The goal of this work is to improve the simultaneous removal of Pb2+, Cu2+, Zn2+, and Cd2+ ions from synthetic wastewater in a fixed bed column by incorporating sodium dodecyl sulfate (SDS) onto the surface of activat...The goal of this work is to improve the simultaneous removal of Pb2+, Cu2+, Zn2+, and Cd2+ ions from synthetic wastewater in a fixed bed column by incorporating sodium dodecyl sulfate (SDS) onto the surface of activated carbon made from coconut shells. The activated carbons were characterized using Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy-energy dispersive x-ray (SEM-EDX). The adsorption column dynamics were studied by varying the flow rates (5, 10 and 15 mL/min), bed heights (10, 15 and 20 cm), and initial concentrations (50, 150, and 250 mg/L). The activated carbon has a pore volume of 0.715 cm3/g and a BET-specific surface area of 1410 m2/g. Sodium dodecyl sulfate (SDS) surfactant incorporation onto the surface of the activated carbon enhances its capacity for simultaneous adsorption of Pb2+, Cu2+, Zn2+, and Cd2+ from the aqueous medium. The affinity of the heavy metals to both unmodified (AC) and modified (AC-SDS) activated carbons followed the order of Pb2+ > Cu2+ > Zn2+ > Cd2+. The dynamic adsorption of the column depends on the flow rate, bed height, initial metal concentration, and SDS surface modification. With a 5 mL/min flow rate, a 20 cm bed height, and a 50 mg/L initial metal concentration, a maximum break-through time of 150 minutes for the unmodified activated carbon (AC) and 180 minutes for the SDS-modified activated carbon (AC-SDS) was reached.展开更多
Soil column liquid chromatography (SCLC) was developed to determine soil organic carbon adsorption coefficients (E-oc) for chemicals. The uptake by soil of pesticides from water can be conveniently calculated from the...Soil column liquid chromatography (SCLC) was developed to determine soil organic carbon adsorption coefficients (E-oc) for chemicals. The uptake by soil of pesticides from water can be conveniently calculated from the related breakthrough curves (BTC). The nine pesticides chosen for determination in this study are soluble ones, with their water solubility ranging from 62 mg/L to Z mg/L. In comparing with existing methods of K-oc, SCLC possesses rapid, online and accurate characteristics.展开更多
The Ordovician carbonate reservoirs in the Tarim Basin with secondary dissolution pores and vugs have complicated pore structures. The weathering crust reservoirs mainly consist of large cavities or vugs connected by ...The Ordovician carbonate reservoirs in the Tarim Basin with secondary dissolution pores and vugs have complicated pore structures. The weathering crust reservoirs mainly consist of large cavities or vugs connected by fractures, but most of the reef-shoal reservoirs have complex and small throats among matrix pores. The pore structure can be divided into four types： big pore and big throat, big pore but small throat, small pore and small throat, and fracture type. Most of the average throat radius falls between 0.03 and 0.07μm, close to that of unconventional reservoirs except in local areas with developed fractures. Fluid driving force analysis shows that the differentiation of fluid is mainly controlled by the throat radius in two kinds of mechanism separated by the critical throat radius about 0.1 μm. There is obvious fluid differentiation and oil/gas/water contact in fracture-cavity reservoirs with big throats. However, most of reservoirs under the critical throat radius have high capillary pressure, which resulted in incomplete differentiation of gas/oil/water, and complicated fluid distribution and fluid properties in the unconventional reservoirs.展开更多
The International Centre for Theoretical Physics(ICTP,Italy) Regional Climate Model version 3.0(RegCM3) is used to simulate spatio-temporal distribution characteristics and radiative forcing(RF) of organic carbon(OC) ...The International Centre for Theoretical Physics(ICTP,Italy) Regional Climate Model version 3.0(RegCM3) is used to simulate spatio-temporal distribution characteristics and radiative forcing(RF) of organic carbon(OC) aerosols in and around China.The preliminary simulation results show that OC aerosols are mostly concentrated in the area to the south of Yellow River and east of Tibetan Plateau.There is a decreasing trend of column burden of OC aerosols from south to north in China.The maximum value of column burden of OC aerosols is above 3 mg/m2 and located in the central and southern China,southeastern Tibet,and southwestern China's Yunnan,Guizhou,Sichuan provinces.The simulation on the seasonal variation shows that the maximum value of column burden of OC aerosols appears in winter and the secondary value is in spring and the minimum in summer.The RF of OC aerosols which varies seasonally is negative at the top of the atmosphere(TOA) and surface.The spatio-temporal characteristics of the RF of OC aerosols are basically consistent with that of IPCC,implying the high accuracy of the parameterization scheme for OC aerosols in RegCM3.展开更多
