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The Factorization of Adjoint Polynomials of E^G(i)-class Graphs and Chromatically Equivalence Analysis 被引量:15
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作者 ZHANG Bing-ru YANG Ji-ming 《Chinese Quarterly Journal of Mathematics》 CSCD 北大核心 2008年第3期376-383,共8页
Let Sn be the star with n vertices, and let G be any connected graph with p vertices. We denote by ErGp(+i)(r-1) the graph obtained from Sr and rG by coinciding the i-th vertex of G with the vertex of degree r-1 of Sr... Let Sn be the star with n vertices, and let G be any connected graph with p vertices. We denote by ErGp(+i)(r-1) the graph obtained from Sr and rG by coinciding the i-th vertex of G with the vertex of degree r-1 of Sr, while the i-th vertex of each component of (r-1)G be adjacented to r-1 vertices of degree 1 of Sr, respectively. By applying the properties of adjoint polynomials, We prove that factorization theorem of adjoint polynomials of kinds of graphs ErGp(+i)(r-1) (r-1)K1 (1 ≤ i ≤ p). Furthermore, we obtain structure characteristics of chromatically equivalent graphs of their complements. 展开更多
关键词 EG(i)类图簇 伴随多项式 图论 数学
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Non-uniqueness and stability of two-family fiber-reinforced incompressible hyper-elastic sheet under equibiaxial loading
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作者 任九生 程昌钧 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2013年第12期1513-1520,共8页
The problems on the non-uniqueness and stability of a two-family fiber- reinforced anisotropic incompressible hyper-elastic square sheet under equibiaxial tensile dead loading are examined within the framework of fini... The problems on the non-uniqueness and stability of a two-family fiber- reinforced anisotropic incompressible hyper-elastic square sheet under equibiaxial tensile dead loading are examined within the framework of finite elasticity. For a two-family fiber-reinforced square sheet, which is in-plane symmetric and subjected to the in-plane symmetric tension in dead loading on the edges, three symmetrically deformed configu- rations and six asymmetrically deformed configurations are possible for any values of the loading. Moreover, another four bifurcated asymmetrically deformed configurations are possible for the loading beyond a certain criticM value. The stability of all the solutions is discussed in comparison with the energy of the sheet. It is shown that only one of the symmetric solutions is stable when the loading is less than the critical value. However, this symmetric solution will become unstable when the loading is larger than the critical value, while one of the four bifurcated asymmetric solutions will be stable. 展开更多
关键词 two-family fiber-reinforced incompressible hyper-elastic square sheet non-uniqueness stability symmetric and asymmetric deformation equibiaxial loading
