Electrification and simple discharge schemes are coupled into a 3D Regional Atmospheric Model System (RAMS) as microphysical parameterizations, in accordance with electrical experiment results. The dynamics, microph...Electrification and simple discharge schemes are coupled into a 3D Regional Atmospheric Model System (RAMS) as microphysical parameterizations, in accordance with electrical experiment results. The dynamics, microphysics, and electrifi- cation components are fully integrated into the RAMS model, and the inductive and non-inductive electrification mechanisms are considered in the charging process. The results indicate that the thunderstorm mainly had a normal tripole charge structure. The simulated charge structure and lightning frequency are basically consistent with observations of the lightning radiation source distribution. The non-inductive charging mechanism contributed to the electrification during the whole lifetime of the thunderstorm, while the inductive electrification mechanism played a significant role in the development period and the mature stage when the electric field reached a large value. The charge structure in the convective region and the rearward region are analyzed, showing that the charge density in the convective region was double that in the rearward region.展开更多
Dominant frequency attenuation is a significant concern for frequency-based criteria of blasting vibration control.It is necessary to develop a concise and practical prediction equation describing dominant frequency a...Dominant frequency attenuation is a significant concern for frequency-based criteria of blasting vibration control.It is necessary to develop a concise and practical prediction equation describing dominant frequency attenuation.In this paper,a prediction equation of dominant frequency that accounts for primary parameters influencing the dominant frequency was proposed based on theoretical and dimensional analyses.Three blasting experiments were carried out in the Chiwan parking lot for collecting blasting vibration data used to conduct regression analysis of the proposed prediction equation.The fitting equations were further adopted to compare the reliability of three different types of dominant frequencies in the proposed equation and to explore the effects of different charge structures on the dominant frequency attenuation.The apparent frequency proved to be more reliable to express the attenuation law of the dominant frequency.The reliability and superiority of the proposed equation employing the apparent frequency were verified by comparison with the other five prediction equations.The smaller blasthole diameter or decoupling ratio leads to the higher initial value and corresponding faster attenuation of the dominant frequency.The blasthole diameter has a greater influence on the dominant frequency attenuation than the decoupling ratio does.Among the charge structures applied in the experiments,the charge structure with decoupling ratio of 1.5 and blasthole diameter of 48 mm results in the greatest initial value and corresponding fastest attenuation of the dominant frequency.展开更多
A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the projectile.The combustion chamber of the launching system is divided into two fixed chambers,one is located in th...A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the projectile.The combustion chamber of the launching system is divided into two fixed chambers,one is located in the breech chamber,and the other is arranged in the barrel.The breech chamber charge was ignited first,and the charges in the auxiliary chambers were ignited by the high-temperature,highpressure combustible gas trailing the projectile.In this way,the combustible gas in the auxiliary chambers could compensate for the pressure drop caused by the movement of the projectile.The proposed device features the advantage of launching a projectile with high muzzle velocity without exceeding the maximum pressure in the chamber.In order to obtain some internal ballistic characteristics of the launch system,some critical structure,such as the length of the filter cartridge auxiliary charge,the combustion degree of the propellant in the chamber,and the length of the barrel,are discussed.The experimental results show that with the increased auxiliary charge length,a pressure plateau or even a secondary peak pressure can be formed,which is less than the peak pressure.The projectile velocity increased by 23.57%,14.64%,and 7.65%when the diaphragm thickness was 0 mm,1 mm,and2 mm,respectively.The muzzle velocity of the projectile can be increased by 13.42%by increasing the length of the barrel.Under the same charge condition,with the increase of barrel length,the energy utilization rate of propellant increases by 28.64%.展开更多
Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery,the predicted performance of power battery,especially the state-of-charge(SOC) estimation has attracted great attention ...Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery,the predicted performance of power battery,especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV.However,the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected.A variable structure extended kalman filter(VSEKF)-based estimation method,which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition,is presented.First,the general lower-order battery equivalent circuit model(GLM),which includes column accumulation model,open circuit voltage model and the SOC output model,is established,and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data.Next,a VSEKF estimation method of SOC,which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method,is executed with different adaptive weighting coefficients,which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes.According to the experimental analysis,the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV.The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method.In Summary,the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system,which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method.The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.展开更多
