Background:The phenomenon of academic anxiety has been demonstrated to exert a considerable influence on students’academic engagement,leading to the emergence of a phenomenon known as“learned helplessness”and under...Background:The phenomenon of academic anxiety has been demonstrated to exert a considerable influence on students’academic engagement,leading to the emergence of a phenomenon known as“learned helplessness”and undermining the selfconfidence and motivation of high school students.Using acceptance-rejection theory,this study elucidated how a rejective parenting style affects Chinese high school students’academic anxiety and explored the urban-rural heterogeneity of this relationship.Methods:Data were analyzed using a stratified whole-cluster random sampling method.There are a total of 30,000 high school students in the three regions of northern and central China(from Shanxi,Hebei and Henan).A sample of 2286 high school students aged 14–19 years was ultimately selected from 2760 respondents for this investigation,which was conducted at the beginning of the 2023 school year.Pearson correlation,ordinary least squares(OLS)regression analysis,path analysis,and Fisher’s permutation test(FPT)were used to examine the effects of rejective parenting style on high school students’academic anxiety.Results:Results indicated a significant positive predictive effect between rejective parenting style and academic anxiety among high school students(β=0.815,t=116.211,p<0.001).Students’self-concept was significantly positively related to positive coping style(β=0.424,t=21.208,p<0.001)and chain-mediated this relationship.Therefore,this parenting style may indirectly mitigate academic anxiety through these mediators.The study also found that the effect of rejective parenting style on academic anxiety varied by students’residential background and was more pronounced in urban areas(0.226)than in rural areas(0.130).Conclusion:The research underscores the imperative for Chinese families to reexamine their utilization of rejection parenting and to prioritize the cultivation of students’intrinsic attributes.These findings offer a theoretical framework and practical evidence for policymakers and educators to develop efficacious and targeted interventions.In particular,greater attention should be directed towards the discrepancies in the manifestation of emotional and academic anxiety between urban and rural students,and prompt guidance should be furnished.展开更多
Through improvements on a fully commercial and automatic system measuring frequency andtemperature spectra of the complex elastic, dielectric, and piezoelectric constants of polymerfilms, the precision for measuring c...Through improvements on a fully commercial and automatic system measuring frequency andtemperature spectra of the complex elastic, dielectric, and piezoelectric constants of polymerfilms, the precision for measuring complex dielectric constants achieved 2‰ from original 1%.The complex dielectric constants of PVDF, VDF (95 )/VF (5), VDF (52)/TrFE (48) and VDF(47. 5)/TrFE(47. 5)/HeFP (5) over a range of-120-140℃, 10-2-10;Hz were measured bythe described system. The diminution of chain regularity due to 5mol% vinyl fluoride in the chainof PVDF led to disappearing of α-relaxation and increase in T;(3℃) of VDF (95)/VF (5).Because of the spatial impediment of 5mol% HeFP in copolymer chain, the Curie point of VDF(52)/TrFE(48) decreased by 30℃ and T;by 3℃. The behavior of dielectric relaxation indicatedthat 5mol% vinyl fluoride and HeFP made the relaxation strength of noncrystalline regionreduced, the activation energy of local relaxation increased and the relaxation time prolonged respectively.展开更多
A theoretical study on oligopeptide chains of glycine-alanine by density functional theory(DFT) is given in this paper. Raman spectra of the oligopeptide chains are examined. The geometric structures, frontier orbit...A theoretical study on oligopeptide chains of glycine-alanine by density functional theory(DFT) is given in this paper. Raman spectra of the oligopeptide chains are examined. The geometric structures, frontier orbital, energy gap, atomic charge distribution, density of states and chemical activity of the side chain are studied at the B3LYP/6-31G(d) level. Results show that, with the number of residues increasing, vibrations of typical functional groups present Raman frequency shift, and the energy gap is gradually reduced. The HOMO and LUMO focus on the amino and carboxyl at the ends of oligopeptides. It is helpful for oligopeptides to self-assemble into chains. In addition, different residues(glycine or alanine) at the ends of chains result in the even-odd effect of orbital energy in the growth process. The size effects of physical and chemical properties only exist when the oligopeptides are shorter, and the phenomenon disappeared as the chain continues to grow.展开更多
