Theoretical investigations on CO oxidation reaction catalyzed by gold nanoparticles

It is crucial to understand the mechanism of low temperature CO oxidation reaction catalyzed by gold nanoparticles so as to find out the origin of the high catalytic reactivity and extend the indus‐trialization applications of nano gold catalysts. In this work, some theoretical works on CO adsorp‐tion, O2 adsorption, atomic oxygen adsorption, formation of surface gold oxide films, reaction mechanisms of CO oxidation involving O2 reaction with CO and O2 dissociation before reacting with CO on gold surfaces and Au/metal oxide were summarized, and the influences of coordination number, charge transfer and relativity of gold on CO oxidation reaction were briefly reviewed. It was found that CO reaction mechanism depended on the systems with or without oxide and the strong relativistic effects might play an important role in CO oxidation reaction on gold catalysts. In particular, the relativistic effects are related to the unique behaviors of CO adsorption, O adsorption, O2 activation on gold surfaces, effects of coordination number and the wide gap between the chem‐ical inertness of bulk gold and high catalytic activity of nano gold. The present work helps us to understand the CO oxidation reaction mechanism on gold catalysts and the influence of relativistic effects on gold catalysis.

High density iridium synergistic sites boosting CO-tolerate performance for PEMFC anode

The usage of cheap crude H2 in proton-exchange membrane fuel cells(PEMFCs)is still unrealistic to date,due to the suffering of the current Pt based nano-catalysts from impurities such as CO in anode.Recently,synergistic active sites between single atom(SA)and nanoparticle(NP)have been found to be promising for overcoming the poisoning problem.However,lengthening the nanoparticle-single atom(SA–NP)interface,i.e.,constructing high density synergistic active sites,remains highly challenging.Herein,we present a new strategy based on molecular fusion strategy to create abundant SA–NP interfaces,with high density SA–NP interfaces created on a two dimensional nitrogen doped carbon nanosheets(Ir-SACs&NPs/NC).Owing to the abundance of SA–NP interface sites,the catalyst was empowered with a high tolerance towards up to 1000ppm CO in H_(2) feed.These findings provide guidelines for the design and construction of active and anti-poisoning catalysts for PEMFC anode.