Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias eff...Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias effect on the film characteristics. Deposited films are characterized by Raman spectroscopy, infrared (IR) and ultraviolet-visible absorption techniques. There are two broad Raman peaks around 1340 cm-1 and 1600 cm-1 and the first one has a greater sp3 component with an increased bias. Infrared spectroscopy has three sp3 C-H modes at 2852 cm-1, 2926 cm-1 and 2962 cm-1, respectively and also shows an intensity increase with the negative bias. Optical band gap is calculated from the ultraviolet-visible absorption spectroscopy and the increased values with negative bias and deposition time are obtained. After a thermal anneal at about 500℃ for an hour to the film deposited under the bias of-90 V, we get an almost unchanged Raman spectrum and a peak intensity-reduced IR signal, which indicates a reduced H-content in the film. Meanwhile the optical band gap changed from 0.85 eV to 1.5 eV.展开更多
Carbon-sulfur nano-composite cathodes for lithium rechargeable batteries were investigated by electrochemical impedance spectroscopy (EIS). The novel carbon-sulfur nano-composite material was synthesized by heating su...Carbon-sulfur nano-composite cathodes for lithium rechargeable batteries were investigated by electrochemical impedance spectroscopy (EIS). The novel carbon-sulfur nano-composite material was synthesized by heating sublimed sulfur and high surface area activated carbon (HSAAC) in certain conditions. Equivalent circuits were used to fit the spectra at different discharge states. The variations of impedance spectra, charge-transfer resistance and double layer capacitance were discussed. The changes of EIS with potential were analyzed based on a plausible electrical equivalent circuit model, and some parameters were measured and analyzed about electrochemical performance and state of charge and discharge of the electrode. The good accuracy in fitting values of the model to the experimental data indicates that the mathematical model gives out a satisfying description upon the mechanism of high rate of capacity fade in lithium-sulfur battery.展开更多
Fructus cnidii （Chinese name shechuangzi） is the fruit produced by Cnidium monnieri （L.） Cusson （Umbelliferae）. It is a perennial herb that is used to treat skin-related diseases and gynecopathyell. Recent pharm...Fructus cnidii （Chinese name shechuangzi） is the fruit produced by Cnidium monnieri （L.） Cusson （Umbelliferae）. It is a perennial herb that is used to treat skin-related diseases and gynecopathyell. Recent pharmacological studies have revealed crude extracts or components isolated from fructus cnidii possess antiallergic, antipruritic, antidermatophytic, antibacterial, antifungal, and antiosteoporotic activities. Osthole and imperatorin are the major compounds present in shechuangzi. They are often used as standards for the evaluation of the quality of shechuangzi products.展开更多
The preparation of crystalline C3N4 films was investigated using pulsed arc discharge from mixed methanol and ammonia water at atmospheric pressure. The X-ray diffraction （XRD） patterns of the films prepared at a su...The preparation of crystalline C3N4 films was investigated using pulsed arc discharge from mixed methanol and ammonia water at atmospheric pressure. The X-ray diffraction （XRD） patterns of the films prepared at a substrate temperature of 450℃ suggested that the film was composed of α-C3N4 and fl-C3N4 crystallites. Raman spectra exhibited distinct peaks which are in good agreement with those predicted theoretically for C3N4 crystallites.展开更多
近年来,近红外光谱技术在作物样品组分检测和育种材料快速筛选等方面得到广泛应用,而关于水稻源库器官,尤其是水稻节间主要碳氮代谢组分高通量检测的研究鲜见报道。本研究以试验获得的576份代表性节间样本为材料,在获得样本化学实测值...近年来,近红外光谱技术在作物样品组分检测和育种材料快速筛选等方面得到广泛应用,而关于水稻源库器官,尤其是水稻节间主要碳氮代谢组分高通量检测的研究鲜见报道。本研究以试验获得的576份代表性节间样本为材料,在获得样本化学实测值的基础上,采集样本的近红外光谱信息,并利用偏最小二乘(partial least square,PLS)法构建水稻节间主要碳氮代谢组分蔗糖、淀粉、总氮模型。模型验证结果显示:水稻节间蔗糖、淀粉、总氮含量PLS模型验证集决定系数分别为0.988、0.977和0.957,相对分析误差均大于3,模型的性能指数分别为85.20、85.80和86.50,表明所建模型预测结果准确可靠。此外,水稻叶片和叶鞘的淀粉、总氮含量和碳氮比的PLS模型也具有较高的精度。本研究构建了水稻节间主要碳氮代谢组分的近红外光谱模型,为水稻栽培生理和高产栽培理论研究提供了技术支撑。展开更多