Bullwhip effect is the most important factor considered in the supply chain management. It gets many scholars' attention that bullwhip effect has been restricting the development of the supply chain all the time. Inf...Bullwhip effect is the most important factor considered in the supply chain management. It gets many scholars' attention that bullwhip effect has been restricting the development of the supply chain all the time. Information Technology (IT) can reduce bullwhip effect by sharing the information among the enterprises in the supply chain.展开更多
The Wulipo landslide, triggered by heavy rainfall on July 10, 2013, transformed into debris flow,resulted in the destruction of 12 houses, 44 deaths, and 117 missing. Our systematic investigation has led to the follow...The Wulipo landslide, triggered by heavy rainfall on July 10, 2013, transformed into debris flow,resulted in the destruction of 12 houses, 44 deaths, and 117 missing. Our systematic investigation has led to the following results and to a new understanding about the formation and evolution process of this hazard. The fundamental factors of the formation of the landslide are a high-steep free surface at the front of the slide mass and the sandstone-mudstone mixed stratum structure of the slope. The inducing factor of the landslide is hydrostatic and hydrodynamic pressure change caused by heavy continuous rainfall. The geological mechanical model of the landslide can be summarized as "instability-translational slide-tension fracture-collapse" and the formation mechanism as "translational landslide induced by heavy rainfall". The total volume of the landslide is 124.6×104 m3, and 16.3% of the sliding mass was dropped down from the cliff and transformed into debris flow during the sliding process, which enlarged 46.7% of the original sliding deposit area. The final accumulation area is found to be 9.2×104 m2. The hazard is a typical example of a disaster chain involving landslide and its induced debris flow. The concealment and disaster chain effect is the main reason for the heavy damage. In future risk assessment, it is suggested to enhance the research onpotential landslide identification for weakly intercalated slopes. By considering the influence of the behaviors of landslide-induced debris flow, the disaster area could be determined more reasonably.展开更多
Elastic impedance inversion with high efficiency and high stability has become one of the main directions of seismic pre-stack inversion. The nonlinear elastic impedance inversion method based on a fast Markov chain M...Elastic impedance inversion with high efficiency and high stability has become one of the main directions of seismic pre-stack inversion. The nonlinear elastic impedance inversion method based on a fast Markov chain Monte Carlo (MCMC) method is proposed in this paper, combining conventional MCMC method based on global optimization with a preconditioned conjugate gradient (PCG) algorithm based on local optimization, so this method does not depend strongly on the initial model. It converges to the global optimum quickly and efficiently on the condition that effi- ciency and stability of inversion are both taken into consid- eration at the same time. The test data verify the feasibility and robustness of the method, and based on this method, we extract the effective pore-fluid bulk modulus, which is applied to reservoir fluid identification and detection, and consequently, a better result has been achieved.展开更多
This research contributes to understanding the spillover effect of customer digital transformation along the supply chain.We take a supply chain relationship perspective to explore the influence of customers’digital ...This research contributes to understanding the spillover effect of customer digital transformation along the supply chain.We take a supply chain relationship perspective to explore the influence of customers’digital transformation on suppliers’audit fees and find a significant reduction in such fees when customers undergo digital transformation.An economic mechanism analysis reveals that this transformation reduces audit fees by lowering the risks and costs encountered by auditors.This is achieved by mitigating suppliers’business risks and improving earnings quality.Heterogeneity analysis reveals that the impact of customers’digital transformation on suppliers’audit fees is more pronounced when the supply chain is geographically distant,suppliers with more specific investments and with high levels of market competition.展开更多
Polymer chain ends play an important role in the glassy dynamics of polymeric materials. In this study, a combination of single molecule defocus fluorescence microscopy and well-controlled atom transfer radical polyme...Polymer chain ends play an important role in the glassy dynamics of polymeric materials. In this study, a combination of single molecule defocus fluorescence microscopy and well-controlled atom transfer radical polymerization was used to investigate site-dependent segmental mobility of poly(n-butyl methacrylate). As the temperature increased, the rotation of fluorophores, which were selectively labelled in chain end and chain middle, was gradually activated. The power spectra of rotation trajectories, the distribution of angular displacement as well as the population of rotating fluorophores demonstrated that the local dynamics was more activated at the chain ends than the middles, showing the unique contribution of the chain end to the dynamics of the system.展开更多
