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Determination of Tramadol in Human Serum by Capillary Electrophoresis with the End-Column Electrochemiluminescence Detection 被引量:3
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作者 Caiyun Zhang Tao Liu +1 位作者 Xiaoli Zhang Erbao Liu 《Open Journal of Biophysics》 2013年第2期121-127,共7页
A capillary electrophoresis (CE) coupled with end-column electrochemiluminescence (ECL) detection method for the analysis of tramadol (TMD) has been investigated. ECL detection was working electrode biased at 1.2 V in... A capillary electrophoresis (CE) coupled with end-column electrochemiluminescence (ECL) detection method for the analysis of tramadol (TMD) has been investigated. ECL detection was working electrode biased at 1.2 V in a 20mmol·L-1 sodium phosphate buffer (pH = 8.0) containing 5 mmol·L-1 Ru (where bpy = 2,2’-bipyridyl). Linear correlation (r ≥ 0.997) between ECL intensity and drug concentration was obtained in the range 3 × 10-4 - 6 × 10-6 mol·L-1. The limits of detection (LODs) for tramadol in water was 3.012 × 10-8 mol·L-1(S/N = 3). The relative standard deviation values on peak size (10-5 mol·L-1 level) and migration time for the tramadol were 4.58% and 1.39% (n = 10), respectively. Applicability of the CE-ECL method to the analysis of human serum spiked with tramadol was 展开更多
关键词 capillary electrophoresis ELECTROCHEMILUMINESCENCE TRAMADOL HYDROCHLORIDE Human Serum
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Interactions Between Thrombin and Natural Proudcts of Coreopsis tinctoria Nuttt. and Cistanche deserticola Ma. in Capillary Zone Electrophoresis 被引量:1
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作者 刘一 张媛 +3 位作者 刘晓明 凌笑梅 屠鹏飞 崔景荣 《Journal of Chinese Pharmaceutical Sciences》 CAS 2006年第1期38-44,共7页
Aim A capillary zone electrophoretic method (CZE) was used to determine the interactions between natural products and thrombin. Methods Samples containing natural products and thrombin at various ratios were incubat... Aim A capillary zone electrophoretic method (CZE) was used to determine the interactions between natural products and thrombin. Methods Samples containing natural products and thrombin at various ratios were incubated at 25 ℃ and then were separated by CZE with Tris-acetate buffer at pH 7.2. Each run could be accomplished within 5 min. Results In CZE, the peak width broadened due to the affinity interaction between natural products and thrombin. Compared with positive and negative control, the natural products (CB-1, CB-2) from Coreopsis tinctoria Nuttt. interacted with thrombin; CB-3 from Coreopsis tinctoria Nuttt. and HC-1, HC-2, HC-3 from Cistanche deserticola Ma. did not bind to thrombin. Both qualification and quantification characterizations of the binding were determined. Conclusion The established method is capable of sensitive and fast determination of natural products and thrombin interactions, it can be employed as an alternative method. 展开更多
关键词 capillary zone electrophoresis Coreopsis tinctoria Nuttt. Cistanche deserticola Ma INTERACTIONS THROMBIN
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Enantioseparation of Several PharmaceuticalRacemates with High PerformanceCapillary electrophoresis
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作者 李方 靳慧 +2 位作者 戴荣继 顾峻岭 傅若农 《Journal of Beijing Institute of Technology》 EI CAS 1997年第3期239-243,共5页
With high performance capillary electrophoresis using -cyclodextrin or its deriveatives as the chiral selectors, five pairs of drug enantiomers were separated, The PH of the back- gmund electrolyte and the chiral sele... With high performance capillary electrophoresis using -cyclodextrin or its deriveatives as the chiral selectors, five pairs of drug enantiomers were separated, The PH of the back- gmund electrolyte and the chiral selector concentrations were optimized; and the effect of organic modifier on separation of chlorpheniramine enantiomers was also inver 展开更多
关键词 capillary electrophoresis ENANTIOSEPARATION chiral drugs
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A Peptides Migration Model in capillary Zone Electrophoresis
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作者 梁恒 王正刚 +2 位作者 顾峻岭 傅若农 林炳承 《Journal of Beijing Institute of Technology》 EI CAS 1996年第1期35-39,共5页
