The special subject 'research on life prediction technology of important in-service pressure' mainly analyzes the failure mechanism of large-sized important and criticalin-service pressure vessels under the ac...The special subject 'research on life prediction technology of important in-service pressure' mainly analyzes the failure mechanism of large-sized important and criticalin-service pressure vessels under the action of working medium and investigates safety assessmentand life prediction technology with a view to enhance the operation reliability of in-servicepressure vessels in China. Based on a series of accident investigation and test & measuringresearch, the cause of cracking of catalytic regenerator is analyzed and the in-line non-destructiveexamination method and failure prevention measures for the cracking of catalytic regenerator areproposed.展开更多
An approach for the simulation and optimization of continuous catalyst-regenerative process of reforming is proposed in this paper.Compared to traditional method such as finite difference method,the orthogonal colloca...An approach for the simulation and optimization of continuous catalyst-regenerative process of reforming is proposed in this paper.Compared to traditional method such as finite difference method,the orthogonal collocation method is less time-consuming and more accurate,which can meet the requirement of real-time optimization(RTO).In this paper,the equation-oriented method combined with the orthogonal collocation method and the finite difference method is adopted to build the RTO model for catalytic reforming regenerator.The orthogonal collocation method was adopted to discretize the differential equations and sequential quadratic programming(SQP)algorithm was used to solve the algebraic equations.The rate constants,active energy and reaction order were estimated,with the sum of relative errors between actual value and simulated value serving as optimization objective function.The model can quickly predict the fields of component concentration,temperature and pressure inside the regenerator under different conditions,as well as the real-time optimized conditions for industrial reforming regenerator.展开更多
The effect of Zr on the catalytic performance of Pd/y-A1203 for the methane combustion was investigated. The results show that the addition of Zr can improve the activity and stability of Pd/γ-Al2O3 catalyst, which, ...The effect of Zr on the catalytic performance of Pd/y-A1203 for the methane combustion was investigated. The results show that the addition of Zr can improve the activity and stability of Pd/γ-Al2O3 catalyst, which, based on the catalyst characterization （N2 adsorption, XRD, CO- Chemisorption, XPS, CHa-TPR and O2-TPO）, is ascribed to the interaction between Pd and Zr. The active phase of methane combustion over supported palladium catalyst is the Pd^0/Pd^2＋ mixture. Zr addition inhibits Pd aggregation and enhances the redox properties of active phase Pd^0/ Pd^2＋. H2 reduction could effectively reduce the oxidation degree of Pd species and regenerate the active sites （Pd^0/ pd^2＋）.展开更多
基金important scientech problemtackling subject foundation under the state 9th 5-year plan(no.96-918-02-04).
文摘The special subject 'research on life prediction technology of important in-service pressure' mainly analyzes the failure mechanism of large-sized important and criticalin-service pressure vessels under the action of working medium and investigates safety assessmentand life prediction technology with a view to enhance the operation reliability of in-servicepressure vessels in China. Based on a series of accident investigation and test & measuringresearch, the cause of cracking of catalytic regenerator is analyzed and the in-line non-destructiveexamination method and failure prevention measures for the cracking of catalytic regenerator areproposed.
基金This work was supported by the Science and Technology Development Project of SINOPEC,China(No.319026).
文摘An approach for the simulation and optimization of continuous catalyst-regenerative process of reforming is proposed in this paper.Compared to traditional method such as finite difference method,the orthogonal collocation method is less time-consuming and more accurate,which can meet the requirement of real-time optimization(RTO).In this paper,the equation-oriented method combined with the orthogonal collocation method and the finite difference method is adopted to build the RTO model for catalytic reforming regenerator.The orthogonal collocation method was adopted to discretize the differential equations and sequential quadratic programming(SQP)algorithm was used to solve the algebraic equations.The rate constants,active energy and reaction order were estimated,with the sum of relative errors between actual value and simulated value serving as optimization objective function.The model can quickly predict the fields of component concentration,temperature and pressure inside the regenerator under different conditions,as well as the real-time optimized conditions for industrial reforming regenerator.
基金Acknowledgements This research was supported by the National High Technology Research and Development Program of China （Nos. 2010AA064904 and 2012AA062702） and the National Natural Science Foundation of China （Grant No. 21177006）.
文摘The effect of Zr on the catalytic performance of Pd/y-A1203 for the methane combustion was investigated. The results show that the addition of Zr can improve the activity and stability of Pd/γ-Al2O3 catalyst, which, based on the catalyst characterization （N2 adsorption, XRD, CO- Chemisorption, XPS, CHa-TPR and O2-TPO）, is ascribed to the interaction between Pd and Zr. The active phase of methane combustion over supported palladium catalyst is the Pd^0/Pd^2＋ mixture. Zr addition inhibits Pd aggregation and enhances the redox properties of active phase Pd^0/ Pd^2＋. H2 reduction could effectively reduce the oxidation degree of Pd species and regenerate the active sites （Pd^0/ pd^2＋）.