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Study on Non-Uniqueness of Taylor Vortex Flow Changing Inner Cylinder Acceleration Time
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作者 Hiroyuki Furukawa Tomohito Suzuki 《World Journal of Mechanics》 2018年第8期301-310,共10页
In concentrically rotating double cylinders consisting of a stationary outer cylinder a rotating inner cylinder, Taylor vortex flow appears. Taylor vortex flow occurs in journal bearings, various fluid machineries, co... In concentrically rotating double cylinders consisting of a stationary outer cylinder a rotating inner cylinder, Taylor vortex flow appears. Taylor vortex flow occurs in journal bearings, various fluid machineries, containers for chemical reaction, and other rotating components. Therefore, the analysis of the flow structure of Taylor vortex flow is highly effective for its control. The main parameters that determine the modes of Taylor vortex flow of a finite length are the aspect ratio, Reynolds number Re. Aspect ratio is defined as the ratio of the cylinder length to the gap length between cylinders, and Re is determined on the basis of the angular speed of the inner cylinder. Aspect ratio was set to be 4.0, and Re to be values in the range from 100 to 1000 at intervals of 100. Thus far, a large number of studies on Taylor vortex flow have been carried out;however, the effects of the differences in initial conditions have not yet been sufficiently clarified. In this study, we changed the acceleration time of the inner cylinder in a numerical analysis, and examined the resulting changes in the mode formation and bifurcation processes. The acceleration time was changed from 1.0 s to 10.0 s. As a result, a difference was observed in the final mode depending on the difference in the acceleration time. From this finding, non-uniqueness, which is a major characteristic of Taylor vortex flow, was confirmed. However, no regularities regarding the difference in mode formation were found and the tendency of the mode formation process was not specified. Moreover, the processes of developing the vortex resulting in different final modes were monitored over time by visual observation. Similar flow behaviors were initially observed after the start of the calculation. Then, a bifurcation point, at which the flow changed to a mode depending on the acceleration time observed, and finally the flow became steady. In addition, there was also a difference in the time taken for the well-developed flow to reach the steady state. Both EFD (Experimental Fluid Dynamics) and CFD (Computational Fluid Dynamics) results show good agreement qualitatively. 展开更多
关键词 ROTATING Cylinders Flow INSTABILITY BIFURCATION EFD and CFD non-uniqueness
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On Chromatically Equivalence of a Class of Graphs
