氢氟酸处理InP/GaP/ZnS量子点的光学性能及其发光二极管应用

采用氢氟酸(HF)原位注入法制备了InP/GaP/ZnS量子点。通过紫外/可见/近红外光谱、光致发光光谱、透射电镜、球差校正透射电镜、X射线衍射、X射线光电子能谱等测试手段分析了HF对InP量子点的发光性能影响。实验结果表明,HF刻蚀减少了量子点表面氧化缺陷状态,有效控制了InP核表面的氧化,并且原子配体形式的F-钝化了量子点表面的悬挂键,显著提升了量子点的光学性能。HF处理的InP/GaP/ZnS量子点具有最佳的发光性能,PLQY高达96%。此外,用HF处理InP/GaP/ZnS量子点制备的发光二极管,其发光的电流效率为6.63 cd/A,最佳外量子效率(EQE)为3.83%。

道地药材云木香GAP研究与规范化种植基地建设实践与展望

云木香原产印度,20世纪30年代初在云南丽江引进种植,并逐渐推广扩展至全省多地,1959年首次出口,誉为“云木香”,为云南省重要道地药材之一,药用历史悠久。为规范云南道地药材云木香的栽培措施,以保证其产品质量,参照国家药品监督管理局颁布实施的《中药材生产质量管理规范》相关要求,综述云木香的道地沿革与种植历史、规范化种植技术研究、传统初加工方法的继承与创新、标准化生产质量管理体系的建立以及规范化种植试验示范基地建设5个方面的研究,以期为云南西北高寒山区该道地药材品种产业化生产提供科学依据。

基于马氏距离和Canopy改进K-means的交通聚类算法

在对交通数据的研究中经常会使用到聚类算法,且不同的聚类算法有不同的特性。K-means作为其中的一种聚类算法,具有较高的准确性和实用性,但其准确性易受主观选取K值和确定初始聚类中心的影响。为了优化聚类中心和K值的选取问题,提出MC-Kmeans算法。在所提方法中,首先通过Canopy算法选取K值,然后依据马氏距离的计算准则来确定初始聚类中心,最后将K值和聚类中心的值作为K-means的参数进行聚类。将MC-Kmeans算法应用到某时间段的纽约出租车交通数据中进行实际的验证。结果表明,与K-means算法比较,所提方法准确度更高,与实际交通情况更加相匹配,更能反映区域内的交通热点情况。

An environmental gradient change of Picea mongolica seedling from the center of a forest canopy gap in forest-steppe ecotone in Inner Mongolia Autonomous Region of China

In sandy forest with a forest canopy gap for a period of over 30 years, the spruce（Picea mongolica） seedlings were monitored on two 5-m- wide transects from the center of a large gap into the surrounding forest. The farther they were to the far center, the taller grew the seedling and the more is the number of seedling. There were many seedlings under the canopy but almost all seedlings died before they grow up. Along the forest edge, growth of seedlings was temporarily enhanced by lateral penetration of light from the gap. The implications for natural forest regeneration dynamics are discussed. Our results prove that in P mongolica forest a gap disturbance creates a non-uniform environment for regeneration of the species, and determines that the forest was a non-even aged forest.

基于5GAP模型的高校食堂服务质量差距分析与对策探讨

食堂服务是高校后勤服务体系中最重要的环节之一,高校食堂管理必须要有的放矢地改进工作。5GAP模型是一种直接有效的服务环节分析工具,更注重找出内部的服务缺陷。在以往的高校食堂研究中,多以顾客满意度的外部视角分析服务质量问题,本文通过5GAP模型以内部视角分析发现引发高校食堂服务质量问题的根源,以期能对高校食堂服务质量的改进和提升起到一定作用。

青年职场“Gap day”现象探究

青年职场“Gap day”现象引起了社会的广泛关注和热烈讨论。青年职场“Gap day”现象的典型特征是:通过语言上的拼贴与再造,表达部分职业青年的困顿疲倦情绪;通过行为上的放空与逃离,排解青年在工作中积攒的情绪和压力;通过价值上的戏谑与自嘲,赋予青年的短暂休息以正向意义。青年职场“Gap day”现象的深层原因是:青年在高压生存环境中的“弹性姿态”、在加速社会运行中的“精神逃离”和在社会时钟齿轮下的“自我审视”。对青年职场“Gap day”现象的有效治理,既要着眼于青年发展,运用公共政策实现青年发展的普遍性诉求,又要立足于青年就业,采取切实措施促进青年实现高质量充分就业。

