Long-Term Manure Amendments Enhance Soil Aggregation and Carbon Saturation of Stable Pools in North China Plain

Organic amendment is considered as an effective way to increase soil organic carbon （SOC） stock in croplands. To better understand its potential for SOC sequestration, whether SOC saturation could be observed in an intensive agricultural ecosystem receiving long-term composted manure were examined. Different SOC pools were isolated by physical fractionation techniques ofa Cambisol soil under a long-term manure experiment with wheat-maize cropping in North China Plain. A field experiment was initiated in 1993, with 6 treatments including control （i.e., without fertilization）, chemical fertilizer only, low rate of traditional composted manure （7.5 t ha-h）, high rate of traditional composted manure （15 t ha-~）, low rate ofbio-composted manure （7.5 t ha-h） and high rate of bio-composted manure （15 t ha-h）. The results showed that consecutive （for up to 20 years） composted manure amendments significantly improved soil macro-aggregation, aggregate associated SOC concentration, and soil structure stability. In detail, SOC concentration in the sand-sized fraction （〉53 ~tm） continued to increase with manure application rate, while the silt （2-53 I.tm） and clay （〈2 ~tm） particles showed no further increase with greater C inputs, exhibiting the C saturation. Further physical separation of small macro-aggregates （250-2 000 tam） into subpools showed that the non-protected coarse particulate organic matter （cPOM, 〉250 pro） was the fraction in which SOC continued to increase with increasing manure application rate. In contrast, the chemical and physical protected C pools （i.e., micro-aggregates and silt-clay occluded in the small macro- aggregates） exhibited no additional C sequestration when the manure application rate was increased. It can be concluded that repeated manure amendments can increase soil macro-aggregation and lead to the increase in relatively stable C pools, showing hierarchical saturation behavior in the intensive cropping system of North China Plain.

Low soil carbon saturation deffcit limits the abundance of cbbL-carrying bacteria under long-term no-tillage maize cultivation in northern China

The responses of cbbL-carrying bacteria to different levels of soil carbon saturation deficits(SCSD)under tillage managements are largely unknown.We assessed the influence of SCSD on the abundance and diversity of cbbLcarrying bacteria under long-term no-tillage with residue retention(NT)and conventional tillage without residue retention(CT)cultivation systems in maize.We found SCSD was smaller under NT than under CT in the 0-15 cm soil layer.The abundance and the Shannon diversity of cbbL-carrying bacteria in the NT treatment were lower than in the CT treatment.Soil carbon saturation and cbbL gene abundance showed a significant positive correlation,but there was no correlation between soil carbon saturation and cbbL gene diversity.However,the long-term NT practice decreased cbbL-carrying bacteria diversity and altered the community structure of the cbbL-carrying bacteria.Our results indicated that low SCSD limited the abundance of cbbL-carrying bacteria,but there was no relationship between low SCSD and diversity of cbbLcarrying bacteria.We suggest that further studies of cbbL-carrying bacteria carbon sequestration rates and capacity should be based on the effect of management practices on cbbL-carrying bacteria abundance and diversity.Our study has important implications for the relationship between the biological and physicochemical mechanisms in CO_(2) fixation.

Changes in particulate and mineral-associated organic carbon with land use in contrasting soils

Soil organic carbon(SOC)is the largest terrestrial carbon(C)stock,and the capacity of soils to preserve organic C(OC)varies with many factors,including land use,soil type,and soil depth.We investigated the effect of land use change on soil particulate organic matter(POM)and mineral-associated organic matter(MOM).Surface(0–10 cm)and subsurface(60–70 cm)samples were collected from paired sites(native and cropped)of four contrasting soils.Bulk soils were separated into POM and MOM fractions,which were analyzed for mineralogy,OC,nitrogen,isotopic signatures,and14C.The POM fractions of surface soils were relatively unaffected by land use change,possibly because of the continuous input of crop residues,whereas the POM fractions in corresponding subsurface soils lost more OC.In surface soils,MOM fractions dominated by the oxides of iron and aluminum(oxide-OM)lost more OC than those dominated by phyllosilicates and quartz,which was attributed to diverse organic matter(OM)input and the extent of OC saturation limit of soils.In contrast,oxide-OM fractions were less affected than the other two MOM fractions in the subsurface soils,possibly due to OC protection via organo-mineral associations.The deviations in isotopic signature(linked with vegetation)across the fractions suggested that fresh crop residues constituted the bulk of OM in surface soils(supported by greater14C).Increased isotopic signatures and lower14C in subsurface MOM fractions suggested the association of more microbially processed,aged OC with oxide-OM fractions than with the other MOM fractions.The results reveal that the quantity and quality of OC after land use change is influenced by the nature of C input in surface soils and by mineral-organic association in subsurface soils.

Modeling the effects of land-use optimization on the soil organic carbon sequestration potential

Increasing soil organic carbon （SOC） sequestration is not only an efficient method to address climate change problems but also a useful way to improve land productivity. It has been reported by many studies that land-use changes can significantly influence the se- questration of SOC. However, the SOC sequestration potential （SOCP, the difference between the saturation and the existing content of SOC） caused by land-use change, and the effects of land-use optimization on the SOCP are still not well understood. In this research, we modeled the effects of land-use optimization on SOCP in Beijing. We simulated three land-use optimization scenarios （uncontrolled scenario, scale control scenario, and spatial restriction scenario） and assessed their effects on SOCP. The total SOCP （0-20 cm） in Beijing in 2010 was estimated as 23.82 Tg C or 18.27 t C/ha. In the uncontrolled scenario, the built-up land area of Beijing would increase by 951 km2 from 2010 to 2030, and the SOCP would decrease by 1.73 Tg C. In the scale control scenario, the built-up land area would de- crease by 25 km2 and the SOCP would increase by 0.07 Tg C from 2010 to 2030. Compared to the uncontrolled scenario, the SOCP in 2030 of Beijing would increase by 0.77 Tg C or 0.64 t C/ha in the spatial restriction scenario. This research provides evidence to guide planning authorities in conducting land-use optimization strategies and estimating their effects on the carbon sequestration function of land-use systems.