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作者 ZHANG Shu-min 《Chinese Quarterly Journal of Mathematics》 CSCD 2010年第2期308-311,共4页
新图的一个班是为一些是上色等价物的这些图的足够的状况被证明的 defined.A。
关键词 色彩的多项式 上色等价物图 梯子图
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A novel method for designing crosstalk-free achromatic full Stokes imaging polarimeter
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作者 Jinghua Teng 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2023年第8期1-3,共3页
Metasurface-based polarimetry techniques have attracted lots of interests and been extensively studied in the past years,but are still hampered by narrow operating bandwidth and large crosstalk.Recently,Xian-Gang Luo&... Metasurface-based polarimetry techniques have attracted lots of interests and been extensively studied in the past years,but are still hampered by narrow operating bandwidth and large crosstalk.Recently,Xian-Gang Luo's group proposed a new method of polarization-dependent phase optimization for the design of crosstalk-free,broadband achromatic,and full Stokes imaging polarimeter,which offers a promising platform for a wide range of applications including bio-photonics and integrated optics. 展开更多
关键词 POLAR chromatIC method
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Mechanical Characterization of Broadband Achromatic Optical Vortex Metalens
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作者 陆哲淳 邓越华 +2 位作者 于洋 黄承志 杨俊波 《Chinese Physics Letters》 SCIE EI CAS CSCD 2023年第11期47-52,共6页
Metalenses,which may effectively manipulate the wavefront of incident light,have been proposed and extensively utilized in the development of various planar optical devices for specialized purposes.However,similar to ... Metalenses,which may effectively manipulate the wavefront of incident light,have been proposed and extensively utilized in the development of various planar optical devices for specialized purposes.However,similar to traditional lenses,the metalens suffers from chromatic aberration problems due to the significant phase dispersion in each unit structure and the limited operational bandwidth.To mitigate the impact of chromatic aberration,we integrate a phase compensation approach with a novel utilization of a phase shift function to define the adjusted phase criterion satisfied by each α-Si resonance unit.This approach may lead to development of an innovative optical tweezer known as an achromatic optical vortex metalens(AOVM),offering reliable focusing capabilities across the 1300 nm and 1600 nm incident light range.Numerical simulations are conducted to investigate the optical properties of 200 nm diameter SiO_(2) particles at the focal plane of the AOVM.The trapping ability of the AOVM is successfully validated,exhibiting favorable characteristics including constant optical force,stable kinematic state of trapped particles,and consistent capture positions,surpassing those of the optical vortex metalens. 展开更多
