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Unraveling the Fundamental Mechanism of Interface Conductive Network Influence on the Fast‑Charging Performance of SiO‑Based Anode for Lithium‑Ion Batteries 被引量:1
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作者 Ruirui Zhang Zhexi Xiao +6 位作者 Zhenkang Lin Xinghao Yan Ziying He Hairong Jiang Zhou Yang Xilai Jia Fei Wei 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期53-68,共16页
Progress in the fast charging of high-capacity silicon monoxide(SiO)-based anode is currently hindered by insufficient conductivity and notable volume expansion.The construction of an interface conductive network effe... Progress in the fast charging of high-capacity silicon monoxide(SiO)-based anode is currently hindered by insufficient conductivity and notable volume expansion.The construction of an interface conductive network effectively addresses the aforementioned problems;however,the impact of its quality on lithium-ion transfer and structure durability is yet to be explored.Herein,the influence of an interface conductive network on ionic transport and mechanical stability under fast charging is explored for the first time.2D modeling simulation and Cryo-transmission electron microscopy precisely reveal the mitigation of interface polarization owing to a higher fraction of conductive inorganic species formation in bilayer solid electrolyte interphase is mainly responsible for a linear decrease in ionic diffusion energy barrier.Furthermore,atomic force microscopy and Raman shift exhibit substantial stress dissipation generated by a complete conductive network,which is critical to the linear reduction of electrode residual stress.This study provides insights into the rational design of optimized interface SiO-based anodes with reinforced fast-charging performance. 展开更多
关键词 Fast charging SiO anode Interface conductive network Ionic transport Mechanical stability
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Collaborative Charging Scheduling in Wireless Charging Sensor Networks
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作者 Qiuyang Wang Zhen Xu Lei Yang 《Computers, Materials & Continua》 SCIE EI 2024年第4期1613-1630,共18页
Wireless sensor networks (WSNs) have the trouble of limited battery power, and wireless charging provides apromising solution to this problem, which is not easily affected by the external environment. In this paper, w... Wireless sensor networks (WSNs) have the trouble of limited battery power, and wireless charging provides apromising solution to this problem, which is not easily affected by the external environment. In this paper, we studythe recharging of sensors in wireless rechargeable sensor networks (WRSNs) by scheduling two mobile chargers(MCs) to collaboratively charge sensors. We first formulate a novel sensor charging scheduling problem with theobjective of maximizing the number of surviving sensors, and further propose a collaborative charging schedulingalgorithm(CCSA) for WRSNs. In the scheme, the sensors are divided into important sensors and ordinary sensors.TwoMCs can adaptively collaboratively charge the sensors based on the energy limit ofMCs and the energy demandof sensors. Finally, we conducted comparative simulations. The simulation results show that the proposed algorithmcan effectively reduce the death rate of the sensor. The proposed algorithm provides a solution to the uncertaintyof node charging tasks and the collaborative challenges posed by multiple MCs in practical scenarios. 展开更多
关键词 Wireless rechargeable sensor network mobile charger collaborative charging adaptive charging
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EV Charging Station Load Prediction in Coupled Urban Transportation and Distribution Networks
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作者 Benxin Li Xuanming Chang 《Energy Engineering》 EI 2024年第10期3001-3018,共18页
The increasingly large number of electric vehicles(EVs)has resulted in a growing concern for EV charging station load prediction for the purpose of comprehensively evaluating the influence of the charging load on dist... The increasingly large number of electric vehicles(EVs)has resulted in a growing concern for EV charging station load prediction for the purpose of comprehensively evaluating the influence of the charging load on distribution networks.To address this issue,an EV charging station load predictionmethod is proposed in coupled urban transportation and distribution networks.Firstly,a finer dynamic urban transportation network model is formulated considering both nodal and path resistance.Then,a finer EV power consumption model is proposed by considering the influence of traffic congestion and ambient temperature.Thirdly,the Monte Carlo method is applied to predict the distribution of