Catalytic cracking oil slurry is a by-product of catalytic cracking projects,and the efficient conversion and sustainable utilization of this material are issues of continuous concern in the petroleum refining industr...Catalytic cracking oil slurry is a by-product of catalytic cracking projects,and the efficient conversion and sustainable utilization of this material are issues of continuous concern in the petroleum refining industry.In this study,oxygen-enriched activated carbon is prepared using a one-step KOH activation method with catalytic cracking oil slurry as the raw material.The as-prepared oil slurry-based activated carbon exhibits a high specific surface area of 2102 m^(2)/g,welldefined micropores with an average diameter of 2 nm,and a rich oxygen doping content of 32.97%.The electrochemical performance of the nitrogen-doped porous carbon is tested in a three-electrode system using a 6 mol/L KOH solution as the electrolyte.It achieves a specific capacitance of up to 230 F/g at a current density of 1 A/g.Moreover,the capacitance retention rate exceeds 89%after 10000 charge and discharge cycles,demonstrating excellent cycle stability.This method not only improves the utilization efficiency of industrial fuel waste but also reduces the production cost of supercapacitor electrode materials,thereby providing a simple and effective strategy for the resource utilization of catalytic cracking oil slurries.展开更多
Fluidized catalytic cracking slurry oil-in-water emulsion(FCCSE)was prepared by using interfacial complexes generation method that was simple and versatile.The critical factors influencing the sample preparation proce...Fluidized catalytic cracking slurry oil-in-water emulsion(FCCSE)was prepared by using interfacial complexes generation method that was simple and versatile.The critical factors influencing the sample preparation process were optimized,for instance,the optimum value of the mixed hydrophile-lipophile balance of compound emulsifier was 11.36,the content of compound emulsifier was 4 wt%,the emulsification temperature was 75C,the agitation speed was 200 rpm,and the emulsification time was 30e45 min.The performance as a drilling fluid additive was also investigated with respect to rheological properties,filtration loss and inhibition of FCCSE.Experimental results showed that FCCSE was favorable to inhibiting clay expansion and dispersion and reducing fluid loss.Furthermore,it had good compatibility with other additives and did not affect the rheological properties of drilling fluids.FCCSE exhibited better performance than the available emulsified asphalt.It has a promising application as anti-collapse agent in petroleum and natural gas drilling.展开更多
Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS)...Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.展开更多
基金the National Natural Science Foundation of China(52206262)Small and Medium-sized Sci-tech Enterprises Innovation Capability Improvement Project of Shandong Province,China(2022TSGC2248,2023TSGC0579)+1 种基金Talent Research Project of Qilu University of Technology(Shandong Academy of Sciences)(2023RCKY170)Natural Science Foundation of Shandong Province,China(ZR2020ME191).
文摘Catalytic cracking oil slurry is a by-product of catalytic cracking projects,and the efficient conversion and sustainable utilization of this material are issues of continuous concern in the petroleum refining industry.In this study,oxygen-enriched activated carbon is prepared using a one-step KOH activation method with catalytic cracking oil slurry as the raw material.The as-prepared oil slurry-based activated carbon exhibits a high specific surface area of 2102 m^(2)/g,welldefined micropores with an average diameter of 2 nm,and a rich oxygen doping content of 32.97%.The electrochemical performance of the nitrogen-doped porous carbon is tested in a three-electrode system using a 6 mol/L KOH solution as the electrolyte.It achieves a specific capacitance of up to 230 F/g at a current density of 1 A/g.Moreover,the capacitance retention rate exceeds 89%after 10000 charge and discharge cycles,demonstrating excellent cycle stability.This method not only improves the utilization efficiency of industrial fuel waste but also reduces the production cost of supercapacitor electrode materials,thereby providing a simple and effective strategy for the resource utilization of catalytic cracking oil slurries.
基金the financial support of Geological Survey project of Ministry of Land and Resources(NO.12120113097400).
文摘Fluidized catalytic cracking slurry oil-in-water emulsion(FCCSE)was prepared by using interfacial complexes generation method that was simple and versatile.The critical factors influencing the sample preparation process were optimized,for instance,the optimum value of the mixed hydrophile-lipophile balance of compound emulsifier was 11.36,the content of compound emulsifier was 4 wt%,the emulsification temperature was 75C,the agitation speed was 200 rpm,and the emulsification time was 30e45 min.The performance as a drilling fluid additive was also investigated with respect to rheological properties,filtration loss and inhibition of FCCSE.Experimental results showed that FCCSE was favorable to inhibiting clay expansion and dispersion and reducing fluid loss.Furthermore,it had good compatibility with other additives and did not affect the rheological properties of drilling fluids.FCCSE exhibited better performance than the available emulsified asphalt.It has a promising application as anti-collapse agent in petroleum and natural gas drilling.
基金supported by the[Natural Science Foundation Project of Shandong Province#1]under Grant[ZR2019MEE033][Fundamental Research Funds for the central Universities#2]under Grant[19CX02035A].
文摘Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.