The dating and temperature measurement technologies for carbonate minerals and their application in hydrocarbon accumulation research in the paleouplift in central Sichuan Basin, SW China

A new method for reconstructing the geological history of hydrocarbon accumulation is developed, which are constrained by U-Pb isotope age and clumped isotope((35)47) temperature of host minerals of hydrocarbon-bearing inclusions. For constraining the time and depth of hydrocarbon accumulation by the laser in-situ U-Pb isotope age and clumped isotope temperature, there are two key steps:(1) Investigating feature, abundance and distribution patterns of liquid and gaseous hydrocarbon inclusions with optical microscopes.(2) Dating laser in-situ U-Pb isotope age and measuring clumped isotope temperature of the host minerals of hydrocarbon inclusions. These technologies have been applied for studying the stages of hydrocarbon accumulation in the Sinian Dengying gas reservoir in the paleo-uplift of the central Sichuan Basin. By dating the U-Pb isotope age and measuring the temperature of clumped isotope((35)47) of the host minerals of hydrocarbon inclusions in dolomite, three stages of hydrocarbon accumulation were identified:(1) Late Silurian: the first stage of oil accumulation at(416±23) Ma.(2) Late Permian to Early Triassic: the second stage of oil accumulation between(248±27) Ma and(246.3±1.5) Ma.(3) Yanshan to Himalayan period: gas accumulation between(115±69) Ma and(41±10) Ma. The reconstructed hydrocarbon accumulation history of the Dengying gas reservoir in the paleo-uplift of the central Sichuan Basin is highly consistent with the tectonic-burial history, basin thermal history and hydrocarbon generation history, indicating that the new method is a reliable way for reconstructing the hydrocarbon accumulation history.

Decomposition analysis of carbon reduction measures and carbon emission changes in five areas in China

Based on the analysis of primary energy consumption structure in five main provinces or municipalities in China,the factors that affect carbon emissions in the five study areas are analyzed quantitatively and comparatively with the decomposition analysis method.Empirical results demonstrate that the decomposition models of carbon emissions can be defined as ＂municipality model＂ and ＂provincial model＂,and the population factor of ＂municipal model＂ plays a significant role in carbon emissions than that of ＂provincial model＂.Either positive or negative effects of energy structure can be found in five different areas.However,there is a general trend that energy structure effort is becoming more and more important.Based on the characteristics and trends of carbon emissions in different areas,the carbon reduction measures are proposed as well.

Key global climate governance problems and Chinese countermeasures

Presently,the full implementation of the negotiations and collaborations under the Paris Agreement faces new key problems and severe challenges.These problems and challenges include the following:how to honor the principle of“common but differentiated responsibilities”to facilitate a comprehensive,balanced,and effective implementation of the key elements of the Paris Agreement,such as adaptation,mitigation,finance,technology,capacity building,and transparency;how to uphold and maintain the status of China and other emerging countries as developing countries in light of the requirements of the United Nations Framework Convention on Climate Change and the historical responsibilities of these countries;and how to assess the goal of limiting the global temperature increase to 1.5℃and what constitutes an equitable carbon mitigation pathway for different types of countries.Developed countries and developing countries have drastically diverging views on carbon border adjustment measures for trade with developing countries proposed by several developed countries such as the European Union.Developed countries have demonstrated obvious intentions and actions designed to weaken and neglect the principle of“common but differentiated responsibilities”,to impose mitigation pressure on developing countries,to shift the responsibilities for emissions onto others,and to pass on the costs of mitigation.The maneuvering among different types of countries and interest groups has become increasingly intense.In response,China must maintain its strategic focus,adhere to the goals and principles established by the Paris Agreement,stick to its strategic positioning as a developing country,solidify strategic support from the developing world,and safeguard the legitimate rights and interests of developing countries.China played a conducive role in facilitating the Paris Agreement and has become an active participant,contributor,and leader in global climate governance.China must continue to follow Xi Jinping Thought on Socialism with Chinese Characteristics for a New Era and its conception of ecological civilization and the concept of building a community of common destiny,to actively lead the cooperation process in the construction of a global climate governance system characterized by equity,justice,and win-win collaborations,and to promote compliance with the Paris Agreement.At the same time,China should accelerate the green,low-carbon,circular transformation of its economy;accelerate the coordinated governance of the economy,environment,and climate change;and formulate and implement a long-term low-carbon development strategy.By the middle of the 21st century,while achieving the goal of building a great modern socialist country,China can also achieve a deep decarbonization development path that is in line with the goal of limiting the global temperature increase to well below 2°C and pursuing efforts to limit the increase to 1.5℃.

First Global Carbon Dioxide Maps Produced from Tan Sat Measurements

1.The need for global carbon monitoring from space and the TanSat mission Global warming is a major problem,for which carbon dioxide（CO2 ）is the main greenhouse gas involved in heating the troposphere.However,the poor availability of global CO2 measurements makes it difficult to estimate CO2 emissions accurately.