Soil organic carbon saturation deficit under primary agricultural managements across major croplands in China

Introduction:To generate information for the effective management of soil organic carbon(SOC)sequestration in Chinese croplands,we compared the additional organic carbon(C)that can be stabilized by fine soil particles(<20μm)with typical fertilization practices across soil types and climate zones.Using data from 30 long-term experimental study sites across the major agricultural zones in China,we estimated stable SOC saturation deficit(SOC_(deficit))under no fertilization(CK),chemical fertilization(CF),straw plus CF(S+CF),and manure plus CF(M+CF).Stable SOC_(deficit)was defined as the difference between potential and current SOC stabilized by fine soil particles.Outcomes:Stable SOC_(deficit)values varied from 51%to 82%.Soils dominated by 2:1 clay minerals showed larger stable SOC_(deficit)than soils dominated by 1:1 clay minerals under each treatment.For soils dominated by 2:1 clay minerals,stable SOC_(deficit)was significantly lower under M+CF(69%)than under CK,CF,and S+CF(78-82%)treatments,and it increased with increasing mean annual temperature(<10°C).In soils dominated by 1:1 clay minerals,stable SOC_(deficit)was considerably lower in paddy and paddy-upland than in upland soils,suggesting that paddies effectively stabilize C inputs.Discussion:Agricultural soils in China have considerable C sequestration potential,despite decades of fertilization practices.To manage soil C sequestration and model soil C dynamics effectively,factors such as soil mineral types,fertilization,and cropland use should be considered.Conclusion:Our results demonstrated that manure addition was the best fertilization method for improving soil fertility,whereas straw return in Chinese croplands should take into account climate mitigation in future.

Q-switched ytterbium doped fiber laser using multi-walled carbon nanotubes saturable absorber

A Q-switched ytterbium-doped fiber laser （YDFL） is proposed and demonstrated using a newly developed multi-walled carbon nanotubes polyethylene oxide （MWCNTs-PEO） film as a passive saturable absorber （SA）. The saturable absorber is prepared by mixing the MWCNTs homogeneous solution into a dilute PEO polymer solution before it is left to dry at room temperature to produce thin film. Then the film is sandwiched between two FC/PC fiber connectors and integrated into the laser cavity for Q-switching pulse generation. The laser generates a stable pulse operating at wavelength of 1060.2 nm with a threshold pump power of 53.43 mW. The YDFL generates a stable pulse train with repetition rates ranging from 7.92 to 24.27 kHz by varying 980-nm pump power from 53.42 to 65.72 mW. At 59.55-mW pump power, the lowest pulse width and the highest pulse energy are obtained at 12.18 μs and 143.5 n J, respectively.

Q-switched fiber laser using carbon platinum saturable absorber on side-polished fiber

A 1550 nm Q-switched fiber laser using a carbon platinum saturable absorber deposited on side-polished fiber（SPF） is proposed and demonstrated. The SPF is approximately 2 mm with a polarization-dependent loss（PDL）of 0.4 dB and an insertion loss of 2.5 dB. A stable Q-switched output spectrum is obtained at 1559.34 nm with a peak power of ~6 mW, a pulse width of 1.02 μs, pulse energy of 5.8 nJ, average output power of 0.76 mW, and a repetition rate of 131.6 kHz taken at a pump power of 230.0 mW. A signal-to-noise ratio of 49.62 d B indicates that the Q-switched pulse is highly stable.

Mode-locked 2 μm fiber laser with a multi-walled carbon nanotube as a saturable absorber

We propose and demonstrate a passively mode-locked fiber laser operating at 1951.8 nm using a commercial thulium-doped fiber （TDF） laser, a homemade double-clad thulium-ytterbium co-doped fiber （TYDF） as the gain media, and a multi-walled carbon nanotube （MWCNT） based saturable absorber （SA）. We prepare the MWCNT composite by mixing a homogeneous solution of MWCNTs with a diluted polyvinyl alcohol （PVA） polymer solution and then drying it at room temperature to form a film. The film is placed between two fiber connectors as a SA before it is integrated into a laser ring cavity. The cavity consists of a 2 m long TDF pumped by a 800 nm laser diode and a 15 m long homemade TYDF pumped by a 905 nm multimode laser diode. A stable mode-locking pulse with a repetition rate of 34.6 MHz and a pulse width of 10.79 ps is obtained when the 905 nm multimode pump power reaches 1.8-2.2 W, while the single-mode 800 nm pump power is fixed at 141.5 mW at all times. To the best of our knowledge, this is the first reported mode-locked fiber laser using a MWCNT-based SA.

Self-starting harmonic mode-locked Tm-Bi co-doped germanate f iber laser with carbon nanotube-based saturable absorber

We report a ring cavity passively harmonic mode-locked fiber laser using a newly developed thulium- bismuth co-doped fiber （TBF） as a gain medium in conjunction with a carbon nanotube （CNT）-based saturable absorber. The TBF laser generates a third harmonic mode-locked soliton pulse train with a high repetition rate of 50 MHz and a pulse duration of 1.86 ps. The laser operates at 1 901.6 nm with an average power of 6.6 mW, corresponding to a pulse energy of 0.132 nJ, at a 1 552 nm pump power of 723.3 roW.