Estimation of soil organic carbon reservoir in China

The paper respectively adopted physio-chemical properties of every soil stratum from 2473 soil profiles of the second national soil survey. The corresponding carbon content of soils is estimated by utilizing conversion coefficient 0.58. In the second soil survey, the total amount of soil organic carbon is about 924.18xl08t and carbon density is about 10.53 kgC/m2 in China according to the area of 877.63x106hm2 surveyed throughout the country. The spatial distribution characteristics of soil organic carbon in China is that the carbon storage increases when latitude increases in eastern China and the carbon storage decreases when longitude reduces in northern China. A transitional zone with great variation in carbon storage exists. Moreover, there is an increasing tendency of carbon density with decrease of latitude in western China. Soil circle is of great significance to global change, but with substantial difference in soil spatial distribution throughout the country. Because the structure of soil is inhomogeneous, it could bring some mistakes in estimating soil carbon reservoirs. It is necessary to farther resolve soil respiration and organic matter conversion and other questions by developing uniform and normal methods of measurement and sampling.

Controlling effects of the Ordovician carbonate pore structure on hydrocarbon reservoirs in the Tarim Basin, China

The Ordovician carbonate reservoirs in the Tarim Basin with secondary dissolution pores and vugs have complicated pore structures. The weathering crust reservoirs mainly consist of large cavities or vugs connected by fractures, but most of the reef-shoal reservoirs have complex and small throats among matrix pores. The pore structure can be divided into four types： big pore and big throat, big pore but small throat, small pore and small throat, and fracture type. Most of the average throat radius falls between 0.03 and 0.07μm, close to that of unconventional reservoirs except in local areas with developed fractures. Fluid driving force analysis shows that the differentiation of fluid is mainly controlled by the throat radius in two kinds of mechanism separated by the critical throat radius about 0.1 μm. There is obvious fluid differentiation and oil/gas/water contact in fracture-cavity reservoirs with big throats. However, most of reservoirs under the critical throat radius have high capillary pressure, which resulted in incomplete differentiation of gas/oil/water, and complicated fluid distribution and fluid properties in the unconventional reservoirs.

Polymer efficiency and sulfate concentration for hybrid EOR application to an acidic carbonate reservoir

Polymers play an important role in hybrid enhanced oil recovery (EOR), which involves both a polymer and low-salinity water. Because the polymer commonly used for low-salinity polymer flooding (LSPF) is strongly sensitive to brine pH, its efficiency can deteriorate in carbonate reservoirs containing highly acidic formation water. In this study, polymer efficiency in an acidic carbonate reservoir was investigated experimentally for different salinity levels and SO42− concentrations. Results indicated that lowering salinity improved polymer stability, resulting in less polymer adsorption, greater wettability alteration, and ultimately, higher oil recovery. However, low salinity may not be desirable for LSPF if the injected fluid does not contain a sufficient number of sulfate (SO42−) ions. Analysis of polymer efficiency showed that more oil can be produced with the same polymer concentration by adjusting the SO42− content. Therefore, when river water, which is relatively easily available in onshore fields, is designed to be injected into an acidic carbonate reservoir, the LSPF method proposed in this study can be a reliable and environmentally friendly method with addition of a sufficient number of SO42− ions to river water.

Control of strike-slip faults on Sinian carbonate reservoirs in Anyue gas field, Sichuan Basin, SW China

The largest Precambrian gas field (Anyue gas field) in China has been discovered in the central Sichuan Basin. However, the deep ancient Ediacaran (Sinian) dolomite presents a substantial challenge due to their tightness and heterogeneity, rather than assumed large-area stratified reservoirs controlled by mound-shoal microfacies. This complicates the characterization of “sweet spot” reservoirs crucial for efficient gas exploitation. By analyzing compiled geological, geophysical and production data, this study investigates the impact of strike-slip fault on the development and distribution of high-quality “sweet spot” (fractured-vuggy) reservoirs in the Ediacaran dolomite of the Anyue gas field. The dolomite matrix reservoir exhibits low porosity (less than 4%) and low permeability (less than 0.5×10^(-3) μm^(2)). Contrarily, fractures and their dissolution processes along strike-slip fault zone significantly enhance matrix permeability by more than one order of magnitude and matrix porosity by more than one time. Widespread “sweet spot” fracture-vuggy reservoirs are found along the strike-slip fault zone, formed at the end of the Ediacaran. These fractured reservoirs are controlled by the coupling mechanisms of sedimentary microfacies, fracturing and karstification. Karstification prevails at the platform margin, while both fracturing and karstification control high-quality reservoirs in the intraplatform, resulting in reservoir diversity in terms of scale, assemblage and type. The architecture of the strike-slip fault zone governed the differential distribution of fracture zones and the fault-controlled “sweet spot” reservoirs, leading to wide fractured-vuggy reservoirs across the strike-slip fault zone. In conclusion, the intracratonic weak strike-slip fault can play a crucial role in improving tight carbonate reservoir, and the strike-slip fault-related “sweet spot” reservoir emerges as a unique and promising target for the efficient development of deep hydrocarbon resources. Tailored development strategies need to be implemented for these reservoirs, considering the diverse and differential impacts exerted by strike-slip faults on the reservoirs.

