Effect of Top Slag Basicity on Quality of Steel Treated by Exothermic Agent SiFe and SiCaBa during Chemical Heating

The effect of top slag basicity on quality of steel treated with SiFe and SiCaBa alloy as exothermic agent in chemical heating was studied.These experiments were carried out in MoSi_2 laboratory furnace with 0.2 kg molten steel for equilibrium test and 2 kg molten steel for simulation test respectively.These results showed that the adjusting basicity of top slag with CaO is effective to prevent rephosphorization and resulphurization,and it is possible to dephosphorize and desulphurize and remove the inclusions from molten steel when basicity R of the top slag is adjusted to 2.0 — 3.10,and SiCaBa alloy is better than SiFe alloy in this relation.

Effect of magnetic field decay on the chemical heating of cooling neutron stars

The effect of magnetic field decay on the chemical heating and thermal evolution of neutron stars is discussed in this paper. Our main goal is to study how the chemical heating mechanism and thermal evolution are changed by the field decay and how the magnetic field decay is modified by the thermal evolution. We compare stars cooling with chemical heating with one without chemical heating and find that the decay of the magnetic field is delayed significantly by the chemical heating. We find that the effect of chemical heating has been suppressed through the decaying magnetic field by the spin-down of the stars at a later stage. Compared with typical chemical heating, we find the decay of the magnetic field can even cause the surface temperature to turn down at an older age. When we discuss the cooling of neutron stars, we should consider the coupling effect of the magnetic field and the rotational evolution of neutron stars on the heating mechanisms.

Reaction Rate Characteristics of SrBr2 Hydration System for Chemical Heat Pump Cooling Mode

Here, we propose a chemical heat pump chiller with a SrBr2 hydration reaction system for utilization of waste heat. The SrBr2 hydration reaction could recover waste heat in low temperatures ranging from 373 K to 353 K, and the system showed good potential in terms of the high cooling thermal-storage density. Previous studies have given little information on the reaction characteristics of the SrBr2 hydration reaction. In this paper, we developed a measuring method for the hydration reaction equilibrium and reaction rate based on the volumetric method. We analyzed the hydration reaction rate with an unreacted-core shell model. In the experiments, the SrBr2 equilibrium temperature observed was equal to the theoretical equilibrium temperature obtained from thermodynamic databases. In addition, the hysteresis gap between the hydration and dehydration values was 2.0 K. Thus, the hysteresis effect was negligible for the chemical heat pump cooling operation. The reaction fraction of the SrBr2 hydration reached 0.7 within 20 s. By analyzing the hydration reaction rate with the unreacted-core shell model, the activation energy value was calculated to be56.6 kJ/mol. The calculation results showed good agreement with those of the experiment as the reaction fraction reached 0.7.

Study on the Pyrolytic Carbon Generated by the Electric Heating CVD Method

A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.

Chemical Heat Storage Using an SiC Honeycomb Packed with CaCl₂Powder

Chemical heat storage is a promising technology for improving thermal energy efficiency. In this study, CaCl2 and H2O were selected as a reaction system for utilization of low-grade exhaust heat that is cooler than 200°C. Heat discharging and charging were conducted through the CaCl2 hydration reaction. A silicon carbide honeycomb was adopted to improve heat transfer in the CaCl2 packed bed. The heat storage, condenser, and evaporator temperature were set at 150°C, 30°C and 90°C respectively. Repeated trials and experiments are time consuming for optimizing design of the equipment. Therefore, in this research, we constructed a simulation that can predict the performance of the device. A numerical simulation model was utilized in preparation for the design of the heat storage module. The consistency of both the simulation and the experimental results was confirmed by comparing them.

Experimental Evaluation of the Heat Output/Input and Coefficient of Performance Characteristics of a Chemical Heat Pump in the Periodic Operation of CaCl₂Hydration

We herein evaluate the use of a chemical heat pump (CHP) for upgrading waste heat. CaCl2 was used in the system of CHP. We evaluated the heat storage and heat releasing of CHP, and confirmed the practicality from the experimental results. The reactor module employed was an aluminum plate-tube heat exchanger with corrugated fins, and the CaCl2 powder was in the form of a packed bed. Heat storage operation and heat dissipation operation are performed at the same time and supplied to the heat demand destination. At this time, an environmental heat source can be used during the heat radiation operation, and the heat output can release more heat than the heat input during heat storage. The heat discharging and charging characteristics of the reactor module were evaluated experimentally. The coefficient of performance (COP) was calculated for the heat upgrading cycle, and the heat output in the system was determined. A COP of 1.42 and output of 650 W/L, based on the heat exchanger volume, were obtained using a 600 s change time for the heat pump.

