This work presents the feasibility of reusing a glass fiber resulting from the thermolysis and gasification of waste composites to obtain glass-ceramic tiles. Polyester fiberglass (PFG) waste was treated at 550℃ for ...This work presents the feasibility of reusing a glass fiber resulting from the thermolysis and gasification of waste composites to obtain glass-ceramic tiles. Polyester fiberglass (PFG) waste was treated at 550℃ for 3 h in a 9.6 dm3 thermolytic reactor. This process yielded an oil (≈24 wt%), a gas (≈8 wt%) and a solid residue (≈68 wt%). After the polymer has been removed, the solid residue is heated in air to oxidize residual char and remove surface contamination. The cleaning fibers were converted into glass-ceramic tile. A mixture consisting of 95 wt% of this solid residue and 5% Na2O was melted at 1450℃ to obtain a glass frit. Powder glass samples (<63 μm) was then sintered and crystallized at 1013℃, leading to the formation of wollastonite-plagioclase glass-ceramic materials for architectural applications. Thermal stability and crystallization mechanism have been studied by Differential Thermal Analysis. Mineralogy analyses of the glass-ceramic materials were carried out using X-ray Diffraction.展开更多
A new composite structure based on aluminum foam sandwich and fiber metal laminate was proposed. A layer of glass fiber was provided at the interface between the metal panel and the aluminum foam core in this composit...A new composite structure based on aluminum foam sandwich and fiber metal laminate was proposed. A layer of glass fiber was provided at the interface between the metal panel and the aluminum foam core in this composite structure, using adhesive technology to bond the materials together by organic glue in the sequence of metal panel, glass fiber, aluminum foam core, glass fiber and metal panel. The experimental results show that the new composite structure has an improved comprehensive performance compared with the traditional aluminum foam sandwiches. The optimized parameters for the fabrication of the new aluminum foam composite structure with best bending strength were obtained. The epoxy resin and low porosity aluminum foams are preferred, the thickness of aluminum sheets should be at least 1.5 mm, and the type of glass fiber has little effect on the bending strength. The main failure modes of the new composite structures with two types of glues were discussed.展开更多
We studied the characteristics of two-scale pore structure of preform in the deposition process and the mass transfer of reactant gas in dual-scale pores, and observed the physiochemical phenomenon associated with the...We studied the characteristics of two-scale pore structure of preform in the deposition process and the mass transfer of reactant gas in dual-scale pores, and observed the physiochemical phenomenon associated with the reaction. Thereby, we established mathematical models on two scales, respectively, preform and reactor. These models were used for the numerical simulation of the process of ceramic matrix composites densified by isothermal chemical vapor infiltration(ICVI). The models were used to carry out a systematic study on the influence of process conditions and the preform structure on the densification behaviors. The most important findings of our study are that the processing time could be reduced by about 50% without compromising the quality of the material, if the processing temperature is 950-1 000 ℃ for the first 70 hours and then raised to 1 100 ℃.展开更多
文摘This work presents the feasibility of reusing a glass fiber resulting from the thermolysis and gasification of waste composites to obtain glass-ceramic tiles. Polyester fiberglass (PFG) waste was treated at 550℃ for 3 h in a 9.6 dm3 thermolytic reactor. This process yielded an oil (≈24 wt%), a gas (≈8 wt%) and a solid residue (≈68 wt%). After the polymer has been removed, the solid residue is heated in air to oxidize residual char and remove surface contamination. The cleaning fibers were converted into glass-ceramic tile. A mixture consisting of 95 wt% of this solid residue and 5% Na2O was melted at 1450℃ to obtain a glass frit. Powder glass samples (<63 μm) was then sintered and crystallized at 1013℃, leading to the formation of wollastonite-plagioclase glass-ceramic materials for architectural applications. Thermal stability and crystallization mechanism have been studied by Differential Thermal Analysis. Mineralogy analyses of the glass-ceramic materials were carried out using X-ray Diffraction.
基金Project(SS2015AA031101)supported by the National High-tech R&D Program of China
文摘A new composite structure based on aluminum foam sandwich and fiber metal laminate was proposed. A layer of glass fiber was provided at the interface between the metal panel and the aluminum foam core in this composite structure, using adhesive technology to bond the materials together by organic glue in the sequence of metal panel, glass fiber, aluminum foam core, glass fiber and metal panel. The experimental results show that the new composite structure has an improved comprehensive performance compared with the traditional aluminum foam sandwiches. The optimized parameters for the fabrication of the new aluminum foam composite structure with best bending strength were obtained. The epoxy resin and low porosity aluminum foams are preferred, the thickness of aluminum sheets should be at least 1.5 mm, and the type of glass fiber has little effect on the bending strength. The main failure modes of the new composite structures with two types of glues were discussed.
基金Funded by the National Natural Science Foundation of China(No.51472092)
文摘We studied the characteristics of two-scale pore structure of preform in the deposition process and the mass transfer of reactant gas in dual-scale pores, and observed the physiochemical phenomenon associated with the reaction. Thereby, we established mathematical models on two scales, respectively, preform and reactor. These models were used for the numerical simulation of the process of ceramic matrix composites densified by isothermal chemical vapor infiltration(ICVI). The models were used to carry out a systematic study on the influence of process conditions and the preform structure on the densification behaviors. The most important findings of our study are that the processing time could be reduced by about 50% without compromising the quality of the material, if the processing temperature is 950-1 000 ℃ for the first 70 hours and then raised to 1 100 ℃.