Characteristics,Formation Periods,and Controlling Factors of Tectonic Fractures in Carbonate Geothermal Reservoirs:A Case Study of the Jixianian System in the Xiong'an New Area,China

As typical carbonate geothermal reservoirs with low porosity in northern China,the Jixianian System in the Xiong’an New Area is the main target for geothermal fluid exploration.The Jixianian System comprises the Gaoyuzhuang,Yangzhuang,Wumishan,Hongshuizhuang,and Tieling formations.The characteristics,formation periods,and controlling factors of reservoir tectonic fractures have been determined based on analyses of outcrops,cores,thin sections,and image logs.The results show that unfilled fractures account for over 87% and most tectonic fractures are high-angle shear fractures with angles concentrated at 40°to 70°and the fracture porosity increases linearly with an increased fracture aperture.Within the same tectonic setting and stress field,the lithology and layer thickness are the dominant factors governing the development of tectonic fractures,which are the most developed in dolomites and thin layers.Tectonic fractures were most likely formed in regions near faults or areas with larger stress gradients.The tectonic fractures in the carbonate geothermal reservoirs are roughly divided into four sets:NNW-SSE and NNE-SSW oriented‘X’-conjugated shear fractures formed from the Paleozoic to the pre-Yanshanian Movement;NE-SW-oriented shear fractures,formed in episode B of the Yanshanian Movement,occurred at the Early Cretaceous;nearly E-W-oriented tensional fractures formed in the late Yanshanian Movement at the Late Cretaceous to Paleogene,and NEE-SW-oriented shear fractures formed during the Himalayan movement.

Ultra-deep carbonate basement reservoirs formed by polyphase fracture-related karstification in the Offshore Bohai Bay Basin, China

The Palaeozoic carbonate basement of the Offshore Bohai Bay Basin (OBBB) presents considerable potential for hydrocarbon exploration. However, the multistage tectonism and complex superimposed palaeo-karstification in the area are unclear, which leads to a lack of understanding on the formation mechanism and distribution of the deep carbonate basement reservoirs. In this study, the occurrence of a fracture-vug network and its fillings in carbonate reservoirs were investigated based on borehole cores, thin sections, and image logs from the southwestern slope of the OBBB's Bozhong Sag. Then the diagenetic fluid properties of the carbonate matrix and fillings were analysed via the data of carbon, oxygen, and strontium isotopes, and major, rare elements from coring intervals. The results revealed that fracture-related karst reservoirs have lithologic selectivity inclined toward dolomite strata. The intersecting relationships, widths, and strikes of the fractures and the regional tectonic background indicate three structural fracture families: NW-, NNE-, and NNW- trending, related to the Indosinian, middle Yanshanian, and late Yanshanian orogeny, respectively. The Indosinian NW- and end-Mesozoic NNE-trending fractures produced by compressional tectonic stress mainly contributed to the formation of the basement reservoirs. The geochemistry of the calcite veins filling these fractures suggests two main types of diagenetic fluids. The fluid of autogenic recharge related to the earlier fills is karstification diffuse flow dominated by internal runoff from rainfall in the highland setting of the Indosinian thrusting orogenic belt. The other fluid of allogenic recharge related to the later fills is the main lateral freshwater flow dominated by external runoff from the catchment in the setting of the horst-lowland within the rifting basin, induced by the Yanshanian destruction of the North China Craton. Finally, the relationship between the three fracture families and two kinds of related fluids is revealed. This allows us to propose a model to understand the polyphase-superimposed fracture-related karst reservoir complexes within the deep carbonate basement of tilting fault blocks that neighbour the Bozhong hydrocarbon kitchen and predict the formation of potential plays with high accuracy.