EVcharging station load based on the proposed dynamic urban transportation network model and finer EV power consumption model.Moreover,a dynamic charging pricing scheme for EVs is devised based on the EV charging station load requirements and the maximum thresholds to ensure the security operation of distribution networks.Finally,the validity of the proposed dynamic urban transportation model was verified by accurately estimating five sets of test data on travel time by contrast with the BPR model.The five groups of travel time prediction results showed that the average absolute percentage errors could be improved from 32.87%to 37.21%compared to the BPR model.Additionally,the effectiveness of the proposed EV charging station load prediction method was demonstrated by four case studies in which the prediction of EV charging load was improved from27.2 to 31.49MWh by considering the influence of ambient temperature and speed on power energy consumption. 展开更多
关键词 Electric vehicle dynamic traffic information charging stations charging load forecasting dynamic electricity pricing
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Robust Charging Demand Prediction and Charging Network Planning for Heterogeneous Behavior of Electric Vehicles
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作者 张轶伦 徐思坤 +3 位作者 徐捷 曾学奇 李铮 谢驰 《Journal of Shanghai Jiaotong university(Science)》 EI 2023年第1期136-149,共14页
This study addresses a new charging station network planning problem for smart connected electric vehicles.We embed a charging station choice model into a charging network planning model that explicitly considers the ... This study addresses a new charging station network planning problem for smart connected electric vehicles.We embed a charging station choice model into a charging network planning model that explicitly considers the heterogeneity of the charging behavior in a data-driven manner.To cope with the deficiencies from a small size and sparse behavioral data,we propose a robust charging demand prediction method that can significantly reduce the impact of sample errors and missing data.On the basis of these two building blocks,we form and solve a new optimal charging station location and capacity problem by minimizing the construction and charging costs while considering the charging service level,construction budget,and limit to the number of chargers.We use a case study of planning charging stations in Shanghai to validate our contributions and provide managerial insight in this area. 展开更多
关键词 electric vehicle charging network planning charging behavior robust demand prediction
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Towards extreme fast charging of 4.6 V LiCoO_(2) via mitigating high-voltage kinetic hindrance 被引量:2
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作者 Yu Tang Jun Zhao +13 位作者 He Zhu Jincan Ren Wei Wang Yongjin Fang Zhiyong Huang Zijia Yin Yalan Huang Binghao Zhang Tingting Yang Tianyi Li Leighanne CGallington Si Lan Yang Ren Qi Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第3期13-20,I0001,共9页
High-voltage LiCoO_(2)(LCO) is an attractive cathode for ultra-high energy density lithium-ion batteries(LIBs) in the 3 C markets.However,the sluggish lithium-ion diffusion at high voltage significantly hampers its ra... High-voltage LiCoO_(2)(LCO) is an attractive cathode for ultra-high energy density lithium-ion batteries(LIBs) in the 3 C markets.However,the sluggish lithium-ion diffusion at high voltage significantly hampers its rate capability.Herein,combining experiments with density functional theory(DFT) calculations,we demonstrate that the kinetic limitations can be mitigated by a facial Mg^(2+)+Gd^(3+)co-doping method.The as-prepared LCO shows significantly enhanced Li-ion diffusion mobility at high voltage,making more homogenous Li-ion de/intercalation at a high-rate charge/discharge process.The homogeneity enables the structural stability of LCO at a high-rate current density,inhibiting stress accumulation and irreversible phase transition.When used in combination with a Li metal anode,the doped LCO shows an extreme fast charging(XFC) capability,with a superior high capacity of 193.1 mAh g^(-1)even at the current density of 20 C and high-rate capacity retention of 91.3% after 100 cycles at 5 C.This work provides a new insight to prepare XFC high-voltage LCO cathode materials. 展开更多
关键词 Li-ion battery High-voltage LiCoO_(2) Li-ion diffusion Structural evolution Fast charging
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Optimization of Charging/Battery-Swap Station Location of Electric Vehicles with an Improved Genetic Algorithm-Based Model 被引量:2
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作者 Bida Zhang Qiang Yan +1 位作者 Hairui Zhang Lin Zhang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第2期1177-1194,共18页