基金funded by the Key Discipline Construction Project of the Liaoning Provincial Social Science Planning Fund(grant ID:L24ZD042)。
文摘Background:The phenomenon of academic anxiety has been demonstrated to exert a considerable influence on students’academic engagement,leading to the emergence of a phenomenon known as“learned helplessness”and undermining the selfconfidence and motivation of high school students.Using acceptance-rejection theory,this study elucidated how a rejective parenting style affects Chinese high school students’academic anxiety and explored the urban-rural heterogeneity of this relationship.Methods:Data were analyzed using a stratified whole-cluster random sampling method.There are a total of 30,000 high school students in the three regions of northern and central China(from Shanxi,Hebei and Henan).A sample of 2286 high school students aged 14–19 years was ultimately selected from 2760 respondents for this investigation,which was conducted at the beginning of the 2023 school year.Pearson correlation,ordinary least squares(OLS)regression analysis,path analysis,and Fisher’s permutation test(FPT)were used to examine the effects of rejective parenting style on high school students’academic anxiety.Results:Results indicated a significant positive predictive effect between rejective parenting style and academic anxiety among high school students(β=0.815,t=116.211,p<0.001).Students’self-concept was significantly positively related to positive coping style(β=0.424,t=21.208,p<0.001)and chain-mediated this relationship.Therefore,this parenting style may indirectly mitigate academic anxiety through these mediators.The study also found that the effect of rejective parenting style on academic anxiety varied by students’residential background and was more pronounced in urban areas(0.226)than in rural areas(0.130).Conclusion:The research underscores the imperative for Chinese families to reexamine their utilization of rejection parenting and to prioritize the cultivation of students’intrinsic attributes.These findings offer a theoretical framework and practical evidence for policymakers and educators to develop efficacious and targeted interventions.In particular,greater attention should be directed towards the discrepancies in the manifestation of emotional and academic anxiety between urban and rural students,and prompt guidance should be furnished.
文摘Through improvements on a fully commercial and automatic system measuring frequency andtemperature spectra of the complex elastic, dielectric, and piezoelectric constants of polymerfilms, the precision for measuring complex dielectric constants achieved 2‰ from original 1%.The complex dielectric constants of PVDF, VDF (95 )/VF (5), VDF (52)/TrFE (48) and VDF(47. 5)/TrFE(47. 5)/HeFP (5) over a range of-120-140℃, 10-2-10;Hz were measured bythe described system. The diminution of chain regularity due to 5mol% vinyl fluoride in the chainof PVDF led to disappearing of α-relaxation and increase in T;(3℃) of VDF (95)/VF (5).Because of the spatial impediment of 5mol% HeFP in copolymer chain, the Curie point of VDF(52)/TrFE(48) decreased by 30℃ and T;by 3℃. The behavior of dielectric relaxation indicatedthat 5mol% vinyl fluoride and HeFP made the relaxation strength of noncrystalline regionreduced, the activation energy of local relaxation increased and the relaxation time prolonged respectively.
基金Supported by the National Natural Science Foundation of China(No.60878063)the Program from Traditional Chinese Medicine Bureau of Guangdong Province(No.2008233)
文摘A theoretical study on oligopeptide chains of glycine-alanine by density functional theory(DFT) is given in this paper. Raman spectra of the oligopeptide chains are examined. The geometric structures, frontier orbital, energy gap, atomic charge distribution, density of states and chemical activity of the side chain are studied at the B3LYP/6-31G(d) level. Results show that, with the number of residues increasing, vibrations of typical functional groups present Raman frequency shift, and the energy gap is gradually reduced. The HOMO and LUMO focus on the amino and carboxyl at the ends of oligopeptides. It is helpful for oligopeptides to self-assemble into chains. In addition, different residues(glycine or alanine) at the ends of chains result in the even-odd effect of orbital energy in the growth process. The size effects of physical and chemical properties only exist when the oligopeptides are shorter, and the phenomenon disappeared as the chain continues to grow.
