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Ascertainment Corrected Prevalence Rate (ACPR) of Leukopenia in Workers Exposed to Benzene in Small-Scale Industries Calculated With Capture-Recapture Methods
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作者 XIA ZHAO-LIN JIN XI-PENG +4 位作者 LU PEI-LIAN GU XUE-QI RONALD E.LAPORTE AND NAOKO TAJIMA(School of Public Health, Post Box 203, Shanghai Medical University,Shanghai 200032, China Department of Epidemiology, Graduate School of Public Health, University of Pit 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 1995年第1期30-34,共5页
ACPRs of leukopenia in peripheral blood of workers exposed to benzene in small-scale industries are calculated using capture-recapture methods. The results from two figures with 6-month apart demonstrate that the ACPR... ACPRs of leukopenia in peripheral blood of workers exposed to benzene in small-scale industries are calculated using capture-recapture methods. The results from two figures with 6-month apart demonstrate that the ACPR in workers exposed to benzene is 36.81(29. 14-44.48)%, significantly higher than that of control 12.71(7.20-18.22)% (P<0.05),with a relative risk of 2.9. The prevalences of 4 cross-sectional investigations in exposure group calculated with routine method are 18.73%, 26.37%, 27.93%, and 36.76% respectively;in controls, 8.38%, 6.85%, 7.94%, and 15.00% respectively and all fall in the range of 95% CI of ACPR. It is suggested that the methods of calculating ACPR by capture-recapture methods is simple, feasible and efficient, with the results more precise than with traditional methods. 展开更多
关键词 ACPR of Leukopenia in Workers Exposed to Benzene in Small-Scale Industries Calculated With capture-recapture methods
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Microstructure and Property of Hypereutectic High Chromium Cast Iron Prepared by Slope Cooling Body-Centrifugal Casting Method 被引量:3
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作者 Zhifu HUANG Jiandong XING Anfeng ZHANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第6期775-778,共4页
In this paper, the ring-type ingot of hypereutectic high Cr cast iron was obtained by slope cooling bodycentrifugal casting method (SC-CCM), and its microstructure and impact toughness were investigated, respectivel... In this paper, the ring-type ingot of hypereutectic high Cr cast iron was obtained by slope cooling bodycentrifugal casting method (SC-CCM), and its microstructure and impact toughness were investigated, respectively. The results indicated that, first, the primary carbides in the microstructure are prominently finer than those in the hypereutectic high Cr cast iron prepared by conventional casting method. Second, in the ring-type ingot, the primary carbides near radial outer field are finer than those near radial inner field; furthermore, there is dividing field in the microstructure. Finally, the impact toughness values of the specimens impacted on the radial outer face and on the radial inner face are improved respectively about 36% and 138% more than that of the hypereutectic high Cr one prepared by conventional casting method. 展开更多
