.The specimens are deposited in the Geological Museum of China.展开更多
Various characterization methods, including scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller surface-area measurements, thermogravimetry–d...Various characterization methods, including scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller surface-area measurements, thermogravimetry–differential scanning calorimetry, X-ray diffraction, and infrared spectroscopy, were used to study the mineral structure and surface characteristics of high-iron hydrargillite. Gibbsite, goethite, and hematite were found to be the main mineral components of hydrargillite, whereas the goethite and hematite were closely clad to the surface of the multilayer gibbsite crystals. Compared with the synthetic gibbsite, the hydrargillite contained more structural micropores generated by the mineral evolution during the mineralization process. The gibbsite in hydrargillite contained less crystal water compared with the synthetic gibbsite, and it was a typical polymorphic structure. The isomorphous substitution of Al and Fe was observed in goethite. The dissolution-controlling step of hydrargillite was the ionic diffusion speed because of the goethite and hematite that closely covered and encapsulated the gibbsite crystals.展开更多
Objective The Lanping-Simao Basin in western Yunnan, located in the southeastern margin of the Tibetan Plateau, is tectonically in the transition zone between the Gondwana and Eurasia tectonic domains. It is also the ...Objective The Lanping-Simao Basin in western Yunnan, located in the southeastern margin of the Tibetan Plateau, is tectonically in the transition zone between the Gondwana and Eurasia tectonic domains. It is also the frontier zone of northeastern extrusion of the Indochina Plate towards the Eurasia Plate as well as the escape zone for the deep material. The middle axial tectonic zone, also known as the Lanping-Simao Fault (LSF) in previous study, is a giant intraplate tectonic belt composed of a series of narrow uplift belt, rupture depression zone, metamorphic belt, alteration belt and marginal fracture system, which were formed by the compressional uplift of the central depression of the Lanping-Simao Basin. This tectonic unit controls the geological evolution, seismic activity, hot spring distribution and ore formation of the LanpingSimao Basin since the Mesozoic and Cenozoic.展开更多
β-TCP, as one of calcium phosphates ceramics, exerts perfect biocompatibility and osteoconductivity, and is clinically used as a bone graft substitute for decades. Consequently, the effects of β-TCP ceramics on intr...β-TCP, as one of calcium phosphates ceramics, exerts perfect biocompatibility and osteoconductivity, and is clinically used as a bone graft substitute for decades. Consequently, the effects of β-TCP ceramics on intracellular Ca2+ concentration, mineralization of osteoblast and BSA protein structure were studied. Results showed that β-TCP could increase the intracelluar Ca2+ concentration and mineralization of osteoblast, indicating that β-TCP ceramics could take part in the organic metabolism and the degradation product had no detrimental effect on osteoblast in vitro. Furthermore, β-TCP ceramics could increase the content of α-helix and β-pleated sheet and change BSA into more ordering structure, those changes might be favorable for the biomineralization after β-TCP ceramics implanted.展开更多
The domain structures in calcium-cerium fluorocarbonate mineral series from a rare earth mineral deposit within an aegirine alkali granite massif in Mianning County, Sichuan Province, China, were studied by means of t...The domain structures in calcium-cerium fluorocarbonate mineral series from a rare earth mineral deposit within an aegirine alkali granite massif in Mianning County, Sichuan Province, China, were studied by means of transmission electron microscopy. Many categories of domain structures in this mineral series were observed and investigated, including the microtwin domains of parisite-6R(2) and B2S-6R, the antiphase domains of B2S-2H. The results show that the antiphase domains which are faults along crystal plane (0001) are formed by the displacement of crystal lattice in c * direction and the displacement is 0.471 nm. A new polytype (B4S2-3R) of regular mixed-layer structure with B4S2 type is found in the domain region of mixed-layer structure.展开更多
Structures and hydration activities of alumi-nates CA and CA2 of cement minerals are studied by SCF —DV —Xa method, one of the molecular orbital calculating method in quantum chemistry. The calculated results of net...Structures and hydration activities of alumi-nates CA and CA2 of cement minerals are studied by SCF —DV —Xa method, one of the molecular orbital calculating method in quantum chemistry. The calculated results of net charges,energy levels of molecular orbitals and covalent bond orders are all consistent with the experimental result that the hydration activity of CA is higher than that of CA2.展开更多