文摘Bullwhip effect is the most important factor considered in the supply chain management. It gets many scholars' attention that bullwhip effect has been restricting the development of the supply chain all the time. Information Technology (IT) can reduce bullwhip effect by sharing the information among the enterprises in the supply chain.
基金funded by the key project of Sichuan province (Grand No. 2014SZ0163)the National Natural Science Foundation of China (Grant No. 41372301)the Key Deployment Project of Chinese Academy of Sciences (Grant No. KZZD-EW-05-01-02)
文摘The Wulipo landslide, triggered by heavy rainfall on July 10, 2013, transformed into debris flow,resulted in the destruction of 12 houses, 44 deaths, and 117 missing. Our systematic investigation has led to the following results and to a new understanding about the formation and evolution process of this hazard. The fundamental factors of the formation of the landslide are a high-steep free surface at the front of the slide mass and the sandstone-mudstone mixed stratum structure of the slope. The inducing factor of the landslide is hydrostatic and hydrodynamic pressure change caused by heavy continuous rainfall. The geological mechanical model of the landslide can be summarized as "instability-translational slide-tension fracture-collapse" and the formation mechanism as "translational landslide induced by heavy rainfall". The total volume of the landslide is 124.6×104 m3, and 16.3% of the sliding mass was dropped down from the cliff and transformed into debris flow during the sliding process, which enlarged 46.7% of the original sliding deposit area. The final accumulation area is found to be 9.2×104 m2. The hazard is a typical example of a disaster chain involving landslide and its induced debris flow. The concealment and disaster chain effect is the main reason for the heavy damage. In future risk assessment, it is suggested to enhance the research onpotential landslide identification for weakly intercalated slopes. By considering the influence of the behaviors of landslide-induced debris flow, the disaster area could be determined more reasonably.
基金the sponsorship of the National Basic Research Program of China (973 Program,2013CB228604,2014CB239201)the National Oil and Gas Major Projects of China (2011ZX05014-001-010HZ,2011ZX05014-001-006-XY570) for their funding of this research
文摘Elastic impedance inversion with high efficiency and high stability has become one of the main directions of seismic pre-stack inversion. The nonlinear elastic impedance inversion method based on a fast Markov chain Monte Carlo (MCMC) method is proposed in this paper, combining conventional MCMC method based on global optimization with a preconditioned conjugate gradient (PCG) algorithm based on local optimization, so this method does not depend strongly on the initial model. It converges to the global optimum quickly and efficiently on the condition that effi- ciency and stability of inversion are both taken into consid- eration at the same time. The test data verify the feasibility and robustness of the method, and based on this method, we extract the effective pore-fluid bulk modulus, which is applied to reservoir fluid identification and detection, and consequently, a better result has been achieved.
基金support provided by the Fundamental Research Funds for the Central Universities,Zhongnan University of Economics and Law(202411107).
文摘This research contributes to understanding the spillover effect of customer digital transformation along the supply chain.We take a supply chain relationship perspective to explore the influence of customers’digital transformation on suppliers’audit fees and find a significant reduction in such fees when customers undergo digital transformation.An economic mechanism analysis reveals that this transformation reduces audit fees by lowering the risks and costs encountered by auditors.This is achieved by mitigating suppliers’business risks and improving earnings quality.Heterogeneity analysis reveals that the impact of customers’digital transformation on suppliers’audit fees is more pronounced when the supply chain is geographically distant,suppliers with more specific investments and with high levels of market competition.
基金financially supported by National Basic Research Program of China(No.2014CB643601)
文摘Polymer chain ends play an important role in the glassy dynamics of polymeric materials. In this study, a combination of single molecule defocus fluorescence microscopy and well-controlled atom transfer radical polymerization was used to investigate site-dependent segmental mobility of poly(n-butyl methacrylate). As the temperature increased, the rotation of fluorophores, which were selectively labelled in chain end and chain middle, was gradually activated. The power spectra of rotation trajectories, the distribution of angular displacement as well as the population of rotating fluorophores demonstrated that the local dynamics was more activated at the chain ends than the middles, showing the unique contribution of the chain end to the dynamics of the system.