关键词 Slope cooling body-centrifugal casting method Hypereutectic high cr cast iron Primary carbides Microstructure Impact toughness
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Forming Mechanism of Gaseous Defect in Ti-48Al-2Cr-2Nb Exhaust Valves Formed with Permanent Mold Centrifugal Casting Method 被引量:2
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作者 Research Notes Wenbin SHENG, Jingjie GUO, Yanqing SU, Hongsheng DING and Jun JIA School of Materials Science and Engineering, Harbin Institute of Technology. Harbin 150001, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第5期569-571,共3页
A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathemat... A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathematical model of the filling process is established and the forming mechanism of internal gaseous defect is summarized. The results of calculation show that the melt fills the mould with varying cross-section area and inclined angle. The filling speed of the cross-section is a function of filling time. The cross-section area is directly proportional to the filling speed and the inclined angle is inversely proportional to the filling speed at a given rotating speed of the platform. Both of them changes more obvious near the mould entrance. The gaseous defect can be formed in several ways and the centrifugal field has an important influence on the formation of the defect. In addition, the filling process in centrifugal field has been verified by wax experiments and the theoretical analysis are consistent with experimental results. 展开更多
关键词 Forming Mechanism of Gaseous Defect in Ti-48Al-2cr-2Nb Exhaust Valves Formed with Permanent Mold Centrifugal Casting method MOLD TI Al cr
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Urinary Creatinine-Skeletal Muscle Mass Method:A Prediction Equation Based on Computerized Axial Tomography
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作者 ZI-MIAN WANG YUN-GAO SUN AND STEVEN B. HEYMSFIELD (Department of Medicine, Obesity Research Center, St. Luke’s-Roosevelt Hospital, Columbia University College of Physicians and Surgeons,Amsterdam Ave. 14C New York, N. Y., USA)(Obesity Research Center, We 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 1996年第2期185-190,共6页
A classic body composition method is estimation of total body skeletal muscle mass (SM, kg) from 24 h urinary creatinine excretion (Cr, g). Two types of prediction equations were suggested: one assumes a constant SM/C... A classic body composition method is estimation of total body skeletal muscle mass (SM, kg) from 24 h urinary creatinine excretion (Cr, g). Two types of prediction equations were suggested: one assumes a constant SM/Cr ratio; and the other assumes a highly variable SM/Cr ratio. We explored these two extreme possibilities by measuring SM with whole-body computerized axial tomography and collecting Cr during meat-free dietary conditions in 12 healthy young men. Prediction equations were developed in the men that fit these two equation types, SM = 21.8×Cr (SD and CV of SM/Cr ratio, 1.3 kg and 6.0%,respectively) and SM = 18.9 × Cr + 4.1 (r = 0.92, p = 2.55 × 10-5, and SEE = 1.9 kg). The validity of each model is reviewed. This is the first investigation of Cr-SM method using modern techniques for quantifying total body SM mass 展开更多