A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass ... A peptides migration model based on the principle of mechanics is presented in capillary zone electrophoresis (CZE). It is shown that the migration that the (tr) is a function of electric (Q), relative molecular mass (Mr), conformation parameter (Rc) of peptides and electrophoretic condition parameter(A). The conformation parameter is introduced to characterize multifarious shapes owing to the complex conlormation and the various kinds of macromolecules, where Rc≥1/3. The parameters A and Rc can be obtained from experimental data. The times of migration of the nine standard peptides were measured in pH 2.5buffer on different electrophoretic conditions in CZE. The experimental results agreed well with the theoretical prediction. 展开更多
关键词 capillary zone electrophoresis migration model conformation parameter
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Separation of Nucleotides in Swine Tissues Using Capillary Zone Electrophoresis
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作者 顾峻岭 刘玉 +2 位作者 傅若农 鲁红军 张燕婉 《Journal of Beijing Institute of Technology》 EI CAS 1994年第2期155-161,共7页
Capillary zone electrophoresis has been applied to the analysis of nucleotides. The effects of buffer concentration. pH and other operating conditions on the separation were investigated and optimized. By using the me... Capillary zone electrophoresis has been applied to the analysis of nucleotides. The effects of buffer concentration. pH and other operating conditions on the separation were investigated and optimized. By using the method, separation and identification of nuclotides in swine tissues were completed. 展开更多
关键词 SEPARATION nucleotides/capillary zone electrophoresis
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Simultaneous Determination of Clonidine Hydrochloride,Hydrochlorothiazide, and Rutin in Zhenju Jiangya Tablet by Capillary Electrophoresis 被引量:4
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作者 苏圣民 郁韵秋 《Journal of Chinese Pharmaceutical Sciences》 CAS 2005年第3期173-175,共3页
Aim To develop a method for the determination of three drug components: clonidine hydrochloride, hydrochlorothiazide and rutin in Zhenju Jiangya tablet. Methods An uncoated capillary tube was used to analyze under 20... Aim To develop a method for the determination of three drug components: clonidine hydrochloride, hydrochlorothiazide and rutin in Zhenju Jiangya tablet. Methods An uncoated capillary tube was used to analyze under 20 kV voltage at 20 ℃. The samples were introduced into the capillary tube by hydrodynamic mode applying 50 kPa for 5 s and detected at 210 nm. Results The linear ranges of clonidine hydrochlofide, hydrochlorothiazide, and rutin were 10 μg· mL^-1 - 100μg· mL^-1, 30μg· mL^-1 - 300 μg· mL^- 1, and 30μg · mL^-1 - 300μg · mL^-1, respectively. Inter-day and intra-day RSD were all below 10.5%. The recoveries were 94.96% for clonidine hydrochloride, 84.45% for hydroehlorothiazide, and 89.88 % for rutin. Conclusion Clonidine hydrochloride, hydrochlorothiazide, and rutin are baseline separated. The method is simple and rapid for simultaneous determination of the three drug components in Zhenju Jiangya tablet. 展开更多
关键词 capillary electrophoresis clonidine hydrochlofide HYDROCHLOROTHIAZIDE RUTIN ZhenjuJiangya tablet
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A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector 被引量:19
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作者 Chen, ZG Mo, JYM +3 位作者 Yang, XY Wang, LS Mei, XT Zhang, MS 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第3期231-234,共4页
A new capillary electrophoresis apparatus was designed. Piezoelectric ceramics transformer technology was first applied in capillary electrophoresis, a high voltage and stable source was made. Amperometric detector wa... A new capillary electrophoresis apparatus was designed. Piezoelectric ceramics transformer technology was first applied in capillary electrophoresis, a high voltage and stable source was made. Amperometric detector was used in which the working electrode was closely opposite to the end of capillary. The apparatus was characterized in good reproducibility, safety and very low cost. 展开更多
关键词 capillary electrophoresis piezoelectric ceramics amperometric detector
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Simultaneous Detection of 13 Key Bacterial Respiratory Pathogens by Combination of Multiplex PCR and Capillary Electrophoresis 被引量:9
