The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does not have...The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does not have evident correlation with the amount of AlCl3. The results show that the reaction proceeds via carbon cation electrophilic substitution reaction-free radical substitution reaction pathway.展开更多
The reaction of acenaphthene with nitrobenzene was investigated in the presence of AlCl3. The results showed that the reaction proceeded via carboncation-electrophilic substitution reaction and free radical substituti...The reaction of acenaphthene with nitrobenzene was investigated in the presence of AlCl3. The results showed that the reaction proceeded via carboncation-electrophilic substitution reaction and free radical substitution reaction pathway. The products of acenaphthenyl phenylamine and biacenaphthyl could be synthesized by this reaction. The influence of the amount of AlCl3 and the temperature on the components of products were also studied in this reaction.展开更多
基金Supported by the National Nature Science Foundation of China ( 2 96 76 0 45 )
文摘The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does not have evident correlation with the amount of AlCl3. The results show that the reaction proceeds via carbon cation electrophilic substitution reaction-free radical substitution reaction pathway.
文摘The reaction of acenaphthene with nitrobenzene was investigated in the presence of AlCl3. The results showed that the reaction proceeded via carboncation-electrophilic substitution reaction and free radical substitution reaction pathway. The products of acenaphthenyl phenylamine and biacenaphthyl could be synthesized by this reaction. The influence of the amount of AlCl3 and the temperature on the components of products were also studied in this reaction.