A review of the roles of forest canopy gaps

Treefall gap, canopy opening caused by the death of one or more trees, is the dominant form of disturbance in many forest systems worldwide. Gaps play an important role in forest ecology helping to pre- serve bio- and pedo-diversity, influencing nutrient cycles, and maintain- ing the complex structure of the late-successional forests. Over the last 30 years, numerous reviews have been written describing gap dynamics. Here we synthesize current understanding on gap dynamics relating to tree regeneration with particular emphasis on gap characteristics consid- ered critical to develop ecologically sustainable forest management sys- tems and to conserve native biodiversity. Specifically, we addressed the question： how do gaps influence forest structure？ From the literature re- viewed, the size of gaps induces important changes in factors such as light intensity, soil humidity and soil biological properties that influence tree species regeneration and differ in gaps of different sizes. Shade- tolerant species can colonize small gaps; shade-intolerant species need large gaps for successful regeneration. Additionally, gap dynamics differ between temperate, boreal, and tropical forests, showing the importance of climate differences in driving forest regeneration. This review summa- rizes information of use to forest managers who design cutting regimes that mimic natural disturbances and who must consider forest structure, forest climate, and the role of natural disturbance in their designs.

Canopy gap characteristics and spatial patterns in a subtropical forest of South China after ice storm damage

The divergent gap characteristics and spatial patterns of canopy gaps created by natural or artificial disturbances can exert a dominant influence on forest structure and composition.However,little research has been conducted on the effects of ice storm damage on canopy gaps in subtropical mature forests of South China.In this study,one semi-natural site was dominated by a broad-leaf forest and two managed sites were representative of plantations with coniferous forests.Based on airborne laser scanning data and field evidence across sites,statistical analyses were used to examine gap characteristics following ice storms of moderate severity.Generalized Ripley’s K-function analysis was applied to test gap spatial patterns at a range of scales,and spatial point pattern analysis was used to quantitate the relative importance of specific influences on patterns of gap occurrence.The results revealed that the average gap size was 75.7 m^2 and that 12.2 gaps occurred per hectare.Most gaps were single-tree fall events.In addition to more gaps,the mean gap size was smaller and the shape was more complex in the semi-natural site than in two managed sites.Large differences in gap characteristics were observed among snapped,uprooted,snag,and artificial gap damage types.Gaps generally showed a clustered distribution at large scales(e.g.70 m),whereas spatial patterns varied with gap damage types at different sites.The occurrence of gaps was strongly related to slope and topographic position at the semi-natural site,whereas slope,stem density,and human accessibility(proximity to pathways)were the most important factors affecting gap occurrence at the managed sites.We suggest that gap-based silvicultural treatments and natural disturbances regimes conjoin,highlighting interactions with other factors such as microsite conditions,non-tree vegetation and more.

Spatiotemporal variation and correlation of soil enzyme activities and soil physicochemical properties in canopy gaps of the Tianshan Mountains,Northwest China

The study of the heterogeneity of soil enzyme activities at different sampling locations in canopy gaps will help understand the influence mechanism of canopy gaps on soil ecological processes.In this paper,we analyzed the spatiotemporal variation of soil enzyme activities and soil physicochemical properties at different sampling locations(closed canopy,expanded edge,canopy edge,gap center)in different sampling time(December,February,April,June,August,and October)on the northern slope of the Tianshan Mountains,Northwest China.The results showed that soil catalase,cellulase,sucrase,and acid phosphatase activities were relatively high from June to October and low from December to April,and most of soil enzyme activities were higher at closed canopy than at gap center.Soil urease activity was high during December-February.The soil temperature reached the highest value during June-August and was relatively high at gap center in October,December,and February.Soil water content was significantly higher in December and April than in other months.Soil bulk density was higher at gap center than at closed canopy in December.Soil pH and soil electrical conductivity in most months were higher at closed canopy than at gap center.Soil organic carbon,soil total nitrogen,and soil total phosphorus were generally higher at gap center than at closed canopy.Furthermore,sampling time played a leading role in the dynamic change of soil enzyme activity.The key factors affecting soil enzyme activity were soil temperature and soil water content,which were governed by canopy gaps.These results provide important support for further understanding the influence mechanism of forest ecosystem management and conservation on the Tianshan Mountains.