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作者 JIANG Lu Xi REN Hong Yu +5 位作者 ZHOU Hai Jian ZHAO Si Hong HOU Bo Yan YAN Jian Ping QIN Tian CHEN Yu 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2017年第8期549-561,共13页
Objective Lower respiratory tract infections continue to pose a significant threat to human health. It is important to accurately and rapidly detect respiratory bacteria. To compensate for the limits of current respir... Objective Lower respiratory tract infections continue to pose a significant threat to human health. It is important to accurately and rapidly detect respiratory bacteria. To compensate for the limits of current respiratory bacteria detection methods, we developed a combination of multiplex polymerase chain reaction (PCR) and capillary electrophoresis (MPCE) assay to detect thirteen bacterial pathogens responsible for lower respiratory tract infections, including Streptococcus pneumoniae, Haemophilus influenzae, Moraxella catorrholis, Pseudomonas aeruginosa, Klebsiella pneumoniae, Escherichia coli, Staphylococcus aureus, Mycoplasma pneumoniae, Legionella spp., Bordetella pertussis, Mycobacterium tuberculosis complex, Corynebactefium diphthefiae, and Streptococcus pyogenes. Methods Three multiplex PCR reactions were built, and the products were analyzed by capillary electrophoresis using the high-throughput DNA analyzer. The specificity of the MPCE assay was examined and the detection limit was evaluated using DNA samples from each bacterial strain and the simulative samples of each strain. This assay was further evaluated using 152 clinical specimens and compared with real-time PCR reactions. For this assay, three nested-multiplex-PCRs were used to detect these clinical specimens. Results The detection limits of the MPCE assay for the 13 pathogens were very low and ranged from 10-7 to 10-2 ng/μL. Furthermore, analysis of the 252 clinical specimens yielded a specificity ranging from 96.5%-100.0%, and a sensitivity of 100.0% for the 13 pathogens. Conclusion This study revealed that the MPCE with high specificity and sensitivity. This assay survey of respiratory pathogens. assay is a rapid, reliable, and high-throughput method has great potential in the molecular epidemiological. 展开更多
关键词 Respiratory pathogens Lower respiratory tract infections Multiplex PCR capillary electrophoresis
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p-Hydrazinobenzenesulfonic Acid Derivatives of Carbohydrates andTheir Capillary Zone Electrophoresis 被引量:6
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作者 Wang, XY Chen, Y 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第12期1081-1084,共4页
p-Hydrazinobenzenesulfonic acid is explored as a novel ultraviolet labeling reagent for capillary electrophoresis (CE) of mono- and disaccharides. The labeling reaction takes less than 10 minutes and introduces both o... p-Hydrazinobenzenesulfonic acid is explored as a novel ultraviolet labeling reagent for capillary electrophoresis (CE) of mono- and disaccharides. The labeling reaction takes less than 10 minutes and introduces both of absorption and charge groups into the sugars. 展开更多
关键词 p-hydrazinobenzenesulfonic acid CARBOHYDRATE DERIVATIZATION capillary zone electrophoresis
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Chiral Separation of Chlorpheniramine by Capillary Electrophoresis *L
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作者 卢光菊 顾峻岭 +1 位作者 张健 傅若农 《Journal of Beijing Institute of Technology》 EI CAS 1999年第1期61-65,共5页
Aim To study the chiral separation of chlorpheniramine(Chp) by using a mixture of β CD and glutamate β CD as the chiral additive in CE. Methods Mixture of β cyclodextrin and glutamate β cyc... Aim To study the chiral separation of chlorpheniramine(Chp) by using a mixture of β CD and glutamate β CD as the chiral additive in CE. Methods Mixture of β cyclodextrin and glutamate β cyclodextrin was used as a chiral selector to the separation of chlorpheniramine. The effects of the concentrations of β cyclodextrin and glutamate β cyclodextrin, the voltage and the pH of buffers on the separation of chlorpheniramine were studied. Results The chiral recognization of the mixed chiral selector was better than that of a single selector. At pH below 4, the pH of buffers did not affect the separation and the separation of chlorpheniramine had good reproducibility. Conclusion Using a mixture of β CD and Glu β CD as chiral selector is useful for the enantioseparation of Chp in CE. 展开更多