Stress sensitivity of carbonate gas reservoirs and its microscopic mechanism

In order to evaluate the stress sensitivity of carbonate reservoirs,a series of rock stress sensitivity tests were carried out under in-situ formation temperature and stress condition.Based on the calibration of capillary pressure curve,the variable fractal dimension was introduced to establish the conversion formula between relaxation time and pore size.By using the nuclear magnetic resonance(NMR)method,the pore volume loss caused by stress sensitivity within different scales of pore throat was quantitatively analyzed,and the microscopic mechanism of stress sensitivity of carbonate gas reservoirs was clarified.The results show that fractures can significantly affect the stress sensitivity of carbonate reservoirs.With the increase of initial permeability,the stress sensitivity coefficient decreases and then increases for porous reservoirs,but increases monotonously for fractured-porous reservoirs.The pore volume loss caused by stress sensitivity mainly occurs for mesopores(0.02–0.50μm),contributing more than 50%of the total volume loss.Single high-angle fracture contributes 9.6%of the stress sensitivity and 15.7%of the irreversible damage.The microscopic mechanism of the stress sensitivity of carbonate gas reservoirs can be concluded as fracture closure,elastic contraction of pores and plastic deformation of rock skeleton.

Fracture characterization of Asmari Formation carbonate reservoirs in G Oilfield, Zagros Basin, Middle East

The Asmari Formation in the G oilfield on the Iran-Iraq border is a fractured-porous multi-lithology mixed reservoir, for which fracture is an important factor affecting oil productivity and water cut. The characterization and modeling of fractures in the carbonate reservoir of G oilfield are challenging due to weak conventional well log responses of fractures and a lack of specific logs, such as image logs. This study proposes an integrated approach for characterizing and modeling fractures in the carbonate reservoir. The features, formation mechanism, influencing factors, and prediction methods of fractures in the Asmari Formation carbonate reservoirs of G oilfield were studied using core observation, thin section, image log, cross-dipole acoustic log (CDAL), geomechanics numerical simulation (GNS), and production data. According to CDAL-based fracture density interpretation, GNS-based fracture intensity prediction between wells, and DFN-based rock fracture properties modeling, the quantitative fracture characterization for G oilfield was realized. This research shows that the fractures in the Asamri Formation are mainly medium-to high-angle shear fractures. The substantial compression stress during the Miocene played a major role in the formation of the prominent fractures and determined their trend in the region, with primary trends of NNW-SSE and NNE-SSW. The fracture distribution has regularity, and the fractures in zone A dolomites are more highly developed than that in zone B limestones vertically. Horizontally, fractures intensity is mainly controlled by faults and structural location. The results of this study may benefit the optimization of well design during field development. From 2019 to 2021, three horizontal wells pilot tests were deployed in the fractures belt in zone A, and these fractures prominently increased the permeability of tight dolomite reservoirs. The initial production of the wells is four to five times the average production of other wells in the area, showing a good development effect. Meanwhile, the updated numerical simulation validates that the history match accuracy of water cut based on the dual-porosity model is significantly improved, proving the fracture evaluation and prediction results to be relatively reliable and applicable.

Characteristics,classification and KNN-based evaluation of paleokarst carbonate reservoirs:A case study of Feixianguan Formation in northeastern Sichuan Basin,China

The Feixianguan Formation reservoirs in northeastern Sichuan are mainly a suite of carbonate platform deposits.The reservoir types are diverse with high heterogeneity and complex genetic mechanisms.Pores,vugs and fractures of different genetic mechanisms and scales are often developed in association,and it is difficult to classify reservoir types merely based on static data such as outcrop observation,and cores and logging data.In the study,the reservoirs in the Feixianguan Formation are grouped into five types by combining dynamic and static data,that is,karst breccia-residual vuggy type,solution-enhanced vuggy type,fractured-vuggy type,fractured type and matrix type(non-reservoir).Based on conventional logging data,core data and formation microscanner image(FMI)data of the Qilibei block,northeastern Sichuan Basin,the reservoirs are classified in accordance with fracture-vug matching relationship.Based on the principle of cluster analysis,K-Nearest Neighbor(KNN)classification templates are established,and the applicability of the model is verified by using the reservoir data from wells uninvolved in modeling.Following the analysis of the results of reservoir type discrimination and the production of corresponding reservoir intervals,the contributions of various reservoir types to production are evaluated and the reliability of reservoir type classification is verified.The results show that the solution-enhanced vuggy type is of high-quality sweet spot reservoir in the study area with good physical property and high gas production,followed by the fractured-vuggy type,and the fractured and karst breccia-residual vuggy types are the least promising.