Spatial correlation of pit and mound topography with canopy gaps in a virgin mixed beech forest, northern Iran

In a reserved forest parcel in a virgin eastern Hyrcanian mixed beech forest,80 ha was surveyed to determine the pit and mound topography,canopy gaps and dead trees.The aim was to investigate the spatial patterns and correlation of pit and mound features with canopy gaps.Seventy-five canopy gaps and 61 pit and mound features were identified.The univariate first order nearest neighbor(R_(CE))and bivariate second order test(Ripley’s K)statistic were applied.R_(CE) statistics highlighted a general aggregation pattern for canopy gaps and pits and mounds,while pits and mounds alone were more clumped.Distances between canopy gaps were 130 m average,whereas distances between pit and mound features and dead trees were 60 and 78 m,respectively.Spatial positive correlation of canopy gaps with pits and mounds were observed with all distances.The result of spatial correlations between canopy gaps with pits and mounds confirmed that windthrows cause micro successions in fallen tree ecosystem-scale correlated with gap phase dynamics in the forest community-scale.

Natural regeneration of oriental beech(Fagus orientalis Lipsky)trees in canopy gaps and under closed canopy in a forest in northern Iran

For developing nature-based silvicultural practices in a beech forest to promote, abundance, height, vitality, and preferred growth form, regenerated trees growing in gaps were compared with those under closed canopies. A systematic 50 ×50 m grid was plotted in a beech stand in the Kheyrud Experimental Forest for selecting trees to measure variables in gaps and under closed canopies. Abundance and mean height of regenerated beech trees were significantly higher in closed canopies than in canopy gaps. Beech seedlings with excurrent growth were significantly taller within regeneration patches under closed canopy. Moreover, regenerated trees with high vitality were more abundant in closed canopy areas than in gaps. Thus, beech regeneration should improve under closed canopies; hence, gaps in a near natural forest should be created only after adequate regeneration and appropriate growth under the parent tree in a closed canopy area is ensured. The results of this research have profound implications for the sustainable management of the forest and for ensuring sustainable beech regeneration. The presence of a closed canopy cover likely will reduce potential stresses on oriental beech regeneration.

Effect of canopy gap size and ecological factors on species diversity and beech seedlings in managed beech stands in Hyrcanian forests

We studied the species diversity of the herb layer and ecological factors in harvest-created gaps in beech stands under a single-tree selection system in Northern Iran. To determine diversity, the number of beech seedlings, and other ecological factors, 16 gaps were selected and subplots of 5 m2 were positioned at the centre and at the cardinal points of each gap. Species richness and Simpson diversity index increased with increasing gap area as did numbers of seedlings. With increasing humus layer thickness, species richness declined but the Hill evenness index increased. Species richness increased with increasing light availability. There was no relationship between crown radii of beech trees and diversity indices. Correlations between environmental factors and numbers of individuals of some species in the herb layer were not significant except in a few cases. The results help explain the effects of man-made gaps on the dynamics of managed beech stands and this benefits evaluation of silvicultural operating plans.

Interception of sulfate deposition from a closed canopy to a forest gap edge canopy in a subalpine dragon spruce plantation

Reducing the threats of sulfate ion(SO42-)deposition to terrestrial ecosystems is a great challenge.The canopy interception effect on SO42-deposition has been well documented,but the interception efficiency of the gap edge remains unknown.Therefore,a subalpine dragon spruce(Picea asperata)plantation was evaluated in the upper reaches of the Yangtze River.The dynamics of the SO42-concentration in the throughfall were investigated from the gap edge to the closed canopy during the rainfall and snowfall periods from August 2015 to July 2016.The annual input of SO42-totaled 2.56 kg/ha through rainfall and 0.69 kg/ha through snowfall.The total annual net interception fluxes(NIFs)of SO42-at the gap edge and in the closed canopy were 1.48 kg/ha and 0.66 kg/ha,respectively,and the net interception ratios(NIRs)accounted for 45.40%and 20.25%,respectively.The NIF and the NIR of SO42-at the gap edge were higher than those in the closed canopy.Therefore,the results suggested that a significant amount of SO42-deposition was intercepted by the tree canopy in the subalpine plantation,with more SO42-deposition at the gap edge than in the closed canopy,which is beneficial for improving the water quality in the upper reaches of the Yangtze River via forest management.