关键词 Mass cr body SM Urinary creatinine-Skeletal Muscle Mass method
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Enhanced Photocatalytic Properties of Pure and Cr-Modified ZnS Powders Synthesized by Precipitation Method 被引量:1
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作者 Bedour A. Mahammed Luma M. Ahmed 《Journal of Geoscience and Environment Protection》 2017年第10期101-111,共11页
Zinc sulfide photocatalysts doped with chromium (1:1)% were synthesized via precipitation technique. Their characteristics were studied by X-ray diffraction (XRD), AFM and Florescence spectrometer. The photocatalytic ... Zinc sulfide photocatalysts doped with chromium (1:1)% were synthesized via precipitation technique. Their characteristics were studied by X-ray diffraction (XRD), AFM and Florescence spectrometer. The photocatalytic reaction was applied under light intensity equal to 1.45 × 10-7 Einstein mol-1 to investigate the kinetics and thermodynamic parameters for photo-decolorization of reactive black 5 dye in collide solution of bare and Cr-doped ZnS. The mean crystal size and particle size for bare ZnS are more than those values for prepared Cr loaded ZnS. 展开更多
关键词 cr-Loaded ZNS NANOPOWDERS Reactive Black 5 DYE AZO DYE Precipitation method
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吸附法处理含Cr(Ⅵ)废水研究进展
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作者 麻倩倩 苏秀霞 +1 位作者 张婧 常瑞琪 《化工新型材料》 CAS CSCD 北大核心 2024年第3期66-70,共5页
近年来随着工业的快速发展,环境污染问题日益突出,其中含Cr(Ⅵ)废水的排放对人类和环境造成了严重威害。因此,寻找合适的方法净化水环境中的Cr(Ⅵ)不容忽视。目前,吸附法被认为是处理含Cr(Ⅵ)废水最有前途和最有效的技术之一,开发经济... 近年来随着工业的快速发展,环境污染问题日益突出,其中含Cr(Ⅵ)废水的排放对人类和环境造成了严重威害。因此,寻找合适的方法净化水环境中的Cr(Ⅵ)不容忽视。目前,吸附法被认为是处理含Cr(Ⅵ)废水最有前途和最有效的技术之一,开发经济高效的吸附剂是吸附法处理含Cr(Ⅵ)废水的关键。综述了吸附法处理含Cr(Ⅵ)废水的研究进展,指出了吸附法处理含Cr(Ⅵ)废水面临的挑战并展望了其未来发展趋势。 展开更多
关键词 cr(Ⅵ) 污染 废水 吸附法 吸附剂
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乳液界面法制备ZnCl_(2)/NH_(2)-MIL-125(Ti)复合材料增强光催化还原Cr(Ⅵ)的研究
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作者 陈志月 杨启鹏 +2 位作者 郭恒 谭伟强 关静 《青岛理工大学学报》 CAS 2024年第5期94-103,共10页
利用乳液界面法制备的复合材料在增强光催化活性方面具有显著优势。通过乳液界面法制备了ZnCl_(2)/NH_(2)-MIL-125(Ti)复合光催化材料,利用X射线粉末衍射、傅里叶变换红外光谱、扫描电子显微镜、X射线光电子能谱、比表面积及孔隙分析、... 利用乳液界面法制备的复合材料在增强光催化活性方面具有显著优势。通过乳液界面法制备了ZnCl_(2)/NH_(2)-MIL-125(Ti)复合光催化材料,利用X射线粉末衍射、傅里叶变换红外光谱、扫描电子显微镜、X射线光电子能谱、比表面积及孔隙分析、紫外-可见漫反射光谱等分析方法对催化剂结构进行了表征,考察了复合材料光催化还原六价铬(Cr(Ⅵ))的性能,探讨了光催化反应机理及催化剂的重复利用性。结果表明,乳液界面法会显著影响ZnCl_(2)/NH_(2)-MIL-125(Ti)复合材料的光电性质,当ZnCl_(2)和NH_(2)-MIL-125(Ti)掺杂质量比为1∶6时,在催化剂质量浓度为0.4 g/L、pH=2、甲醇添加量为0.5 mL条件下,复合材料紫外光催化还原Cr(Ⅵ)的效率最高可达95%,循环使用5次后还原效率为75%。 展开更多
关键词 乳液界面法 ZnCl_(2)/NH_(2)-MIL-125(Ti) 光催化 六价铬(cr(Ⅵ))
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A Data Treatment Method of Carbon Saturated Solubility in Fe-C-Cr Melt
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作者 Haichuan Wang Shijun Wang +1 位作者 Yuanchi Dong Wenchao Li 《Journal of University of Science and Technology Beijing》 CSCD 2002年第1期16-19,共4页
