In recent decades,the potential health hazards of microwave exposure have been attracting increasing attention.Our previous studies have demonstrated that microwave exposure impaired learning and memory in experimenta...In recent decades,the potential health hazards of microwave exposure have been attracting increasing attention.Our previous studies have demonstrated that microwave exposure impaired learning and memory in experimental animal models[1,2].展开更多
The activated carbon(AC)was prepared from Solidago Canadensis(SC),an alien invasive plant.The plant was firstly carbonized under nitrogen at 400 ℃ for 90 min in an electrical furnace,and then the carbonized product w...The activated carbon(AC)was prepared from Solidago Canadensis(SC),an alien invasive plant.The plant was firstly carbonized under nitrogen at 400 ℃ for 90 min in an electrical furnace,and then the carbonized product was activated with KOH through microwave radiation.Effects of KOH/C ratio,microwave power,microwave radiation time on the adsorption capacities and yield of AC were evaluated.It indicated that the optimum conditions were KOH/C ratio 2 g/g,microwave power 700 W,and microwave radiation time 6 min.The carbonation process of SC was analyzed by thermogravimetry(TG).The pore structural parameters and surface functional groups of the AC were characterized by nitrogen adsorption-desorption and Fourier Transformed Infrared Spectroscopy(FTIR),respectively.The activation yield,the surface area,the average pore size,and the average micropore size of AC prepared from optimum conditions were 53.75%,1 888 m2/g,0.567 nm,and 0.488 nm,respectively.The adsorption amounts of AC were 302.4 mg/g for methylene blue and 1 470.27 mg/g for iodine.展开更多
Using a walnut shellas a carbon source and ZnCl_2 as an activating agent,we resolved the temperature gradient problems of activated carbon in the microwave desorption process.An appropriate amount of silicon carbide w...Using a walnut shellas a carbon source and ZnCl_2 as an activating agent,we resolved the temperature gradient problems of activated carbon in the microwave desorption process.An appropriate amount of silicon carbide was added to prepare the composite activated carbon with high thermalconductivity while developing VOC adsorption-microwave regeneration technology.The experimentalresults show that the coefficient of thermalconductivity of SiC-AC is three times as much as those of AC and SY-6.When microwave power was 480 W in its microwave desorption,the temperature of the bed thermaldesorption was 10 ℃ to 30 ℃ below that of normalactivated carbon prepared in our laboratory.The toluene desorption activation energy was 16.05 k J·mol^(-1),which was 15% less than the desorption activation energy of commercialactivated carbon.This study testified that the process could maintain its high adsorption and regeneration desorption performances.展开更多
Introduction The surface structure, distribution and strength of the active centers of a catalyst would directly affect its catalytic activity and selectivity. In principle all the techniques and methods which can mod...Introduction The surface structure, distribution and strength of the active centers of a catalyst would directly affect its catalytic activity and selectivity. In principle all the techniques and methods which can modify the surface and body structure of a catalyst, or influence its physicochemical properties can be used to change the activity and selectivity of a practical catalyst.展开更多
The buoyancy driven flow of a second-grade nanofluid in the presence of a binary chemical reaction is analyzed in the context of a model based on the balance equations for mass,species concentration,momentum and energ...The buoyancy driven flow of a second-grade nanofluid in the presence of a binary chemical reaction is analyzed in the context of a model based on the balance equations for mass,species concentration,momentum and energy.The elastic properties of the considered fluid are taken into account.The two-dimensional slip flow of such non-Newtonian fluid over a porous flat material which is stretched vertically upwards is considered.The role played by the activation energy is accounted for through an exponent form modified Arrhenius function added to the Buongiorno model for the nanofluid concentration.The effects of thermal radiation are also examined.A similarity transformations is used to turn the problem based on partial differential equations into a system of ordinary differential equations.The resulting system is solved using a fourth order RK and shooting methods.The velocity profile,temperature profile,concentration profile,local skin friction,local Nusselt number and local Sherwood number are reported for several circumstances.The influence of the chemical reaction on the properties of the concentration and momentum boundary layers is critically discussed.展开更多