Species diversity, regeneration and dominance as influenced by canopy gaps and their characteristics in tropical evergreen forests of Western Ghats, India

Canopy gaps play a significant role in maintaining structure and composition of tropical forests. This study was carried out in tropical evergreen forests of central Western Ghats in India to understand the influence of canopy gap size and the relationship of gap regime attributes to diversity measures and regeneration. The average gap size in the study area was found to be 396 m2 and around half of gaps were 4–8 years old. Gaps created by natural single tree fall were smaller in size but significantly higher in number. Diversity and regeneration of woody species were compared with canopy gaps and intact vegetation. Species richness and diversity was higher in gaps than in intact vegetation. Macaranga peltata, a shade intolerant species dominated gaps while intact vegetation was dominated by shade tolerant Kingiodendron pinnatum.Gap size significantly influenced species diversity and regeneration. Gap area and age were significantly and negatively correlated with diversity measures but positively correlated with regeneration. Among all the attributes of gaps, regeneration was significantly positively correlated with light intensity. Gaps maintained species diversity and favored regeneration of woody species. In addition to gap size and age, other gap ecological attributes also affected species diversity and regeneration.

基于信息熵和Canopy-K-Means算法的货车驾驶风格识别

为识别货车的激进驾驶行为,保障货车行车安全,提出1种基于信息熵和Canopy-K-Means算法的货车驾驶风格识别方法。首先,从货车自然驾驶数据中提取出604个驾驶片段,根据信息熵理论计算各个驾驶片段的速度熵值、横向加速度熵值和纵向加速度熵值,构成货车驾驶风格表征指标集;其次,针对K-Means算法的聚类数量主观选取、初始聚类中心随机选取的问题,使用Canopy算法改进K-Means算法(Canopy-K-Means算法);最后,分别使用K-Means算法和Canopy-K-Means算法对货车驾驶风格进行识别。研究结果显示,Canopy-K-Means算法的轮廓系数和Calinski-Harabasz指数均大于K-Means算法,表现出更优的聚类性能。根据Canopy-K-Means算法,可将货车驾驶风格分为沉稳型、常规型和激进型3类,其中激进型货车驾驶风格的指标熵值和极差均较大,存在较高的安全隐患,需要引起相关部门的高度重视。

Canopy gap characteristics and its influence on the regeneration of broad-leaved Korean pine forests in Changbai Mountain

With the concem of regcneration, characteristics of canopy gaps in broad-leaved Korean pine forest were studied.The areas of actual gap, expanded gap and maximum gap were analyzed respectively. The species composition, number, origin,decayed class and sizes of gap makers were studied comprehensively. The comparative studies of regencration inside and outside of canopy gap showed that the density of regeneration inside canopy gaps was 30% higher than that outside canopy gaps. The specific species regeneration response to canopy gap varied greatly. Pinus koraiensis, Picea jezoensis Frarinlis nla)ldshurica, JItghI)ls )nalJholu-i`a and Acer mono generally did not response to canopy gap disturbance. The Regeneration Importantce Valuc (RIV) of Abies nephrolepis, Ulmus Japonica increased with canopy gap disturbance. RIV of Tilia amurensis, Acer madshurica and Ulmus laciniata decreased with canopy gap disturbance. Canopy gap disturbance was not strong enough to result in the regeneration of some rpecies of shade intolerance such as Larix olgensis, Betula platyphylla.

共混GAP基含能热塑性弹性体的氢键行为与力学性能

为了改善GAP热塑性弹性体的力学性能,采用了DSC、低场核磁测试、静态力学测试和动态力学测试的方法对两种异氰酸酯固化的弹性体共混体系的氢键行为和力学性能进行分析,建立微观结构与宏观性能的关系。结果表明,由于分子结构原因,HMDI固化的GAP热塑性弹性体和IPDI固化的弹性体显示出不同的氢键行为和力学性能,通过物理共混得到了兼具抗拉强度及断裂延伸率的弹性体,50℃下抗拉强度高于1.5MPa,-40℃下延伸率不低于300%,相较于纯HMDI固化的弹性体,低温延伸率提升了约150%,IPDI固化的弹性体高温抗拉强度提升了约1.4MPa,说明通过共混可得到性能更为均衡的含能热塑性弹性体。