关键词 capillary electrophoresis enantiomer separation cyclodextrin additives CHLORPHENIRAMINE
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Capillary electrophoresis with electrochemiluminescence detection for the analysis of quinolone drugs and pharmacokinetics study 被引量:5
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作者 Yan Ming Liu Jun Tao Cao Hui Wang 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第8期962-964,共3页
A novel method for the determination of two quinolone drugs norfloxacin (NOR) and levofloxacin (LVX) was described by capillary electrophoresis with electrochemiluminescence detection. The good relationship (r ≥... A novel method for the determination of two quinolone drugs norfloxacin (NOR) and levofloxacin (LVX) was described by capillary electrophoresis with electrochemiluminescence detection. The good relationship (r ≥ 0.9991) between peak area and concentration of analytes was established over two orders of magnitude. The limits of detection (LOD, S/N = 3) in standard solution are 4.8 × 10^-7 mol/L for NOR and 6.4 × 10^-7 mol/L for LVX, respectively. The limits of quantitation (LOQ, S/N = 10) in real human urine samples are 1.2 × 10^-6 mol/L for NOR and 1.4 × 10^-6 mol/L for LVX, respectively. The present method was successfully applied to the determination of NOR and LVX in human urine and the studv of oharmacokinetics of NOR. 展开更多
关键词 capillary electrophoresis Electrochemiluminescence detection Quinolone drugs Urine analysis PHARMACOKINETICS
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Recent advances in screening of enzymes inhibitors based on capillary electrophoresis 被引量:5
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作者 Mengxia Cheng Zilin Chen 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2018年第4期226-233,共8页
Capillary electrophoresis with many advantages plays an important role in pharmaceutical analysis and drug screening. This review gives an overview on the recent advances in the developments and applications of capill... Capillary electrophoresis with many advantages plays an important role in pharmaceutical analysis and drug screening. This review gives an overview on the recent advances in the developments and applications of capillary electrophoresis in the field of enzyme inhibitor screening. The period covers 2013 to 2017. Both the pre-capillary enzyme assays and in-capillary enzyme assays which include electrophoretically mediated microanalysis(EMMA) and immobilized enzyme microreactor(IMER) are summarized in this article. 展开更多
关键词 capillary electrophoresis Enzyme inhibitor screening Pre-capillary enzyme assays Electrophoretically mediated microanalysis Immobilized enzyme microreactor
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Determination of Nicotine in Tobacco by Capillary Electrophoresis with Electrochemical Detection 被引量:4
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作者 SUN Jin-ying XU Xiao-yu +1 位作者 YU Huan YOU Tian-yan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2012年第3期415-418,共4页
A sensitive, simple and low-cost method based on capillary electrophoresis(CE) with electrochemical(EC) detection at a carbon fiber microdisk electrode(CFE) was developed for the determination of nicotine. Effec... A sensitive, simple and low-cost method based on capillary electrophoresis(CE) with electrochemical(EC) detection at a carbon fiber microdisk electrode(CFE) was developed for the determination of nicotine. Effects of de- tection potential, concentration and pH value of the phosphate buffer, and injection time as well as separation voltage were investigated. Under the optimized conditions: a detection potential of 1.20 V, 40 rnmol/L phosphate buffer(pH 2.0), a sample injection time of 10 s at 10 kV and a separation voltage of 16 kV, the linear range obtained was from 5.0×10^-7 mol/L to 1.0×10^-4 mol/L with a correlation coefficient of 0.9989 and the limit of detection(LOD, S/N=3) obtained was 5.0×10^-8 mol/L. The method was also used to determine the nicotine in cigarettes. Nicotine amount ranged from 0.211 mg/g to 0.583 mg/g in the pipe tobacco of seven brands of cigarette and the amount in one ciga- rette varied from 0.136 mg/cigarette to 0.428 mg/cigarette. 展开更多