Based on systematic analyses of 72 samples of different basic-ultrabasic rocks, the present paper discusses the relationship between melt structure and Cu and Au mineralization. It is found that if the NBO/T, NBO, M2+...Based on systematic analyses of 72 samples of different basic-ultrabasic rocks, the present paper discusses the relationship between melt structure and Cu and Au mineralization. It is found that if the NBO/T, NBO, M2+, FeO and MgO values are relatively high and the T, M3+, Fe2O3 and CaO values are low the basic-ultrabasic melt will be favourable to Cu (Ni) mineralization, but if the former are low and the latter are high it is favourable to Au metallization. Cu ions occupy dominantly octahedra in basic-ultrabasic melt and the higher the NBO/T, NBO and M2+ values, the more the octahedra in the melt. Au element mainly takes the form of Au+ ions in basic-ultrabasic melt and the Au+ ions constitute tetrahedral sites together with Fe3+ ions. Therefore, low M2+ and high Fe3+, i.e. high oxygen fu-gacity, can promote the enrichment of Au+ ions and Au mineralization. Components NT (other than Au+), Al2O3 and SiO2 in basic-ultrabasic melt have no effect on metallogenetic species. As mentioned above, in relevant diagrams distribution areas of the characteristic values of ore-free melt and those of ore-forming melt are overlapped in different degrees, which possibly indicates that not all the magmas have mineralizing ability. It can be well distinguished whether basic-ultrabasic rocks are favourable to Cu or Au mineralization or they are just ore-free rocks by analysing integrated diagrams of the characteristic values of the magmatic melt structure.展开更多
Microtextures and struetures of 9 hydrothermal chimneys sampled on the small spreading ridge Of the Mari ana Trough during SONNE Cruise 57 (SO57) and 69 (SO69) in 1988 and 1990 were studied by means of scanning elec...Microtextures and struetures of 9 hydrothermal chimneys sampled on the small spreading ridge Of the Mari ana Trough during SONNE Cruise 57 (SO57) and 69 (SO69) in 1988 and 1990 were studied by means of scanning electron microscope. The results reveal that the two types of chimneys from the Mariana Trough. the 'silicic chimneys' containing Fe sulfide and the pure 'silica chimneys' without sulfide, vary distinctly not only in mineral and chemical compositions, but also in microtextures and structures. The silicic chimneys generally show three major types of microtextures.The inside of the chimneys is dominated by holocrystalline or semicrystalline idiomorphic and hypidiomorphic granular textures and the outwall by amorphous colloidal texture. In some of the silicic chimneys relict texture is observed. However,the pure silica chimneys show chiefly amorphous colloidal texture from the inside to the outwall. Microstructurally. theinside of the silicic chimneys is dominated by a 'silica-covering' structure and a 'voidfilling' structure, and the outwall by a chain-like or three-dimentional chain-network structure built up by individual opal globules, whereas the pure silica chimneys are mainly three-dimentional chain-network and the dense silica bands in structure. These variations suggest that not only mineralizing conditions but also processes differ distinctly during the formation of the two types of chimneys, and that hydrothermal mineralization in the Mariana Trough shows a multistage or multieplsodical nature.展开更多
The microstructural features of clacium rare earth(Ca RE) fluorocarbonate minerals from Southwest China were studied by using selected area electron diffraction(SAED) and high resolution transmission electron micros...The microstructural features of clacium rare earth(Ca RE) fluorocarbonate minerals from Southwest China were studied by using selected area electron diffraction(SAED) and high resolution transmission electron microscopy(HRTEM). Three new regularly mixed layer structures of B 8S 6 type with long period and different stacking sequence, i.e. B 8S 6 Ⅰ, B 8S 6 Ⅱ, and B 8S 6 Ⅲ, were found in the derived polycrystal of parisite, in which their structural symmetry, cell parameters, chemical formulas of crystal and stacking models of structural unit layer, etc. were determined. The results of this study also show that these new regularly mixed layer structrues were formed by order stacking unit layer of bastnaesite(B) and synchisite(S) in varying proportion along c axis. The observation under HRTEM reveals that in the three new regularly mixed layer structures there are different distribution modes of Ce F ion layers, CO 2- 3 ion groups between the Ce F ion layers, and CO 2- 3 ion groups between Ce F and Ca 2+ ion layers, and there are some heterogeneous textures, such as disorder interlayer and stacking fault. It further proves the complexity of the crystal structure of the Ca RE fluorocarbonate minerals.展开更多