基金The project supported by the National Natural Science Foundation of China (No. 19835030 and 19875053)
文摘Diamond-like carbon (DLC) films are deposited on quartz substrate using pure CH4 in the surface wave plasma equipment. A direct current negative bias up to -90 V is applied to the substrate to investigate the bias effect on the film characteristics. Deposited films are characterized by Raman spectroscopy, infrared (IR) and ultraviolet-visible absorption techniques. There are two broad Raman peaks around 1340 cm-1 and 1600 cm-1 and the first one has a greater sp3 component with an increased bias. Infrared spectroscopy has three sp3 C-H modes at 2852 cm-1, 2926 cm-1 and 2962 cm-1, respectively and also shows an intensity increase with the negative bias. Optical band gap is calculated from the ultraviolet-visible absorption spectroscopy and the increased values with negative bias and deposition time are obtained. After a thermal anneal at about 500℃ for an hour to the film deposited under the bias of-90 V, we get an almost unchanged Raman spectrum and a peak intensity-reduced IR signal, which indicates a reduced H-content in the film. Meanwhile the optical band gap changed from 0.85 eV to 1.5 eV.
文摘Carbon-sulfur nano-composite cathodes for lithium rechargeable batteries were investigated by electrochemical impedance spectroscopy (EIS). The novel carbon-sulfur nano-composite material was synthesized by heating sublimed sulfur and high surface area activated carbon (HSAAC) in certain conditions. Equivalent circuits were used to fit the spectra at different discharge states. The variations of impedance spectra, charge-transfer resistance and double layer capacitance were discussed. The changes of EIS with potential were analyzed based on a plausible electrical equivalent circuit model, and some parameters were measured and analyzed about electrochemical performance and state of charge and discharge of the electrode. The good accuracy in fitting values of the model to the experimental data indicates that the mathematical model gives out a satisfying description upon the mechanism of high rate of capacity fade in lithium-sulfur battery.
基金Supported by the Talented Young Pressional Foundation of Jilin Province(No 2005123)
文摘Fructus cnidii （Chinese name shechuangzi） is the fruit produced by Cnidium monnieri （L.） Cusson （Umbelliferae）. It is a perennial herb that is used to treat skin-related diseases and gynecopathyell. Recent pharmacological studies have revealed crude extracts or components isolated from fructus cnidii possess antiallergic, antipruritic, antidermatophytic, antibacterial, antifungal, and antiosteoporotic activities. Osthole and imperatorin are the major compounds present in shechuangzi. They are often used as standards for the evaluation of the quality of shechuangzi products.
基金supported by Natural Science Foundation of Hubei Province(No.2005ABA023)
文摘The preparation of crystalline C3N4 films was investigated using pulsed arc discharge from mixed methanol and ammonia water at atmospheric pressure. The X-ray diffraction （XRD） patterns of the films prepared at a substrate temperature of 450℃ suggested that the film was composed of α-C3N4 and fl-C3N4 crystallites. Raman spectra exhibited distinct peaks which are in good agreement with those predicted theoretically for C3N4 crystallites.
文摘近年来,近红外光谱技术在作物样品组分检测和育种材料快速筛选等方面得到广泛应用,而关于水稻源库器官,尤其是水稻节间主要碳氮代谢组分高通量检测的研究鲜见报道。本研究以试验获得的576份代表性节间样本为材料,在获得样本化学实测值的基础上,采集样本的近红外光谱信息,并利用偏最小二乘(partial least square,PLS)法构建水稻节间主要碳氮代谢组分蔗糖、淀粉、总氮模型。模型验证结果显示:水稻节间蔗糖、淀粉、总氮含量PLS模型验证集决定系数分别为0.988、0.977和0.957,相对分析误差均大于3,模型的性能指数分别为85.20、85.80和86.50,表明所建模型预测结果准确可靠。此外,水稻叶片和叶鞘的淀粉、总氮含量和碳氮比的PLS模型也具有较高的精度。本研究构建了水稻节间主要碳氮代谢组分的近红外光谱模型,为水稻栽培生理和高产栽培理论研究提供了技术支撑。