The fly ash generated from local pulp and paper industries was transformed into activated carbon (AC) through physical activation process in a high temperature tube furnace in this study. Effects of two factors includ...The fly ash generated from local pulp and paper industries was transformed into activated carbon (AC) through physical activation process in a high temperature tube furnace in this study. Effects of two factors including activation temperature and activation time were investigated. Iodine number (IN), methylene blue value (MBV), and surface microstructure were all analyzed to assess the adsorption capacity of different carbon samples. The surface area of the carbon sample increased significantly from 486.44 m<sup>2</sup>/g to 847.26 m<sup>2</sup>/g before and after activation. The jar tests revealed that the use of 0.5 g (AC)/L (water) has the highest adsorption effectiveness. Meanwhile, the column filtration experiment indicated more than 60% of the organic matter can be removed by the carbon barrier within 2 hours filtration. The follow-up chlorination experiment illustrated that the formation of trihalomethanes (THMs) and haloacetic acids (HAAs) could be considerably prevented after filtration. Above all, the cost-effective carbon filtration technology developed in this study can potentially be applied as a pre-treatment technology for intake source waters for local communities.展开更多
热电联产(combined heat and power,CHP)机组与虚拟电厂(virtual power plant,VPP)结合,可以有效提高能源利用效率,增强电力系统运行的可靠性及稳定性。为保证CHP-VPP灵活、低碳、经济运行,文中提出一种聚合风电、光伏、CHP机组、锅炉...热电联产(combined heat and power,CHP)机组与虚拟电厂(virtual power plant,VPP)结合,可以有效提高能源利用效率,增强电力系统运行的可靠性及稳定性。为保证CHP-VPP灵活、低碳、经济运行,文中提出一种聚合风电、光伏、CHP机组、锅炉、碳捕集设备、燃气轮机、燃料电池、储能及电、热负荷的综合能源VPP,并在参与电-热-旋转备用-碳等多市场下,研究其低碳经济协同调度问题。首先,以各时刻VPP在多市场下整体净收益最大为目标,建立其CHP-VPP两阶段鲁棒优化调度模型;然后,考虑新能源出力、市场价格及负荷的不确定性,利用蒙特卡洛法进行场景削减,从而降低系统风险,增强其鲁棒性;最后,采用列与约束生成算法对模型进行求解,得到最恶劣场景下系统运行的经济性最优调度方案。仿真结果表明:所提综合能源VPP结构合理,可通过动态调整碳捕集设备及储能电池,达到平抑新能源出力波动的效果,从而实现碳排放的大幅降低;所提调度策略可有效保证源-荷-储多侧电、热资源的协同优化运行,提高VPP的灵活性、经济性和低碳性。展开更多
文摘The goal of this work is to improve the simultaneous removal of Pb2+, Cu2+, Zn2+, and Cd2+ ions from synthetic wastewater in a fixed bed column by incorporating sodium dodecyl sulfate (SDS) onto the surface of activated carbon made from coconut shells. The activated carbons were characterized using Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy-energy dispersive x-ray (SEM-EDX). The adsorption column dynamics were studied by varying the flow rates (5, 10 and 15 mL/min), bed heights (10, 15 and 20 cm), and initial concentrations (50, 150, and 250 mg/L). The activated carbon has a pore volume of 0.715 cm3/g and a BET-specific surface area of 1410 m2/g. Sodium dodecyl sulfate (SDS) surfactant incorporation onto the surface of the activated carbon enhances its capacity for simultaneous adsorption of Pb2+, Cu2+, Zn2+, and Cd2+ from the aqueous medium. The affinity of the heavy metals to both unmodified (AC) and modified (AC-SDS) activated carbons followed the order of Pb2+ > Cu2+ > Zn2+ > Cd2+. The dynamic adsorption of the column depends on the flow rate, bed height, initial metal concentration, and SDS surface modification. With a 5 mL/min flow rate, a 20 cm bed height, and a 50 mg/L initial metal concentration, a maximum break-through time of 150 minutes for the unmodified activated carbon (AC) and 180 minutes for the SDS-modified activated carbon (AC-SDS) was reached.
基金Supported by the National Natural Science Foundation （51208268）the Pubiic-Welfare-Technology Research Industry Project of Science Technology Department of Zhejiang （2011 C21078） the Social Development Project of Science Technology Bureau of Ningbo （2011CS0017）.
基金Bayer AG and Chinese Academy of Agricultural Sciences for kindly supplying the pesticides.
