Permutation codes over finite chain rings are introduced; by using the character of the finite chain rings and the knowledge of representation of group, some conditions for existence or non-existence of self-dual perm...Permutation codes over finite chain rings are introduced; by using the character of the finite chain rings and the knowledge of representation of group, some conditions for existence or non-existence of self-dual permutation codes over finite chain rings are obtained. Specially, when the group is a direct product of a 2-group and a T-group, and the group action is transitive, the sufficient and necessary condition of the existence of permutation codes is given.展开更多
The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983...The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983(18), b = 17.6929(15), c = 17.0897(15) nm, V= 6167.8(9) nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F(000) = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.展开更多
Using a transfer matrix method, we investigate spin transport through a chain of polygonal rings with Dresselhaus spin-orbit coupling(DSOC). The spin conductance is dependent on the number of sides in the polygons. ...Using a transfer matrix method, we investigate spin transport through a chain of polygonal rings with Dresselhaus spin-orbit coupling(DSOC). The spin conductance is dependent on the number of sides in the polygons. When DSOC is considered in a chain which also has Rashba spin-orbit coupling(RSOC) of the same magnitude, the total conductance is the same as that for the same chain with no SOC. However, when the two types of SOC have different values, there results a unique anisotropic conductance.展开更多
The main results of this paper are following theorems: (1)A left A-injective ring satisfying the ascending chain condition on right annihilator is QF ring. (2)A left A-injective ring satisfying the ascending hain cond...The main results of this paper are following theorems: (1)A left A-injective ring satisfying the ascending chain condition on right annihilator is QF ring. (2)A left A-injective ring satisfying the ascending hain condition on left annihilator is QF ring. (3)If R satisfies the following conditions: (ⅰ) r(A∩B)=r(A)+r(B), for each pair of left ils A,B;(ⅱ) rl(I)=I, for every right ideal I. Then R is semiperfect ring and has essential left s. In particular, any right CF left A-injective (or E(_RR) is projective left R-module) is QF ring展开更多
In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube ...In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thor- oughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materi- als, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.展开更多
A single set of vertically aligned cracks embedded in a purely isotropic background may be con- sidered as a long-wavelength effective transversely iso- tropy (HTI) medium with a horizontal symmetry axis. The crack-...A single set of vertically aligned cracks embedded in a purely isotropic background may be con- sidered as a long-wavelength effective transversely iso- tropy (HTI) medium with a horizontal symmetry axis. The crack-induced HTI anisotropy can be characterized by the weakly anisotropic parameters introduced by Thomsen. The seismic scattering theory can be utilized for the inversion for the anisotropic parameters in weakly aniso- tropic and heterogeneous HTI media. Based on the seismic scattering theory, we first derived the linearized PP- and PS-wave reflection coefficients in terms of P- and S-wave impedances, density as well as three anisotropic parameters in HTI media. Then, we proposed a novel Bayesian Mar- kov chain Monte Carlo inversion method of PP- and PS- wave for six elastic and anisotropic parameters directly. Tests on synthetic azimuthal seismic data contaminated by random errors demonstrated that this method appears more accurate, anti-noise and stable owing to the usage of the constrained PS-wave compared with the standards inver- sion scheme taking only the PP-wave into account.展开更多
BACKGROUND Gastric cancer(GC)is one of the most prevalent malignant tumors that endangers human health.Early diagnosis is essential for improving the prognosis and survival rate of GC patients.Ring finger protein 180(...BACKGROUND Gastric cancer(GC)is one of the most prevalent malignant tumors that endangers human health.Early diagnosis is essential for improving the prognosis and survival rate of GC patients.Ring finger protein 180(RNF180)is involved in the regulation of cell differentiation,proliferation,apoptosis,and tumorigenesis,and aberrant hypermethylation of CpG islands in the promoter is strongly associated with the occurrence and development of GC.Thus,methylated RNF180 can be used as a potential biomarker for GC diagnosis.AIM