The joint location planning of charging/battery-swap facilities for electric vehicles is a complex problem.Considering the differences between these two modes of power replenishment,we constructed a joint location-pla... The joint location planning of charging/battery-swap facilities for electric vehicles is a complex problem.Considering the differences between these two modes of power replenishment,we constructed a joint location-planning model to minimize construction and operation costs,user costs,and user satisfaction-related penalty costs.We designed an improved genetic algorithm that changes the crossover rate using the fitness value,memorizes,and transfers excellent genes.In addition,the present model addresses the problem of“premature convergence”in conventional genetic algorithms.A simulated example revealed that our proposed model could provide a basis for optimized location planning of charging/battery-swapping facilities at different levels under different charging modes with an improved computing efficiency.The example also proved that meeting more demand for power supply of electric vehicles does not necessarily mean increasing the sites of charging/battery-swap stations.Instead,optimizing the level and location planning of charging/battery-swap stations can maximize the investment profit.The proposed model can provide a reference for the government and enterprises to better plan the location of charging/battery-swap facilities.Hence,it is of both theoretical and practical value. 展开更多
关键词 charging/battery-swapping facility genetic algorithm location planning excellent gene cluster
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Electric Vehicle Charging Capacity of Distribution Network Considering Conventional Load Composition 被引量:1
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作者 Pengwei Yang Yuqi Cao +4 位作者 Jie Tan Junfa Chen Chao Zhang Yan Wang Haifeng Liang 《Energy Engineering》 EI 2023年第3期743-762,共20页
At present,the large-scale access to electric vehicles(EVs)is exerting considerable pressure on the distribution network.Hence,it is particularly important to analyze the capacity of the distribution network to accomm... At present,the large-scale access to electric vehicles(EVs)is exerting considerable pressure on the distribution network.Hence,it is particularly important to analyze the capacity of the distribution network to accommodate EVs.To this end,we propose a method for analyzing the EV capacity of the distribution network by considering the composition of the conventional load.First,the analysis and pretreatment methods for the distribution network architecture and conventional load are proposed.Second,the charging behavior of an EVis simulated by combining the Monte Carlo method and the trip chain theory.After obtaining the temporal and spatial distribution of the EV charging load,themethod of distribution according to the proportion of the same type of conventional load among the nodes is adopted to integrate the EV charging load with the conventional load of the distribution network.By adjusting the EV ownership,the EV capacity in the distribution network is analyzed and solved on the basis of the following indices:node voltage,branch current,and transformer capacity.Finally,by considering the 10-kV distribution network in some areas of an actual city as an example,we show that the proposed analysis method can obtain a more reasonable number of EVs to be accommodated in the distribution network. 展开更多
关键词 Capacity charging load distribution charging load forecasting conventional load composition electric vehicle trip behavior
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Jet formation and penetration performance of a double-layer charge liner with chemically-deposited tungsten as the inner liner 被引量:2
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作者 Bihui Hong Wenbin Li +2 位作者 Yiming Li Zhiwei Guo Binyou Yan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期374-385,共12页
This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double... This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner. 展开更多
关键词 Shaped charge Chemical vapor deposition TUNGSTEN Double-layer charge liner X-ray PEnetRATION
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ZnO Additive Boosts Charging Speed and Cycling Stability of Electrolytic Zn–Mn Batteries 被引量:2
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作者 Jin Wu Yang Tang +6 位作者 Haohang Xu Guandie Ma Jinhong Jiang Changpeng Xian Maowen Xu Shu‑Juan Bao Hao Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期293-304,共12页
