Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%an...Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%and 72%,respectively.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in monoclinic,space group Pn with a=15.2988(12),b=13.6388(10),c=15.6761(13)A,β=98.677(7)°,V=3233.5(4)A^(3),Z=4,D_(c)=1.459 g·cm^(-3),F(000)=1440,μ=1.370 mm^(-1),R=0.0589 and wR=0.1366(I>2σ(I));2 crystallizes in the hexagonal space group of P63 with a=27.7471(6),b=27.7471(6),c=8.9811(2)A,V=5988.2(3)A^(3),Z=6,D_(c)=1.391 g·cm^(-3),F(000)=2592,μ=1.121 mm^(-1),R=0.0420 and wR=0.0726(I>2σ(I)).The photophysical properties of the title compounds were studied by solid-state optical absorption,photoluminescent excitation/emission(PLE/PL),PL decay spectra and photoluminescent quantum yield(PLQY).1 and 2 exhibit PL peaks at 627 and 607 nm,Stokes shifts of 257 and 242 nm,and PLQY of 32.5%and 49.2%,respectively.The distinct photo physical characteristics of 1 and 2 are highly related to the distortion extent of the[SbCl_(6)]^(3-)unit.展开更多
基金the National Natural Science Foundation of China(No.21671187)the Natural Science Foundation of Fujian Province(No.2020J01118)。
文摘Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%and 72%,respectively.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in monoclinic,space group Pn with a=15.2988(12),b=13.6388(10),c=15.6761(13)A,β=98.677(7)°,V=3233.5(4)A^(3),Z=4,D_(c)=1.459 g·cm^(-3),F(000)=1440,μ=1.370 mm^(-1),R=0.0589 and wR=0.1366(I>2σ(I));2 crystallizes in the hexagonal space group of P63 with a=27.7471(6),b=27.7471(6),c=8.9811(2)A,V=5988.2(3)A^(3),Z=6,D_(c)=1.391 g·cm^(-3),F(000)=2592,μ=1.121 mm^(-1),R=0.0420 and wR=0.0726(I>2σ(I)).The photophysical properties of the title compounds were studied by solid-state optical absorption,photoluminescent excitation/emission(PLE/PL),PL decay spectra and photoluminescent quantum yield(PLQY).1 and 2 exhibit PL peaks at 627 and 607 nm,Stokes shifts of 257 and 242 nm,and PLQY of 32.5%and 49.2%,respectively.The distinct photo physical characteristics of 1 and 2 are highly related to the distortion extent of the[SbCl_(6)]^(3-)unit.