This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both...This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both noninductive and inductive charge separation schemes,was utilized.The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development,electrification,and charge structure of thunderstorms.Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops,which were primarily responsible for the development of positive charge regions through a non-inductive charging process.Conversely,heterogeneous freezing resulted in larger ice crystals,enhancing graupel formation and leading to a more rapid and intense charge separation rate of around-15°C.Ice crystals formed heterogeneously and charged negatively during the development stage,resulting in an inverted dipole charge structure.When both immersion and homogeneous freezing processes were considered,the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification.Under conditions of low cloud water content at lower storm levels,graupel particles were negatively charged through non-inductive charging,causing the charge structure to quickly revert to a normal dipole structure.展开更多
The structural features and three-dimensional nature of the charge density wave (CDW) state of the layered chalcogenide 1T-TaSe2-xTex (0≤x≤2.0) are characterized by Cs-corrected transmission electron microscopy ...The structural features and three-dimensional nature of the charge density wave (CDW) state of the layered chalcogenide 1T-TaSe2-xTex (0≤x≤2.0) are characterized by Cs-corrected transmission electron microscopy measurements. Notable changes of both average structure and the CDW state arising from Te substitution for Se are clearly demonstrated in samples with x〉0.3. The commensurate CDW state characterized by the known star-of-David clustering in the 1T-TaSe2 crystal becomes visibly unstable with Te substitution and vanishes when x=0.3. The 1T-TaSe2-xTex (0.3≤x≤1.3) samples generally adopt a remarkable incommensurate CDW state with monoclinic distortion, which could be fundamentally in correlation with the strong qq-dependent electron-phonon coupling-induced period-lattice-distortion as identified in TaTe22. Systematic analysis demonstrates that the occurrence of superconductivity is related to the suppression of the commensurate CDW phase and the presence of discommensuration is an evident structural feature observed in the superconducting samples.展开更多
Electrical characteristics of an isolated supercell storm observed on 13 June 2014 over Beijing were investigated using lightning data obtained from the Beijing Lightning Network,radar reflectivity,and hydrometeor ret...Electrical characteristics of an isolated supercell storm observed on 13 June 2014 over Beijing were investigated using lightning data obtained from the Beijing Lightning Network,radar reflectivity,and hydrometeor retrievals during the 6-h lifetime.Positive cloud-to-ground(+CG)lightning took a high percentage of CG lightning.Before and during a hail event,+CG lightning was more frequent than negative cloud-to-ground(-CG)lightning,except that+CG lightning took a high percentage at the beginning and in the dissipating stage.After the hail event ended,-CG lightning dominated and reached its maximum value.An analysis of hydrometeors retrieved by X-band polarimetric radar revealed that the discharge concentrated in the convective region with graupel particles and hailstones,whereas graupel,snow and ice crystals in the stratiform region.Lightning radiation sources were located mainly in the convective region,some of which were distributed along a gradient of radar reflectivity from the convective region to the stratiform region.The indication is that the supercell demonstrated an inverted tripole charge structure before the hail event,which converted to a normal tripole structure after the hail event.展开更多
The importance of atmospheric electricity research has been increasingly recognized in recent decades. Research on atmospheric electricity has been actively conducted since the 1980 s in China. Lightning physics and i...The importance of atmospheric electricity research has been increasingly recognized in recent decades. Research on atmospheric electricity has been actively conducted since the 1980 s in China. Lightning physics and its effects, as important branches of atmospheric electricity, have received more attention because of their significance both in scientific research and lightning protection applications. This paper reviews atmospheric electricity research based primarily on ground-based field experiments at different regions in China in the last decade. The results described in this review include physics and effects of lightning, rocket-triggered lightning and its physical processes of discharge, thunderstorm electricity on the Tibetan Plateau and its surrounding areas, lightning activity associated with severe convective storms, the effect and response of lightning to climate change, numerical simulation of thunderstorm electrification and lightning discharge, lightning detection and location techniques, and transient luminous events above thunderstorms.展开更多
Lightning meteorology focuses on investigating the lightning activities in different types of convective weather systems and the relationship of lightning to the dynamic and microphysical processes in thunder- storms....Lightning meteorology focuses on investigating the lightning activities in different types of convective weather systems and the relationship of lightning to the dynamic and microphysical processes in thunder- storms. With the development and application of advanced lightning detection and location technologies, lightning meteorology has been developed into an important interdiscipline between atmospheric electricity and meteorology. This paper mainly reviews the advances of lightning meteorology research in recent years in China from the following five aspects: 1) development of advanced lightning location technology, 2) char- acteristics of lightning activity in different convective systems, 3) relationship of lightning to the dynamic and microphysical processes in thunderstorms, 4) charge structure of thunderstorms, and 5) lightning data assimilation techniques and application to severe weather forecasting. In addition, some important aspects on future research of the lightning meteorology are proposed.展开更多