文摘Soil column liquid chromatography (SCLC) was developed to determine soil organic carbon adsorption coefficients (E-oc) for chemicals. The uptake by soil of pesticides from water can be conveniently calculated from the related breakthrough curves (BTC). The nine pesticides chosen for determination in this study are soluble ones, with their water solubility ranging from 62 mg/L to Z mg/L. In comparing with existing methods of K-oc, SCLC possesses rapid, online and accurate characteristics.
基金supported by the National Basic Research Program of China (973 Program,Grant No.2011CB201106)
文摘The Ordovician carbonate reservoirs in the Tarim Basin with secondary dissolution pores and vugs have complicated pore structures. The weathering crust reservoirs mainly consist of large cavities or vugs connected by fractures, but most of the reef-shoal reservoirs have complex and small throats among matrix pores. The pore structure can be divided into four types： big pore and big throat, big pore but small throat, small pore and small throat, and fracture type. Most of the average throat radius falls between 0.03 and 0.07μm, close to that of unconventional reservoirs except in local areas with developed fractures. Fluid driving force analysis shows that the differentiation of fluid is mainly controlled by the throat radius in two kinds of mechanism separated by the critical throat radius about 0.1 μm. There is obvious fluid differentiation and oil/gas/water contact in fracture-cavity reservoirs with big throats. However, most of reservoirs under the critical throat radius have high capillary pressure, which resulted in incomplete differentiation of gas/oil/water, and complicated fluid distribution and fluid properties in the unconventional reservoirs.
基金National Fundamental Research Program of China (2011CB403202)National Natural Science Foundation of China (40675040)
文摘The International Centre for Theoretical Physics(ICTP,Italy) Regional Climate Model version 3.0(RegCM3) is used to simulate spatio-temporal distribution characteristics and radiative forcing(RF) of organic carbon(OC) aerosols in and around China.The preliminary simulation results show that OC aerosols are mostly concentrated in the area to the south of Yellow River and east of Tibetan Plateau.There is a decreasing trend of column burden of OC aerosols from south to north in China.The maximum value of column burden of OC aerosols is above 3 mg/m2 and located in the central and southern China,southeastern Tibet,and southwestern China's Yunnan,Guizhou,Sichuan provinces.The simulation on the seasonal variation shows that the maximum value of column burden of OC aerosols appears in winter and the secondary value is in spring and the minimum in summer.The RF of OC aerosols which varies seasonally is negative at the top of the atmosphere(TOA) and surface.The spatio-temporal characteristics of the RF of OC aerosols are basically consistent with that of IPCC,implying the high accuracy of the parameterization scheme for OC aerosols in RegCM3.
文摘The fly ash generated from local pulp and paper industries was transformed into activated carbon (AC) through physical activation process in a high temperature tube furnace in this study. Effects of two factors including activation temperature and activation time were investigated. Iodine number (IN), methylene blue value (MBV), and surface microstructure were all analyzed to assess the adsorption capacity of different carbon samples. The surface area of the carbon sample increased significantly from 486.44 m<sup>2</sup>/g to 847.26 m<sup>2</sup>/g before and after activation. The jar tests revealed that the use of 0.5 g (AC)/L (water) has the highest adsorption effectiveness. Meanwhile, the column filtration experiment indicated more than 60% of the organic matter can be removed by the carbon barrier within 2 hours filtration. The follow-up chlorination experiment illustrated that the formation of trihalomethanes (THMs) and haloacetic acids (HAAs) could be considerably prevented after filtration. Above all, the cost-effective carbon filtration technology developed in this study can potentially be applied as a pre-treatment technology for intake source waters for local communities.
文摘热电联产(combined heat and power,CHP)机组与虚拟电厂(virtual power plant,VPP)结合,可以有效提高能源利用效率,增强电力系统运行的可靠性及稳定性。为保证CHP-VPP灵活、低碳、经济运行,文中提出一种聚合风电、光伏、CHP机组、锅炉、碳捕集设备、燃气轮机、燃料电池、储能及电、热负荷的综合能源VPP,并在参与电-热-旋转备用-碳等多市场下,研究其低碳经济协同调度问题。首先,以各时刻VPP在多市场下整体净收益最大为目标,建立其CHP-VPP两阶段鲁棒优化调度模型;然后,考虑新能源出力、市场价格及负荷的不确定性,利用蒙特卡洛法进行场景削减,从而降低系统风险,增强其鲁棒性;最后,采用列与约束生成算法对模型进行求解,得到最恶劣场景下系统运行的经济性最优调度方案。仿真结果表明:所提综合能源VPP结构合理,可通过动态调整碳捕集设备及储能电池,达到平抑新能源出力波动的效果,从而实现碳排放的大幅降低;所提调度策略可有效保证源-荷-储多侧电、热资源的协同优化运行,提高VPP的灵活性、经济性和低碳性。