To use droplet digital polymerase chain reaction(ddPCR)to quantify the methylation level of the RN180 gene.A reproducible ddPCR assay to detect methylated RNF180 from trace DNA was designed and optimized.METHODS The primer and probe were designed and selected,the conversion time of bisulfite was optimized,the ddPCR system was adjusted by primer concentration,amplification temperature and amplification cycles,and the detection limit of ddPCR was determined.RESULTS The best conversion time for blood DNA was 2 h 10 min,and that for plasma DNA was 2 h 10 min and 2 h 30 min.The results of ddPCR were better when the amplification temperature was 56°C and the number of amplification cycles was 50.Primer concentrations showed little effect on the assay outcome.Therefore,the primer concentration could be adjusted according to the reaction system and DNA input.The assay required at least 0.1 ng of input DNA.CONCLUSION In summary,a ddPCR assay was established to detect methylated RNF180,which is expected to be a new diagnostic biomarker for GC.展开更多
Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylform...Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylformamide) and [Fe(Phen)2(CN)2Zn(Cyclam)](PF6)2·CH3CN 2, were prepared by the reaction of [Fe(Phen)2(CN)2]·2H2O with M(Cyclam)^2+ (M = Ni, Zn). In complexes 1 and 2, the metal atoms are connected alternatively with CN groups. X-ray structure and IR analyses for 1 and 2 were performed. Structure analysis revealed that both complexes are centrosymmetric and the geometry around each metal atom is an octahedron. The two complexes crystallize in triclinic with space group of P^1-. For 1, a = 10.439(4), b = 14.976(7), c = 15.914(8)A,α = 83.168(15), β = 74.338(15), γ = 78.023(15)°, V = 2338.3(18)A^3, Z = 2, Mr = 1035.37, Dc = 1.471 g/cm^3, F(000) = 1076,μ = 0.895 mm^-1, the final R = 0.0616 and wR = 0.1414 for 5849 observed reflections (1 〉 2σ(I)). For 2, a = 9.656(6), b = 15.404(9), c = 15.822(10)A, α = 78.68(2), β= 78.917(19), γ = 77.15(2)°, V = 2223(2)A^3, Z = 2, Mr = 1064.87, Dc = 1.587 g/cm^3, F(000) = 1078,μ = 1.032 mm^-1, the final R = 0.0672 and wR = 0.1595 for 6819 observed reflections (I 〉 2σ(I)).展开更多
The phase behaviour of polyethylene knotted ring chains is investigated by using molecular dynamics simulations. In this paper, we focus on the collapse of the polyethylene knotted ring chain, and also present the res...The phase behaviour of polyethylene knotted ring chains is investigated by using molecular dynamics simulations. In this paper, we focus on the collapse of the polyethylene knotted ring chain, and also present the results of linear and ring chains for comparison. At high temperatures, a fully extensive knot structure is observed. The mean-square radius of gyration per bond (S2)/(Nb2) and the shape factor ((δ*) depend on not only the chain length but also the knot type. With temperature decreasing, chain collapse is observed, and the collapse temperature decreases with the chain length increasing. The actual collapse transition can be determined by the specific heat capacity Cv, and the knotted ring chain undergoes gas-liquid-solid-like transition directly. The phase transition of a knotted ring chain is only one-stage collapse, which is different from the polyethylene linear and ring chains. This investigation can provide some insights into the statistical properties of knotted polymer chains.展开更多
Synchronization of N different coupled chaotic systems with ring and chain connections is investigated. The New system, the Chen system, the Lii system, the Lorenz system, and the Rossler system are used as examples i...Synchronization of N different coupled chaotic systems with ring and chain connections is investigated. The New system, the Chen system, the Lii system, the Lorenz system, and the Rossler system are used as examples in verifying effectiveness of the method. Based on the Lyapunov stability theory, the form of the controller is designed and the area of the coupling coefficients is determined. Simulations indicate that global synchronization of the N different chaotic systems can be realized by choosing appropriate coupling coefficients by using the controller.展开更多
Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_(24)Cl_(13)(1) and MgCsV_2O_6Cl(2),were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm(No. 123),with a = 14.801(2),c = 12....Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_(24)Cl_(13)(1) and MgCsV_2O_6Cl(2),were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm(No. 123),with a = 14.801(2),c = 12.341(3) ?,V = 2703.5(8) ?~3,Z = 2,Mr = 3015.56,F(000) = 2640,μ = 11.044 mm-1,Dc = 3.704 g/cm3,the final R = 0.0380 and wR = 0.0937 for 1654 observed reflections with I 〉 2σ(I). 2 crystallizes in a monoclinic space group C2/c(No. 15) with a = 11.128(2),b = 10.540(2),c = 6.9892(14) ?,β = 118.38(3)°,V = 721.2(2) ?~3,Z = 4,M_r = 390.55,F(000) = 712,μ = 7.997 mm-1,D_c = 3.597 g/cm^3,the final R = 0.0537 and w R = 0.1363 for 740 observed reflections with I 〉 2σ(I). 1 exhibits a novel 8-membered-ring [V_8O_(24)] consisting of 8 corner-shared VO_4 tetrahetra,but in 2,an infinite ladder-like [VO_3]_∞ chain is formed by VO_5 square pyramids through sharing the edges.展开更多