Types of Karst-fractured and Porous Reservoirs in China's Carbonates and the Nature of the Tahe Oilfield in the Tarim Basin

Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule uplift and the Tahe Oilfield are assemblages of various types of reservoirs, which have an overall oil-bearing potential and obvious uneven distribution. Testing and producing tests are the major means to evaluate this type of reservoirs and acid fracturing improvement is a key link in petroleum exploration and development.

A review of development methods and EOR technologies for carbonate reservoirs

Carbonate reservoirs worldwide are complex in structure,diverse in form,and highly heterogeneous.Based on these characteristics,the reservoir stimulation technologies and fluid flow characteristics of carbonate reservoirs are briefly described in this study.The development methods and EOR technologies of carbonate reservoirs are systematically summarized,the relevant mechanisms are analyzed,and the application status of oil fields is catalogued.The challenges in the development of carbonate reservoirs are discussed,and future research directions are explored.In the current development processes of carbonate reservoirs,water flooding and gas flooding remain the primary means but are often prone to channeling problems.Chemical flooding is an effective method of tertiary oil recovery,but the harsh formation conditions require high-performance chemical agents.The application of emerging technologies can enhance the oil recovery efficiency and environmental friendliness to a certain extent,which is welcome in hard-to-recover areas such as heavy oil reservoirs,but the economic cost is often high.In future research on EOR technologies,flow field control and flow channel plugging will be the potential directions of traditional development methods,and the application of nanoparticles will revolutionize the chemical EOR methods.On the basis of diversified reservoir stimulation,combined with a variety of modern data processing schemes,multichannel EOR technologies are being developed to realize the systematic,intelligent,and cost-effective development of carbonate reservoirs.

The influence of pore structure on P-& S-wave velocities in complex carbonate reservoirs with secondary storage space

Secondary storage spaces with very complex geometries are well developed in Ordovician carbonate reservoirs in the Tarim Basin,which is taken as a study case in this paper.It is still not clear how the secondary storage space shape influences the P-＆ S-wave velocities （or elastic properties） in complex carbonate reservoirs.In this paper,three classical rock physics models （Wyllie timeaverage equation,Gassmann equation and the Kuster-Toks z model） are comparably analyzed for their construction principles and actual velocity prediction results,aiming at determining the most favourable rock physics model to consider the influence of secondary storage space shape.Then relationships between the P-＆ S-wave velocities in carbonate reservoirs and geometric shapes of secondary storage spaces are discussed from different aspects based on actual well data by employing the favourable rock physics model.To explain the influence of secondary storage space shape on V P-V S relationship,it is analyzed for the differences of S-wave velocities between derived from common empirical relationships （including Castagna＇s mud rock line and Greenberg-Castagna V P-V S relationship） and predicted by the rock physics model.We advocate that V P-V S relationship for complex carbonate reservoirs should be built for different storage space types.For the carbonate reservoirs in the Tarim Basin,the V P-V S relationships for fractured,fractured-cavernous,and fractured-hole-vuggy reservoirs are respectively built on the basis of velocity prediction and secondary storage space type determination.Through the discussion above,it is expected that the velocity prediction and the V P-V S relationships for complex carbonate reservoirs should fully consider the influence of secondary storage space shape,thus providing more reasonable constraints for prestack inversion,further building a foundation for realizing carbonate reservoir prediction and fluid prediction.

Pre-stack inversion for caved carbonate reservoir prediction:A case study from Tarim Basin,China

The major storage space types in the carbonate reservoir in the Ordovician in the TZ45 area are secondary dissolution caves.For the prediction of caved carbonate reservoir,post-stack methods are commonly used in the oilfield at present since pre-stack inversion is always limited by poor seismic data quality and insufficient logging data.In this paper,based on amplitude preserved seismic data processing and rock-physics analysis,pre-stack inversion is employed to predict the caved carbonate reservoir in TZ45 area by seriously controlling the quality of inversion procedures.These procedures mainly include angle-gather conversion,partial stack,wavelet estimation,low-frequency model building and inversion residual analysis.The amplitude-preserved data processing method can achieve high quality data based on the principle that they are very consistent with the synthetics.Besides,the foundation of pre-stack inversion and reservoir prediction criterion can be established by the connection between reservoir property and seismic reflection through rock-physics analysis.Finally,the inversion result is consistent with drilling wells in most cases.It is concluded that integrated with amplitude-preserved processing and rock-physics,pre-stack inversion can be effectively applied in the caved carbonate reservoir prediction.