Evolution of the electrifi cation of an idealized tropical cyclone (TC) is simulated by using the Advanced Weather Research and Forecasting (WRF-ARW) model. The model was modifi ed by addition of explicit electrif...Evolution of the electrifi cation of an idealized tropical cyclone (TC) is simulated by using the Advanced Weather Research and Forecasting (WRF-ARW) model. The model was modifi ed by addition of explicit electrifi cation and a new bulk discharge scheme. The characteristics of TC lightning is further examined by analyses of the electrifi cation and the charge structure of the TC. The fi ndings thus obtained are able to unify most of the previous inconsisitent observational and simulation studies. The results indicate that the TC eyewall generally exhibits an inverted dipole charge structure with negative charge above the positive. In the intensifi cation stage, however, the extremely tall towers of the eyewall may exhibit a normal tripole structure with a main negative region between two regions of positive charge. The outer spiral rainband cells display a simple normal dipole structure during all the stages. It is further found that the diff erences in the charge structure are associated with diff erent updrafts and particle distributions. Weak updrafts, together with a coexistence region of diff erent particles at lower levels in the eyewall, result in charging processes that occur mainly in the positive graupel charging zone (PGCZ). In the intensifi cation stage, the occurrence of charging processes in both positive and negative graupel charging zones is associated with strong updraft in the extremely tall towers. In addition, the coexistence region of graupel and ice crystals is mainly situated at upper levels in the outer rainband, so the charging processes mainly occur in the negative graupel charging zone (NGCZ).展开更多
The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (st) for amphoteric solid with structural charges was established in order to...The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (st) for amphoteric solid with structural charges was established in order to investigate the effect of st on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC+log[(1+2aPZNC)/(1-2aPZNC)], where aPZNC≡st/eNANs, in which e is the elementary charge, NA the Avogadro抯 constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl, OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H+ or OH- and the electrostatic interaction between charging surface and H+ or OH-.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.41175002, 40930949)National Key Basic Research Program of China (2014CB441401)
文摘Electrification and simple discharge schemes are coupled into a 3D Regional Atmospheric Model System (RAMS) as microphysical parameterizations, in accordance with electrical experiment results. The dynamics, microphysics, and electrifi- cation components are fully integrated into the RAMS model, and the inductive and non-inductive electrification mechanisms are considered in the charging process. The results indicate that the thunderstorm mainly had a normal tripole charge structure. The simulated charge structure and lightning frequency are basically consistent with observations of the lightning radiation source distribution. The non-inductive charging mechanism contributed to the electrification during the whole lifetime of the thunderstorm, while the inductive electrification mechanism played a significant role in the development period and the mature stage when the electric field reached a large value. The charge structure in the convective region and the rearward region are analyzed, showing that the charge density in the convective region was double that in the rearward region.
基金supported by National Natural Science Foundation of China(Grant Nos.51779190 and 51909196)Postdoctoral Science Foundation of China(Grant No.2020T130569)。
文摘Dominant frequency attenuation is a significant concern for frequency-based criteria of blasting vibration control.It is necessary to develop a concise and practical prediction equation describing dominant frequency attenuation.In this paper,a prediction equation of dominant frequency that accounts for primary parameters influencing the dominant frequency was proposed based on theoretical and dimensional analyses.Three blasting experiments were carried out in the Chiwan parking lot for collecting blasting vibration data used to conduct regression analysis of the proposed prediction equation.The fitting equations were further adopted to compare the reliability of three different types of dominant frequencies in the proposed equation and to explore the effects of different charge structures on the dominant frequency attenuation.The apparent frequency proved to be more reliable to express the attenuation law of the dominant frequency.The reliability and superiority of the proposed equation employing the apparent frequency were verified by comparison with the other five prediction equations.The smaller blasthole diameter or decoupling ratio leads to the higher initial value and corresponding faster attenuation of the dominant frequency.The blasthole diameter has a greater influence on the dominant frequency attenuation than the decoupling ratio does.Among the charge structures applied in the experiments,the charge structure with decoupling ratio of 1.5 and blasthole diameter of 48 mm results in the greatest initial value and corresponding fastest attenuation of the dominant frequency.