Whole-lithosphere structure has direct implications for both the genesis of minerals and the locations of mineral emplacement;thus knowledge of the deep structural framework of the lithosphere can advance understandin...Whole-lithosphere structure has direct implications for both the genesis of minerals and the locations of mineral emplacement;thus knowledge of the deep structural framework of the lithosphere can advance understanding of the development and evolution of mineral systems.展开更多
The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of fou...The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of four famous major Mesozoic metallogenic belts,involving the Middle-Lower Yangtze Fe-Cu-Au metallogenic belt(MYMB).展开更多
Indus basin hosts many significant mineral deposits like gypsum and cement raw materials, gemstones, iron, coal, marble, dimension and construction stones, petroleum and water resources, world class pink salt and othe...Indus basin hosts many significant mineral deposits like gypsum and cement raw materials, gemstones, iron, coal, marble, dimension and construction stones, petroleum and water resources, world class pink salt and other many minerals in different regions which need further exploitation and development. The construction of new water dams in different regions are vital (for availability of cheap electricity), because of available barren and fertile lands and wastage of water as flood. Further the installation of more cement industries in different regions of Indus Basin especially in middle Indus (Sulaiman Range where gypsum, clays and limestones can be available via belt) can increase export to receive more foreign exchange and make local cement cheap for the sustainable development of Pakistan. 31 stratigraphic sequential sections at different sections of Indus basins are presented to know the variation and local stratigraphy. Further here three new titanosaur taxa are being described. Saraikimasoom is based on snout;Gspsaurus, (Maojandino), Nicksaurus and Khanazeem are based on cranial, vertebral and appendicular elements;Balochisaurus, Marisaurus, Pakisaurus, and 3 new genera and species Imrankhanhero zilefatmi, Qaikshaheen masoomniazi and Ikqaumishan smqureshi based on vertebral and appendicular elements;and Sulaimanisaurus and Khetranisaurus based on only caudal vertebrae. Although Pakistani Titanosaurians seem to be proliferated found from one horizon of Vitakri Formation just below the K-Pg boundary they have a wide range of diagnostic features and key elements among titanosaurs which can be used for comparison and phylogenetic analyses with broad updated character data set of titanosaurs.展开更多
Pseudosection modeling for the garnet amphibolite samples from the Western Dabie Mountains show they have experienced similar HP metamorphic evolution with that of the adjected eclogites.The common assemblage of
The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Z...The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should展开更多
In recent2 0 years,because of the finding ofmany large- superlargegold deposits,we re- new the theories for prospecting and gain many things and conceptions.The current geo- chemical and gold- forming theories underli...In recent2 0 years,because of the finding ofmany large- superlargegold deposits,we re- new the theories for prospecting and gain many things and conceptions.The current geo- chemical and gold- forming theories underline the importance of the early submarine volcano- sedimentation,metamorphic differention,sedimentation of terrigenous clastics,thermal spring and it’s sedimentation,syngenesis process and other hypergene supplying the source for metallogenic materials.According to the study for source bed(rock) and depsitional for- mation of gold,we find that gold will be gradually enriched and mineralized in source bed (rock) ,because of variousgeologicprocesses,such as regional metamorphism ormigmatiza- tion,geothermal bittern,volcanism. The ore- control of deep and giant fault and ductile shear beltand tectono- flash space is emphasized,especially,we should notice the long- term, succession and multistage of the展开更多