A new method of formation evaluation for fractured and caved carbonate reservoirs:A case study from the Lundong area,Tarim Basin,China

The carbonate reservoirs in the Tarim Basin are characterized by low matrix-porosity,heterogeneity and anisotropy,which make it difficult to predict and evaluate these reservoirs.The reservoir formations in Lundong area experienced a series of diagenesis and tectonic evolution stages.And secondary storage spaces such as fractures and dissolution caves were developed while nearly all the primary pores have disappeared.Based on a summary of different types of storage spaces and their responses in conventional logs,FMI and full waveform sonic logs which are sensitive to different reservoirs,the comprehensive probability index （CPI） method is applied to evaluating the reservoirs and a standard of reservoir classification is established.By comparing the evaluation results with actual welllogging results,the method has proven to be practical for formation evaluation of carbonate reservoirs,especially for the fractured carbonate reservoirs.In reservoir fluid identification,the multivariate stepwise discriminant analysis （MSDA） method is introduced.Combining the CPI method and MSDA method,comprehensive formation evaluation has been performed for fractured and caved carbonate reservoirs in the Tarim Basin.Additionally,on the basis of secondary pore inversion results,another new method of formation evaluation is also proposed in the discussion part of this paper.Through detailed application result analysis,the method shows a promising capability for formation evaluation of complex carbonate reservoirs dominated by various secondary pores such as holes,caves,and cracks.

The application of amplitude-preserved processing and migration for carbonate reservoir prediction in the Tarim Basin,China

Conventional seismic exploration method based on post-stack data usually fails to identify the distribution of fractured and caved carbonate reservoirs in the Tarim Basin,so the rich pre-stack information should be applied to the prediction of carbonate reservoirs.Amplitude-preserved seismic data processing is the foundation.In this paper,according to the feature of desert seismic data （including weak reflection,fast attenuation of high frequency components,strong coherent noises,low S/N and resolution）,a set of amplitude-preserved processing techniques is applied and a reasonable processing flow is formed to obtain the high quality data.After implementing a set of pre-stack amplitude-preserved processing,we test and define the kernel parameters of amplitude-preserved Kirchhoff PSTM （pre-stack time migration） and subsequent gathers processing,in order to obtain the amplitude-preserved gathers used to the isotropic pre-stack inversion for the identification of caved reservoirs.The AVO characteristics of obtained gathers fit well with the synthetic gathers from logging data,and it proves that the processing above is amplitudepreserved.The azimuthal processing techniques,including azimuth division and binning enlargement,are implemented for amplitude-preserved azimuthal gathers with the uniform fold.They can be used in the anisotropic inversion to detect effective fractures.The processing techniques and flows are applied to the field seismic data,and are proved available for providing the amplitude-preserved gathers for carbonate reservoir prediction in the Tarim Basin.

A two-step method to apply Xu–Payne multi-porosity model to estimate pore type from seismic data for carbonate reservoirs

Carbonate reservoirs exhibit strong heterogeneity in the distribution of pore types that can be quantitatively characterized by applying Xu–Payne multi-porosity model.However,there are some prerequisites to this model the porosity and saturation need to be provided.In general,these application conditions are difficult to satisfy for seismic data.In order to overcome this problem,we present a two-step method to estimate the porosity and saturation and pore type of carbonate reservoirs from seismic data.In step one,the pore space of the carbonate reservoir is equivalent to a single-porosity system with an effective pore aspect ratio;then,a 3D rock-physics template(RPT)is established through the Gassmann’s equations and effective medium models;and then,the effective aspect ratio of pore,porosity and fluid saturation are simultaneously estimated from the seismic data based on 3D RPT.In step two,the pore space of the carbonate reservoir is equivalent to a triple-porosity system.Combined with the inverted porosity and saturation in the first step,the porosities of three pore types can be inverted from the seismic elastic properties.The application results indicate that our method can obtain accurate physical properties consistent with logging data and ensure the reliability of characterization of pore type.

