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Charge Structure of a Summer Thunderstorm in North China:Simulation Using a Regional Atmospheric Model System 被引量:16
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作者 LIU Dongxia QIE Xiushu +1 位作者 PENG Liang LI Wanli 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2014年第5期1022-1034,共13页
Electrification and simple discharge schemes are coupled into a 3D Regional Atmospheric Model System (RAMS) as microphysical parameterizations, in accordance with electrical experiment results. The dynamics, microph... Electrification and simple discharge schemes are coupled into a 3D Regional Atmospheric Model System (RAMS) as microphysical parameterizations, in accordance with electrical experiment results. The dynamics, microphysics, and electrifi- cation components are fully integrated into the RAMS model, and the inductive and non-inductive electrification mechanisms are considered in the charging process. The results indicate that the thunderstorm mainly had a normal tripole charge structure. The simulated charge structure and lightning frequency are basically consistent with observations of the lightning radiation source distribution. The non-inductive charging mechanism contributed to the electrification during the whole lifetime of the thunderstorm, while the inductive electrification mechanism played a significant role in the development period and the mature stage when the electric field reached a large value. The charge structure in the convective region and the rearward region are analyzed, showing that the charge density in the convective region was double that in the rearward region. 展开更多
关键词 RAMS electrification parameterization discharge parameterization charge structure THUNDERSTORM
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Numerical investigation of effect of eccentric decoupled charge structure on blasting-induced rock damage 被引量:11
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作者 PAN Cheng XIE Li-xiang +3 位作者 LI Xing LIU Kai GAO Peng-fei TIAN Long-gang 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第2期663-679,共17页
Eccentric decoupling blasting is commonly used in underground excavation.Determination of perimeter hole parameters(such as the blasthole diameter,spacing,and burden)based on an eccentric charge structure is vital for... Eccentric decoupling blasting is commonly used in underground excavation.Determination of perimeter hole parameters(such as the blasthole diameter,spacing,and burden)based on an eccentric charge structure is vital for achieving an excellent smooth blasting effect.In this paper,the Riedel-Hiermaier-Thoma(RHT)model was employed to study rock mass damage under smooth blasting.Firstly,the parameters of the RHT model were calibrated by using the existing SHPB experiment,which were then verified by the existing blasting experiment results.Secondly,the influence of different charge structures on the blasting effect was investigated using the RHT model.The simulation results indicated that eccentric charge blasting has an obvious pressure eccentricity effect.Finally,to improve the blasting effect,the smooth blasting parameters were optimized based on an eccentric charge structure.The overbreak and underbreak phenomena were effectively controlled,and a good blasting effect was achieved with the optimized blasting parameters. 展开更多
关键词 eccentric charge structure smooth blasting rock mass damage RHT model parameter optimization
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Comparison of dominant frequency attenuation of blasting vibration for different charge structures 被引量:5
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作者 Pengchang Sun Wenbo Lu +3 位作者 Junru Zhou Xincheng Huang Ming Chen Qi Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2022年第2期448-459,共12页
Dominant frequency attenuation is a significant concern for frequency-based criteria of blasting vibration control.It is necessary to develop a concise and practical prediction equation describing dominant frequency a... Dominant frequency attenuation is a significant concern for frequency-based criteria of blasting vibration control.It is necessary to develop a concise and practical prediction equation describing dominant frequency attenuation.In this paper,a prediction equation of dominant frequency that accounts for primary parameters influencing the dominant frequency was proposed based on theoretical and dimensional analyses.Three blasting experiments were carried out in the Chiwan parking lot for collecting blasting vibration data used to conduct regression analysis of the proposed prediction equation.The fitting equations were further adopted to compare the reliability of three different types of dominant frequencies in the proposed equation and to explore the effects of different charge structures on the dominant frequency attenuation.The apparent frequency proved to be more reliable to express the attenuation law of the dominant frequency.The reliability and superiority of the proposed equation employing the apparent frequency were verified by comparison with the other five prediction equations.The smaller blasthole diameter or decoupling ratio leads to the higher initial value and corresponding faster attenuation of the dominant frequency.The blasthole diameter has a greater influence on the dominant frequency attenuation than the decoupling ratio does.Among the charge structures applied in the experiments,the charge structure with decoupling ratio of 1.5 and blasthole diameter of 48 mm results in the greatest initial value and corresponding fastest attenuation of the dominant frequency. 展开更多