关键词 capillary electrophoresis Electrochemical detection NICOTINE TOBACCO
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A novel method for Co(Ⅱ) and Cu(Ⅱ) analysis by capillary electrophoresis with chemiluminescence detection 被引量:4
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作者 Xiao Ming Guo Xiang Dong Xu +2 位作者 Hui Jing Zhang Yong Gang Hu Jie Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第9期1095-1098,共4页
Based on the fact that some metal ions can catalyze the chemiluminescence(CL)reaction of luminol with K_3Fe(CN)_6,a novel capillary electrophoresis CL method was developed for the determination of Co(Ⅱ)and Cu(Ⅱ).The... Based on the fact that some metal ions can catalyze the chemiluminescence(CL)reaction of luminol with K_3Fe(CN)_6,a novel capillary electrophoresis CL method was developed for the determination of Co(Ⅱ)and Cu(Ⅱ).The separation was carried out with a 10 mmol/L sodium acetate solution containing 0.8 mmol/L luminol and 2.0 mmol/Lα-HIBA(adjusted to pH 4.8 by HAc solution).The post-capillary reagent was 2.0 mmol/L K_3Fe(CN)_6 which was adjusted to pH 13.0 by NaOH solution.Under the optimum conditions,the detection limits(S/N=3)for Co(Ⅱ)and Cu(Ⅱ)were 7.5×10^(-11)mol/L and 7.5×10^(-9)mol/L,with the linear range of 7.5×10^(-9)mol/L to 1.0×10^(-6)mol/L and 7.5×10^(-8)mol/L to 5.0×10^(-5)mol/L, respectively. 展开更多
关键词 capillary electrophoresis CHEMILUMINESCENCE Co(Ⅱ) Cu(Ⅱ)
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Studies on Human Immunoglobulin G from GBS Patient (Ⅲ)-The Determination of Molecular Weight of Human Immunoglobulin G by Capillary SDS Gel Electrophoresis 被引量:5
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作者 Qin Hua RU Yi Ming WANG Guo An LUO(Department of Chemistry. School of Life Science and Engineering,Tsinghua University. Beijing, 100084) 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第1期55-58,共4页
Guillain-Barre syndrome (GBS) is considered to be an autoimmune disorder of peripheralnervous system. In this paper. capillary SDS gel electrophoresis was performed on neutral coatedfused-silica capillary to determine... Guillain-Barre syndrome (GBS) is considered to be an autoimmune disorder of peripheralnervous system. In this paper. capillary SDS gel electrophoresis was performed on neutral coatedfused-silica capillary to determine the molecular weight of purified IgG samples from GBS patient. 展开更多
关键词 Immunoglobulin G Guillain-Barre syndrome capillary SDS gel electrophoresis Molecular weight of protein
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Simultaneous determination of flavonoids and anthraquinones in chrysanthemum by capillary electrophoresis with amperometry detection 被引量:3
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作者 Yin Yan Zhang Zi Cheng Li Jin Kun Zhu Zhi Yong Yang Qing Jiang Wang Pin Gang He Yu Zhi Fang 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第10期1231-1234,共4页
A high-performance capillary electrophoresis with amperometry detection method (CE-AD) has been developed for the analysis of flavonoids and anthraquinones (emodin, kaempferol, apigenin, luteolin and rhein) in chr... A high-performance capillary electrophoresis with amperometry detection method (CE-AD) has been developed for the analysis of flavonoids and anthraquinones (emodin, kaempferol, apigenin, luteolin and rhein) in chrysanthemum. Under optimum conditions, these five analytes were base-line separated within 17 min using a borate-phosphate running buffer (1.5 ×10^-2 mol/L borate-3× 10^-2 mol/L phosphate running buffer, pH 9.0) at a working potential of +0.90 V (vs. SCE) and a separation voltage of 19 kV. The linear relationship between concentration and current response was obtained with detection limits (S/N = 3) ranging from 1.0 × 10^-7 to 2.1 × 10^-7 g/mL for all analytes. This proposed method was successfully used in the analysis of four kinds of chrysanthemum with relatively simple extraction procedures, the assay results were satisfactory. 展开更多
关键词 capillary electrophoresis Amperometry detection Chrysanthemu FLAVONOIDS ANTHRAQUINONES
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Study on Rhizoma Chuanxiong based on capillary electrophoresis with amperometric detection 被引量:3
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作者 Chu, Qing Cui Zhang, Dong Li +1 位作者 Zhang, Hai Tao Ye, Jian Nong 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第2期217-220,共4页