Prediction of Fracture-Cavity System in Carbonate Reservoir： A Case Study in the Tahe Oilfield

The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs are diversified in scale, space configuration, and complex in filling. For this kind of reservoir, a suite of seismic prestack or poststack prediction techniques has been developed based on the separation of seismic wave fields. Through cross-verification of the estimated results,a detailed description of palaeogeomorphology and structural features such as pores, cavities, and fractures in unaka has been achieved, the understanding of the spatial distribution of reservoir improved.

Eogenetic Karst in Interbedded Carbonates and Evaporites and Its Impact on Hydrocarbon Reservoir: A New Case from Middle Triassic Leikoupo Formation in Sichuan Basin, Southwest China

Karst in interbedded carbonates and evaporites has been reported to have important and complex impacts on reservoir. It is significant for exploration and karst geology. Here, we report such a new case from Middle Triassic Leikoupo Formation of Sichuan Basin, Southwest China. Stratigraphic incompleteness and the occurrence of unconformity provide evidence for the presence of eogenetic karst. Under the impact of this eogenetic karst, residual weathered and solution-collapse breccia, solution pores and silicification and dedolomitization have been observed. Classic stratigraphic zonation of karst is not readily distinguishable, which is ascribed to the stratigraphic collapse of carbonate rocks resulting from the dissolution of evaporites by lateral subsurface fluid flow. In terms of impact on reservoir quality, karst can generally improve the initial physical property of the porous layers in theory. However, subsurface fluid flow dissolved the evarporitic beds and facilitated the collapse of overlying strata. As a consequence, the lateral continuity of the reservoirs would be destroyed, and relatively high-quality reservoirs can only be developed with little collapse of overlying strata, reflecting reservoir heterogeneities. This may be a general feature of reservoir formation under the impact of karst in interbedded carbonates and evaporites.

Coherent variations of the obliquity components in global ice volume and ocean carbon reservoir over the past 5 Ma

The Milankovi theory stresses that the summer insolation in the high northern latitudes that is dominated by the precession cycle controls the glacial/interglacial cycles in global climate change.If the climate system responds linearly to the external insolation forcing,the precession cycle of 23 or 19 ka should dominate the variations in the climatic proxy records.I performed spectral and evolutive cross spectral analyses on the high resolution benthic 18O and 13C records from the South China Sea and the North Atlantic,the proxies of global ice volume and ocean carbon reservoir respectively.I found that the obliquity instead of the eccentricity or the precession is the most marked cycle in the global ice volume and ocean carbon reservoir variations over the past 5 Ma.The analysis further reveals that only at the obliquity band instead of the eccentricity or the precession band does the global ice volume and ocean carbon reservoir display consistently high coherency and stable phase relationship over the past 5 Ma.The consistently positive or near-zero phases of the benthic 18O relative to the benthic13C at the obliquity band suggest that the global carbon cycle is involved in the polar ice sheet growth as an important internal feedback,not a determinative driving factor.The obliquity instead of the precession or the eccentricity takes the dominant role of driving the global climate change during the Pliocene and Pleistocene.

Geochemical Characteristics and Migration Pathways of Ordovician Carbonate Oil Reservoirs in the Tuoputai Area,Tarim Basin,Northwestern China

Exploration potential is huge and the oil resources are rich in the Ordovician reservoirs of the Tarim Basin.However,the mechanism of hydrocarbon accumulation is complex and not yet fully understood.In the Tuoputai area,the hydrocarbon migration pathways and characteristics of deep hydrocarbon accumulation are revealed through analyses of the physical data of rich oil and gas,the geochemical parameters of oil,and fluid inclusions.The results show that the Ordovician oils in the Tuoputai area have the same geochemical characteristics as the mixed oil from the Lower Cambrian source rock and the Middle–Upper Ordovician source rock.The Ordovician reservoirs have been charged three times:in the late Caledonian,late Hercynian,and Himalayan stages.Oil charging occurred in the Hercynian stage,in particular,as it is the main filling period of hydrocarbon.The north-northeast(NNE)-trending TP12 CX major fault,active in in these times and is dominant migration channel of hydrocarbon,but there is segmentation affected by the difference of activities.Oil maturity is higher in the south than in the north and is abnormally high near the major fault.Parameters related to migration indicate that oil migrated northeastward along the NNE-trending TP12 CX major fault and adjusted laterally along the secondary faults and weathering crust,forming the present characteristics of oil and gas distribution.