关键词 Dominant frequency Blasting vibration Attenuation law Prediction equation charge structures
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Experimental research on the launching system of auxiliary charge with filter cartridge structure
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作者 Zi-Jun Chen Ze He +2 位作者 Hong-Hao Ma Lu-Qing Wang Zhao-Wu Shen 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期41-48,共8页
A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the projectile.The combustion chamber of the launching system is divided into two fixed chambers,one is located in th... A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the projectile.The combustion chamber of the launching system is divided into two fixed chambers,one is located in the breech chamber,and the other is arranged in the barrel.The breech chamber charge was ignited first,and the charges in the auxiliary chambers were ignited by the high-temperature,highpressure combustible gas trailing the projectile.In this way,the combustible gas in the auxiliary chambers could compensate for the pressure drop caused by the movement of the projectile.The proposed device features the advantage of launching a projectile with high muzzle velocity without exceeding the maximum pressure in the chamber.In order to obtain some internal ballistic characteristics of the launch system,some critical structure,such as the length of the filter cartridge auxiliary charge,the combustion degree of the propellant in the chamber,and the length of the barrel,are discussed.The experimental results show that with the increased auxiliary charge length,a pressure plateau or even a secondary peak pressure can be formed,which is less than the peak pressure.The projectile velocity increased by 23.57%,14.64%,and 7.65%when the diaphragm thickness was 0 mm,1 mm,and2 mm,respectively.The muzzle velocity of the projectile can be increased by 13.42%by increasing the length of the barrel.Under the same charge condition,with the increase of barrel length,the energy utilization rate of propellant increases by 28.64%. 展开更多
关键词 Interior ballistics charge structures Launch system charge design
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The role of dynamic transport in the formation of the inverted charge structure in a simulated hailstorm 被引量:7
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作者 XU Liang Tao ZHANG Yi Jun +2 位作者 LIU Heng Yi ZHENG Dong WANG Fei 《Science China Earth Sciences》 SCIE EI CAS CSCD 2016年第7期1414-1426,共13页
The inverted charge structure formation of a hailstorm was investigated using the Advanced Weather Research and Forecasting(WRF-ARW) model coupled with electrification and discharge schemes. Different processes may ... The inverted charge structure formation of a hailstorm was investigated using the Advanced Weather Research and Forecasting(WRF-ARW) model coupled with electrification and discharge schemes. Different processes may be responsible for inverted charge structure in different storms and regions.A dynamical-derived mechanism of inverted charge structure formation was confirmed by the numerical model: the inverted structure was formed by strong updraft and downdraft under normal-polarity charging conditions such that the graupel charged negatively in the main charging region in the middle-upper level of the cloud. The simulation results showed the storm presented a normal charge structure before and after hail-fall; while during the hail-fall stage, it showed an inverted charge structure—negative charge region in the upper level of the cloud and a positive charge region in the middle level of the cloud—appearing at the front edge near the strong updraft in the hailstorm. The charging processes between the two particles mainly occurred at the top of the cloud, where the graupel charged negatively and ice crystals positively due to the strong updraft. When the updraft air reached the top of the storm, it would spread to the rear and front. The light ice crystals were transported backward and forward more easily. Meanwhile, the positively charged ice crystals were transported downward by the frontal subsidence, and then a positive charge region formed between the -10°C and -25°C levels. Subsequently, a negative charge region materialized in the upper level of the cloud, and the inverted charge structure formed. 展开更多
关键词 Severe storm Mesoscale model Inverted charge structure
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Estimation Method of State-of-Charge For Lithium-ion Battery Used in Hybrid Electric Vehicles Based on Variable Structure Extended Kalman Filter 被引量:18
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作者 SUN Yong MA Zilin +2 位作者 TANG Gongyou CHEN Zheng ZHANG Nong 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2016年第4期717-726,共10页
Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery,the predicted performance of power battery,especially the state-of-charge(SOC) estimation has attracted great attention ... Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery,the predicted performance of power battery,especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV.However,the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected.A variable structure extended kalman filter(VSEKF)-based estimation method,which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition,is presented.First,the general lower-order battery equivalent circuit model(GLM),which includes column accumulation model,open circuit voltage model and the SOC output model,is established,and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data.Next,a VSEKF estimation method of SOC,which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method,is executed with different adaptive weighting coefficients,which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes.According to the experimental analysis,the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV.The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method.In Summary,the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system,which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method.The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions. 展开更多
关键词 state of charge estimation hybrid electric vehicle general lower-order model variable structure EKF
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Numerical Sensitivity Studies on Effects of Ice Nucleating Processes on Electrification in Thunderstorms
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作者 师正 曲凯悦 +5 位作者 李璐滢 管啸林 孙京 崔雪东 胡佳瑞 吴子珉 《Journal of Tropical Meteorology》 SCIE 2024年第2期149-167,共19页
This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both... This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds.A two-dimensional cumulus model,incorporating both noninductive and inductive charge separation schemes,was utilized.The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development,electrification,and charge structure of thunderstorms.Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops,which were primarily responsible for the development of positive charge regions through a non-inductive charging process.Conversely,heterogeneous freezing resulted in larger ice crystals,enhancing graupel formation and leading to a more rapid and intense charge separation rate of around-15°C.Ice crystals formed heterogeneously and charged negatively during the development stage,resulting in an inverted dipole charge structure.When both immersion and homogeneous freezing processes were considered,the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification.Under conditions of low cloud water content at lower storm levels,graupel particles were negatively charged through non-inductive charging,causing the charge structure to quickly revert to a normal dipole structure. 展开更多
关键词 homogeneous freezing heterogeneous freezing immersion freezing non-inductive charging charge structure
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Theory and practice of the optimizing of charging structure in EAF steelmaking 被引量:2
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作者 Yu Chen Shiqi Li Shujuan Ji Runzao Liu 《Journal of University of Science and Technology Beijing》 CSCD 2005年第4期313-316,共4页
The viewpoint about harmful residual element control, the charging structure and its influence on production index due to the diversification of raw material in EAF steelmaking was expatiated. The residual element con... The viewpoint about harmful residual element control, the charging structure and its influence on production index due to the diversification of raw material in EAF steelmaking was expatiated. The residual element control model, the concept of the proportion of iron and steel and the charging structure triangle were putted forward. Based on theoretical calculation and statistical analysis, the influence of charging structure on production index was discussed, and it was found that the utilizing efficiency of energy will reduce as the proportion of iron and steel in EAF steelmaking increases. 展开更多
关键词 charging structure element control EAF steelmaking
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Charge Density Wave States and Structural Transition in Layered Chalcogenide TaSe_(2-x)Te_x 被引量:1
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作者 尉琳琳 孙帅帅 +6 位作者 孙开 刘育 邵定夫 鲁文建 孙玉平 田焕芳 杨槐馨 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第8期108-112,共5页
The structural features and three-dimensional nature of the charge density wave (CDW) state of the layered chalcogenide 1T-TaSe2-xTex (0≤x≤2.0) are characterized by Cs-corrected transmission electron microscopy ... The structural features and three-dimensional nature of the charge density wave (CDW) state of the layered chalcogenide 1T-TaSe2-xTex (0≤x≤2.0) are characterized by Cs-corrected transmission electron microscopy measurements. Notable changes of both average structure and the CDW state arising from Te substitution for Se are clearly demonstrated in samples with x〉0.3. The commensurate CDW state characterized by the known star-of-David clustering in the 1T-TaSe2 crystal becomes visibly unstable with Te substitution and vanishes when x=0.3. The 1T-TaSe2-xTex (0.3≤x≤1.3) samples generally adopt a remarkable incommensurate CDW state with monoclinic distortion, which could be fundamentally in correlation with the strong qq-dependent electron-phonon coupling-induced period-lattice-distortion as identified in TaTe22. Systematic analysis demonstrates that the occurrence of superconductivity is related to the suppression of the commensurate CDW phase and the presence of discommensuration is an evident structural feature observed in the superconducting samples. 展开更多