关键词 chromatIC VORTEX utilized
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Chromatic and achromatic differences of melanin-and carotenoid-based plumage coloration in five minivet species(Pericrocotus spp.)under conspecific and predator visual systems
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作者 Yan Cai Xiangyang Chen +1 位作者 Neng Wu Canchao Yang 《Avian Research》 SCIE CSCD 2023年第1期93-98,共6页
Adaptive mate choice has been accepted as the leading theory to explain the colorful plumage of birds.This theory hypothesizes that conspicuous colors act as signals to advertise the qualities of the owners.However,a ... Adaptive mate choice has been accepted as the leading theory to explain the colorful plumage of birds.This theory hypothesizes that conspicuous colors act as signals to advertise the qualities of the owners.However,a dilemma arises in that conspicuous colors may not only attract mates,but also alert predators.The"private channels of communication"hypothesis proposes that some intraspecific signals may not be visible to heterospecific animals because of different visual systems.To better understand the evolution of plumage colors and sexual selection in birds,here we studied the chromatic difference and achromatic differences of melanin-and carotenoid-based plumage coloration in five minivet species(Pericrocotus spp.)under conspecific and predator visual systems.We found that either the chromatic or achromatic difference among male or female minivets’plumage was consistently higher under conspecific vision than under predator vision for all five studied species of minivets.This result indicated that individual differences in plumage colors of minivets were visible to the conspecific receivers and hidden from potential predators as a result of evolution under predation risk and conspecific communication.However,males were under a higher risk of predation because they were more conspicuous than females to the vision of a nocturnal predator. 展开更多
关键词 Achromatic difference Adaptive mate choice chromatic difference Omamental plumage Visual modelling
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Study of strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet
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作者 HE Yutian HUANG Shengbiao ZHANG Baoping 《Baosteel Technical Research》 CAS 2023年第2期7-14,共8页
Strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet were systematically studied using Thermo-Calc thermodynamic calculations,scanning electron microscope and X... Strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet were systematically studied using Thermo-Calc thermodynamic calculations,scanning electron microscope and X-ray diffractometer analyses,and rapid heat treatment simulation technology.The formation mechanism of these defects was also analyzed.The results show a strong correlation between the defects and the uneven distribution of the Fe(001)component on the surface of the steel substrate.The relatively high proportion of Fe(001)components on the surface of the steel substrate affects the distribution density of the Zn crystal cells in different orientations during the electrodeposition process,which causes the reflection intensity of the light of the galvanized layer to differ from various visual perspectives,and macroscopic strip-shaped chromatic aberration defects are finally formed.The high proportion of the Fe(001)component on the surface of the steel substrate is mainly related to the following two factors.First,when the strip steel is hot-rolled,the finishing hot-rolling temperature is close to theγ→αphase transition temperature.When the local temperature on the upper surface of the strip steel is low,γ+αtwo-phase rolling easily occurs,and this results in an uneven stress distribution between theγandαphases after the hot-rolling process.This uneven distribution of hot-rolling stress results in the formation of a coarse grain structure in the local area on the surface of the hot-rolled sheet,which strongly affects the subsequent cold rolling and annealing process,and the annealed steel sheet substrate ultimately contains a greater proportion of the Fe(001)component.And second,a fast cooling rate(>10 K/s)during the slow cooling stage in the continuous annealing process inhibits the transformation of the Fe(001)to the Fe(111)component on the surface of the cold-rolled steel sheet,and it is then not possible to effectively eliminate the influence of the unevenly distributed Fe(001)component on the surface of the annealed steel sheet(originating from the uneven hot-rolled microstructure).This uneven distribution of the Fe(001)component on the surface of the annealed steel sheet following the continuous annealing heat treatment has a strong effect on the electrodeposition behavior of the Zn crystal cell in the subsequent electroplating process and the formation of macroscopic strip-shaped chromatic aberration defects on the surface of electro-galvanized fingerprint-resistant sheet. 展开更多
关键词 electro-galvanized fingerprint-resistant sheet strip-shaped chromatic aberration defects texture
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菱铁矿对六价铬阴离子吸附-还原耦合固定的去除机理研究
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作者 张璇 陈静 +1 位作者 吴宏海 魏燕富 《华南师范大学学报(自然科学版)》 CAS 北大核心 2024年第3期25-33,共9页
为了揭示菱铁矿对水中六价铬Cr(Ⅵ)阴离子的吸附-还原耦合固定去除特性,采用合成菱铁矿矿物材料开展铬的吸附等温线和动力学特征探究,着重考察溶液pH对铬去除效率的影响,并对铬反应前后菱铁矿样品进行表征与分析。结果表明:采用Langmui... 为了揭示菱铁矿对水中六价铬Cr(Ⅵ)阴离子的吸附-还原耦合固定去除特性,采用合成菱铁矿矿物材料开展铬的吸附等温线和动力学特征探究,着重考察溶液pH对铬去除效率的影响,并对铬反应前后菱铁矿样品进行表征与分析。结果表明:采用Langmuir等温吸附模型,能更好地描述合成菱铁矿对Cr(Ⅵ)的去除,而铬去除动力学则更符合伪二级吸附动力学模型。Cr(Ⅵ)可被菱铁矿表面Fe(Ⅱ)快速还原转化为Cr(Ⅲ)离子,但由于pH升高,Cr(Ⅵ)的氧化性能有所降低,因而导致铬的去除率明显下降。菱铁矿表面形成了Fe(Ⅲ)-Cr(Ⅲ)氢氧化物共沉淀,从而实现菱铁矿对六价铬离子的有效去除。 展开更多