Long-Term Trends of Carbon Monoxide Total Columnar Amount in Urban Areas and Background Regions:Ground-and Satellite-based Spectroscopic Measurements

A comparative study was carried out to explore carbon monoxide total columnar amount（CO TC） in background and polluted atmosphere, including the stations of ZSS（Zvenigorod）, ZOTTO（Central Siberia）, Peterhof, Beijing, and Moscow,during 1998–2014, on the basis of ground-and satellite-based spectroscopic measurements. Interannual variations of CO TC in different regions of Eurasia were obtained from ground-based spectroscopic observations, combined with satellite data from the sensors MOPITT（2001–14）, AIRS（2003–14）, and IASI Met Op-A（2010–13）. A decreasing trend in CO TC（1998–2014） was found at the urban site of Beijing, where CO TC decreased by 1.14% ± 0.87% yr^（-1）. Meanwhile, at the Moscow site, CO TC decreased remarkably by 3.73% ± 0.39% yr^（-1）. In the background regions（ZSS, ZOTTO, Peterhof）, the reduction was 0.9%–1.7% yr^（-1） during the same period. Based on the AIRSv6 satellite data for the period 2003–14, a slight decrease（0.4%–0.6% yr^（-1）） of CO TC was detected over the midlatitudes of Eurasia, while a reduction of 0.9%–1.2% yr^（-1） was found in Southeast Asia. The degree of correlation between the CO TC derived from satellite products（MOPITTv6 Joint, AIRSv6 and IASI Met Op-A） and ground-based measurements was calculated, revealing significant correlation in unpolluted regions.While in polluted areas, IASI Met Op-A and AIRSv6 data underestimated CO TC by a factor of 1.5–2.8. On average, the correlation coefficient between ground-and satellite-based data increased significantly for cases with PBL heights greater than 500 m.

Relative Irradiance Measurement and Bonding Configurations of Amorphous Fluorinated Carbon Films Deposited by Electron Cyclotron Resonance Plasma

a-C:F films are deposited by microwave electron cyclotron resonance (ECR)plasma chemical vapor deposition (CVD) using trifluoromethane (CHF3) and benzene (C6H6) as source gases at different microwave powers. The radicals in plasma originating from source gases dissociation are analyzed by relative irradiance measurement. The bonding configurations and binding state of a-C:F films are measured with Fourier-transformed infrared spectrometer (FTIR) and x-ray photoelectron spectroscopy (XPS). The results show that a-C:F films are mainly composed of CF radical at lower powers but of CF2 radical at higher powers. The deposition of films is related to the radicals generated in plasma and the main bonding configurations are dependent on the ratio of CF to CF2 radicals in films.

Carbon Emission Measurement and the Decoupling Effect Under the“Double Carbon”Goal in Xi’an,China

Cities generate more than 60%of carbon emissions and are the main battleground for achieving the target.However,there is no unified and standardized measurement methods of carbon emissions in cities.In this paper,we took Xi’an as an example and started by measuring carbon emissions with the new standards.Then,the decoupling of economic development from carbon emissions was studied according to the Tapio decoupling theory.Based on the generalized Divisia index method,the decoupling effort model was proposed to study the impact of carbon emission factors contributing to carbon reduction.The results show:(i)During the period 1995–2021,the carbon emissions of Xi’an increased rapidly,with an average annual growth rate of 6.06%,due to the accelerating pace of urbanization and industrialization.(ii)The energy consumption sector accounted for the largest share of carbon emissions,ranging from 77.38%to 89.46%.Xi’an’s energy structure is primarily based on fossil fuels,especially coal,which holds a significant proportion.To achieve the“double carbon”goal,it is crucial to reduce the dependence on fossil fuels.(iii)The 10th Five-Year Plan was in the state of“expansive coupling”,while other periods were in the“weak decoupling”state from the 9th to 14th Five-Year Plan periods.After the carbon peak year in the 15th Five-Year Plan,it would be in a state of“strong decoupling”.The agricultural production account was the first to achieve a“strong decoupling”state.(iv)The government of Xi’an made efforts to decouple,but these were not enough.Technological innovation played a crucial role in the carbon reduction of Xi’an,and was a key factor in achieving the“double carbon”goal.

Decomposition and decoupling analysis of electricity consumption carbon emissions in China

Electricity consumption is one of the major contributors to greenhouse gas emissions.In this study,we build a power consumption carbon emission measurement model based on the operating margin factor.We use the decomposition and decoupling technology of logarithmic mean Divisia index method to quantify six effects(emission intensity,power generation structure,consumption electricity intensity,economic scale,population structure,and population scale)and comprehensively reflect the degree of dependence of electricity consumption carbon emissions on China's economic development and population changes.Moreover,we utilize the decoupling model to analyze the decoupling state between carbon emissions and economic growth and identify corresponding energy efficiency policies.The results of this study provide a new perspective to understand carbon emission reduction potentials in the electricity use of China.