A natural force has been proposed, which is required to prevent the fusion and disappearance of the discrete electrical charges that are present on electrostatically attached opposing electrical charges. This force ma...A natural force has been proposed, which is required to prevent the fusion and disappearance of the discrete electrical charges that are present on electrostatically attached opposing electrical charges. This force may also explain the repulsion between objects with either matching positive or negative electrical charges. The energy of this force is referred to as KELEA (kinetic energy limiting electrostatic attraction). KELEA is especially attracted to dipolar compounds and to other materials with spatially separated opposite electrical charges. These compounds can be used to increase the level of KELEA in water. KELEA activated water can become an added source of KELEA for objects that are placed in close proximity to the water. It is generally held that the weight of an object is solely determined by its mass in relation to that of the earth. Yet, it was previously reported that the measured weight of certain KELEA attracting objects can undergo considerable variability over time. This observation is consistent with the concept that KELEA can contribute to the measured weight of certain objects. The present study strengthens this concept by demonstrating that the weight of cellulose containing materials, including paper, cotton fabrics, and wood, is increased if the materials are placed close to containers of KELEA activated water. It is further shown that electromagnetic radiation can significantly reduce the added weight of the KELEA exposed cellulose containing materials. Moreover, the previously added weight of the materials can be regained by replacing the materials back into the KELEA enhanced environment. It is proposed that the electrical charges that accompany electromagnetic radiation are able to competitively withdraw some of the KELEA from certain KELEA-enhanced objects. This effect can be reliably demonstrated using single sheets of writing paper, which are primarily composed of mechanically-bonded, branched cellulose fibers. There can be considerable fluctuations of the weight of the materials exposed to electromagnetic radiation after having been placed nearby to KELEA activated water. The weight instability is interpreted as being due to the electromagnetic radiation also triggering a dynamic process of rapid additions and removals of significant quantities of KELEA to and from objects. These observations are relevant to the further understanding of KELEA and to the potential health and climate consequences of manmade electromagnetic radiation causing a reduction in the environmental levels of KELEA.展开更多
为探究封闭式除草剂苗后喷施对小麦生长和杂草的影响,以周麦22为试验材料,设置砜吡草唑用量125(T1)、250(T2)、500(T3)、1000(T4)、2000(T5)g a.i./hm^(2)和氟噻草胺用量184.5(T6)、369(T7)、738(T8)、1476(T9)g a.i./hm^(2)9个喷药处理...为探究封闭式除草剂苗后喷施对小麦生长和杂草的影响,以周麦22为试验材料,设置砜吡草唑用量125(T1)、250(T2)、500(T3)、1000(T4)、2000(T5)g a.i./hm^(2)和氟噻草胺用量184.5(T6)、369(T7)、738(T8)、1476(T9)g a.i./hm^(2)9个喷药处理和1个空白(清水)对照,研究不同除草剂对小麦光合特性、叶绿素SPAD值、光合有效辐射(IPAR)、叶面积指数(LAI)、鲜质量的影响及对杂草的化除效果。结果表明:T1、T6处理下小麦叶片的净光合速率高于对照,9个处理蒸腾速率均低于对照,T6、T1处理数值较大,气孔导度T1处理最大;胞间CO_(2)浓度T9处理最大,T1处理最小。在除草剂施用21 d时,T1处理SPAD值与对照差异有统计学意义。T1、T2、T3、T6、T7处理下,小麦IPAR和LAI均高于对照,且以T1处理下值最大,较对照分别增加18.37%、37.77%,T2次之。砜吡草唑施药剂量在125、250 g a.i./hm^(2)时(T1和T2)对小麦株高和鲜质量没有显著性影响;当剂量>250 g a.i./hm^(2)时,则会出现抑制症状,氟噻草胺不同用量小麦株高和鲜质量均受抑制。可见,T1和T2处理对小麦生长发育影响较小。T4、T5和T93个处理对所试杂草鲜质量防效均高于95%,T1和T62个处理对野燕麦的防效不明显。考虑到对小麦生长安全和用药成本,在对节节麦和野燕麦鲜质量防效达到50%~95%且对其余供试杂草鲜质量防效均高于95%的6个处理(T2、T3、T4、T5、T8、T9)中,推荐T2处理用于麦田苗后喷施。展开更多
基金supported by National Science Foundation of China[No.81172620]。
文摘In recent decades,the potential health hazards of microwave exposure have been attracting increasing attention.Our previous studies have demonstrated that microwave exposure impaired learning and memory in experimental animal models[1,2].