关键词 Ta TE CDW charge Density Wave States and Structural Transition in Layered Chalcogenide TaSe x)Te_x
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A Review of Atmospheric Electricity Research in China 被引量:6
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作者 QIE Xiushu ZHANG Yijun +8 位作者 YUAN Tie ZHANG Qilin ZHANG Tinglong ZHU Baoyou LU Weitao MA Ming YANG Jing ZHOU Yunjun FENG Guili 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2015年第2期169-191,共23页
The importance of atmospheric electricity research has been increasingly recognized in recent decades. Research on atmospheric electricity has been actively conducted since the 1980 s in China. Lightning physics and i... The importance of atmospheric electricity research has been increasingly recognized in recent decades. Research on atmospheric electricity has been actively conducted since the 1980 s in China. Lightning physics and its effects, as important branches of atmospheric electricity, have received more attention because of their significance both in scientific research and lightning protection applications. This paper reviews atmospheric electricity research based primarily on ground-based field experiments at different regions in China in the last decade. The results described in this review include physics and effects of lightning, rocket-triggered lightning and its physical processes of discharge, thunderstorm electricity on the Tibetan Plateau and its surrounding areas, lightning activity associated with severe convective storms, the effect and response of lightning to climate change, numerical simulation of thunderstorm electrification and lightning discharge, lightning detection and location techniques, and transient luminous events above thunderstorms. 展开更多
关键词 atmospheric electricity lightning physics rocket-triggered lightning thunderstorm charge structure lightning location techniques
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Investigating Lightning Characteristics through a Supercell Storm by Comprehensive Coordinated Observations over North China 被引量:6
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作者 Dongxia LIU Xiushu QIE +2 位作者 Yichen CHEN Zhuling SUN Shanfeng YUAN 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2020年第8期861-872,共12页
Electrical characteristics of an isolated supercell storm observed on 13 June 2014 over Beijing were investigated using lightning data obtained from the Beijing Lightning Network,radar reflectivity,and hydrometeor ret... Electrical characteristics of an isolated supercell storm observed on 13 June 2014 over Beijing were investigated using lightning data obtained from the Beijing Lightning Network,radar reflectivity,and hydrometeor retrievals during the 6-h lifetime.Positive cloud-to-ground(+CG)lightning took a high percentage of CG lightning.Before and during a hail event,+CG lightning was more frequent than negative cloud-to-ground(-CG)lightning,except that+CG lightning took a high percentage at the beginning and in the dissipating stage.After the hail event ended,-CG lightning dominated and reached its maximum value.An analysis of hydrometeors retrieved by X-band polarimetric radar revealed that the discharge concentrated in the convective region with graupel particles and hailstones,whereas graupel,snow and ice crystals in the stratiform region.Lightning radiation sources were located mainly in the convective region,some of which were distributed along a gradient of radar reflectivity from the convective region to the stratiform region.The indication is that the supercell demonstrated an inverted tripole charge structure before the hail event,which converted to a normal tripole structure after the hail event. 展开更多
关键词 LIGHTNING SUPERCELL Beijing Lightning Network charge structure
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Model experiment of rock blasting with single borehole and double free-surface 被引量:5
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作者 TIAN Jian-sheng QU Fan-fei 《Mining Science and Technology》 EI CAS 2009年第3期395-398,404,共5页
In order to improve the quality of laneways and tunnel excavation by drilling and blasting and by making effective use of explosive energy, a model experiment of rock blasting with a single borehole and a double free-... In order to improve the quality of laneways and tunnel excavation by drilling and blasting and by making effective use of explosive energy, a model experiment of rock blasting with a single borehole and a double free-surface was performed with the objective of studying the effect of parameters such as charge structure, free-surface and rock compressive strength on rock blasting.The model experiments indicate that:1) the smaller the rock compressive strength and density, the more distinctive the cavity expanding action by blasting;2) the powder factor in an air-decoupling charge structure is larger than that in a coupling charge structure, i.e., the explosive energy in an air-decoupling charge structure transferred to the rocks is less than that in a coupling charge structure;3) a free-surface improves the utilizations of explosive energy;4) an air-decoupling charge structure helps to maintain the integrity and stability of wall rock in controlled perimeter blasting, such as in roadways and tunnel excavation by drilling and blasting. 展开更多