基金financially supported by the National Natural Science Foundation of China under Project No.51874267 and No.12272374the Fundamental Research Funds for the Central Universities under Project Nos.WK2480000008,WK2480000007,and WK2320000049。
文摘A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the projectile.The combustion chamber of the launching system is divided into two fixed chambers,one is located in the breech chamber,and the other is arranged in the barrel.The breech chamber charge was ignited first,and the charges in the auxiliary chambers were ignited by the high-temperature,highpressure combustible gas trailing the projectile.In this way,the combustible gas in the auxiliary chambers could compensate for the pressure drop caused by the movement of the projectile.The proposed device features the advantage of launching a projectile with high muzzle velocity without exceeding the maximum pressure in the chamber.In order to obtain some internal ballistic characteristics of the launch system,some critical structure,such as the length of the filter cartridge auxiliary charge,the combustion degree of the propellant in the chamber,and the length of the barrel,are discussed.The experimental results show that with the increased auxiliary charge length,a pressure plateau or even a secondary peak pressure can be formed,which is less than the peak pressure.The projectile velocity increased by 23.57%,14.64%,and 7.65%when the diaphragm thickness was 0 mm,1 mm,and2 mm,respectively.The muzzle velocity of the projectile can be increased by 13.42%by increasing the length of the barrel.Under the same charge condition,with the increase of barrel length,the energy utilization rate of propellant increases by 28.64%.
基金Supported by National Key Technology R&D Program of Ministry of Science and Technology of China(Grant No.2013BAG14B01)
文摘Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery,the predicted performance of power battery,especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV.However,the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected.A variable structure extended kalman filter(VSEKF)-based estimation method,which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition,is presented.First,the general lower-order battery equivalent circuit model(GLM),which includes column accumulation model,open circuit voltage model and the SOC output model,is established,and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data.Next,a VSEKF estimation method of SOC,which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method,is executed with different adaptive weighting coefficients,which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes.According to the experimental analysis,the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV.The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method.In Summary,the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system,which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method.The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.
基金National Natural Science Foundation of China (41805002)Joint Funds of the Zhejiang Provincial Natural Science Foundation of China (LZJMZ24D050009)+1 种基金Startup Foundation for Introducing Talent of NUIST (2016r042)Hubei Provincial Natural Science Foundation of China (2021CFB571)。
文摘This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both noninductive and inductive charge separation schemes,was utilized.The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development,electrification,and charge structure of thunderstorms.Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops,which were primarily responsible for the development of positive charge regions through a non-inductive charging process.Conversely,heterogeneous freezing resulted in larger ice crystals,enhancing graupel formation and leading to a more rapid and intense charge separation rate of around-15°C.Ice crystals formed heterogeneously and charged negatively during the development stage,resulting in an inverted dipole charge structure.When both immersion and homogeneous freezing processes were considered,the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification.Under conditions of low cloud water content at lower storm levels,graupel particles were negatively charged through non-inductive charging,causing the charge structure to quickly revert to a normal dipole structure.
基金Supported by the National Basic Research Program of China under Grant Nos 2015CB921300 and 2012CB821404the National Key Research and Development Program of China under Grant Nos 2016YFA0300300 and 2016YFA0300404+1 种基金the National Natural Science Foundation of China under Grant Nos 11474323,11604372,11274368,91221102,11190022,11674326 and 91422303the Strategic Priority Research Program(B)of the Chinese Academy of Sciences under Grant No XDB07020000
文摘The structural features and three-dimensional nature of the charge density wave (CDW) state of the layered chalcogenide 1T-TaSe2-xTex (0≤x≤2.0) are characterized by Cs-corrected transmission electron microscopy measurements. Notable changes of both average structure and the CDW state arising from Te substitution for Se are clearly demonstrated in samples with x〉0.3. The commensurate CDW state characterized by the known star-of-David clustering in the 1T-TaSe2 crystal becomes visibly unstable with Te substitution and vanishes when x=0.3. The 1T-TaSe2-xTex (0.3≤x≤1.3) samples generally adopt a remarkable incommensurate CDW state with monoclinic distortion, which could be fundamentally in correlation with the strong qq-dependent electron-phonon coupling-induced period-lattice-distortion as identified in TaTe22. Systematic analysis demonstrates that the occurrence of superconductivity is related to the suppression of the commensurate CDW phase and the presence of discommensuration is an evident structural feature observed in the superconducting samples.
