Laser-induced voltage effects in c-axis oriented Ca3Co4O9 thin films have been studied with samples fabricated on 10°tilted LaAIO3 (001) substrates by a simple chemical solution deposition method. An open-circu...Laser-induced voltage effects in c-axis oriented Ca3Co4O9 thin films have been studied with samples fabricated on 10°tilted LaAIO3 (001) substrates by a simple chemical solution deposition method. An open-circuit voltage with a rise time of about 10 ns and full width at half maximum of about 28 ns is detected when the film surface is irradiated by a 308-nm laser pulse with a duration of 25 ns. Besides, opemcircuit voltage signals are also observed when the film surface is irradiated separately by the laser pulses of 532 nm and 1064 nm. The results indicate that Ca3Co4O9 thin films have a great potential application in the wide range photodetctor from the ultraviolet to near infrared regions.展开更多
Ca3Co409 thin films have been first prepared on polycrystalline AI203 substrates using chemical solution deposition method by multiple annealing processing. It is observed that the derived thin films are c-axis orient...Ca3Co409 thin films have been first prepared on polycrystalline AI203 substrates using chemical solution deposition method by multiple annealing processing. It is observed that the derived thin films are c-axis oriented although the substrates are polycrystalline AI203 substrates, suggesting the self-assembled c-axis orientation. The annealing temperature effects on the properties are investigated and discussed. The best performances are attributed to the 850 ℃-annealed sample, whose resistivity, Seebeck coefficient and power factor at 300 K are 7.4 mΩ cm, 117 μV/K and 0.18 mW/m K-2 respectively, which is even better than those of the thin films deposited on single crystal substrates. The results will provide an effective route to optimize the properties of Ca3Co409 thin films using chemical solution deposition by multiple annealing processing even the substrates are polycrystalline.展开更多
High transparency in visible region was required for red-light-emitting Y2O3:Eu3+ thin film phosphors. Such films were obtained via chemical bath deposition on bare SiO2 glass substrates through heterogeneous nucleati...High transparency in visible region was required for red-light-emitting Y2O3:Eu3+ thin film phosphors. Such films were obtained via chemical bath deposition on bare SiO2 glass substrates through heterogeneous nucleation with further heat treatment. Thin amorphous yttrium basic carbonate films could be completely transformed to crystalline Y2O3 at 650 °C. X-ray diffraction and field-emission scanning electron microscopy were used to characterize these products. The deposition temperature and the post-anneali...展开更多
Three Bi2Sr2Co2Oy thin films with different microstructures have been prepared by chemical solution deposition on LaAlO 3(001) through varying the annealing temperature.With the decrease in the annealing temperature...Three Bi2Sr2Co2Oy thin films with different microstructures have been prepared by chemical solution deposition on LaAlO 3(001) through varying the annealing temperature.With the decrease in the annealing temperature,both the size and c-axis alignment degree of grains in the film decrease as well,leading to an increase in the film resistivity.In addition,the decrease in the annealing temperature also results in a slight increase in the Seebeck coefficient due to the enhanced energy filtering effect of the small-grain film.The nanostructured Bi2Sr2Co2Oy film with an average grain size of about 100 nm shows a power factor comparable to that of films with larger grains.Since the thermal conductivity of the nanostructured films can be depressed due to the enhanced phonon scattering by grain boundary,a higher figure of merit is expected in Bi2Sr2Co2Oy thin film with grains in nanometer size.展开更多