A high-performance capillary electrophoresis with amperometric detection(CE-AD) method has been developed for the analysis of seven bioactive ingredients,namely ferulic acid(FA),vanillin,vanillic acid,p-hydroxybenzoic... A high-performance capillary electrophoresis with amperometric detection(CE-AD) method has been developed for the analysis of seven bioactive ingredients,namely ferulic acid(FA),vanillin,vanillic acid,p-hydroxybenzoic acid,caffeic acid,gallic acid and protocatechuic acid,in Rhizoma Chuanxiong.The effects of several factors such as the acidity and concentration of running buffer,the separation voltage,the applied potential to working electrode and the injection time were investigated.Under the optimum condit... 展开更多
关键词 capillary electrophoresis Amperometric detection Rhizoma Chuanxiong Phenolic acids Electrochemical profiles
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Optimized Separation of Pharmacologically Active Xanthones from Securidaca inappendiculata by Capillary Electrophoresis 被引量:3
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作者 TaoBO XueDongYANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第3期269-272,共4页
A capillary electrophoresis (CE) method has been firstly used for the separation of the therapeutically important xanthones from Securidaca inappendiculata. The separation of the nine xanthones was systematically opt... A capillary electrophoresis (CE) method has been firstly used for the separation of the therapeutically important xanthones from Securidaca inappendiculata. The separation of the nine xanthones was systematically optimized with respect to pH, concentration of running buffers, addition of sulfated b-CD, applied voltage and column temperature. Baseline separation was achieved for the nine xanthones in less than 15 minutes using a background electrolyte consisting of 200 mmol/L borate (pH 9.5) and 10 mmol/L sulfated b-CD. 展开更多
关键词 SEPARATION XANTHONES Securidaca inappendiculata capillary electrophoresis sulfated b-CD. Introduction
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Determination of Magnolol and Honokiol by Non-aqueous Capillary Electrophoresis 被引量:3
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作者 TIAN Yi-ling CHEN Guan-hua 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第3期335-338,共4页
Two active principles in traditional Chinese medicine Magnolia officinalis, magnolol and honokiol, were successfully separated by means of nonaqueous capillary electrophoresis. The effect of the composition of a nonaq... Two active principles in traditional Chinese medicine Magnolia officinalis, magnolol and honokiol, were successfully separated by means of nonaqueous capillary electrophoresis. The effect of the composition of a nonaqueous buffer on column efficiency and resolution, and the effect of acid additives on peak shapes were researched. The separation was conducted with a running buffer in a mixture of methanol/aeetonitrile/formamide ( volume ratio : 1 : 2 : 2 ), in which the concentrations of Tris, acetic acid, and water were 60 retool/L, 0. 04 mmol/L and 5% ( volume fration), respectively, and the pH^* (apperent pH) of the running buffer was 8.96. Magnolol and honokiol were separated on baseline within 20 min. The relative standard deviation of the analytes' concentrations in the sample is 1.32% for magnolol and 1.60% for honokiol, and the recoveries of the spiked sample are 98.4% for magnolol and 98. 0% for honokiol, respectively. 展开更多
关键词 Nonaqueous capillary electrophoresis MAGNOLOL HONOKIOL
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Synthesis and Characterisation of Water-Soluble Carboxymethyl-Cyclodextrin Polymer as Capillary Electrophoresis Chiral Selector 被引量:3
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作者 Xue Yan SHI Rui Fang FAN +2 位作者 Yue Qin ZHANG Jun Ling GU Ruo Nong FU( College of Chemical Engineering and Material Science Beijing Institute of Technology, Beijing 100081) 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第1期69-70,共2页
The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as c... The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as chiral selector. 展开更多
关键词 Carboxymethyl-cyclodextrin polymer capillary electrophoresis chiral selector.
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