关键词 菱铁矿 六价铬阴离子 吸附 还原 去除 矿物材料
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大量程高线性光谱共焦位移测量系统
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作者 肖康 陈小君 吴永前 《激光杂志》 CAS 北大核心 2024年第6期33-38,共6页
兼具高精度、高稳定性并能实现非接触测量的光谱共焦位移测量系统在工业、医疗、科研等许多领域得到了广泛应用。目前制约光谱共焦位移测量系统应用发展的因素是大量程和高线性度。讨论了光谱共焦位移测量系统中色散物镜实现线性轴向色... 兼具高精度、高稳定性并能实现非接触测量的光谱共焦位移测量系统在工业、医疗、科研等许多领域得到了广泛应用。目前制约光谱共焦位移测量系统应用发展的因素是大量程和高线性度。讨论了光谱共焦位移测量系统中色散物镜实现线性轴向色散的条件,设计了一种高线性色散和大色散范围的色散物镜,指定了适合的公差范围,加工装配了一组色散物镜,搭建了光谱共焦位移测量系统,采用双频激光干涉仪进行了位移标定,并对标准量块进行了厚度测量。结果表明,该系统工作波段为450 nm~650 nm,实际位移范围为10 200μm,线性拟合判定系数R^(2)达到0.993 7,实际测量最大误差仅为3μm,证明该光谱共焦位移测量系统同时具备大量程、高线性度和高测量精度的特点。 展开更多
关键词 光谱共焦 色散物镜 位移测量 非接触 光学设计
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外场快速修复用六价铬转化膜的性能
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作者 齐建涛 赵亓新 +6 位作者 冯孟 安洋 杨玉龙 卞贵学 付明 解二伟 韩力 《海军航空大学学报》 2024年第3期357-364,388,共9页
外场装备损伤部位快速修复可维持装备服役期间的功能性及寿命。文章对比分析了AA7B04铝合金表面损伤部位及六价铬转化膜再修复样品的表面微观组织、化学成分、电化学性能、酸性盐雾性能。研究结果表明,自主研发六价铬溶液可有效修复划... 外场装备损伤部位快速修复可维持装备服役期间的功能性及寿命。文章对比分析了AA7B04铝合金表面损伤部位及六价铬转化膜再修复样品的表面微观组织、化学成分、电化学性能、酸性盐雾性能。研究结果表明,自主研发六价铬溶液可有效修复划痕样品。划痕修复部位形成一层致密薄膜,且主要成分包括Cr、F、O、K等元素;对比分析拉曼光谱结果,划痕修复部位存在显著的六价铬CrO_(4)^(2-)(847 cm^(-1));电化学阻抗谱结果证明再修复样品在10-2Hz处阻抗膜值为5.09×10^(5)Ω⋅cm^(-2),比划痕样品提高了5倍;电动位极化曲线显示再修复样品自腐蚀电流密度为10^(-5.5)A·cm^(-2),与划痕样品相比下降了1个数量级;此外,再修复样品耐酸性盐雾周期超过336 h,样品表面无腐蚀点,表面盐雾评级达到10级,失重法表征的腐蚀速度比划痕样品下降1个数量级。 展开更多
关键词 六价铬 转化膜 再修复 铬酸盐 腐蚀
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不同类型果袋对蟠桃果实品质的影响
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作者 李杰 田启航 +5 位作者 王雨 王召元 常瑞丰 刘国俭 陈湖 李永红 《河北农业科学》 2024年第3期31-34,共4页
为了明确蟠桃果实优质生产的果袋类型,以金霞油蟠和瑞油蟠2号2个蟠桃品种为试验材料,6月上旬分别选用外黄内黑双层袋、白色单层袋进行果实套袋处理,以不套袋处理为对照,研究了不同类型果袋对蟠桃果实外观品质和内在品质的影响。结果表明... 为了明确蟠桃果实优质生产的果袋类型,以金霞油蟠和瑞油蟠2号2个蟠桃品种为试验材料,6月上旬分别选用外黄内黑双层袋、白色单层袋进行果实套袋处理,以不套袋处理为对照,研究了不同类型果袋对蟠桃果实外观品质和内在品质的影响。结果表明:与未套袋的对照相比,2个蟠桃品种果实套袋后单果重和可食率明显增大,成熟期果面黄色度增加、红色度降低,果面亮度和光洁度有效提高,果皮擦伤度和果实裂果率明显降低,带皮硬度、去皮硬度和可溶性固形物含量降低不显著,其中套外黄内黑双层袋的效果优于套白色单层袋。外黄内黑双层袋对提高蟠桃果实外观品质和内在品质的效果优于白色单层袋,研究结果可为今后生产实践中提高蟠桃果实品质,尤其是解决蟠桃裂果问题提供理论参考。 展开更多
关键词 蟠桃 套袋 果实品质 色差
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基于可视化热重分析技术的宣纸热分解特性研究及动力学分析
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作者 陈彪 付小航 +2 位作者 谭静 卢郁静 丁延伟 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2024年第1期95-105,I0001,共12页
为了解宣纸的劣化机理,本文利用可视化热重分析技术对宣纸在氮气与空气中的热分解过程进行了实验和分析,结果表明其过程主要阶段为发挥性成分的析出过程,宣纸样品经历快速失重、面积收缩且颜色加深,其中空气气氛可促进热分解反应并在反... 为了解宣纸的劣化机理,本文利用可视化热重分析技术对宣纸在氮气与空气中的热分解过程进行了实验和分析,结果表明其过程主要阶段为发挥性成分的析出过程,宣纸样品经历快速失重、面积收缩且颜色加深,其中空气气氛可促进热分解反应并在反应后期氧化前期生成的炭化物;然后以高斯分布函数对微商热重(DTG)曲线进行拟合得到三组分,并且三组分的反应区间符合生物质的热分解特性且受气氛影响;此外,本文还基于Lab色彩空间对实时观察热分解图像进行了分析,其结果相比热失重数据在反应起始和中止阶段灵敏度更高,并可对热失重数据进行补充;同时,本文以Friedman法、FWO法计算宣纸在氮气与空气中的表观活化能E,得到氮气与空气气氛中的结果分别为195.4kJ/mol、162.98kJ/mol;最后通过Malek法对宣纸样品的热分解数据进行最概然机理函数的选择,并得到氮气中的热分解活化能E为245.60kJ/mol,指前因子的自然对数lnA为37.39s^(-1);空气中活化能E在150.18~305.41kJ/mol,lnA在49.13~20.18s^(-1)。 展开更多