This paper presents the results of a set of numerical models focussing on structural controls on hydrothermal mineralization. We first give an overview of natural phenomena of structurally-controlled ore formation and...This paper presents the results of a set of numerical models focussing on structural controls on hydrothermal mineralization. We first give an overview of natural phenomena of structurally-controlled ore formation and the background theory and mechanisms for such controls. We then provide the results of a group of simple 2D numerical models validated through comparison with Cu-vein structure observed near the Shilu Copper deposit (Yangchun, Guangdong Province, China) and finally a case study of 3D numerical modelling applied to the Hodgkinson Province in North Queensland (Australia). Two modelling approaches, discrete deformation modelling and continuum coupled deformation and fluid flow modelling, are involved. The 2D model-derived patterns are remarkably consistent with the Cu-vein structure from the Shilu Copper deposit, and show that both modelling approaches can realistically simulate the mechanical behaviours of shear and dilatant fractures. The continuum coupled deformation and fluid flow model indicates that pattern of the Cu- veins near the Shilu deposit is the result of shear strain localization, development of dilation and fluid focussing into the dilatant fracture segments. The 3D case-study models (with deformation and fluid flow coupling) on the Hodgkinson Province generated a number of potential gold mineralization展开更多
文摘Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the information of geophysical field was divided into two parts: deep and sh allow focus fields. And then, the information of two different fields was c ombined with that of deep seated geology and ore deposit features. The syntheti c result was adopted to analyze three dimension structure, to probe into crust mantle coupling effects of mineralization and dynamics of ore formation system .
基金supported by the National Science and Technology Support Program(2015BAD09B010102)International Science and Technology Cooperation Program of Fujian Agriculture and Forestry University(KXB16008A)
文摘To investigate the effects of biochar addition(1 or 3%)to the soil of a China fir plantation with or without litter,we conducted a 90-day incubation experiment.We also studied the C and N dynamics and the microbial community structure of the soil.In soil without litter,the application of biochar at a rate of 3%significantly decreased CO2 emissions,while addition of 1%biochar had no effect.Biochar application did not affect the net N mineralization rate but significantly reduced the NH4?concentration after 90 days.In litter-enriched soil,biochar application had no significant effect on total CO2 emissions;however,application of 3%biochar significantly reduced the net N mineralization rate.Biochar application to soil with or without litter immediately reduced the dissolved organic carbon(DOC)concentration independent of the application rate,which was primarily due to sorption of DOC by the biochar.Phospholipid fatty acid analysis demonstrated that both concentrations of added biochar to soil(with or without litter)altered the soil microbial community structure at the end of incubation,although the effect of biochar was not as strong as the effect of time or litter application.The effect of biochar addition alone on microbial community structure was inconsistent over time.Litter added to soil significantly increased fungi and reduced Gram-positive bacteria.In the presence of litter,biochar applied at both 1%and 3%significantly increased(p<0.05)the proportion of actinomycete only at day 90.Our results indicate biochar as a potentially effective measure for C sequestration in the test soil of a China fir plantation,even in the presence of litter.
基金This project was supported by the 863 Project (2003AA322020)
文摘By adding small amount of TiO2, aluminum slag could be used to synthesize cor- dierite. α-Al2O3, TiO2 and dehydrated talc could generate solid solution to accelerate the solid-state reaction to form cordierite. The experimental results show that the content of cordierite increases with the increase of TiO2 added. 3.0% of TiO2 is determined to be the best amount, because all crystalline substances are converted into cordierite at this content. Philips X’pert plus software analysis shows that when the content of TiO2 is from 0 to 1.0%, cordierite has the same hexagonal structure as the single crystal and the lattice parameters change slightly; when the content of TiO2 is from 1.0 to 2.0%, the cordierite still keeps hexagonal structure but the lattice parameters change greatly; when the content of TiO2 is from 2.0 to 3.5%, the cordierite is converted from hexagonal into rhombic and the lattice parameters change accordingly.
