LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）Hxalloys were prepared by hydrogenation.Samples were annealed at 1343Kfor30-90 hto form the NaZn13 phase.La-rich andα-Fe secondary phases were also detected.Saturated hydr...LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）Hxalloys were prepared by hydrogenation.Samples were annealed at 1343Kfor30-90 hto form the NaZn13 phase.La-rich andα-Fe secondary phases were also detected.Saturated hydrogenation at 553 Kand 0.15 MPa of H_2 pressure for 5hwas employed to improve the Curie temperature of the alloys to 279 K.The maximum magnetic entropy change,relative cooling power,and adiabatic temperature change of LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x annealed at 1343 Kfor 90hafter hydrogen absorption are 6.38J/（kg·K）（magnetic changesμ0ΔH =1.65T）,100.1J/kg（μ0ΔH =1.65T）,and 2.2 K（μ0ΔH =1.48T）,respectively.Although the maximum magnetic entropy change of the LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys is lower than those of similar alloys with high purity raw materials,the relative cooling power is nearly the same.The effect of impurities of the raw materials used was also discussed.It is assumed that the impurity of 0.2wt.% Al is responsible for the reduced entropy change of the resulted alloys.The LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys prepared by this method could be a low cost alternative material for room temperature magnetic cooling applications.展开更多
基金financially supported by Inner Mongolia Natural Science Foundation of China(2013MS0802)
文摘LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）Hxalloys were prepared by hydrogenation.Samples were annealed at 1343Kfor30-90 hto form the NaZn13 phase.La-rich andα-Fe secondary phases were also detected.Saturated hydrogenation at 553 Kand 0.15 MPa of H_2 pressure for 5hwas employed to improve the Curie temperature of the alloys to 279 K.The maximum magnetic entropy change,relative cooling power,and adiabatic temperature change of LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x annealed at 1343 Kfor 90hafter hydrogen absorption are 6.38J/（kg·K）（magnetic changesμ0ΔH =1.65T）,100.1J/kg（μ0ΔH =1.65T）,and 2.2 K（μ0ΔH =1.48T）,respectively.Although the maximum magnetic entropy change of the LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys is lower than those of similar alloys with high purity raw materials,the relative cooling power is nearly the same.The effect of impurities of the raw materials used was also discussed.It is assumed that the impurity of 0.2wt.% Al is responsible for the reduced entropy change of the resulted alloys.The LaFe_（11.39）Mn_（0.35）Si_（1.26）B_（0.1）H_x alloys prepared by this method could be a low cost alternative material for room temperature magnetic cooling applications.