关键词 model experiment single borehole cylindrical charge air-decoupling charge structure free surface
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Synthesis,structure and electrical properties of charge transfer complex [MDA][Pd(dmit)_2 ]_2
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《Chinese Science Bulletin》 SCIE CAS 1998年第17期1494-1496,共3页
关键词 PD Synthesis structure and electrical properties of charge transfer complex DMIT MDA
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Strain induced polymorphism and band structure modulation in low-temperature 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene single crystal
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作者 Jianfeng Chen Wen Shi +2 位作者 Yuqian Jiang Dong Wang Zhigang Shuai 《Science China Chemistry》 SCIE EI CAS CSCD 2017年第2期275-283,共9页
Organic semiconductors are inherently soft,making it possible to increase their mobilities by strains.Such a unique feature can be exploited directly in flexible electronics for improved device performance.The 2,7-dio... Organic semiconductors are inherently soft,making it possible to increase their mobilities by strains.Such a unique feature can be exploited directly in flexible electronics for improved device performance.The 2,7-dioctyl[1]benzothieno[3,2-b][1]-benzothiophene derivative,C8-BTBT is one of the best small-molecule hole transport materials.Here,we demonstrated its band structure modulation under strains by combining the non-equilibrium molecular dynamics simulations and first-principles calculations.We found that the C8-BTBT lattice undergoes a transition from monoclinic to triclinic crystal system at the temperature below 160 K.Both shear and uniaxial strains were applied to the low-temperature triclinic phase of C8-BTBT,and polymorphism was identified in the shear process.The band width enhancement is up to 8%under 2%of compressive strain along the x direction,and 14%under 4%of tensile strain along the y direction.The band structure modulation of C8-BTBT can be well related to its herringbone packing motifs,where the edge to face and edge to edge pairs constitute two-dimensional charge transport pathways and their electronic overlaps determine the band widths along the two directions respectively.These findings pave the way for utilizing strains towards improved performance of organic semiconductors on flexible substrates,for example,by bending the substrates. 展开更多
关键词 charge transport shear strain polymorphism band structure modulation flexible electronics
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Recent Advances in Research of Lightning Meteorology 被引量:4
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作者 郄秀书 刘冬霞 孙竹玲 《Journal of Meteorological Research》 SCIE 2014年第5期983-1002,共20页
Lightning meteorology focuses on investigating the lightning activities in different types of convective weather systems and the relationship of lightning to the dynamic and microphysical processes in thunder- storms.... Lightning meteorology focuses on investigating the lightning activities in different types of convective weather systems and the relationship of lightning to the dynamic and microphysical processes in thunder- storms. With the development and application of advanced lightning detection and location technologies, lightning meteorology has been developed into an important interdiscipline between atmospheric electricity and meteorology. This paper mainly reviews the advances of lightning meteorology research in recent years in China from the following five aspects: 1) development of advanced lightning location technology, 2) char- acteristics of lightning activity in different convective systems, 3) relationship of lightning to the dynamic and microphysical processes in thunderstorms, 4) charge structure of thunderstorms, and 5) lightning data assimilation techniques and application to severe weather forecasting. In addition, some important aspects on future research of the lightning meteorology are proposed. 展开更多
关键词 lightning activity lightning detection charge structure lightning assimilation convectiveweather system
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Simulation of the Electrification of a Tropical Cyclone Using the WRF-ARW Model: An Idealized Case 被引量:4
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作者 徐良韬 张义军 +1 位作者 王飞 郑栋 《Journal of Meteorological Research》 SCIE 2014年第3期453-468,共16页