基金Shanghai Leading Academic Discipline Project,China(No.B604)
文摘The activated carbon(AC)was prepared from Solidago Canadensis(SC),an alien invasive plant.The plant was firstly carbonized under nitrogen at 400 ℃ for 90 min in an electrical furnace,and then the carbonized product was activated with KOH through microwave radiation.Effects of KOH/C ratio,microwave power,microwave radiation time on the adsorption capacities and yield of AC were evaluated.It indicated that the optimum conditions were KOH/C ratio 2 g/g,microwave power 700 W,and microwave radiation time 6 min.The carbonation process of SC was analyzed by thermogravimetry(TG).The pore structural parameters and surface functional groups of the AC were characterized by nitrogen adsorption-desorption and Fourier Transformed Infrared Spectroscopy(FTIR),respectively.The activation yield,the surface area,the average pore size,and the average micropore size of AC prepared from optimum conditions were 53.75%,1 888 m2/g,0.567 nm,and 0.488 nm,respectively.The adsorption amounts of AC were 302.4 mg/g for methylene blue and 1 470.27 mg/g for iodine.
基金Funded by the National High Technology Research and Development Program of China("863"Program)(No.2006AA06A310)
文摘Using a walnut shellas a carbon source and ZnCl_2 as an activating agent,we resolved the temperature gradient problems of activated carbon in the microwave desorption process.An appropriate amount of silicon carbide was added to prepare the composite activated carbon with high thermalconductivity while developing VOC adsorption-microwave regeneration technology.The experimentalresults show that the coefficient of thermalconductivity of SiC-AC is three times as much as those of AC and SY-6.When microwave power was 480 W in its microwave desorption,the temperature of the bed thermaldesorption was 10 ℃ to 30 ℃ below that of normalactivated carbon prepared in our laboratory.The toluene desorption activation energy was 16.05 k J·mol^(-1),which was 15% less than the desorption activation energy of commercialactivated carbon.This study testified that the process could maintain its high adsorption and regeneration desorption performances.
文摘Introduction The surface structure, distribution and strength of the active centers of a catalyst would directly affect its catalytic activity and selectivity. In principle all the techniques and methods which can modify the surface and body structure of a catalyst, or influence its physicochemical properties can be used to change the activity and selectivity of a practical catalyst.
基金United Arab Emirates University,Al Ain,UAE with Grant No.31S363-UPAR(4)2018.
文摘The buoyancy driven flow of a second-grade nanofluid in the presence of a binary chemical reaction is analyzed in the context of a model based on the balance equations for mass,species concentration,momentum and energy.The elastic properties of the considered fluid are taken into account.The two-dimensional slip flow of such non-Newtonian fluid over a porous flat material which is stretched vertically upwards is considered.The role played by the activation energy is accounted for through an exponent form modified Arrhenius function added to the Buongiorno model for the nanofluid concentration.The effects of thermal radiation are also examined.A similarity transformations is used to turn the problem based on partial differential equations into a system of ordinary differential equations.The resulting system is solved using a fourth order RK and shooting methods.The velocity profile,temperature profile,concentration profile,local skin friction,local Nusselt number and local Sherwood number are reported for several circumstances.The influence of the chemical reaction on the properties of the concentration and momentum boundary layers is critically discussed.