基金supported by the National Natural Science Foundation of China(Grant Nos.41875007 and 41630425)the Special Fund for Meteorology-Scientific Research in the Public Interest(Grant No.GYHY201506004)the 2018 Open Research Program of the State Key Laboratory of Severe Weather(Grant No.2018LASWB06)。
文摘Electrical characteristics of an isolated supercell storm observed on 13 June 2014 over Beijing were investigated using lightning data obtained from the Beijing Lightning Network,radar reflectivity,and hydrometeor retrievals during the 6-h lifetime.Positive cloud-to-ground(+CG)lightning took a high percentage of CG lightning.Before and during a hail event,+CG lightning was more frequent than negative cloud-to-ground(-CG)lightning,except that+CG lightning took a high percentage at the beginning and in the dissipating stage.After the hail event ended,-CG lightning dominated and reached its maximum value.An analysis of hydrometeors retrieved by X-band polarimetric radar revealed that the discharge concentrated in the convective region with graupel particles and hailstones,whereas graupel,snow and ice crystals in the stratiform region.Lightning radiation sources were located mainly in the convective region,some of which were distributed along a gradient of radar reflectivity from the convective region to the stratiform region.The indication is that the supercell demonstrated an inverted tripole charge structure before the hail event,which converted to a normal tripole structure after the hail event.
基金supported by the National Key Basic Research and Development (973) Program of China (2014CB441400)the National Natural Science Foundation of China (Grant No. 41475002)
文摘The importance of atmospheric electricity research has been increasingly recognized in recent decades. Research on atmospheric electricity has been actively conducted since the 1980 s in China. Lightning physics and its effects, as important branches of atmospheric electricity, have received more attention because of their significance both in scientific research and lightning protection applications. This paper reviews atmospheric electricity research based primarily on ground-based field experiments at different regions in China in the last decade. The results described in this review include physics and effects of lightning, rocket-triggered lightning and its physical processes of discharge, thunderstorm electricity on the Tibetan Plateau and its surrounding areas, lightning activity associated with severe convective storms, the effect and response of lightning to climate change, numerical simulation of thunderstorm electrification and lightning discharge, lightning detection and location techniques, and transient luminous events above thunderstorms.
基金Supported by the National Key Basic Research and Development(973)Program of China(2014CB441401)National Natural Science Foundation of China(40930949)
文摘Lightning meteorology focuses on investigating the lightning activities in different types of convective weather systems and the relationship of lightning to the dynamic and microphysical processes in thunder- storms. With the development and application of advanced lightning detection and location technologies, lightning meteorology has been developed into an important interdiscipline between atmospheric electricity and meteorology. This paper mainly reviews the advances of lightning meteorology research in recent years in China from the following five aspects: 1) development of advanced lightning location technology, 2) char- acteristics of lightning activity in different convective systems, 3) relationship of lightning to the dynamic and microphysical processes in thunderstorms, 4) charge structure of thunderstorms, and 5) lightning data assimilation techniques and application to severe weather forecasting. In addition, some important aspects on future research of the lightning meteorology are proposed.
基金Supported by the National(Key)Basic Research and Development(973)Program of China(2014CB441406 and 2014CB441402)National Natural Science Foundation of China(41030960)Basic Research Fund of Chinese Academy of Meteorological Sciences(2013Z006)
文摘Evolution of the electrifi cation of an idealized tropical cyclone (TC) is simulated by using the Advanced Weather Research and Forecasting (WRF-ARW) model. The model was modifi ed by addition of explicit electrifi cation and a new bulk discharge scheme. The characteristics of TC lightning is further examined by analyses of the electrifi cation and the charge structure of the TC. The fi ndings thus obtained are able to unify most of the previous inconsisitent observational and simulation studies. The results indicate that the TC eyewall generally exhibits an inverted dipole charge structure with negative charge above the positive. In the intensifi cation stage, however, the extremely tall towers of the eyewall may exhibit a normal tripole structure with a main negative region between two regions of positive charge. The outer spiral rainband cells display a simple normal dipole structure during all the stages. It is further found that the diff erences in the charge structure are associated with diff erent updrafts and particle distributions. Weak updrafts, together with a coexistence region of diff erent particles at lower levels in the eyewall, result in charging processes that occur mainly in the positive graupel charging zone (PGCZ). In the intensifi cation stage, the occurrence of charging processes in both positive and negative graupel charging zones is associated with strong updraft in the extremely tall towers. In addition, the coexistence region of graupel and ice crystals is mainly situated at upper levels in the outer rainband, so the charging processes mainly occur in the negative graupel charging zone (NGCZ).
基金Project supported by the National Natural Science Foundation of China (No. 20273041) and State Education Ministry.
文摘The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (st) for amphoteric solid with structural charges was established in order to investigate the effect of st on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC+log[(1+2aPZNC)/(1-2aPZNC)], where aPZNC≡st/eNANs, in which e is the elementary charge, NA the Avogadro抯 constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl, OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H+ or OH- and the electrostatic interaction between charging surface and H+ or OH-.