Ba0.6Sr0.4TiO3 thin films doped with K were deposited on Pt/Ti/SiO2/Si substrates by the chemical solution deposition method. The structure, surface morphology and the dielectric and tunable properties of Bao.6Sro.4Ti...Ba0.6Sr0.4TiO3 thin films doped with K were deposited on Pt/Ti/SiO2/Si substrates by the chemical solution deposition method. The structure, surface morphology and the dielectric and tunable properties of Bao.6Sro.4TiO3 thin films have been studied in detail. The K content in Ba0.6Sro.4TiO3 thin films has a strong influence on the material's properties including surface morphology and the dielectric and tunable properties. It was found that the Curie temperature of K-doped Bao.6Sr0.4TiO3 films shifts to a higher value compared with that of undoped Ba0.6Sr0.4TiO3 thin films, which leads to a dielectric enhancement of K-doped Ba0.6Sr0.4TiO3 films at room temperature. At the optimized content of 0.02 mol, the dielectric loss tangent is reduced significantly from 0.057 to 0.020. Meanwhile, the tunability is enhanced obviously from 26% to 48% at the measured frequency of 1 MHz and the maximum value of the figure of merit is 23.8. This suggests that such films have potential applications for tunable devices.展开更多
The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,c...The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,compared with conventional superconducting materials.Using commercial 2G-HTS tapes,more than a dozen cable vendors had been manufacturing REBCO cables,such as the latest kilometer-class REBCO cable,which was incorporated into a civil grid on December 2021,as part of the recordbreaking 35-kV-voltage superconductor cable demonstration project in downtown Shanghai.This paper describes the development of HTS-coated conductors,then outlines the various technological routes for their preparation,reviews the artificial flux pinning of coated conductors,and finally summarizes the technological breakthroughs,the latest research advances,and provides an outlook on their application prospects.展开更多
In this work, water-based precursor solutions suitable for dip-coating of thick La2Zr2O7 (LZO) buffer layers for coated conductors on Ni-5%W substrates with an inclusion of polymeric polyvinyl pyrrolidone were devel...In this work, water-based precursor solutions suitable for dip-coating of thick La2Zr2O7 (LZO) buffer layers for coated conductors on Ni-5%W substrates with an inclusion of polymeric polyvinyl pyrrolidone were developed. The effect of varying percentage of the polymer addition on the preparation of the deposited films with maximum crack-free thickness was investigated. This novel water-based chemical solution deposition method involving polymers in two different chelate-chemistry compositions revealed the possibility to grow single, crack-free layers with thicknesses ranging from 140 to 280 nm, with good crystallinity and epitaxial growth. The effect of increasing polymer concentrations on the morphology and the structure of the films was studied. The appropriate buffer layer action of the films in preventing Ni diffusion was studied by X-ray photoelectron spectroscopy.展开更多
基金Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 10904030)the Natural Science Foundation of Hebei Province, China (Grant No. A2009000144)
文摘Laser-induced voltage effects in c-axis oriented Ca3Co4O9 thin films have been studied with samples fabricated on 10°tilted LaAIO3 (001) substrates by a simple chemical solution deposition method. An open-circuit voltage with a rise time of about 10 ns and full width at half maximum of about 28 ns is detected when the film surface is irradiated by a 308-nm laser pulse with a duration of 25 ns. Besides, opemcircuit voltage signals are also observed when the film surface is irradiated separately by the laser pulses of 532 nm and 1064 nm. The results indicate that Ca3Co4O9 thin films have a great potential application in the wide range photodetctor from the ultraviolet to near infrared regions.
基金supported by the National Natural Science Foundation of China (Nos. 50802096, 10904150 and10904151)
文摘Ca3Co409 thin films have been first prepared on polycrystalline AI203 substrates using chemical solution deposition method by multiple annealing processing. It is observed that the derived thin films are c-axis oriented although the substrates are polycrystalline AI203 substrates, suggesting the self-assembled c-axis orientation. The annealing temperature effects on the properties are investigated and discussed. The best performances are attributed to the 850 ℃-annealed sample, whose resistivity, Seebeck coefficient and power factor at 300 K are 7.4 mΩ cm, 117 μV/K and 0.18 mW/m K-2 respectively, which is even better than those of the thin films deposited on single crystal substrates. The results will provide an effective route to optimize the properties of Ca3Co409 thin films using chemical solution deposition by multiple annealing processing even the substrates are polycrystalline.