Electrolytic aqueous zinc-manganese(Zn–Mn) batteries have the advantage of high discharge voltage and high capacity due to two-electron reactions. However, the pitfall of electrolytic Zn–Mn batteries is the sluggish... Electrolytic aqueous zinc-manganese(Zn–Mn) batteries have the advantage of high discharge voltage and high capacity due to two-electron reactions. However, the pitfall of electrolytic Zn–Mn batteries is the sluggish deposition reaction kinetics of manganese oxide during the charge process and short cycle life. We show that, incorporating ZnO electrolyte additive can form a neutral and highly viscous gel-like electrolyte and render a new form of electrolytic Zn–Mn batteries with significantly improved charging capabilities. Specifically, the ZnO gel-like electrolyte activates the zinc sulfate hydroxide hydrate assisted Mn^(2+) deposition reaction and induces phase and structure change of the deposited manganese oxide(Zn_(2)Mn_(3)O_8·H_(2)O nanorods array), resulting in a significant enhancement of the charge capability and discharge efficiency. The charge capacity increases to 2.5 mAh cm^(-2) after 1 h constant-voltage charging at 2.0 V vs. Zn/Zn^(2+), and the capacity can retain for up to 2000 cycles with negligible attenuation. This research lays the foundation for the advancement of electrolytic Zn–Mn batteries with enhanced charging capability. 展开更多
关键词 Electrolytic aqueous zinc-manganese batteries Electrolyte pH value ZnO electrolyte additive Fast constant-voltage charging ability
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All‑Covalent Organic Framework Nanofilms Assembled Lithium‑Ion Capacitor to Solve the Imbalanced Charge Storage Kinetics 被引量:2
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作者 Xiaoyang Xu Jia Zhang +6 位作者 Zihao Zhang Guandan Lu Wei Cao Ning Wang Yunmeng Xia Qingliang Feng Shanlin Qiao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期246-260,共15页
Free-standing covalent organic framework(COFs)nanofilms exhibit a remarkable ability to rapidly intercalate/de-intercalate Li^(+) in lithium-ion batteries,while simultaneously exposing affluent active sites in superca... Free-standing covalent organic framework(COFs)nanofilms exhibit a remarkable ability to rapidly intercalate/de-intercalate Li^(+) in lithium-ion batteries,while simultaneously exposing affluent active sites in supercapacitors.The development of these nanofilms offers a promising solution to address the persistent challenge of imbalanced charge storage kinetics between battery-type anode and capacitor-type cathode in lithium-ion capacitors(LICs).Herein,for the first time,custom-made COFBTMB-TP and COFTAPB-BPY nanofilms are synthesized as the anode and cathode,respectively,for an all-COF nanofilm-structured LIC.The COFBTMB-TP nanofilm with strong electronegative–CF3 groups enables tuning the partial electron cloud density for Li^(+) migration to ensure the rapid anode kinetic process.The thickness-regulated cathodic COFTAPB-BPY nanofilm can fit the anodic COF nanofilm in the capacity.Due to the aligned 1D channel,2D aromatic skeleton and accessible active sites of COF nanofilms,the whole COFTAPB-BPY//COFBTMB-TP LIC demonstrates a high energy density of 318 mWh cm^(−3) at a high-power density of 6 W cm^(−3),excellent rate capability,good cycle stability with the capacity retention rate of 77%after 5000-cycle.The COFTAPB-BPY//COFBTMB-TP LIC represents a new benchmark for currently reported film-type LICs and even film-type supercapacitors.After being comprehensively explored via ex situ XPS,7Li solid-state NMR analyses,and DFT calculation,it is found that the COFBTMB-TP nanofilm facilitates the reversible conversion of semi-ionic to ionic C–F bonds during lithium storage.COFBTMB-TP exhibits a strong interaction with Li^(+) due to the C–F,C=O,and C–N bonds,facilitating Li^(+) desolation and absorption from the electrolyte.This work addresses the challenge of imbalanced charge storage kinetics and capacity between the anode and cathode and also pave the way for future miniaturized and wearable LIC devices. 展开更多
关键词 Covalent organic frameworks Lithium-ion capacitor Charge storage kinetic
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A comparative study of data-driven battery capacity estimation based on partial charging curves 被引量:1
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作者 Chuanping Lin Jun Xu +5 位作者 Delong Jiang Jiayang Hou Ying Liang Xianggong Zhang Enhu Li Xuesong Mei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期409-420,I0010,共13页