This study attempted to examine the importance of storeenvironment in affecting consumers’store choice deci-sion;the relative importance among the three environ-mental factors;and consumers’expectations on store en-...This study attempted to examine the importance of storeenvironment in affecting consumers’store choice deci-sion;the relative importance among the three environ-mental factors;and consumers’expectations on store en-vironment for the casual-wear chain stores in HongKong.Julie Baker’s Three-category framework onstore environments namely ambient,design and socialfactors was adopted for investigation.The results indi-cated that the store environment was important in affect-ing consumers’selection of store for shopping.It alsorevealed that social factor was perceived relatively im-portant than ambient and design factors.Nine store ex-pectation dimensions were categorised and the resultdemonstrated that most respondents were concerned onthe social aspect in their expectation of having a satisfy-ing store environment.展开更多
A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2),...A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2), b = 8.225(3), c = 10.845(3)A, α= 86.996(4), β = 76.292(4), γ= 68.890(4)°, V = 620.0(3)A^3, Z = 2, Dc = 1.841 g/cm^3, F(000) = 354 and μ = 1.971 mm^-1. The structure was refined to R = 0.0269 and wR = 0.0659 for 1838 observed reflections (I 〉 2a(/)). The structure consists of [Cu(3-ampy)(H2O)4]^2+ cations, SO4^2- anions and lattice water molecules. 3-Ampy acting as a bidentate bridging ligand generates a 1D covalent chain. A supramolecular 2D framework is formed through π-π stacking of pyridine rings. The lattice water molecules and SO4^2- anions are located between the adjacent 2D frameworks. The hydrogen bonding interactions from lattice water molecules and SO4^2- anions to coordinate water extend the 2D framework into a 3D network.展开更多
A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with...A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.展开更多
Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines...Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines. This research presents the thermodynamic analysis on cascade refrigeration system (CRS) with several refrigerant pairs which are R32/R170, R123/R170, R134a/R170, R404A/R170, R407c/R170, R410/R170, and the hydrocarbon (HC) refrigerant pair Propane/Ethane, namely R290/R170. Besides, the results of R22/R170 pair, which is not recommended to be used due to phase out of R22 as per Montréal Protocol, are included as base case to compare the novel hydrocarbon pairs in CRS and the old trend of refrigerant pairs. Thermodynamic properties of all these pairs were investigated and compared under different intermediate temperature used in CRS heat exchanger, which thermally connected both the Low and High temperature cycles (LTC) and (HTC). By applying the first law of thermodynamics, the coefficients of performance (COPs) and the specific power consumptions (SPC) in kW/TR are presented and compared. In addition, by applying the second law of thermodynamics the exergetic efficiencies were estimated. The results reveal the promising opportunity of using the HC pair (R290/R170). The minimum SPC in kW/TR is recorded for the pair R123/R170. One the other hand, the highest exegetic efficiency values are observed to be 40%, 38%, and 35% for the pairs R123/R170, R290/R170, and R134/R170, respectively. This research concludes that the HC pair (R290/R170) is highly recommended for CRS applications either to transport the COVID-19 or store it in cold storage rooms in hospitals and clinics. All precautionary measures should be carefully applied in design and operation of HC pair (R290/R170) due to its flammability hazard.展开更多
基金Supported by the National Natural Science Foundation of China (60373087, 60473023, 90104005, 60673071)
文摘Permutation codes over finite chain rings are introduced; by using the character of the finite chain rings and the knowledge of representation of group, some conditions for existence or non-existence of self-dual permutation codes over finite chain rings are obtained. Specially, when the group is a direct product of a 2-group and a T-group, and the group action is transitive, the sufficient and necessary condition of the existence of permutation codes is given.