Based on the current situation of studying the thermodynamic property of Fe-C-Cr melt using the carbon saturated solubility, an experimental data treatment method of the carbon saturated solubility was put forward. Wi... Based on the current situation of studying the thermodynamic property of Fe-C-Cr melt using the carbon saturated solubility, an experimental data treatment method of the carbon saturated solubility was put forward. With this method a linear relationship ex- pression of the carbon saturated solubility in Fe-C-Cr melt was obtained, which intercept is dependent on temperature and independent of third component [Cr], but which slope is dependent on third component [Cr] and independent of temperature. Through this expression activity interaction coefficients at different temperatures were calculated and the relationship between activity interaction coefficients and temperature is also obtained. 展开更多
关键词 data treatment method intercept slope carbon-saturated solubility Fe-C-cr melt
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Cr^(3+)掺杂对Mn_(3)O_(4)结构、形貌以及磁电性能的影响
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作者 崔梦范 王松伟 +4 位作者 张鑫 杨瑞鑫 张亚乐 邓胜龙 周欣 《桂林电子科技大学学报》 2024年第3期292-298,共7页
为了探究Cr^(3+)掺杂对Mn_(3)O_(4)体系磁电效应的影响,采用传统固相法成功制备了Mn_(3)O_(4)及Mn_(1.8)Cr_(1.2)O_(4)的单相多晶样品。X射线衍射及精修结果表明,掺杂前后存在晶体结构的改变,由四方晶系转变为立方晶系,其空间群由I41/am... 为了探究Cr^(3+)掺杂对Mn_(3)O_(4)体系磁电效应的影响,采用传统固相法成功制备了Mn_(3)O_(4)及Mn_(1.8)Cr_(1.2)O_(4)的单相多晶样品。X射线衍射及精修结果表明,掺杂前后存在晶体结构的改变,由四方晶系转变为立方晶系,其空间群由I41/amd变为Fd3m。场发射扫描电镜结果显示,掺杂前样品的晶粒呈紧密的镶嵌结构,掺杂后样品呈离散的五面体及八面体形貌,且尺寸约是掺杂前的1/8。磁性研究结果表明,掺杂前、后样品Yafet-Kittel型亚铁磁相变温度由43 K提高到60 K,这源自Cr^(3+)掺杂使Mn^(3+)(Cr^(3+))/Mn^(2+)—O键长缩短,Mn^(3+)(Cr^(3+))—O—Mn^(3+)(Cr^(3+))键角增大,磁相互作用增强。此外,掺杂后矫顽力显著降低,这可根据离散的晶粒间作用力减小来理解。介电效应研究发现,掺杂前、后样品在磁相变点附近存在不随频率移动的介电异常峰,表明该体系存在与磁序相关的铁电极化,这源自体系的非线性磁结构。 展开更多
关键词 固相法 cr^(3+)掺杂 磁性测量 介电测量 磁电耦合
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A synthetic differencein-differences model for the influence of CR Express on Chongqing's economy
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作者 Rong Zhang Qi Li 《Railway Sciences》 2024年第3期295-310,共16页
Purpose-The China-Europe Railway Express(CR Express)in Chongqing has operated regularly and undergone large-scale development.Its impact on Chongqing's economic growth has become increasingly evident,necessitating... Purpose-The China-Europe Railway Express(CR Express)in Chongqing has operated regularly and undergone large-scale development.Its impact on Chongqing's economic growth has become increasingly evident,necessitating further research in this field.Design/methodology/approach-This study employs the opening of CR Express as a quasi-natural experiment,designating Chongqing,which inaugurated the CR Express in 2011,as the treatment group.13 provinces and cities that had not yet opened the CR Express until 2017 were selected as the control group.Utilizing panel data from 14 provinces across China spanning from 2006 to 2017,the synthetic control method(SCM)is employed to synthetically