With its generality and practicality, the combination of partial charging curves and machine learning(ML) for battery capacity estimation has attracted widespread attention. However, a clear classification,fair compar... With its generality and practicality, the combination of partial charging curves and machine learning(ML) for battery capacity estimation has attracted widespread attention. However, a clear classification,fair comparison, and performance rationalization of these methods are lacking, due to the scattered existing studies. To address these issues, we develop 20 capacity estimation methods from three perspectives:charging sequence construction, input forms, and ML models. 22,582 charging curves are generated from 44 cells with different battery chemistry and operating conditions to validate the performance. Through comprehensive and unbiased comparison, the long short-term memory(LSTM) based neural network exhibits the best accuracy and robustness. Across all 6503 tested samples, the mean absolute percentage error(MAPE) for capacity estimation using LSTM is 0.61%, with a maximum error of only 3.94%. Even with the addition of 3 m V voltage noise or the extension of sampling intervals to 60 s, the average MAPE remains below 2%. Furthermore, the charging sequences are provided with physical explanations related to battery degradation to enhance confidence in their application. Recommendations for using other competitive methods are also presented. This work provides valuable insights and guidance for estimating battery capacity based on partial charging curves. 展开更多
关键词 Lithium-ion battery Partial charging curves Capacity estimation DATA-DRIVEN Sampling frequency
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On the apparent line-of-sight alignment of the peak X-ray intensity of the magnetosheath and the tangent to the magnetopause,as viewed by SMILE-SXI 被引量:2
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作者 Andrew Read 《Earth and Planetary Physics》 EI CSCD 2024年第1期155-172,共18页
The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible f... The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible from the position of SMILE are created for a range of solar wind densities by using 3 years of the SMILE mission orbit,together with models of the expected X-ray emissivity from the Earth’s magnetosheath.Results from global magnetohydrodynamic simulations and a simple model for exospheric neutral densities are used to compare the locations of the lines of sight along which integrated soft X-ray intensities peak with the lines of sight lying tangent to surfaces(defined here to be the magnetopause)along which local soft X-ray intensities peak or exhibit their strongest gradients,or both,for strongly southward interplanetary magnetic field conditions when no depletion or low-latitude boundary layers are expected.Where,in the parameter space of the various times and seasons,orbital phases,solar wind conditions,and magnetopause models,the alignment of the X-ray emission peak with the magnetopause tangent is good,or is not,is presented.The main results are as follows.The spacecraft needs to be positioned well outside the magnetopause;low-altitude times near perigee are not good.In addition,there are seasonal aspects:dayside-apogee orbits are generally very good because the spacecraft travels out sunward at high altitude,but nightside-apogee orbits,behind the Earth,are bad because the spacecraft only rarely leaves the magnetopause.Dusk-apogee and dawnapogee orbits are intermediate.Dayside-apogee orbits worsen slightly over the first three mission years,whereas nightside-apogee orbits improve slightly.Additionally,many more times of good agreement with the peak-to-tangent hypothesis occur when the solar wind is in a high-density state,as opposed to a low-density state.In a high-density state,the magnetopause is compressed,and the spacecraft is more often a good distance outside the magnetopause. 展开更多
关键词 X-rays MAGnetOSPHERE MAGnetOSHEATH MAGnetOPAUSE Solar wind Magnetosphere Ionosphere Link Explorer(SMILE) Earth solar wind charge exchange
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Flexible bidirectional pulse charging regulation achieving long-life lithium-ion batteries 被引量:1
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作者 Xiaodong Xu Shengjin Tang +9 位作者 Xuebing Han Languang Lu Yudi Qin Jiuyu Du Yu Wu Yalun Li Chuanqiang Yu Xiaoyan Sun Xuning Feng Minggao Ouyang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期59-71,共13页
Typical application scenarios,such as vehicle to grid(V2G)and frequency regulation,have imposed significant long-life demands on lithium-ion batteries.Herein,we propose an advanced battery life-extension method employ... Typical application scenarios,such as vehicle to grid(V2G)and frequency regulation,have imposed significant long-life demands on lithium-ion batteries.Herein,we propose an advanced battery life-extension method employing bidirectional pulse charging(BPC)strategy.Unlike traditional constant current charging methods,BPC strategy not only achieves comparable charging speeds but also facilitates V2G frequency regulation simultaneously.It significantly enhances battery cycle ampere-hour throughput and demonstrates remarkable life