Study of Interfacial Tension between Molten Steel and Na2O-Li2O-SiO2-B2O3 Slag

The effect of top slag basicity on quality of steel treated with SiFe and SiCaBa alloy as exothermic agent in chemical heating was studied. These experiments were carried out in MoSi 2 laboratory furnace with 0 2?kg molten steel for equilibrium test and 2?kg molten steel for simulation test respectively. These results showed that the adjusting basicity of top slag with CaO is effective to prevent rephosphorization and resulphurization, and it is possible to dephosphorize and desulphurize and remove the inclusions from molten steel when basicity R of the top slag is adjusted to 2 0-3 10, and SiCaBa alloy is better than SiFe alloy in this relation.

APPLICATION OF RARE EARTH IN SURFACE HEAT TREATMENT OF HOT-WORKING DIE STEELS

This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused layer. XRD and SEM energy spectrum prove that trace RE element actually penetrates into the surface layer of steels. The result shows that RE can reduce the gradient of change of hardness in diffused layer, improve the morphology and distribution of compounds , and reduce the degree of surface alligator crack for thermal fatigue. The behavior of thermal fatigue of hot-working die steels is raised by 70% or so after the application of RE. The effect of RE is analysed according to the theory.

Nonequilibrium modeling study on plasma flow features in a low-power nitrogen/hydrogen arcjet thruster

Gasdynamic flow features in an electrothermal arcjet thruster with a mixture of 1：2 nitrogen/hydrogen as the working gas have been studied by a two-temperature numerical simulation.Seven species and 17 kinetic processes are included in the chemical kinetic model used to represent dissociation, ionization, and the corresponding recombination reactions in this nitrogen/hydrogen mixture system. Based on the gas flow characteristics inside the arcjet nozzle,a new method is introduced to define the edge of the cold boundary layer, which is more convenient to analyze the evolution and development of plasma flow in an arcjet thruster. The results show that the arcjet thruster performance is determined largely by the exchange of energy and momentum between the low-density, high-temperature arc region and the high-density, coolflow region near the nozzle wall. A significant thermal nonequilibrium is found in the cold boundary layer in the expansion portion of the nozzle. The important chemical kinetic processes determining the distribution of hydrogen and nitrogen species in different flow regions are presented. It has been shown that the reaction rate of hydrogen species ionization impacted by electrons is much higher than that of nitrogen species ionization in the center of the constrictor of the arcjet thruster. This indicates that hydrogen species is very important in the conversion of applied electric energy into thermal energy in the constrictor region of the arcjet thruster.

Investigation on Steelmaking with Hot Metal Containing Low Silicon Content in Large Converter

There are some problems in steelmaking with hot metal containing low silicon content such as difficulty in slag formation, less slag for dephosphorization and slag adhesion on oxygen lance and hood. To overcome these problems, experiments wcrc conducted and some improvements were obtained, such as adding appropriate flux, increasing the lance position slightly during steelmaking and using effective multi-outlet nozzle. Moreover, to keep normal heating rate, the ore and scrap charge should be reduced due to less chemical heat input in steelmaking.

Synthesis of Sodium Beta Alumina Films by Heat Treatment of Sodium Aluminum Oxides

Sodium beta alumina（Na-β-alumina） films were synthesized by heat treatment of NaAl6O（9.5）and γ-NaA1O2 films at temperatures of 1 373-1 573 K.Single-phase γ-NaA1O2 and NaAl6O（9.5） films were prepared by laser chemical vapor deposition at the deposition temperatures of 976 and 1 100 K,respectively.Subsequent heat treatment of the films resulted in the formation of Na-β-alumina with α-Al2O3 at temperatures above 1 373 K for NaAl6O（9.5） and 1 473 K for γ-NaA1O2.On heat treatment at temperatures of 1 473-1 573 K,the faceted morphology with terraces of the as-deposited（110）-oriented γ-NaAlO2 films transformed to a porous morphology with platelet grains comprising Na-β-alumina and α-Al2O3.On heat treatment at temperatures of1 373-1 473 K,the pyramidal,faceted grains of as-deposited NaAl6O（9.5） films transformed to planer,shapeanisotropic morphology in the film of mixed Na-β-alumina and α-Al2O3.A dense morphology was observed in both the as-deposited and heat-treated NaAl6O（9.5） films.

Influence of Heat Treatment Temperature on Microstructure and Bonding of TiO2 Film Coated on Diamond Particles Surface

TiO_2 films were coated on the surface of diamond particles using a sol-gel method. The effects of heat treatment temperature on the morphology, phase composition and chemical bond of diamond particles coated with TiO2 films were investigated through SEM, TEM, X-ray diffraction analysis, Raman spectroscopy, FTIR, and XPS. The results showed that when being heat-treated at 600 ℃, the amorphous TiO_2 film transfered to the anatase film which bonded well with diamond substrate. Meanwhile, the Ti-O-C bond formed between TiO2 film and diamond substrate. When being heat-treated at 800 ℃, TiO2 film was still anatase, and partial diamond began to graphitize. The graphitizated carbon could also form the Ti-O-C bond with TiO_2 film, although TiO_2 film would tend to crack in this case.

