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A CENTROSYMMETRIC CHAOS
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作者 刘曾荣 赵南 谢惠民 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 1992年第1期21-23,共3页
Symmetry plays an important pan in the research of the dynamical behavior of nonlinear sys- tem. It is proved in this paper that, for a class of centrosymmetric systems with parametric excitation, chaos behaves in cen... Symmetry plays an important pan in the research of the dynamical behavior of nonlinear sys- tem. It is proved in this paper that, for a class of centrosymmetric systems with parametric excitation, chaos behaves in centrosymmetric manner, which implies that chaos need not to be an unsymmetric dynamical state. 展开更多
关键词 CHAOS parametric excitation centrosymmetry
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Crystal Structure of Bis(O,O′-diisopropyl dithiophosphate): [(C_3H_7O)_2PS_2]_2
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作者 ZHANGShu-sheng LIXue-mei WANGJin-li WANJun JIAOKui 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第2期146-148,共3页
The crystal and molecular structures of [(C 3H 7O) 2PS 2] 2(CCDC No.217201) were determined by means of X-ray crystallography. It crystallized in a triclinic system with space group P1 and lattice parameters a=0.... The crystal and molecular structures of [(C 3H 7O) 2PS 2] 2(CCDC No.217201) were determined by means of X-ray crystallography. It crystallized in a triclinic system with space group P1 and lattice parameters a=0.82794(3) nm, b=0.84764(2) nm, c=0.85034(3) nm, α=97.78(3)°, β=110.77(3)°, γ=94.95(3)°, V=0.54701(9) nm3, Z=1. In this molecule, the two diisopropyl dithiophosphate groups, [(C 3H 7O) 2PS 2] 2, which are parallel to each other, are linked by an S—S bond and there exist inversion centers in the molecule. In the structure, the PS bonds in the two dithiophosphate units are trans-oriented to each other. 展开更多
关键词 X-ray crystallography DITHIOPHOSPHATE centrosymmetry
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SHG from centrosymmetric supermolecular crystal
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作者 郭文生 刘祁涛 +4 位作者 邵宗书 郭放 周广勇 魏春生 王东 《Science China Chemistry》 SCIE EI CAS 2002年第3期267-274,共8页
Supermolecular crystal composed of p-nitrophenol, hexamethylenetetramine, phosphoric acid and water was obtained by supermolecular assembly. The crystal has a centrosymmetric structure with space group P21/c. The rela... Supermolecular crystal composed of p-nitrophenol, hexamethylenetetramine, phosphoric acid and water was obtained by supermolecular assembly. The crystal has a centrosymmetric structure with space group P21/c. The relative intensity and integral value of green frequency doubling of light from the crystal powder compared with that from KDP powder measured by pico-second Nd:YAG laser are 757.3 (KDP: 183.4) and 1771.7 (KDP: 423.98), respectively. In supermolecular crystal, due to the arrangement of centrosymmetric p-nitrophenol molecules in the inorganic-organic host framework formed by hexamethylenetetramine, phosphoric acid and water, the distances between the p-nitrophenol molecules with centrosymmetry are changed (N1A-O1A: 0.8158 nm, N1B’-O1B: 1.4450 nm, N1A-N1A’: 0.5837 nm, N1B’-N1B: 0.6898 nm), and the interaction between the dipoles becomes weak, which is easy for the ground state to turn into the excited state charge separated form, and generate the stable asymmetrical distribution of π-electron cloud density of quinonal structure, thus exhibiting SHG effect. 展开更多
关键词 supermolecular CRYSTAL SHG EFFECT centrosymmetry p-nitrophenol.
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