extension capabilities.For this interesting conclusion,adopting model identification and postmortem characterization to reveal the life regulation mechanism of BPC:it mitigates battery capacity loss attributed to loss of lithium-ion inventory(LLI)in graphite anodes by intermittently regulating the overall battery voltage and anode potential using a negative charging current.Then,from the perspective of internal side reaction,the life extension mechanism is further revealed as inhibition of solid electrolyte interphase(SEI)and lithium dendrite growth by regulating voltage with a bidirectional pulse current,and a semi-empirical life degradation model combining SEI and lithium dendrite growth is developed for BPC scenarios health management,the model parameters are identified by genetic algorithm with the life simulation exhibiting an accuracy exceeding 99%.This finding indicates that under typical rate conditions,adaptable BPC strategies can extend the service life of LFP battery by approximately 123%.Consequently,the developed advanced BPC strategy offers innovative perspectives and insights for the development of long-life battery applications in the future. 展开更多
关键词 Lithium-ion battery Long-life regulation Bidirectional pulse charging Mechanism identification
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Ultraconformable Integrated Wireless Charging Micro-Supercapacitor Skin 被引量:1
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作者 Chang Gao Qing You +5 位作者 Jiancheng Huang Jingye Sun Xuan Yao Mingqiang Zhu Yang Zhao Tao Deng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期46-58,共13页
Conformable and wire-less charging energy storage devices play important roles in enabling the fast development of wearable,non-contact soft electronics.However,current wire-less charging power sources are still restr... Conformable and wire-less charging energy storage devices play important roles in enabling the fast development of wearable,non-contact soft electronics.However,current wire-less charging power sources are still restricted by limited flexural angles and fragile connection of components,resulting in the failure expression of performance and constraining their fur-ther applications in health monitoring wearables and moveable artificial limbs.Herein,we present an ultracompatible skin-like integrated wireless charging micro-supercapacitor,which building blocks(including electrolyte,electrode and substrate)are all evaporated by liquid precursor.Owing to the infiltration and permeation of the liquid,each part of the integrated device attached firmly with each other,forming a compact and all-in-one configuration.In addition,benefitting from the controllable volume of electrode solution precursor,the electrode thickness is easily regulated varying from 11.7 to 112.5μm.This prepared thin IWC-MSC skin can fit well with curving human body,and could be wireless charged to store electricity into high capacitive micro-supercapacitors(11.39 F cm-3)of the integrated device.We believe this work will shed light on the construction of skin-attachable electronics and irregular sensing microrobots. 展开更多
关键词 Micro-supercapacitor Electronic skin Supercapacitor skin Wireless charging energy storage device
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Electrochemical Hydrogen Charging on Corrosion Behavior of Ti-6Al-4V Alloy in Artificial Seawater 被引量:1
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作者 Yanxin Qiao Yue Qin +5 位作者 Huiling Zhou Lanlan Yang Xiaojing Wang Zhengbin Wang Zhenguang Liu Jiasheng Zou 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第1期296-308,共13页
This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy.The ... This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy.The findings revealed the formation ofγ-TiH andδ-TiH_(2) hydrides in the alloy after hydrogen charging.Prolonging hydrogen charging resulted in more significant degradation of the alloy microstructure,leading to deteriorated protectiveness of the surface film.This trend was further confirmed by the electrochemical measurements,which showed that the corrosion resistance of the alloy progressively worsened as the hydrogen charging time was increased.Consequently,this work provides valuable insights into the mechanisms underlying the corrosion of Ti-6Al-4V alloy under hydrogen charging conditions. 展开更多
关键词 Ti-6Al-4V alloy Hydrogen charging Electrochemical corrosion Passive film
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Two methods for separating the magnetospheric solar wind charge exchange soft X-ray emission from the diffuse X-ray background 被引量:2
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作者 YingJie Zhang TianRan Sun +5 位作者 JenniferACarter WenHao Liu Steve Sembay ShuiNai Zhang Li Ji Chi Wang 《Earth and Planetary Physics》 EI CSCD 2024年第1期119-132,共14页
Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is propo... Solar wind charge exchange(SWCX)is the process of solar wind high-valence ions exchanging charges with neutral components and generating soft X-rays.Recently,detecting the SWCX emission from the magnetosphere is proposed as a new technique to study the magnetosphere using panoramic soft X-ray imaging.To better prepare for the data analysis of upcoming magnetospheric soft X-ray imaging missions,this paper compares the magnetospheric SWCX emission obtained by two methods in an XMM-Newton observation,during which the solar wind changed dramatically.The two methods differ in the data used to fit the diffuse X-ray background(DXB)parameters in spectral analysis.The method adding data from the ROSAT All-Sky Survey(RASS)is called the RASS method.The method using the quiet observation data is called the Quiet method,where quiet observations usually refer to observations made by the same satellite with the same target but under weaker solar wind conditions.Results show that the spectral compositions of magnetospheric SWCX emission obtained by the two methods are very similar,and the changes in intensity over time are highly consistent,although the intensity obtained by the RASS method is about 2.68±0.56 keV cm^(-2)s^(-1)sr^(-1)higher than that obtained by the Quiet method.Since the DXB intensity obtained by the RASS method is about 2.84±0.74 keV cm^(-2)s^(-1)sr^(-1)lower than that obtained by the Quiet method,and the linear correlation coefficient between the difference of SWCX and DXB obtained by the two methods in diffe rent energy band is close to-1,the diffe rences in magnetospheric SWCX can be fully attributed to the diffe rences in the fitted DXB.The difference between the two methods is most significant when the energy is less than 0.7 keV,which is also the main energy band of SWCX emission.In addition,the difference between the two methods is not related to the SWCX intensity and,to some extent,to solar wind conditions,because SWCX intensity typically va ries with the solar wind.In summary,both methods are robust and reliable,and should be considered based on the best available options. 展开更多
关键词 solar wind charge exchange(SWCX) ROSAT All-Sky Survey(RASS) soft X-ray X-ray imaging MAGnetOSPHERE
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Multilevel carbon architecture of subnanoscopic silicon for fast‐charging high‐energy‐density lithium‐ion batteries 被引量:1
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作者 Meisheng Han Yongbiao Mu +2 位作者 Lei Wei Lin Zeng Tianshou Zhao 《Carbon Energy》 SCIE EI CAS CSCD 2024年第4期256-268,共13页
Silicon(Si)is widely used as a lithium‐ion‐battery anode owing to its high capacity and abundant crustal reserves.However,large volume change upon cycling and poor conductivity of Si cause rapid capacity decay and p... Silicon(Si)is widely used as a lithium‐ion‐battery anode owing to its high capacity and abundant crustal reserves.However,large volume change upon cycling and poor conductivity of Si cause rapid capacity decay and poor fast‐charging capability limiting its commercial applications.Here,we propose a multilevel carbon architecture with vertical graphene sheets(VGSs)grown on surfaces of subnanoscopically and homogeneously dispersed Si–C composite nanospheres,which are subsequently embedded into a carbon matrix(C/VGSs@Si–C).Subnanoscopic C in the Si–C nanospheres,VGSs,and carbon matrix form a three‐dimensional conductive and robust network,which significantly improves the conductivity and suppresses the volume expansion of Si,thereby boosting charge transport and improving electrode stability.The VGSs with vast exposed edges considerably increase the contact area with the carbon matrix and supply directional transport channels through the entire material,which boosts charge transport.The carbon matrix encapsulates VGSs@Si–C to decrease the specific surface area and increase tap density,thus yielding high first Coulombic efficiency and electrode compaction density.Consequently,C/VGSs@Si–C delivers excellent Li‐ion storage performances under industrial electrode conditions.In particular,the full cells show high energy densities of 603.5 Wh kg^(−1)and 1685.5 Wh L^(−1)at 0.1 C and maintain 80.7%of the energy density at 3 C. 展开更多
关键词 fast charging high energy densities lithium‐ion batteries multilevel carbon architecture subnanoscopic silicon anode
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The magnetosheath at high spectral resolution 被引量:1
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作者 K.D.Küntz D.Koutroumpa +4 位作者 W.R.Dunn A.Foster F.S.Porter D.G.Sibeck B.Walsh 《Earth and Planetary Physics》 EI CSCD 2024年第1期234-246,共13页