High Temperature Catalytic Hydrogenation of Acetone over Raney Ni for Chemical Heat Pump

Exothermic hydrogenation reaction of acetone is an important part of an IAH-CHP, and the performance of IAH-CHP is affected directly by this reaction. This paper studies the influence of space velocity, temperature, hydrogen flow rate and pressure on conversion and selectivity experimentally. The byproducts are analyzed and classified into three types: hydrogenation product, cracking products and condensation products. Both the conversion and selectivity of this reaction have the same trend with the change of space velocity, temperature and hydrogen flow rate, and has the opposite trend with the change of pressure. As the space velocity increases, the conversion curve is a gradual decline parabola but the selectivity curve is close to a straight line. Hydrogen flow rate has a more obvious influence on conversion than temperature, whereas on selectivity the situation is opposite. High pressure increases the conversion of acetone to all products, but the increment of byproducts is more than that of isopropanol, so the selectivity decreases as pressure increases.

Simulation of Gas Exothermic Chemical Reaction in Porous Media Reactor with Lattice Boltzmann Method

Exothermic reactor is the main part in a chemical heat pump. It involves complex multi-component exothermal chemical reaction in catalyst-filled porous media. The lattice Boltzmann method (LBM) is developed to simulate the characteristics of fluid flow, heat and mass transfer coupling chemical reaction in the exothermic reactor of the isopropanol/acetone/hydrogen chemical heat pump system. Fractal theory is used to structure a porous medium model in the reactor. The simulation results show that LBM is suitable for the simulation and the conversion has an optimal value with different inlet velocities.

Regulating metal-acid double site balance on mesoporous SiO_(2)-Al_(2)O_(3) composite oxide for supercritical n-decane cracking

The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.

Mass and Heat Transfer Enhancement of Chemical Heat Pumps

An inert additive, expanded graphite (EG), has been prepared and used to enhance the heat and mass transfer process of chemical heat pumps. The effects of mixing ratio and mixing method on the chemical reaction time are investigated.

Exergy analysis and performance enhancement of isopropanol-acetone-hydrogen chemical heat pump

Exergy loss analysis was conducted to identify the irreversibility in each component of the isopropanol- acetone-hydrogen chemical heat pump （IAH-CHP）. The results indicate that the highest irreversibility on a system basis occurs in the distillation column. Moreover, the effect of operating parameters on thermodynamic performances of the IAH-CHP was studied and the optimal conditions were obtained. Finally, the potential methods to reduce the irreversibility of the IAH-CHP system were investigated. It is found that reactive distillation is apromising alternative. The enthalpy and exergy efficiency of the IAH-CHP with reactive distillation increases by 24.1% and 23.2%, respectively.

Modelling of the Absorption and Desorption Process of Chemical Heat Pumps

A simple model for the desorption and absorption process of the chemical heat pump is presented in this paper, It is based on the assumption of a definite reaction front. The results from m this model are compared with those obtained by finite difference method and it is observed that there is almost no difference between them.

A critical transition rule for broadening exponent of fluctuation and its effect on dissipation in chemical reaction-heat conduction coupling systems

A stochastic model of chemical reaction-heat conduction-diffusion for a one-dimensional gaseous system under Dirichlet or zero-fluxes boundary conditions is proposed in this paper. Based on this model,we extend the theory of the broadening exponent of critical fluctuations to cover the chemical reaction-heat conduction coupling systems as an asymptotic property of the corresponding Markovian master equation (ME),and establish a valid stochastic thermodynamics for such systems. As an illustration,the non-isothermal and inhomogeneous Schl-gl model is explicitly studied. Through an order analysis of the contributions from both the drift and diffusion to the evolution of the probability distribution in the corresponding Fokker-Planck equation(FPE) in the approach to bifurcation,we have identified the critical transition rule for the broadening exponent of the fluctuations due to the coupling between chemical reaction and heat conduction. It turns out that the dissipation induced by the critical fluctuations reaches a deterministic level,leading to a thermodynamic effect on the nonequilibrium physico-chemical processes.

Working state map of hydrocarbon fuels for regenerative cooling

Regenerative cooling by endothermic hydrocarbon fuel(EHF)is one of the most promising techniques for thermal management of supersonic or hypersonic aircraft.How to maintain the fuel working in proper states is an important issue to maximize the cooling potential of EHT.This work proposes a novel working state map,including risking zone(RZ),thermal cracking zone(TCZ),supercritical zone(SupZ)and subcritical zone(SubZ),to differentiate possible working states of an EHF during regenerative cooling.Using n-decane flowing in a circular tube as an example,the boundaries of four zones are determined by numerical simulation covering different heat fluxes(0.2-4.0 MW·m^(-2))and mass flow rates(0.5-10.5 g·s^(-1))under two operating pressures(3.45 and 5.00 MPa).Empirical correlations for three boundary lines are obtained and the maximum cooling capacity is identified,as well as the identification of the pressure effect.The revelation of such new perspective of regenerative cooling is of great implication to the design and optimization of cooling system for future thermal management.