基金Project(No.39770427)supported by the National Natural Science Foundation of China.
文摘The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It could be concluded that the fixation capacity is determined by the total amount of interlayer charge originating from both octahedral and tetrahedral sheets. The relationship between interlayer cation fixation and octahedral structure of the secondary minerals may be different from that of the primary minerals. The oxidation and reduction of cations with variable valence can greatly influence the cation-fixation capacity.
基金supported by the Program"China's Mineral Species and Systematic Mineralogy Research"with Grant No.201011005-1A,B and C,from The Ministry of Science and Technology of the People's Republic of China
文摘A new mineral,jichengite ideally 3CuIr_2S_4·(Ni,Fe)_9S_8,was found as a constituent of placer concentrates at a branch of the Luanhe River,about 220 km NNE of Beijing.Its associated minerals are chromite,magnetite,ilmenite,zircon,native gold,iridium,ferrian platinum and osmium.The placer is distributed at places around ultrabasic rock,which hosts chromite orebodies,from which PGM originated.Jichengite occurs commonly as massive or granular aggregates.No perfect morphology of jichengite was observed.It is steel gray and opaque with metallic luster and black streak.It has a Mohs hardness of 5,VHN(d) urn 21.65,H_m 4.465,Hv = 268.1 N/um^2.It is brittle and weakly magnetic. Cleavage {010} is rarely observed.No fracture was observed.Density could not be measured because of its too small grain size.Density(calc.) is 7.003 g/cm^3.Reflect light is reddish-brown,without internal reflections.Anisotropism is distinct with grayish or yellowish white in crossed nicols and bluish violetcopper red in uncrossed nicols.Jichengite shows weak pleochroism and strong bireflectance.The reflectance values in air at the Standard Commission on Ore Mineralogy wavelengths are:38.9,34.3 at 470 nm,38.9,34.5 at 546 nm,39.1,35.3 at 590 nm,39.2,36.8 at 650 nm,parallel-axial extinction.The six strongest lines in the X-ray powder-diffraction pattern[d in A,(I),(hkl)]are:3.00(100)(116),2.80(50) (205),2.48.(50)(208),1.916(40)(2,1,10),1.765(60)(220),1.753(50)(2,0,16).Five chemical analyses carried out,yielding the following results:S 25.76(25.49-5.97),Fe 10.03(9.78-10.31),Co 0.78 (0.75-0.81),Ni 12.48(12.32-12.85),Cu 4.77(4.69-4.83),Ir 46.98(46.14-47.89),sum 100.80wt%,which produced a formula(Cu_(1.556)Fe_(0.976))_(2.532)(Ir_(5.063)S_(10.126))·(Fe_(2.7451)Ni_(4.404)Co_(0.273))_(7.422)S_(6.517).The ideal formula is X_(10)Ir_5S_(17.5),which was calculated by single crystal structure analyses,where X=Cu(Ⅱ)+Fe(Ⅱ)+Ni(Ⅱ) +Co(Ⅱ).The single crystal data were collected using a diffractometer with Mo Kαradiation and a graphite monochromate.The crystal system is trigonal with space group R3m and unit cell parameters a=7.0745(14) A,c=34.267(10) A(The superstructure not found),and the final R Indices[with 564 observed reflections,I>2sigma(Ⅰ)]are R_1=0.0495,wR_2=0.1349.The specimens are deposited in the Geological Museum of China.