Evolution of the electrifi cation of an idealized tropical cyclone (TC) is simulated by using the Advanced Weather Research and Forecasting (WRF-ARW) model. The model was modifi ed by addition of explicit electrif... Evolution of the electrifi cation of an idealized tropical cyclone (TC) is simulated by using the Advanced Weather Research and Forecasting (WRF-ARW) model. The model was modifi ed by addition of explicit electrifi cation and a new bulk discharge scheme. The characteristics of TC lightning is further examined by analyses of the electrifi cation and the charge structure of the TC. The fi ndings thus obtained are able to unify most of the previous inconsisitent observational and simulation studies. The results indicate that the TC eyewall generally exhibits an inverted dipole charge structure with negative charge above the positive. In the intensifi cation stage, however, the extremely tall towers of the eyewall may exhibit a normal tripole structure with a main negative region between two regions of positive charge. The outer spiral rainband cells display a simple normal dipole structure during all the stages. It is further found that the diff erences in the charge structure are associated with diff erent updrafts and particle distributions. Weak updrafts, together with a coexistence region of diff erent particles at lower levels in the eyewall, result in charging processes that occur mainly in the positive graupel charging zone (PGCZ). In the intensifi cation stage, the occurrence of charging processes in both positive and negative graupel charging zones is associated with strong updraft in the extremely tall towers. In addition, the coexistence region of graupel and ice crystals is mainly situated at upper levels in the outer rainband, so the charging processes mainly occur in the negative graupel charging zone (NGCZ). 展开更多
关键词 tropical cyclone charge structure ELECTRIFICATION WRF
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Occurrence conditions of positive cloud-to-ground flashes in severe thunderstorms 被引量:6
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作者 GUO Feng Xia LU Gan Yi +4 位作者 WU Xin WANG Hao Liang LIU Zu Pei BAO Min LI Ya Wen 《Science China Earth Sciences》 SCIE EI CAS CSCD 2016年第7期1401-1413,共13页
The purpose of this study was to understand the reasons why frequent positive cloud-to-ground(+CG) flashes occur in severe thunderstorms. A three-dimensional dynamics-electrification coupled model was used to simulate... The purpose of this study was to understand the reasons why frequent positive cloud-to-ground(+CG) flashes occur in severe thunderstorms. A three-dimensional dynamics-electrification coupled model was used to simulate a severe thunderstorm to permit analysis of the conditions that might easily cause +CG flashes. The results showed that strong updrafts play an important role in the occurrence of intracloud flashes. However, frequent +CG flashes require not only strong updrafts but also strong downdrafts in the lower cloud region, conditions that correspond to the later phase of the mature stage and the period of the heaviest solid precipitation of a thunderstorm. During this stage, strong updrafts elevated each charge area in the updraft region to a higher level, which resulted in an inverted tripole charge structure. A wide mid-level region of strong positive charge caused largely by positively charged graupel, presented in the middle of the updraft region because of a non-inductive ice-ice collisional charging mechanism. The charge structure in the downdraft region was consistently more complex and revealed several vertically stacked charge regions, alternating in polarity. Much of the graupel/hail outside the updrafts was lowered to cloud-base by strong downdrafts. In this area, the graupel/hail was charged negatively because of the transportation of negatively charged graupel/hail from higher regions of negative charge in the updrafts, and via the inductive charging mechanism of collisions between graupel/hail and cloud droplets at the bottom of the cloud. Consequently, a large region of negative charge formed near the ground. This meant that +CG flashes were initiated more easily in the lower inverted dipole, i.e., the middle region of positive charge and lower region of negative charge. Frequent +CG flashes began almost synchronously with dramatic increases in the storm updrafts, hail volume, and total flash rate. Therefore, the occurrence of +CG flashes appears a good indicator of storm intensification and it could have some use as a predictor of severe weather in the form of hail. 展开更多
关键词 Severe thunderstorm +CG flash Updraft Downdraft Graupel Hail charge structure
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Intrinsic Surface Reaction Constant in 1-pK Model of Mg-Fe Hydrotalcite-like Compounds
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作者 侯万国 韩书华 +1 位作者 李东祥 张高勇 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2004年第3期268-270,共3页
The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (st) for amphoteric solid with structural charges was established in order to... The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (st) for amphoteric solid with structural charges was established in order to investigate the effect of st on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC+log[(1+2aPZNC)/(1-2aPZNC)], where aPZNC≡st/eNANs, in which e is the elementary charge, NA the Avogadro抯 constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl, OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H+ or OH- and the electrostatic interaction between charging surface and H+ or OH-. 展开更多
关键词 surface complexation electric double layer points of zero charge acid-base chemistry structurally charged material
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