关键词 色度分析 动力学 活化能 反应机理函数
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一类仙人掌图的星边染色
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作者 红霞 张素萍 《海南大学学报(自然科学版)》 CAS 2024年第1期1-7,共7页
图G的星边染色是指G的一个正常边染色,使得G中任一长为4的路和长为4的圈均不是2-边染色的.图G的星边色数χ’_(st)(G)表示图G有星边染色的最小颜色数.仙人掌图是一个连通图使得每个块是圈或者边.利用数学归纳法得到了一类仙人掌图C_(n)&... 图G的星边染色是指G的一个正常边染色,使得G中任一长为4的路和长为4的圈均不是2-边染色的.图G的星边色数χ’_(st)(G)表示图G有星边染色的最小颜色数.仙人掌图是一个连通图使得每个块是圈或者边.利用数学归纳法得到了一类仙人掌图C_(n)·C_(m)(n≥3,m≥3)的星边色数,从而推广已知结果. 展开更多
关键词 仙人掌图 星边染色 星边色数
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电动力耦合循环井技术修复低渗透含水层污染 被引量:2
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作者 杜中海 董艳红 +4 位作者 刘方圆 董书君 陈韶音 董倩 周睿 《中国环境科学》 EI CAS CSCD 北大核心 2024年第2期841-850,共10页
提出一种电动力耦合循环井修复技术,以铬酸盐为典型目标污染物,研究该技术对低渗透含水层中地下水污染的修复效果及去除规律.结果表明:电动力耦合循环井技术相比循环井技术,修复半径扩大为原来的1.25倍,修复盲区面积占比从35.56%降为0,... 提出一种电动力耦合循环井修复技术,以铬酸盐为典型目标污染物,研究该技术对低渗透含水层中地下水污染的修复效果及去除规律.结果表明:电动力耦合循环井技术相比循环井技术,修复半径扩大为原来的1.25倍,修复盲区面积占比从35.56%降为0,污染物的去除率从76.01%提高到了90.56%,相较于电动力修复技术电动力能耗降低了3个数量级,污染物去除率更高,可提升2~3倍.该技术耦合电动力方法实现了低渗透含水层中带电离子组分的强化定向迁移,解决了循环井在低渗透含水层中传质效率低、修复范围小、存在水力循环盲区等问题,修复效果显著提升. 展开更多
关键词 低渗透含水层 电动力修复 循环井技术 地下水污染修复 铬酸盐
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环境艺术设计用铜合金的表面改性处理研究
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作者 沈婷 轩德军 史进 《太原学院学报(自然科学版)》 2024年第2期74-78,共5页
为了提升环境艺术用铜合金的耐腐蚀性能,提升艺术观赏性,对环境艺术设计用铜合金进行了表面改性处理,对比分析了打磨态、酸洗态、无铬钝化态和铬酸盐钝化态铜合金的表面物相组成、表面形貌,以及盐雾腐蚀、失重腐蚀和电化学腐蚀性能。结... 为了提升环境艺术用铜合金的耐腐蚀性能,提升艺术观赏性,对环境艺术设计用铜合金进行了表面改性处理,对比分析了打磨态、酸洗态、无铬钝化态和铬酸盐钝化态铜合金的表面物相组成、表面形貌,以及盐雾腐蚀、失重腐蚀和电化学腐蚀性能。结果表明,无铬钝化和铬酸盐钝化处理后的铜合金表面都形成了钝化膜,且铬酸盐钝化处理后铜合金表面形成了致密钝化膜;盐雾腐蚀后,无铬钝化态和铬酸盐钝化态铜合金的表面腐蚀程度会相对打磨态和酸洗态腐蚀较轻;在相同腐蚀时间下,腐蚀失重从小到大顺序为:铬酸盐钝化态<无铬钝化态<酸洗态<打磨态;无铬钝化态和铬酸盐钝化态铜合金的腐蚀电位相对打磨态、酸洗态更正,腐蚀电流密度相对小一个数量级,打磨态、酸洗态、无铬钝化态和铬酸盐钝化态的缓蚀率分别为32.32%、51.66%、89.34%和96.84%,铜合金的耐腐蚀性能从大到小顺序为:铬酸盐钝化态>无铬钝化态>酸洗态>打磨态。 展开更多
关键词 铜合金 无铬钝化 铬酸盐钝化 表面形貌 腐蚀性能
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Ag_(2)CrO_(4)/g-C_(3)N_(4)复合材料光催化产氢性能及机理
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作者 芦涛 张安超 +4 位作者 孙志君 陈国艳 张倩倩 敬曼曼 倪飞翔 《功能材料》 CAS CSCD 北大核心 2024年第6期6128-6137,共10页
采用原位化学沉积法制备了一系列具有光催化产氢性能的Ag_(2)CrO_(4)/g-C_(3)N_(4)复合材料。利用X射线衍射、傅里叶变换红外、场发射扫描电子显微镜、透射电子显微镜、X射线光电子能谱明确了复合物的物相组成、官能团结构、微观形貌、... 采用原位化学沉积法制备了一系列具有光催化产氢性能的Ag_(2)CrO_(4)/g-C_(3)N_(4)复合材料。利用X射线衍射、傅里叶变换红外、场发射扫描电子显微镜、透射电子显微镜、X射线光电子能谱明确了复合物的物相组成、官能团结构、微观形貌、元素组成及其存在形态。采用紫外可见光漫反射、光致发光光谱和光电流测试探究了复合材料光吸收性能及光生载流子的分离情况,研究了光催化剂的产氢性能及其影响因素。结果表明,Ag_(2)CrO_(4)的引入不会改变g-C_(3)N_(4)原有的碳氮杂环结构,且Ag_(2)CrO_(4)以纳米颗粒形式分散于g-C_(3)N_(4)表面。虽然Ag_(2)CrO_(4)没有产氢效果,但随着Ag_(2)CrO_(4)含量的增加,复合材料的产氢速率先增大后减小。最优光催化剂Ag_(2)CrO_(4)/C_(3)N_(4)-4%的产氢速率是纯g-C_(3)N_(4)的2.7倍,其原因可能是Ag_(2)CrO_(4)和g-C_(3)N_(4)的耦合形成了Z型异质结,拓宽了g-C_(3)N_(4)的可见光响应范围,降低了电荷转移的阻抗,促进了光生载流子的迁移和分离。 展开更多
关键词 氮化碳 铬酸银 异质结 光催化剂 产氢