基金financially supported by the National Natural Science Foundation of China (No.51104041)
文摘Various characterization methods, including scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller surface-area measurements, thermogravimetry–differential scanning calorimetry, X-ray diffraction, and infrared spectroscopy, were used to study the mineral structure and surface characteristics of high-iron hydrargillite. Gibbsite, goethite, and hematite were found to be the main mineral components of hydrargillite, whereas the goethite and hematite were closely clad to the surface of the multilayer gibbsite crystals. Compared with the synthetic gibbsite, the hydrargillite contained more structural micropores generated by the mineral evolution during the mineralization process. The gibbsite in hydrargillite contained less crystal water compared with the synthetic gibbsite, and it was a typical polymorphic structure. The isomorphous substitution of Al and Fe was observed in goethite. The dissolution-controlling step of hydrargillite was the ionic diffusion speed because of the goethite and hematite that closely covered and encapsulated the gibbsite crystals.
基金financially by the National Science and Technology Support Project (grant No.2006BAB01B07)the National Natural Science Foundation of China (grant No.41202057)
文摘Objective The Lanping-Simao Basin in western Yunnan, located in the southeastern margin of the Tibetan Plateau, is tectonically in the transition zone between the Gondwana and Eurasia tectonic domains. It is also the frontier zone of northeastern extrusion of the Indochina Plate towards the Eurasia Plate as well as the escape zone for the deep material. The middle axial tectonic zone, also known as the Lanping-Simao Fault (LSF) in previous study, is a giant intraplate tectonic belt composed of a series of narrow uplift belt, rupture depression zone, metamorphic belt, alteration belt and marginal fracture system, which were formed by the compressional uplift of the central depression of the Lanping-Simao Basin. This tectonic unit controls the geological evolution, seismic activity, hot spring distribution and ore formation of the LanpingSimao Basin since the Mesozoic and Cenozoic.
基金Funded by the Research Fund of Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province (AE201037)the Foundation for Talent Recruitment of Yancheng Institute of Technology (XKR2011007)"973" Chinese National Key Fundamental Research and Development Program (No.G1999064701)
文摘β-TCP, as one of calcium phosphates ceramics, exerts perfect biocompatibility and osteoconductivity, and is clinically used as a bone graft substitute for decades. Consequently, the effects of β-TCP ceramics on intracellular Ca2+ concentration, mineralization of osteoblast and BSA protein structure were studied. Results showed that β-TCP could increase the intracelluar Ca2+ concentration and mineralization of osteoblast, indicating that β-TCP ceramics could take part in the organic metabolism and the degradation product had no detrimental effect on osteoblast in vitro. Furthermore, β-TCP ceramics could increase the content of α-helix and β-pleated sheet and change BSA into more ordering structure, those changes might be favorable for the biomineralization after β-TCP ceramics implanted.
文摘The domain structures in calcium-cerium fluorocarbonate mineral series from a rare earth mineral deposit within an aegirine alkali granite massif in Mianning County, Sichuan Province, China, were studied by means of transmission electron microscopy. Many categories of domain structures in this mineral series were observed and investigated, including the microtwin domains of parisite-6R(2) and B2S-6R, the antiphase domains of B2S-2H. The results show that the antiphase domains which are faults along crystal plane (0001) are formed by the displacement of crystal lattice in c * direction and the displacement is 0.471 nm. A new polytype (B4S2-3R) of regular mixed-layer structure with B4S2 type is found in the domain region of mixed-layer structure.
文摘Structures and hydration activities of alumi-nates CA and CA2 of cement minerals are studied by SCF —DV —Xa method, one of the molecular orbital calculating method in quantum chemistry. The calculated results of net charges,energy levels of molecular orbitals and covalent bond orders are all consistent with the experimental result that the hydration activity of CA is higher than that of CA2.
