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A FTIR STUDY OF DISSOLUTION AND PRECIPITA-TION OF SILICA IN BAYER PROCESS
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作者 龚文琪 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 1997年第Z1期1-8,共8页
A quantitative Fourier transform infrared (FTIR) technique mas established by comparison with chemical analysis and quantitative X-ray diffraction (XRD) analysis. By the quantitative FTIR analysis of bauxite during di... A quantitative Fourier transform infrared (FTIR) technique mas established by comparison with chemical analysis and quantitative X-ray diffraction (XRD) analysis. By the quantitative FTIR analysis of bauxite during dissolution , the process of dissolution and precipitation of silica was found to occur in three stages. In the first stage, there was no precipitation of desilication product (DSP). All the silica dissolved from kaolinite went into the solution. In the second stage, the silica concentration in solution attained a maximum and then dropped very quickly. The precipitation of DSP was the main cause of the reduction of the silica concentration in solution. In the third stage, the concentration of DSP reached a constant level. The dissolution and precipitation process gradually attained an equilibrium. The mechanism of silica dissolution and DSP precipitation was discussed on the basis of the FTIR quantitative analysis of kaolinite and DSP in bauxite. 展开更多
关键词 FTIR study Bayer process characterization of colloidal minerals BAUXITE KAOLINITE desili-cation product
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