基金Supported by the Key Laboratory of Non-ferrous Metal Materials and New Processing TechnologyMinistry of Education and the State Key Laboratory of Coordination Chemistry
文摘The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983(18), b = 17.6929(15), c = 17.0897(15) nm, V= 6167.8(9) nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F(000) = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61176089 and 11504083)the Foundation of Shijiazhuang University,China(Grant No.XJPT002)
文摘Using a transfer matrix method, we investigate spin transport through a chain of polygonal rings with Dresselhaus spin-orbit coupling(DSOC). The spin conductance is dependent on the number of sides in the polygons. When DSOC is considered in a chain which also has Rashba spin-orbit coupling(RSOC) of the same magnitude, the total conductance is the same as that for the same chain with no SOC. However, when the two types of SOC have different values, there results a unique anisotropic conductance.
文摘The main results of this paper are following theorems: (1)A left A-injective ring satisfying the ascending chain condition on right annihilator is QF ring. (2)A left A-injective ring satisfying the ascending hain condition on left annihilator is QF ring. (3)If R satisfies the following conditions: (ⅰ) r(A∩B)=r(A)+r(B), for each pair of left ils A,B;(ⅱ) rl(I)=I, for every right ideal I. Then R is semiperfect ring and has essential left s. In particular, any right CF left A-injective (or E(_RR) is projective left R-module) is QF ring
基金supported by the National Natural Science Foundation of China (11272357 and 11102140)Doctoral Fund of Ministry of Education of China (200804251520 and 20110141120024)Natural Science Foundation of Shandong Province (ZR2009AQ006)
文摘In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thor- oughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materi- als, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.
基金sponsorship of the National Natural Science Foundation of China (No.41674130)the National Basic Research Program of China (973 Program,Nos.2013CB228604,2014CB239201)+1 种基金the National Oil and Gas Major Projects of China (Nos.2016ZX05027004-001,2016ZX05002005-009)the Fundamental Research Funds for the Central Universities (15CX08002A) for their funding in this research
文摘A single set of vertically aligned cracks embedded in a purely isotropic background may be con- sidered as a long-wavelength effective transversely iso- tropy (HTI) medium with a horizontal symmetry axis. The crack-induced HTI anisotropy can be characterized by the weakly anisotropic parameters introduced by Thomsen. The seismic scattering theory can be utilized for the inversion for the anisotropic parameters in weakly aniso- tropic and heterogeneous HTI media. Based on the seismic scattering theory, we first derived the linearized PP- and PS-wave reflection coefficients in terms of P- and S-wave impedances, density as well as three anisotropic parameters in HTI media. Then, we proposed a novel Bayesian Mar- kov chain Monte Carlo inversion method of PP- and PS- wave for six elastic and anisotropic parameters directly. Tests on synthetic azimuthal seismic data contaminated by random errors demonstrated that this method appears more accurate, anti-noise and stable owing to the usage of the constrained PS-wave compared with the standards inver- sion scheme taking only the PP-wave into account.
基金Supported by the National Key Research and Development Program of China,No.2020YFC2002700the National Natural Science Foundation of China,No.81972010+1 种基金the CAMS Initiative for Innovative Medicine,No.2016-I2M-1-007the Science Developing Funds of Navy General Hospital,No.CXPY201810.
文摘BACKGROUND Gastric cancer(GC)is one of the most prevalent malignant tumors that endangers human health.Early diagnosis is essential for improving the prognosis and survival rate of GC patients.Ring finger protein 180(RNF180)is involved in the regulation of cell differentiation,proliferation,apoptosis,and tumorigenesis,and aberrant hypermethylation of CpG islands in the promoter is strongly associated with the occurrence and development of GC.Thus,methylated RNF180 can be used as a potential biomarker for GC diagnosis.AIM To use droplet digital polymerase chain reaction(ddPCR)to quantify the methylation level of the RN180 gene.A reproducible ddPCR assay to detect methylated RNF180 from trace DNA was designed and optimized.METHODS The primer and probe were designed and selected,the conversion time of bisulfite was optimized,the ddPCR system was adjusted by primer concentration,amplification temperature and amplification cycles,and the detection limit of ddPCR was determined.RESULTS The best conversion time for blood DNA was 2 h 10 min,and that for plasma DNA was 2 h 10 min and 2 h 30 min.The results of ddPCR were better when the amplification temperature was 56°C and the number of amplification cycles was 50.Primer concentrations showed little effect on the assay outcome.Therefore,the primer concentration could be adjusted according to the reaction system and DNA input.The assay required at least 0.1 ng of input DNA.CONCLUSION In summary,a ddPCR assay was established to detect methylated RNF180,which is expected to be a new diagnostic biomarker for GC.