文摘Based on systematic analyses of 72 samples of different basic-ultrabasic rocks, the present paper discusses the relationship between melt structure and Cu and Au mineralization. It is found that if the NBO/T, NBO, M2+, FeO and MgO values are relatively high and the T, M3+, Fe2O3 and CaO values are low the basic-ultrabasic melt will be favourable to Cu (Ni) mineralization, but if the former are low and the latter are high it is favourable to Au metallization. Cu ions occupy dominantly octahedra in basic-ultrabasic melt and the higher the NBO/T, NBO and M2+ values, the more the octahedra in the melt. Au element mainly takes the form of Au+ ions in basic-ultrabasic melt and the Au+ ions constitute tetrahedral sites together with Fe3+ ions. Therefore, low M2+ and high Fe3+, i.e. high oxygen fu-gacity, can promote the enrichment of Au+ ions and Au mineralization. Components NT (other than Au+), Al2O3 and SiO2 in basic-ultrabasic melt have no effect on metallogenetic species. As mentioned above, in relevant diagrams distribution areas of the characteristic values of ore-free melt and those of ore-forming melt are overlapped in different degrees, which possibly indicates that not all the magmas have mineralizing ability. It can be well distinguished whether basic-ultrabasic rocks are favourable to Cu or Au mineralization or they are just ore-free rocks by analysing integrated diagrams of the characteristic values of the magmatic melt structure.
文摘Microtextures and struetures of 9 hydrothermal chimneys sampled on the small spreading ridge Of the Mari ana Trough during SONNE Cruise 57 (SO57) and 69 (SO69) in 1988 and 1990 were studied by means of scanning electron microscope. The results reveal that the two types of chimneys from the Mariana Trough. the 'silicic chimneys' containing Fe sulfide and the pure 'silica chimneys' without sulfide, vary distinctly not only in mineral and chemical compositions, but also in microtextures and structures. The silicic chimneys generally show three major types of microtextures.The inside of the chimneys is dominated by holocrystalline or semicrystalline idiomorphic and hypidiomorphic granular textures and the outwall by amorphous colloidal texture. In some of the silicic chimneys relict texture is observed. However,the pure silica chimneys show chiefly amorphous colloidal texture from the inside to the outwall. Microstructurally. theinside of the silicic chimneys is dominated by a 'silica-covering' structure and a 'voidfilling' structure, and the outwall by a chain-like or three-dimentional chain-network structure built up by individual opal globules, whereas the pure silica chimneys are mainly three-dimentional chain-network and the dense silica bands in structure. These variations suggest that not only mineralizing conditions but also processes differ distinctly during the formation of the two types of chimneys, and that hydrothermal mineralization in the Mariana Trough shows a multistage or multieplsodical nature.
文摘The microstructural features of clacium rare earth(Ca RE) fluorocarbonate minerals from Southwest China were studied by using selected area electron diffraction(SAED) and high resolution transmission electron microscopy(HRTEM). Three new regularly mixed layer structures of B 8S 6 type with long period and different stacking sequence, i.e. B 8S 6 Ⅰ, B 8S 6 Ⅱ, and B 8S 6 Ⅲ, were found in the derived polycrystal of parisite, in which their structural symmetry, cell parameters, chemical formulas of crystal and stacking models of structural unit layer, etc. were determined. The results of this study also show that these new regularly mixed layer structrues were formed by order stacking unit layer of bastnaesite(B) and synchisite(S) in varying proportion along c axis. The observation under HRTEM reveals that in the three new regularly mixed layer structures there are different distribution modes of Ce F ion layers, CO 2- 3 ion groups between the Ce F ion layers, and CO 2- 3 ion groups between Ce F and Ca 2+ ion layers, and there are some heterogeneous textures, such as disorder interlayer and stacking fault. It further proves the complexity of the crystal structure of the Ca RE fluorocarbonate minerals.
基金part of the research project"Crustmantle interactions beneath the Hangai Mountains in western Mongolia"the financial support of the DFG and the SNF,awarded through the DACH program
文摘Whole-lithosphere structure has direct implications for both the genesis of minerals and the locations of mineral emplacement;thus knowledge of the deep structural framework of the lithosphere can advance understanding of the development and evolution of mineral systems.