基于Roussouly分型的脊柱形态和GAP评分对成人脊柱畸形术后临床疗效的影响

目的评估成人脊柱畸形(ASD)手术前后的Roussouly矢状面脊柱形态及全脊柱序列比例(GAP)评分对术后临床疗效的影响。方法回顾性分析2016年1月至2021年12月在宁夏医科大学总医院行手术治疗的72例ASD患者临床资料,其中男性20例,女性52例,年龄(46.9±19.0)岁。将纳入患者按照“当前”[依据骶骨倾斜角(SS)]和“理论”[依据骨盆入射角(PI)]Roussouly分型脊柱形态进行划分。根据一个恒定参数(PI)判断出患者“理论”形态,然后将此种类型的理想形态参数与实际参数作对比,若术后3个月患者的“当前”Roussouly脊柱形态与其“理论”Roussouly脊柱形态各项参数均符合则归入匹配组,否则归入非匹配组。根据相关参数计算两组患者手术前后GAP评分,并收集术前、术后3个月和末次随访时的疼痛视觉模拟评分(VAS)、Oswestry功能障碍指数(ODI)及术前和末次随访时SRS-22评分(包括总分、疼痛、功能、自我形象、心理健康和治疗满意度),同时记录患者随访时机械并发症发生情况。比较两组患者的影像学参数、GAP评分、临床疗效评分及机械并发症中的差异。结果72例ASD患者术前以RoussoulyⅠ型和Ⅱ型脊柱形态为主,术后以RoussoulyⅡ型和Ⅲ型为主。所有患者术后影像学参数和临床疗效评分较术前均得到改善(P均<0.05)。组间比较,非匹配组末次随访骨盆倾斜角和躯干整体倾斜角大于匹配组(P均<0.05),术后3个月及末次随访,匹配组GAP评分均低于非匹配组(P均<0.05),匹配组较非匹配组在术后3个月和末次随访有更好的VAS评分、ODI评分及SRS-22评分(包括总分、疼痛、功能和治疗满意度)(P均<0.05)。匹配组术后机械并发症发生率更低(P<0.05),腰椎前凸顶点位于理想位置可降低机械并发症发生率。结论ASD术后脊柱矢状面匹配理想Roussouly分型的患者临床疗效和GAP评分更好、机械并发症发生率更低,PI术中应尽可能矫正至理想Roussouly分型脊柱形态。

基于改进的Canopy-k-means的大跨屋盖表面风荷载分区方法

针对k-means聚类算法在大跨屋盖结构表面风荷载分区计算中,聚类数k值随机选取容易导致结果不稳定和计算效率低等问题,提出改进的Canopy-k-means聚类算法。首先,引入Canopy算法并对其初始阈值和聚类中心的选取方式进行改进,减少初始值选取的盲目性,以提高风荷载分区结果的可靠性;其次,通过改进Canopy算法对风荷载数据集进行预处理,快速准确地确定聚类数k值;第三,将改进Canopy算法与k-means结合使用,实现最优分类数k值的精准识别,使得改进的Canopy-k-means聚类算法进行大跨屋盖结构表面风荷载分区时能够快速准确地得到分区结果;最后,以一大跨柱面屋盖干煤棚结构为例,基于风洞试验所得结构表面风荷载数据测试结果,采用所提改进的Canopy-k-means聚类算法对其表面风荷载进行分区计算。结果表明,采用改进的Canopy-k-means聚类算法,将0°、50°和90°风向角时大跨屋盖表面风荷载划分为了3个不同的分区,其对应的SD值分别为2.36、3.51和2.52,较传统k-means聚类算法所得对应值明显降低,类内紧凑性和类间分散性明显提升。所提改进Canopy-k-means聚类算法能够快速准确地得到最优分区结果,对大跨屋盖表面风荷载分区具有工程参考价值。

核电站控制棒驱动机构Canopy焊缝焊接温度场和应力-应变场模拟

目的研究机加工和拉拔2种成形方式下得到的填充环对Canopy焊缝的影响,获取焊接焊缝成形、焊接残余应力和变形的相关数据,以指导Canopy焊缝焊接工艺。方法采用数值模拟的方法,建立Canopy焊缝焊接数值分析模型,模拟焊接温度场、焊接残余应力和焊接残余变形。结果拉拔成形环焊接熔池高度为9 mm,机加工成形环焊接熔池高度为8.3 mm;机加工成形环焊接最大残余应力为255.6 MPa,而拉拔成形环焊接最大残余应力为277.8 MPa,均出现在管座紧贴焊缝的位置;机加工成形环焊接残余变形为0.19 mm,拉拔成形环焊接残余变形为0.186 mm,最大残余变形均出现在焊接起始位置附近,在焊缝与管座交接的位置。结论熔池形貌直接影响了热影响区域的大小,拉拔Y型环焊接熔池高度更大,焊接的热影响区域更大;拉拔Y型环焊接残余应力略大于机加工Y型环焊接残余应力;机加工成形环和拉拔成形环焊接残余变形相近。