基金the grants from 973 Program (2007CB815301 and 2006CB932904)the National Natural Science Foundation of China (20333070 and 20673118)+1 种基金the Science Foundation of CAS (KJCX2-YW-M05)Fujian Province (2006L2005, 2006F3132 and 2007J0171)
文摘Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylformamide) and [Fe(Phen)2(CN)2Zn(Cyclam)](PF6)2·CH3CN 2, were prepared by the reaction of [Fe(Phen)2(CN)2]·2H2O with M(Cyclam)^2+ (M = Ni, Zn). In complexes 1 and 2, the metal atoms are connected alternatively with CN groups. X-ray structure and IR analyses for 1 and 2 were performed. Structure analysis revealed that both complexes are centrosymmetric and the geometry around each metal atom is an octahedron. The two complexes crystallize in triclinic with space group of P^1-. For 1, a = 10.439(4), b = 14.976(7), c = 15.914(8)A,α = 83.168(15), β = 74.338(15), γ = 78.023(15)°, V = 2338.3(18)A^3, Z = 2, Mr = 1035.37, Dc = 1.471 g/cm^3, F(000) = 1076,μ = 0.895 mm^-1, the final R = 0.0616 and wR = 0.1414 for 5849 observed reflections (1 〉 2σ(I)). For 2, a = 9.656(6), b = 15.404(9), c = 15.822(10)A, α = 78.68(2), β= 78.917(19), γ = 77.15(2)°, V = 2223(2)A^3, Z = 2, Mr = 1064.87, Dc = 1.587 g/cm^3, F(000) = 1078,μ = 1.032 mm^-1, the final R = 0.0672 and wR = 0.1595 for 6819 observed reflections (I 〉 2σ(I)).
基金supported by the National Natural Science Foundation of China (Grant Nos. 20574052,20774066,20974081,and 20934004)the Program for New Century Excellent Talents in University of the Ministry of Education of China (Grant No. NCET-05-0538)the Ph.D. Program Foundation of the Ministry of Education of China (Grant No. 20090101110002)
文摘The phase behaviour of polyethylene knotted ring chains is investigated by using molecular dynamics simulations. In this paper, we focus on the collapse of the polyethylene knotted ring chain, and also present the results of linear and ring chains for comparison. At high temperatures, a fully extensive knot structure is observed. The mean-square radius of gyration per bond (S2)/(Nb2) and the shape factor ((δ*) depend on not only the chain length but also the knot type. With temperature decreasing, chain collapse is observed, and the collapse temperature decreases with the chain length increasing. The actual collapse transition can be determined by the specific heat capacity Cv, and the knotted ring chain undergoes gas-liquid-solid-like transition directly. The phase transition of a knotted ring chain is only one-stage collapse, which is different from the polyethylene linear and ring chains. This investigation can provide some insights into the statistical properties of knotted polymer chains.
基金the Natural Science Foundation of Liaoning Province(No.20052151)the Innovative Team Program of Liaoning Educational Committee
文摘Synchronization of N different coupled chaotic systems with ring and chain connections is investigated. The New system, the Chen system, the Lii system, the Lorenz system, and the Rossler system are used as examples in verifying effectiveness of the method. Based on the Lyapunov stability theory, the form of the controller is designed and the area of the coupling coefficients is determined. Simulations indicate that global synchronization of the N different chaotic systems can be realized by choosing appropriate coupling coefficients by using the controller.
基金supported by the National Natural Science Foundation of China(No.21541009)
文摘Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_(24)Cl_(13)(1) and MgCsV_2O_6Cl(2),were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm(No. 123),with a = 14.801(2),c = 12.341(3) ?,V = 2703.5(8) ?~3,Z = 2,Mr = 3015.56,F(000) = 2640,μ = 11.044 mm-1,Dc = 3.704 g/cm3,the final R = 0.0380 and wR = 0.0937 for 1654 observed reflections with I 〉 2σ(I). 2 crystallizes in a monoclinic space group C2/c(No. 15) with a = 11.128(2),b = 10.540(2),c = 6.9892(14) ?,β = 118.38(3)°,V = 721.2(2) ?~3,Z = 4,M_r = 390.55,F(000) = 712,μ = 7.997 mm-1,D_c = 3.597 g/cm^3,the final R = 0.0537 and w R = 0.1363 for 740 observed reflections with I 〉 2σ(I). 1 exhibits a novel 8-membered-ring [V_8O_(24)] consisting of 8 corner-shared VO_4 tetrahetra,but in 2,an infinite ladder-like [VO_3]_∞ chain is formed by VO_5 square pyramids through sharing the edges.