While we eagerly anticipate SMILE’s(Solar wind Magnetosphere Ionosphere Link Explorer)unprecedented X-ray observations of the Earth’s magnetosheath and the initiation of a new era of magnetospheric research,it seems... While we eagerly anticipate SMILE’s(Solar wind Magnetosphere Ionosphere Link Explorer)unprecedented X-ray observations of the Earth’s magnetosheath and the initiation of a new era of magnetospheric research,it seems appropriate to look ahead to the abilities of the next generation of astrophysics missions.Of these,the Line Emission Mapper(LEM),a large aperture micro-calorimeter based mission,is currently planned to be able to observe the magnetosheath at high spectral resolution(~2 eV).With a field of view of~30′,LEM will allow higher spatial resolution and higher cadence measurement of the motion of a very small portion of the magnetopause over relatively short periods of time(multiple hours),complementing SMILE’s global mapping.LEM’s strength is its spectral resolution.It will be able to measure the abundance of a broad range of elements and ionization states,many of which are inaccessible to current in situ instruments,and will be able to separate the emission from the magnetosheath from the emission from the cosmic X-ray background using the difference in their relative velocities. 展开更多
关键词 MAGnetOSHEATH charge exchange solar wind abundances
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Simulation of the SMILE Soft X-ray Imager response to a southward interplanetary magnetic field turning 被引量:1
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作者 Andrey Samsonov Graziella Branduardi-Raymont +3 位作者 Steven Sembay Andrew Read David Sibeck Lutz Rastaetter 《Earth and Planetary Physics》 EI CSCD 2024年第1期39-46,共8页
The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)Soft X-ray Imager(SXI)will shine a spotlight on magnetopause dynamics during magnetic reconnection.We simulate an event with a southward interplanetary magne... The Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)Soft X-ray Imager(SXI)will shine a spotlight on magnetopause dynamics during magnetic reconnection.We simulate an event with a southward interplanetary magnetic field turning and produce SXI count maps with a 5-minute integration time.By making assumptions about the magnetopause shape,we find the magnetopause standoff distance from the count maps and compare it with the one obtained directly from the magnetohydrodynamic(MHD)simulation.The root mean square deviations between the reconstructed and MHD standoff distances do not exceed 0.2 RE(Earth radius)and the maximal difference equals 0.24 RE during the 25-minute interval around the southward turning. 展开更多
关键词 MAGnetOPAUSE magnetic reconnection solar wind charge exchange southward interplanetary magnetic field numerical modeling Solar wind Magnetosphere Ionosphere Link Explorer(SMILE) Soft X-ray Imager
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The principle and amelioration of lithium plating in fast-charging lithium-ion batteries
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作者 Yi Yang Xia-Lin Zhong +3 位作者 Lei Xu Zhuo-Lin Yang Chong Yan Jia-Qi Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期453-459,I0009,共8页
Fast charging is restricted primarily by the risk of lithium(Li)plating,a side reaction that can lead to the rapid capacity decay and dendrite-induced thermal runaway of lithium-ion batteries(LIBs).Investigation on th... Fast charging is restricted primarily by the risk of lithium(Li)plating,a side reaction that can lead to the rapid capacity decay and dendrite-induced thermal runaway of lithium-ion batteries(LIBs).Investigation on the intrinsic mechanism and the position of Li plating is crucial to improving the fast rechargeability and safety of LIBs.Herein,we investigate the Li plating behavior in porous electrodes under the restricted transport of Li^(+).Based on the theoretical model,it can be concluded that the Li plating on the anodeseparator interface(ASI)is thermodynamically feasible and kinetically advantageous.Meanwhile,the prior deposition of metal Li on the ASI rather than the anode-current collector interface(ACI)is verified experimentally.In order to facilitate the transfer of Li^(+)among the electrode and improve the utilization of active materials without Li plating,a bilayer asymmetric anode composed of graphite and hard carbon(GH)is proposed.Experimental and simulation results suggest that the GH hybrid electrode homogenizes the lithiated-rate throughout the electrode and outperforms the pure graphite electrode in terms of the rate performance and inhibition of Li plating.This work provides new insights into the behavior of Li plating and the rational design of electrode structure. 展开更多
关键词 GRAPHITE Hard carbon Fast charging Lithium plating Lithium-ion batteries
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