construct Chongqing.To quantify the difference in economic development levels between Chongqing with the operation of the CR express and Chongqing without its operation.Key metrics such as gross domestic product(GDP),per capita GDP,total retail sales of consumer goods,import and export value and the proportions of the secondary and tertiary industries are employed to measure urban economic development capabilities.Chongqing is designated as the experimental group,and a double-difference model is constructed to regress the operation of the CR Express against economic development capabilities.Robustness tests are conducted to validate the analytical results.Findings-The results indicate that,compared to provinces without the operation of the CR Express,the initiation of the CR Express in Chongqing significantly enhances the economic development level of the city.The opening of the CR Express exhibits a pronounced positive impact on Chongqing's economic development,and these findings remain robust and effective even after parallel trend tests and placebo tests.Originalitylvalue-The study represents an expansion of the theoretical framework.In contrast to previous studies that relied on a single indicator such as GDP,this study selects six indicators from the dimensions of economy,trade and industry to measure regional economic development capabilities.Furthermore,employing the grey relational analysis method,the study screens these indicators,thereby providing a theoretical basis for the selection of indicators for measuring regional economic development capabilities. 展开更多
关键词 cr Express Regional economic development Synthetic model Difference-indifferences method Papertype Research paper
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大尺寸优质Cr^(3+)∶BeAl_(2)O_(4)晶体生长与性能研究
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作者 王鸿雁 王世武 +5 位作者 聂奕 张行愚 张芳 许辉 李瑞茂 匡永飞 《人工晶体学报》 CAS 北大核心 2024年第6期947-952,共6页
本文采用感应加热提拉法结合上称重自动控径技术,成功生长出大尺寸、高质量的翠绿宝石(Cr^(3+)∶BeAl_(2)O_(4))晶体。晶坯等径圆柱体尺寸达到ϕ70 mm×140 mm,晶坯质量超过2800 g。通过冷光源照射晶坯,发现晶坯中心区域ϕ10~15 mm存... 本文采用感应加热提拉法结合上称重自动控径技术,成功生长出大尺寸、高质量的翠绿宝石(Cr^(3+)∶BeAl_(2)O_(4))晶体。晶坯等径圆柱体尺寸达到ϕ70 mm×140 mm,晶坯质量超过2800 g。通过冷光源照射晶坯,发现晶坯中心区域ϕ10~15 mm存在气泡。采用5 mW绿光激光照射ϕ8 mm×130 mm的翠绿宝石晶体棒,晶体内部无散射颗粒。利用Zygo激光平面干涉仪对晶体棒进行测试,波前畸变为0.3λ@632.8 nm。用电感耦合等离子体原子发射光谱法测定了翠绿宝石晶体的铬离子掺杂浓度,并计算出轴向浓度梯度为0.5×10^(-4)~1.9×10^(-4)cm^(-1)(摩尔分数)。用Perkin Elmer Lambda-950紫外可见近红外分光光度计测试了不同掺杂浓度的翠绿宝石晶体在室温下的吸收光谱,并计算了吸收系数。这些研究结果为翠绿宝石晶体的应用提供了重要的基础数据。 展开更多
关键词 翠绿宝石(cr^(3+)∶BeAl_(2)O_(4))晶体 提拉法 自动控径技术 波前畸变 浓度梯度 吸收系数
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食品中Cr(Ⅲ)和Cr(Ⅵ)分离及ICP-MS法测定研究 被引量:8
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作者 黄冬根 廖世军 贺咏梅 《食品科学》 EI CAS CSCD 北大核心 2005年第7期172-174,共3页
本文报道了食品中Cr(Ⅲ)和Cr(Ⅵ)分离并用ICP-MS仪进行测定方法.食品经微波消化后,用离子交换树脂进行交换,以45Sc为内标元素,采用内标法进行测定。该方法加标回收率是98.6%~99.6%,相对标准偏差RSD是2.1%~3.5%,检测限是0.006~0.01ng/... 本文报道了食品中Cr(Ⅲ)和Cr(Ⅵ)分离并用ICP-MS仪进行测定方法.食品经微波消化后,用离子交换树脂进行交换,以45Sc为内标元素,采用内标法进行测定。该方法加标回收率是98.6%~99.6%,相对标准偏差RSD是2.1%~3.5%,检测限是0.006~0.01ng/ml,可用于食品以及饮用水、废水中Cr(Ⅲ)和Cr(Ⅵ)的测定。 展开更多
关键词 ICP-MS 食品 cr(Ⅲ) cr(Ⅵ) 离子交换法
