The purpose of this study is to optimize the existing carbon dioxide （CO2） flood in deep dolomite formations by improving oil sweep efficiency of miscible CO2 floods and enhancing the conformance control. A full com...The purpose of this study is to optimize the existing carbon dioxide （CO2） flood in deep dolomite formations by improving oil sweep efficiency of miscible CO2 floods and enhancing the conformance control. A full compositional simulation model using a detailed geologic characterization was built to optimize the injection pattern. The model is a quarter of an inverted nine-spot and covers 20 acres of field formation. Geologic description was used to construct the simulation grids. The simulation layers represent actual flow units and resemble the large variation of reservoir properties. History match was performed to validate the model. Several sensitivity runs were made to improve the CO2 sweep efficiency and increase the oil recovery. Finally, the optimum CO2 injection rate for dolomite formations was determined approximately. Simulation results also indicate that a water-alternating-gas （WAG） ratio of 1：1 along with an ultimate CO2 slug of 100% hydrocarbon pore volume （HCPV） will allow an incremental oil recovery of 18%. The additional recovery increases to 34% if a polymer is injected as a conformance control agent during the course of the WAG process at a ratio of 1：1. According to the results, a pattern reconfiguration change from the nine spot to staggered line drive would represent an incremental oil recovery of 26%.展开更多
Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S ...Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S in oil recovery processes showed that H_(2)S has the potential of improving the oil recovery,and it can be even more effective than using CO_(2) in some processes.H_(2)S can equally dissolve in the water,react with the reservoir rock to change its surface charge,porosity,and permeability.However,previous in-vestigations on H_(2)S oil recovery attributed the improved oil recoveries to the higher miscibility of H_(2)S in the oil,and the reduction in the oil viscosity.Therefore,there is limited understanding on the H_(2)S-oil-brine-rock geochemical interactions,and how they impact the oil recovery process.This study aims to investigate the interactions between H_(2)S,oil,and carbonate formations,and to assess how the combi-nation of H_(2)S and low salinity water can impact the wettability and porosity of the reservoirs.A triple layer surface complexation model was used to understand the influence of key parameters(e.g.,pressure,brine salinity,and composition)on the H_(2)S-brine-oil-rock interactions.Moreover,the effects of mineral content of the carbonate rock on H_(2)S interactions were studied.Thereafter,the results of the H_(2)S-oil-brine-rock interactions were compared with a study where CO_(2) was used as the injected gas.Results of the study showed that the seawater and its diluted forms yielded identicalζ-potential values of about 3.31 mV at a pH of 3.24.This indicates that at very low pH condition,pH controls the ζ-potential of the oil-brine interface regardless of the brine's ionic strength.The study further demonstrated that the presence of other minerals in the carbonate rock greatly reduced the calcite dissolution.For instance,the calcite dissolution was reduced by 4.5%when anhydrite mineral was present in the carbonate rock.Findings from the simulation also indicated that CO_(2) produced negative ζ-potential values for the car-bonate rocks,and these values were reduced by 18.4%-20% when H_(2)S was used as the gas phase.This implies that the H_(2)S shifted the carbonate rockζ-potentials towards positive.The outcomes of this study can be applied when designing CO_(2) flooding and CO_(2) storage where the gas stream contains H_(2)S gas since H_(2)S greatly influences the dissolution of the carbonate mineral.展开更多
文摘The purpose of this study is to optimize the existing carbon dioxide （CO2） flood in deep dolomite formations by improving oil sweep efficiency of miscible CO2 floods and enhancing the conformance control. A full compositional simulation model using a detailed geologic characterization was built to optimize the injection pattern. The model is a quarter of an inverted nine-spot and covers 20 acres of field formation. Geologic description was used to construct the simulation grids. The simulation layers represent actual flow units and resemble the large variation of reservoir properties. History match was performed to validate the model. Several sensitivity runs were made to improve the CO2 sweep efficiency and increase the oil recovery. Finally, the optimum CO2 injection rate for dolomite formations was determined approximately. Simulation results also indicate that a water-alternating-gas （WAG） ratio of 1：1 along with an ultimate CO2 slug of 100% hydrocarbon pore volume （HCPV） will allow an incremental oil recovery of 18%. The additional recovery increases to 34% if a polymer is injected as a conformance control agent during the course of the WAG process at a ratio of 1：1. According to the results, a pattern reconfiguration change from the nine spot to staggered line drive would represent an incremental oil recovery of 26%.
文摘Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S in oil recovery processes showed that H_(2)S has the potential of improving the oil recovery,and it can be even more effective than using CO_(2) in some processes.H_(2)S can equally dissolve in the water,react with the reservoir rock to change its surface charge,porosity,and permeability.However,previous in-vestigations on H_(2)S oil recovery attributed the improved oil recoveries to the higher miscibility of H_(2)S in the oil,and the reduction in the oil viscosity.Therefore,there is limited understanding on the H_(2)S-oil-brine-rock geochemical interactions,and how they impact the oil recovery process.This study aims to investigate the interactions between H_(2)S,oil,and carbonate formations,and to assess how the combi-nation of H_(2)S and low salinity water can impact the wettability and porosity of the reservoirs.A triple layer surface complexation model was used to understand the influence of key parameters(e.g.,pressure,brine salinity,and composition)on the H_(2)S-brine-oil-rock interactions.Moreover,the effects of mineral content of the carbonate rock on H_(2)S interactions were studied.Thereafter,the results of the H_(2)S-oil-brine-rock interactions were compared with a study where CO_(2) was used as the injected gas.Results of the study showed that the seawater and its diluted forms yielded identicalζ-potential values of about 3.31 mV at a pH of 3.24.This indicates that at very low pH condition,pH controls the ζ-potential of the oil-brine interface regardless of the brine's ionic strength.The study further demonstrated that the presence of other minerals in the carbonate rock greatly reduced the calcite dissolution.For instance,the calcite dissolution was reduced by 4.5%when anhydrite mineral was present in the carbonate rock.Findings from the simulation also indicated that CO_(2) produced negative ζ-potential values for the car-bonate rocks,and these values were reduced by 18.4%-20% when H_(2)S was used as the gas phase.This implies that the H_(2)S shifted the carbonate rockζ-potentials towards positive.The outcomes of this study can be applied when designing CO_(2) flooding and CO_(2) storage where the gas stream contains H_(2)S gas since H_(2)S greatly influences the dissolution of the carbonate mineral.