基金Project supported by the National Basic Research Program of China (2007CB936704)Major Basic Research Program of Shanghai (07DJ14001)+2 种基金"Pujiang Talent Project" of Shanghai Science and Technology Committee (09PJ1410600)Innovation Group for the Ministry of Science and Technology of ChinaPHD Innovation Program 2009 by NSRL of Ministry of Education
文摘High transparency in visible region was required for red-light-emitting Y2O3:Eu3+ thin film phosphors. Such films were obtained via chemical bath deposition on bare SiO2 glass substrates through heterogeneous nucleation with further heat treatment. Thin amorphous yttrium basic carbonate films could be completely transformed to crystalline Y2O3 at 650 °C. X-ray diffraction and field-emission scanning electron microscopy were used to characterize these products. The deposition temperature and the post-anneali...
基金Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 10904030)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20091301120002 )
文摘Three Bi2Sr2Co2Oy thin films with different microstructures have been prepared by chemical solution deposition on LaAlO 3(001) through varying the annealing temperature.With the decrease in the annealing temperature,both the size and c-axis alignment degree of grains in the film decrease as well,leading to an increase in the film resistivity.In addition,the decrease in the annealing temperature also results in a slight increase in the Seebeck coefficient due to the enhanced energy filtering effect of the small-grain film.The nanostructured Bi2Sr2Co2Oy film with an average grain size of about 100 nm shows a power factor comparable to that of films with larger grains.Since the thermal conductivity of the nanostructured films can be depressed due to the enhanced phonon scattering by grain boundary,a higher figure of merit is expected in Bi2Sr2Co2Oy thin film with grains in nanometer size.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10874051 and 50802096) and the Innovation Project for Young Talents of Hefei Institutes of Physical Science, Chinese Academy of Sciences (Grant No. O84N391123).
文摘Ba0.6Sr0.4TiO3 thin films doped with K were deposited on Pt/Ti/SiO2/Si substrates by the chemical solution deposition method. The structure, surface morphology and the dielectric and tunable properties of Bao.6Sro.4TiO3 thin films have been studied in detail. The K content in Ba0.6Sro.4TiO3 thin films has a strong influence on the material's properties including surface morphology and the dielectric and tunable properties. It was found that the Curie temperature of K-doped Bao.6Sr0.4TiO3 films shifts to a higher value compared with that of undoped Ba0.6Sr0.4TiO3 thin films, which leads to a dielectric enhancement of K-doped Ba0.6Sr0.4TiO3 films at room temperature. At the optimized content of 0.02 mol, the dielectric loss tangent is reduced significantly from 0.057 to 0.020. Meanwhile, the tunability is enhanced obviously from 26% to 48% at the measured frequency of 1 MHz and the maximum value of the figure of merit is 23.8. This suggests that such films have potential applications for tunable devices.
基金supported in part by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB25000000)by the National Natural Science Foundation(Grant No.52172271)by the National Key R&D Program of China(Grant No.2022YFE03150200)。
文摘The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,compared with conventional superconducting materials.Using commercial 2G-HTS tapes,more than a dozen cable vendors had been manufacturing REBCO cables,such as the latest kilometer-class REBCO cable,which was incorporated into a civil grid on December 2021,as part of the recordbreaking 35-kV-voltage superconductor cable demonstration project in downtown Shanghai.This paper describes the development of HTS-coated conductors,then outlines the various technological routes for their preparation,reviews the artificial flux pinning of coated conductors,and finally summarizes the technological breakthroughs,the latest research advances,and provides an outlook on their application prospects.
基金funding under the project grants P2/00/03 (CHEMAT)IAP/VI-17(INANOMAT) and FP7-NMP-2007- SMALL-1 Grant No.205854(EFECTS)
文摘In this work, water-based precursor solutions suitable for dip-coating of thick La2Zr2O7 (LZO) buffer layers for coated conductors on Ni-5%W substrates with an inclusion of polymeric polyvinyl pyrrolidone were developed. The effect of varying percentage of the polymer addition on the preparation of the deposited films with maximum crack-free thickness was investigated. This novel water-based chemical solution deposition method involving polymers in two different chelate-chemistry compositions revealed the possibility to grow single, crack-free layers with thicknesses ranging from 140 to 280 nm, with good crystallinity and epitaxial growth. The effect of increasing polymer concentrations on the morphology and the structure of the films was studied. The appropriate buffer layer action of the films in preventing Ni diffusion was studied by X-ray photoelectron spectroscopy.