基金jointly sponsored by the National Natural Science Foundation of China(Grant Nos.41630320,92062108)the Geology Survey Project(Grant Nos.DD20190012,DD20160082)the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resource,Institute of Geology,Chinese Academy of Geological Sciences(Grant No.J1901-16)
文摘The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of four famous major Mesozoic metallogenic belts,involving the Middle-Lower Yangtze Fe-Cu-Au metallogenic belt(MYMB).
文摘Indus basin hosts many significant mineral deposits like gypsum and cement raw materials, gemstones, iron, coal, marble, dimension and construction stones, petroleum and water resources, world class pink salt and other many minerals in different regions which need further exploitation and development. The construction of new water dams in different regions are vital (for availability of cheap electricity), because of available barren and fertile lands and wastage of water as flood. Further the installation of more cement industries in different regions of Indus Basin especially in middle Indus (Sulaiman Range where gypsum, clays and limestones can be available via belt) can increase export to receive more foreign exchange and make local cement cheap for the sustainable development of Pakistan. 31 stratigraphic sequential sections at different sections of Indus basins are presented to know the variation and local stratigraphy. Further here three new titanosaur taxa are being described. Saraikimasoom is based on snout;Gspsaurus, (Maojandino), Nicksaurus and Khanazeem are based on cranial, vertebral and appendicular elements;Balochisaurus, Marisaurus, Pakisaurus, and 3 new genera and species Imrankhanhero zilefatmi, Qaikshaheen masoomniazi and Ikqaumishan smqureshi based on vertebral and appendicular elements;and Sulaimanisaurus and Khetranisaurus based on only caudal vertebrae. Although Pakistani Titanosaurians seem to be proliferated found from one horizon of Vitakri Formation just below the K-Pg boundary they have a wide range of diagnostic features and key elements among titanosaurs which can be used for comparison and phylogenetic analyses with broad updated character data set of titanosaurs.
文摘Pseudosection modeling for the garnet amphibolite samples from the Western Dabie Mountains show they have experienced similar HP metamorphic evolution with that of the adjected eclogites.The common assemblage of
文摘The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should
文摘In recent2 0 years,because of the finding ofmany large- superlargegold deposits,we re- new the theories for prospecting and gain many things and conceptions.The current geo- chemical and gold- forming theories underline the importance of the early submarine volcano- sedimentation,metamorphic differention,sedimentation of terrigenous clastics,thermal spring and it’s sedimentation,syngenesis process and other hypergene supplying the source for metallogenic materials.According to the study for source bed(rock) and depsitional for- mation of gold,we find that gold will be gradually enriched and mineralized in source bed (rock) ,because of variousgeologicprocesses,such as regional metamorphism ormigmatiza- tion,geothermal bittern,volcanism. The ore- control of deep and giant fault and ductile shear beltand tectono- flash space is emphasized,especially,we should notice the long- term, succession and multistage of the
文摘This paper presents the results of a set of numerical models focussing on structural controls on hydrothermal mineralization. We first give an overview of natural phenomena of structurally-controlled ore formation and the background theory and mechanisms for such controls. We then provide the results of a group of simple 2D numerical models validated through comparison with Cu-vein structure observed near the Shilu Copper deposit (Yangchun, Guangdong Province, China) and finally a case study of 3D numerical modelling applied to the Hodgkinson Province in North Queensland (Australia). Two modelling approaches, discrete deformation modelling and continuum coupled deformation and fluid flow modelling, are involved. The 2D model-derived patterns are remarkably consistent with the Cu-vein structure from the Shilu Copper deposit, and show that both modelling approaches can realistically simulate the mechanical behaviours of shear and dilatant fractures. The continuum coupled deformation and fluid flow model indicates that pattern of the Cu- veins near the Shilu deposit is the result of shear strain localization, development of dilation and fluid focussing into the dilatant fracture segments. The 3D case-study models (with deformation and fluid flow coupling) on the Hodgkinson Province generated a number of potential gold mineralization