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Cr掺杂TiO2纳米线/还原氧化石墨烯复合物的制备及光催化活性 被引量:9
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作者 朱洁莲 夏晓峰 +2 位作者 朱珊珊 刘湘 李和兴 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2016年第10期1833-1839,共7页
以TiO_2纳米颗粒P25和氧化石墨烯(GO)为原料,Cr(NO_3)_3·9H_2O为Cr源,采用碱性水热法制备了Cr掺杂TiO_2纳米线/还原氧化石墨烯复合物(Cr-Ti O2 NWs/RGO).采用类似方法合成了TiO_2纳米线(Ti O2NWs)、Cr掺杂Ti O2纳米线(Cr-TiO_2NWs)... 以TiO_2纳米颗粒P25和氧化石墨烯(GO)为原料,Cr(NO_3)_3·9H_2O为Cr源,采用碱性水热法制备了Cr掺杂TiO_2纳米线/还原氧化石墨烯复合物(Cr-Ti O2 NWs/RGO).采用类似方法合成了TiO_2纳米线(Ti O2NWs)、Cr掺杂Ti O2纳米线(Cr-TiO_2NWs)和TiO_2纳米线/还原氧化石墨烯复合物(TiO_2 NWs/RGO)等其它样品.通过X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、拉曼(Raman)光谱、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和紫外-可见漫反射光谱(UV-VisDRS)等方法对样品进行了表征.测试了样品在可见光下对亚甲基蓝(MB)的降解活性,结果表明,Cr-TiO_2NWs/RGO在120 min内对MB的催化降解率为TiO_2NWs的2.2倍,催化降解速度为TiO_2NWs的5.8倍. 展开更多
关键词 cr掺杂TiO2 石墨烯复合物 光催化 水热法
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重铬酸钾法快速检测COD_(Cr)在污水处理工程运行中的应用 被引量:5
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作者 李善评 张彦丽 +3 位作者 庞艳 冀贞泉 叶新强 胡雪莲 《环境工程》 CAS CSCD 北大核心 2004年第4期55-56,共2页
例行监测中CODCr的测定 ,采用重铬酸钾法[1 ] ,此方法测定准确可靠 ,但回流时间较长 ,耗水、耗电、耗时 ,分析速度慢。本方法改用硫磷混合酸代替硫酸 硫酸银溶液进行回流操作 ,极大地缩短了回流时间 ,提高了分析速度并能得到满意结果。
关键词 重铬酸钾法 CODC 污水处理工程 回流时间 硫磷 硫酸银 耗水 银溶液 代替 混合酸
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ICP-AES法同时测定合金工具钢中的Cr、Mo、V 被引量:3
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作者 梁烽 杨左军 +1 位作者 李泳涛 廖文忠 《分析科学学报》 CAS CSCD 北大核心 2001年第5期407-409,共3页
采用盐酸 -硫酸对以 Cr、Mo、V为主要合金元素的工具钢试样进行消化 ,用ICP- AES法同时测定试样中 Cr、Mo、V的含量。方法简便 ,结果满意。方法的加标回收率为 95 .5 %~ 1 0 3.2 % ,相对标准偏差 ( n=9)为 1 .61 %~ 6.64%
关键词 cr MO V ICP-AES法 合金工具钢 同时测定 电感耦合等离子体发射光谱
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ZnGa_2O_4∶Cr^(3+)红色荧光粉的光致及电致发光性能 被引量:7
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作者 乔彬 唐子龙 +1 位作者 张中太 陈雷 《物理化学学报》 SCIE CAS CSCD 北大核心 2006年第10期1291-1295,共5页
采用柠檬酸络合溶胶-凝胶法合成ZnGa2O4∶Cr3+红色荧光粉,在空气气氛中1000℃煅烧得到ZnGa2O4单相.对粉体进行X射线光电子能谱(XPS)和电子顺磁共振(EPR)测试,结果显示,在空气气氛中煅烧,铬离子以三价形式存在(Cr3+),未出现高价铬离子(Cr... 采用柠檬酸络合溶胶-凝胶法合成ZnGa2O4∶Cr3+红色荧光粉,在空气气氛中1000℃煅烧得到ZnGa2O4单相.对粉体进行X射线光电子能谱(XPS)和电子顺磁共振(EPR)测试,结果显示,在空气气氛中煅烧,铬离子以三价形式存在(Cr3+),未出现高价铬离子(Cr5+,Cr6+).Cr3+取代Ga3+占据八面体格位,位于695nm的红光发射带属于Cr3+的2E-4A2跃迁.Cr3+的激发带与基质发射带间有大面积重叠,两者间存在有效的能量传递.利用丝网印刷方法制成电致发光器件,与硫化物电致发光器件相似,ZnGa2O4∶Cr3+电致发光器件的亮度与电压满足L=L0exp(-bV-1/2)关系,且亮度与频率成正比.器件的Q-V曲线为闭合回路,发光效率η约为13lm·W-1. 展开更多
关键词 ZnGa2O4:cr^3+ 柠檬酸溶胶-凝胶法 光致发光 电致发光
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微波改性活性炭及其吸附去除苯胺和Cr(Ⅵ)的试验研究 被引量:10
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作者 马燕娜 吴慧英 +3 位作者 施周 黄为炜 谷妲琳 齐琳 《安全与环境学报》 CAS CSCD 北大核心 2009年第1期33-35,共3页
采用5种方法改性活性炭,研究不同改性活性炭对苯胺和Cr(Ⅵ)的吸附性能。结果表明,微波改性硝酸氧化后的活性炭(1#、2#炭)吸附苯胺和Cr(Ⅵ)的性能最佳,与原炭(0#炭)相比,1#和2#炭对苯胺的去除率分别提高了13.19%和11.34%,对Cr(Ⅵ)的去除... 采用5种方法改性活性炭,研究不同改性活性炭对苯胺和Cr(Ⅵ)的吸附性能。结果表明,微波改性硝酸氧化后的活性炭(1#、2#炭)吸附苯胺和Cr(Ⅵ)的性能最佳,与原炭(0#炭)相比,1#和2#炭对苯胺的去除率分别提高了13.19%和11.34%,对Cr(Ⅵ)的去除率分别提高了47.32%和44.28%。未经酸化处理而直接进行载氮气微波辐照的改性活性炭(3#炭)对苯胺的去除效果较好,但对Cr(Ⅵ)的去除效果不如原炭。Boehm试验表明,硝酸氧化使活性炭表面酸性基团增加,从而明显提高了Cr(Ⅵ)吸附量;经微波热处理后,活性炭表面孔隙结构发生了变化,提高了苯胺吸附量。 展开更多
关键词 环境工程 改性方法 活性炭 吸附 微波 苯胺 cr(Ⅵ)
