The competition in 21st century will be the competition among different manufacturing chains.Manufacturing chain makes decision not only the core enterprise of the manufacturing chain but also a group of enterprises.A...The competition in 21st century will be the competition among different manufacturing chains.Manufacturing chain makes decision not only the core enterprise of the manufacturing chain but also a group of enterprises.Any significant decision in manufacturing chain will affect each enterprise in manufacturing chain,thus every significant decision should meet the desire and requests of each enterprise that be affected.Any significant decision should concentrate in the opinion of each member in the rep- resentative assembly or committee and obtain the authorization of the congress.Any vital question also should be discussed,made the decision and coordinated the moves by the representative assembly or the committee.With society’s development and the technical progress,the knowledge and the information content is growing suddenly,the questions needs making the decision are more and complex,the single enterprise only depended on its own resources and the strength is unable to grasp all essential information,and hard to face all questions.The representative assembly formed by representatives from each enterprise in manufacturing chain can gather together experts of different knowledge structure and different experience,which make up the deficiency of single enterprise in resources,strength and experience with the aid of many enterprises’resources and the strength.This is not just increase several brains,but to establish an information complex to ensure the scientific of decision,which formed by different knowledge structure, applies scientific theory method and means,can mutually enlighten and has abundant knowledge.So it comes down to the group decision.Group decision questions have two types,one is the collectivity decision which pursue the holistic benefit of the group,the other is that the members in the group pursue its’own benefit and value against others,that means the game theory of interest con- flict existed among the members.Currently,most scholars research the questions in manufacturing chain from the point of game theory,the research on collectivity decision,which pursues the holistic benefit of manufacturing chain,is limited.The group deci- sion support systems used in the later stage of 1990s includes electronic conference system and working flow system.展开更多
The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983...The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983(18), b = 17.6929(15), c = 17.0897(15) nm, V= 6167.8(9) nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F(000) = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.展开更多
A main-chain liquid crystalline ionomer(MLCI) containing sulfonic group was synthesized by an interfacial condensation reaction.The MLCI was blended with polybutylene terephthalate(PBT) and polypropylene(PP).MLC...A main-chain liquid crystalline ionomer(MLCI) containing sulfonic group was synthesized by an interfacial condensation reaction.The MLCI was blended with polybutylene terephthalate(PBT) and polypropylene(PP).MLCI interacted with both the dispersed(PP) phase and the matrix(PBT) phase to modify the interfacial interaction of PBT and PP.Differential scanning calorimetry(DSC),scanning electron microscopy(SEM) and FTIR imaging system analysis demonstrated the significance of interfacial interaction in the polymer blends.MLCI brought about good adhesion at the interfacial,which reduced the disperse phase size and enabled a fine PP phase at matrix.The mechanical properties of the ternary blends were improved when a proper amount of MLCI was added.This was attributed to enhanced adhesion at the interface,which invoked better mechanical properties in the blends.展开更多
A new side chain liquid crystalline poly[4 (methacryloxy)hexanoloxy 4′ benzyloxy biphenyl] was synthesized. The phase behavior of the monomer and homopolymer was studied. The monomer shows a smectic B phase, while...A new side chain liquid crystalline poly[4 (methacryloxy)hexanoloxy 4′ benzyloxy biphenyl] was synthesized. The phase behavior of the monomer and homopolymer was studied. The monomer shows a smectic B phase, while the homopolymer shows a nematic phase. The nonmesogenic nonlinear optical group was introduced to synthesize a series of side chain liquid crystalline copolymers which also show a nematic phase. Owing to the liquid crystallinity of the copolymer has been the orientational stability improved, down the relax of the orientation slowed and the nonlinear optical properties enhanced.展开更多
文摘The competition in 21st century will be the competition among different manufacturing chains.Manufacturing chain makes decision not only the core enterprise of the manufacturing chain but also a group of enterprises.Any significant decision in manufacturing chain will affect each enterprise in manufacturing chain,thus every significant decision should meet the desire and requests of each enterprise that be affected.Any significant decision should concentrate in the opinion of each member in the rep- resentative assembly or committee and obtain the authorization of the congress.Any vital question also should be discussed,made the decision and coordinated the moves by the representative assembly or the committee.With society’s development and the technical progress,the knowledge and the information content is growing suddenly,the questions needs making the decision are more and complex,the single enterprise only depended on its own resources and the strength is unable to grasp all essential information,and hard to face all questions.The representative assembly formed by representatives from each enterprise in manufacturing chain can gather together experts of different knowledge structure and different experience,which make up the deficiency of single enterprise in resources,strength and experience with the aid of many enterprises’resources and the strength.This is not just increase several brains,but to establish an information complex to ensure the scientific of decision,which formed by different knowledge structure, applies scientific theory method and means,can mutually enlighten and has abundant knowledge.So it comes down to the group decision.Group decision questions have two types,one is the collectivity decision which pursue the holistic benefit of the group,the other is that the members in the group pursue its’own benefit and value against others,that means the game theory of interest con- flict existed among the members.Currently,most scholars research the questions in manufacturing chain from the point of game theory,the research on collectivity decision,which pursues the holistic benefit of manufacturing chain,is limited.The group deci- sion support systems used in the later stage of 1990s includes electronic conference system and working flow system.
基金Supported by the Key Laboratory of Non-ferrous Metal Materials and New Processing TechnologyMinistry of Education and the State Key Laboratory of Coordination Chemistry
文摘The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983(18), b = 17.6929(15), c = 17.0897(15) nm, V= 6167.8(9) nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F(000) = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
基金Supported by the High-Tech Research and Development Program of China(No.2006AA02Z291)the National Natural Science Foundation of China(No.50673105)
文摘A main-chain liquid crystalline ionomer(MLCI) containing sulfonic group was synthesized by an interfacial condensation reaction.The MLCI was blended with polybutylene terephthalate(PBT) and polypropylene(PP).MLCI interacted with both the dispersed(PP) phase and the matrix(PBT) phase to modify the interfacial interaction of PBT and PP.Differential scanning calorimetry(DSC),scanning electron microscopy(SEM) and FTIR imaging system analysis demonstrated the significance of interfacial interaction in the polymer blends.MLCI brought about good adhesion at the interfacial,which reduced the disperse phase size and enabled a fine PP phase at matrix.The mechanical properties of the ternary blends were improved when a proper amount of MLCI was added.This was attributed to enhanced adhesion at the interface,which invoked better mechanical properties in the blends.
文摘A new side chain liquid crystalline poly[4 (methacryloxy)hexanoloxy 4′ benzyloxy biphenyl] was synthesized. The phase behavior of the monomer and homopolymer was studied. The monomer shows a smectic B phase, while the homopolymer shows a nematic phase. The nonmesogenic nonlinear optical group was introduced to synthesize a series of side chain liquid crystalline copolymers which also show a nematic phase. Owing to the liquid crystallinity of the copolymer has been the orientational stability improved, down the relax of the orientation slowed and the nonlinear optical properties enhanced.