文摘This study attempted to examine the importance of storeenvironment in affecting consumers’store choice deci-sion;the relative importance among the three environ-mental factors;and consumers’expectations on store en-vironment for the casual-wear chain stores in HongKong.Julie Baker’s Three-category framework onstore environments namely ambient,design and socialfactors was adopted for investigation.The results indi-cated that the store environment was important in affect-ing consumers’selection of store for shopping.It alsorevealed that social factor was perceived relatively im-portant than ambient and design factors.Nine store ex-pectation dimensions were categorised and the resultdemonstrated that most respondents were concerned onthe social aspect in their expectation of having a satisfy-ing store environment.
基金the Natural Science Found Council of China (Nos. 20671011, 20331010, 90406002 and 90406024) the Key Laboratory of Structural Chemistry Foundation (No. 060017)
文摘A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2), b = 8.225(3), c = 10.845(3)A, α= 86.996(4), β = 76.292(4), γ= 68.890(4)°, V = 620.0(3)A^3, Z = 2, Dc = 1.841 g/cm^3, F(000) = 354 and μ = 1.971 mm^-1. The structure was refined to R = 0.0269 and wR = 0.0659 for 1838 observed reflections (I 〉 2a(/)). The structure consists of [Cu(3-ampy)(H2O)4]^2+ cations, SO4^2- anions and lattice water molecules. 3-Ampy acting as a bidentate bridging ligand generates a 1D covalent chain. A supramolecular 2D framework is formed through π-π stacking of pyridine rings. The lattice water molecules and SO4^2- anions are located between the adjacent 2D frameworks. The hydrogen bonding interactions from lattice water molecules and SO4^2- anions to coordinate water extend the 2D framework into a 3D network.
基金the Natural Science Foundation of Jiangsu province (Grant No Bk2001031)
文摘A new imidazolium compound, C15H17N4ClO4, was prepared from a flexible bidentate ligand of 1,3-di(imidazol-1-ylmethyl)-5-methylbenzene, and characterized by X-ray analysis. It is of orthorhombic, space group Pnma with a = 8.182(2), b = 12.874(3), c = 15.611(4) ? V = 1644.4(7) 3, Dc = 1.425 g/cm3, Z = 4, Mr = 352.78, m(MoKa) = 0.944 mm-1, F(000) = 736, S = 1.036, the final R = 0.0521 and wR = 0.1187 for 1128 observed reflections (I > 2s(I)). An infinite one-dimensional zigzag chain is formed by NH…N hydrogen bonding interactions between the imidazolium salt cations.
文摘Several media report highlight on that the pharmaceutical companies require ultra-low temperatures -80<span style="white-space:nowrap;">°</span>C to transport and store its COVID-19 vaccines. This research presents the thermodynamic analysis on cascade refrigeration system (CRS) with several refrigerant pairs which are R32/R170, R123/R170, R134a/R170, R404A/R170, R407c/R170, R410/R170, and the hydrocarbon (HC) refrigerant pair Propane/Ethane, namely R290/R170. Besides, the results of R22/R170 pair, which is not recommended to be used due to phase out of R22 as per Montréal Protocol, are included as base case to compare the novel hydrocarbon pairs in CRS and the old trend of refrigerant pairs. Thermodynamic properties of all these pairs were investigated and compared under different intermediate temperature used in CRS heat exchanger, which thermally connected both the Low and High temperature cycles (LTC) and (HTC). By applying the first law of thermodynamics, the coefficients of performance (COPs) and the specific power consumptions (SPC) in kW/TR are presented and compared. In addition, by applying the second law of thermodynamics the exergetic efficiencies were estimated. The results reveal the promising opportunity of using the HC pair (R290/R170). The minimum SPC in kW/TR is recorded for the pair R123/R170. One the other hand, the highest exegetic efficiency values are observed to be 40%, 38%, and 35% for the pairs R123/R170, R290/R170, and R134/R170, respectively. This research concludes that the HC pair (R290/R170) is highly recommended for CRS applications either to transport the COVID-19 or store it in cold storage rooms in hospitals and clinics. All precautionary measures should be carefully applied in design and operation of HC pair (R290/R170) due to its flammability hazard.