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微波辅助合成促进铬酸铋晶体的光生电荷分离
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作者 张珹博 陶晓萍 +4 位作者 蒋文超 郭俊雪 张鹏飞 李灿 李仁贵 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第1期28-29,共2页
为了将可再生太阳能转化为化学物质,探索具有宽光谱响应的光催化剂用于光催化分解水越来越受到人们的关注。作为铋基层状金属氧化物的一员,铬酸铋(Bi_(2)CrO_(6))的带隙约为1.9 eV,在利用大范围太阳光谱方面具有潜力。然而,Bi_(2)CrO_(6... 为了将可再生太阳能转化为化学物质,探索具有宽光谱响应的光催化剂用于光催化分解水越来越受到人们的关注。作为铋基层状金属氧化物的一员,铬酸铋(Bi_(2)CrO_(6))的带隙约为1.9 eV,在利用大范围太阳光谱方面具有潜力。然而,Bi_(2)CrO_(6)较差的电荷分离性能限制了其在光催化中的应用。本文采用微波辅助水热合成方法制备了具有规则形貌的Bi_(2)CrO_(6)晶体,该晶体具有结晶度高、形貌均匀的优点。与传统制备方法相比,微波辐照实现了体系的快速加热,极大地加速了成核和生长的化学反应,从而在几分钟内形成了Bi_(2)CrO_(6)晶体。微波辅助合成的Bi_(2)CrO_(6)晶体在光催化和光电化学测试中表现出更好的光生电荷分离以及水氧化活性。此外实验中观察到光生电子和空穴在Bi_(2)CrO_(6)晶体的不同晶面之间发生空间分离,通过进一步在不同晶面上光沉积选择性负载还原和氧化助催化剂,显著增强了光催化活性。这项工作为制备高效太阳能转换的半导体光催化剂提供了一种可行的解决方案。 展开更多
关键词 微波合成 铬酸铋 半导体 光催化 水氧化
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基于性别差异的化生型慢性萎缩性胃炎患者色诊特征研究
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作者 陈佳萍 杜正光 +4 位作者 关贝 吉星宇 陈龙畅 王永吉 马赟 《世界科学技术-中医药现代化》 CSCD 北大核心 2024年第1期129-136,共8页
目的基于性别差异,分别探讨男性与女性化生型慢性萎缩性胃炎(Chronic atrophic gastritis,CAG)患者颜面色诊特征,从中医发病学角度出发探究不同性别患者的病变机理,为中医药防治化生型CAG提供个性化参考。方法本研究应用MT-BX-01四诊仪... 目的基于性别差异,分别探讨男性与女性化生型慢性萎缩性胃炎(Chronic atrophic gastritis,CAG)患者颜面色诊特征,从中医发病学角度出发探究不同性别患者的病变机理,为中医药防治化生型CAG提供个性化参考。方法本研究应用MT-BX-01四诊仪采集慢性非萎缩性胃炎(Chronic non atrophic gastritis,CNG)与CAG患者的面色信息,采用病例对照研究方法,分别从男性与女性化生型CAG患者及CNG患者的面色色度学特征进行分析。结果在女性患者中,CAG伴轻度和中、重度肠化(Intestinal metaplasia,IM)组面部肝区位点L值、a值均显著低于CNG组(P<0.05)。在男性患者中,CAG伴中、重度IM组脾区位点b值显著高于CNG组(P<0.05)。结论化生型CAG患者的面色特征存在一定的性别差异,化生型CAG女性患者面部色度值在肝区变化最显著,男性患者则主要表现于脾区。提示女性化生型CAG发病多与肝相关,男性发病则多与脾相关,为临床针对不同性别化生型CAG患者进行中医临床诊疗与防治提供了个性化思路。 展开更多
关键词 慢性萎缩性胃炎 肠上皮化生 色诊 客观化 色度值
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基于拉曼光谱与色度学的彩色淡水有核珍珠研究
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作者 王子轩 杨淼 +2 位作者 柳迪文 孟彬 祖恩东 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2024年第6期1684-1688,共5页
淡水有核珍珠因为其粒径大、圆度好、色彩丰富、光泽强等优点,在珍珠市场上占据了较大份额。目前关于彩色淡水有核珍珠的致色机理尚没有一致的结论,且关于该致色物质如何使淡水有核珍珠呈现多种颜色的研究较少。基于此研究现状,选取多... 淡水有核珍珠因为其粒径大、圆度好、色彩丰富、光泽强等优点,在珍珠市场上占据了较大份额。目前关于彩色淡水有核珍珠的致色机理尚没有一致的结论,且关于该致色物质如何使淡水有核珍珠呈现多种颜色的研究较少。基于此研究现状,选取多种颜色的淡水有核珍珠进行激光拉曼光谱与色度学研究。拉曼光谱研究发现样品具有三种不同的C—C与C C峰,且表现出对应关系:1123~1125 cm^(-1)处的C—C峰常与1506~1509 cm^(-1)处的C C峰同时出现;1132~1134 cm^(-1)处的C—C峰常与1522~1523或1525 cm^(-1)处的C C峰同时出现;1128~1131 cm^(-1)处的C—C峰常与1506~1509与1520~1523或1525 cm^(-1)的C C双重峰同时出现。依据拉曼光谱中C C键峰的差异将全部样品分为P、T、G、P+T、T+G、P+G共6种类型。结合样品的色度学参数,在同类型样品中,建立亮度L或饱和度S与其拉曼光谱中CO_(3)/C—C峰面积比的相关性,发现P型珠的亮度L与CO_(3)/C—C峰面积比有明显的正相关性,而P、T、G型珠的饱和度S都与CO_(3)/C—C峰面积比有明显的负相关性,证实三种不同的C—C与C C峰是由不同的致色物质所致。并根据拉曼谱峰将彩色淡水有核珍珠中的致色有机物归属为线性多烯类分子。线性多烯分子的拉曼峰位随着有序度的增加而红移,拉曼峰位更靠近红外区的线性多烯分子的碳骨架更长更直,这导致不同类型样品的拉曼光谱中C—C与C C的峰有所区别。此外,依据色度学参数对彩色淡水有核珍珠进行颜色系列的划分。将色调角h∈(0,15)的珍珠归为红色系列;将色调角h∈(15,45)的珍珠归为黄色系列;将色调角h∈(335,360)的珍珠归为紫色系列。 展开更多
关键词 淡水有核珍珠 拉曼光谱 色度学 峰面积比 线性多烯
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