文摘A natural force has been proposed, which is required to prevent the fusion and disappearance of the discrete electrical charges that are present on electrostatically attached opposing electrical charges. This force may also explain the repulsion between objects with either matching positive or negative electrical charges. The energy of this force is referred to as KELEA (kinetic energy limiting electrostatic attraction). KELEA is especially attracted to dipolar compounds and to other materials with spatially separated opposite electrical charges. These compounds can be used to increase the level of KELEA in water. KELEA activated water can become an added source of KELEA for objects that are placed in close proximity to the water. It is generally held that the weight of an object is solely determined by its mass in relation to that of the earth. Yet, it was previously reported that the measured weight of certain KELEA attracting objects can undergo considerable variability over time. This observation is consistent with the concept that KELEA can contribute to the measured weight of certain objects. The present study strengthens this concept by demonstrating that the weight of cellulose containing materials, including paper, cotton fabrics, and wood, is increased if the materials are placed close to containers of KELEA activated water. It is further shown that electromagnetic radiation can significantly reduce the added weight of the KELEA exposed cellulose containing materials. Moreover, the previously added weight of the materials can be regained by replacing the materials back into the KELEA enhanced environment. It is proposed that the electrical charges that accompany electromagnetic radiation are able to competitively withdraw some of the KELEA from certain KELEA-enhanced objects. This effect can be reliably demonstrated using single sheets of writing paper, which are primarily composed of mechanically-bonded, branched cellulose fibers. There can be considerable fluctuations of the weight of the materials exposed to electromagnetic radiation after having been placed nearby to KELEA activated water. The weight instability is interpreted as being due to the electromagnetic radiation also triggering a dynamic process of rapid additions and removals of significant quantities of KELEA to and from objects. These observations are relevant to the further understanding of KELEA and to the potential health and climate consequences of manmade electromagnetic radiation causing a reduction in the environmental levels of KELEA.
文摘为探究封闭式除草剂苗后喷施对小麦生长和杂草的影响,以周麦22为试验材料,设置砜吡草唑用量125(T1)、250(T2)、500(T3)、1000(T4)、2000(T5)g a.i./hm^(2)和氟噻草胺用量184.5(T6)、369(T7)、738(T8)、1476(T9)g a.i./hm^(2)9个喷药处理和1个空白(清水)对照,研究不同除草剂对小麦光合特性、叶绿素SPAD值、光合有效辐射(IPAR)、叶面积指数(LAI)、鲜质量的影响及对杂草的化除效果。结果表明:T1、T6处理下小麦叶片的净光合速率高于对照,9个处理蒸腾速率均低于对照,T6、T1处理数值较大,气孔导度T1处理最大;胞间CO_(2)浓度T9处理最大,T1处理最小。在除草剂施用21 d时,T1处理SPAD值与对照差异有统计学意义。T1、T2、T3、T6、T7处理下,小麦IPAR和LAI均高于对照,且以T1处理下值最大,较对照分别增加18.37%、37.77%,T2次之。砜吡草唑施药剂量在125、250 g a.i./hm^(2)时(T1和T2)对小麦株高和鲜质量没有显著性影响;当剂量>250 g a.i./hm^(2)时,则会出现抑制症状,氟噻草胺不同用量小麦株高和鲜质量均受抑制。可见,T1和T2处理对小麦生长发育影响较小。T4、T5和T93个处理对所试杂草鲜质量防效均高于95%,T1和T62个处理对野燕麦的防效不明显。考虑到对小麦生长安全和用药成本,在对节节麦和野燕麦鲜质量防效达到50%~95%且对其余供试杂草鲜质量防效均高于95%的6个处理(T2、T3、T4、T5、T8、T9)中,推荐T2处理用于麦田苗后喷施。