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罗丹明B荧光猝灭法测定痕量Cr(VI)的研究 被引量:12
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作者 曾铭 李树伟 李小燕 《西南民族大学学报(自然科学版)》 CAS 2005年第5期728-730,共3页
基于六价铬与碘化钾反应生成了单质碘,碘可以使罗丹明B发生荧光猝灭,从而间接测定六价铬的含量.六价铬浓度在0.01-0.5μg/mL范围内,荧光强度差值与六价铬浓度呈线形关系,线性回归方程为△F=121.58CCr(VI)(μg/mL)+16.17,相关系数r=0.99... 基于六价铬与碘化钾反应生成了单质碘,碘可以使罗丹明B发生荧光猝灭,从而间接测定六价铬的含量.六价铬浓度在0.01-0.5μg/mL范围内,荧光强度差值与六价铬浓度呈线形关系,线性回归方程为△F=121.58CCr(VI)(μg/mL)+16.17,相关系数r=0.9990,检测限为2.4ng/mL.该方法简便,快速,灵敏度高,已用于环境样品中六价铬的测定,回收率在99.8%-104.2%,结果满意. 展开更多
关键词 荧光猝灭法 单质碘 罗丹明B cr(VI)
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反复熔铸Ni-Cr烤瓷合金体外细胞毒性实验(MTT法) 被引量:12
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作者 张长源 程辉 +2 位作者 王希 郑明 李秀容 《实用口腔医学杂志》 CAS CSCD 北大核心 2010年第3期306-309,共4页
目的:初步评价反复熔铸后Ni-Cr烤瓷合金的生物相容性。方法:根据ISO标准采用体外细胞毒性试验(MTT法)测试不同熔铸次数Ni-Cr烤瓷合金不同浓度的浸提液培养小鼠结缔组织成纤维细胞(L-929)的结果,从而对反复熔铸后Ni-Cr烤瓷合金的生物相... 目的:初步评价反复熔铸后Ni-Cr烤瓷合金的生物相容性。方法:根据ISO标准采用体外细胞毒性试验(MTT法)测试不同熔铸次数Ni-Cr烤瓷合金不同浓度的浸提液培养小鼠结缔组织成纤维细胞(L-929)的结果,从而对反复熔铸后Ni-Cr烤瓷合金的生物相容性进行初筛。结果:各浓度实验组细胞生长形态良好、细胞毒性级为0~1级;经过2~5次熔铸的Ni-Cr烤瓷合金不同浓度的浸提液、不同培养时间的A492均值与经过1次熔铸的Ni-Cr烤瓷合金相应A492均值无显著性差异(P>0.05)。结论:初步认为Ni-Cr烤瓷合金经过1~5次熔铸后具有较好的生物相容性。 展开更多
关键词 反复熔铸 Ni-cr烤瓷合金 体外细胞毒性实验(MTT法)
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Experimental study and numerical analysis on dry friction and wear performance of co-continuous SiC/Fe-40Cr against SiC/2618 Al alloy composites 被引量:1
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作者 姜澜 姜艳丽 +2 位作者 喻亮 苏楠 丁友东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第12期2913-2924,共12页
The dry friction and wear behaviors of co-continuous composites SiC/Fe–40Cr against SiC/Al 2618 alloy were investigated on a ring-on-ring friction and wear tester at sliding speed of 30-105 m/s under the load of 1.0-... The dry friction and wear behaviors of co-continuous composites SiC/Fe–40Cr against SiC/Al 2618 alloy were investigated on a ring-on-ring friction and wear tester at sliding speed of 30-105 m/s under the load of 1.0-2.5 MPa. The experimental result reveals that the characteristic of two body abrasive wear and oxidation wear mechanisms are present for SiCn/2618 Al composite under higher load and sliding speed. SiC ceramic continuous network as the reinforcement can avoid composite from the third body wear that usually occurs in traditional particle reinforced composite. The mechanically mixed layer (MML) controls greatly the wear rate and friction coefficient of the composites. The composites tested at higher sliding speed exhibit higher value of friction coefficient and fluctuation, which is associated with the intermittent formation and removal of the MML. The wear and stress—strain behaviors of SiCn/Fe–40Cr against SiCn/Al 2168 at 30-105 m/s under 1.0-2.5 MPa were analyzed by finite element method with the software Solidwork2012 Simulation, respectively. The wear and stress–strain behavior of the composite predicted by the FEM correlated well with the experimental results. 展开更多
关键词 wear SiC/Al 2618 alloy SiC/Fe-40cr co-continuous composite finite element method
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