I MWth Test Facilities for Circulating Fluidized Bed Combustion

This paper presents the technical parameters and features of 1 MWth test facilities for circulating fluidized bed combustion (CFBC) at Thermal Power Research Institute (TPRI) of State Power Corporation (SP), introduces the test items that can be proceeded and trial combustion projects completed. The development status of CFBC technologies abroad and the level of China in this field are also introduced in the paper.

Emissions of SO_2, NO and N_2O in a circulating fluidized bed combustor during co-firing coal and biomass

This paper presents the experimental investigations of the emissions of SO2, NO and N20 in a bench scale circulating fluidized bed combustor for coal combustion and co-firing coal and biomass. The thermal capacity of the combustor is 30 kW. The setup is electrically heated during startup. The infuence of the excess air, the degree of the air staging, the biomass share and the feeding position of the fuels on the emissions of SO2, NO and N2O were studied. The results showed that an increase in the biomass shares resulted in an increase of the CO concentration in the flue gas, probably due to the high volatile content of the biomass. In co-firing, the emission of SO2 increased with increasing biomass share slightly, however, non-linear increase relationship between SO2 emission and fuel sulfur content was observed. Air staging significantly decreased the NO emission without raising the SO2 level. Although the change of the fuel feeding position from riser to downer resulted in a decrease in the NO emission level, no obvious change was observed for the SO2 level. Taking the coal feeding position R as a reference, the relative NO emission could significantly decrease during co-firing coal and biomass when feeding fuel at position D and keeping the first stage stoichiometry greater than 0.95. The possible mechanisms of the sulfur and nitrogen chemistry at these conditions were discussed and the ways of simultaneous reduction of SO2, NO and N2O were proposed.

Hydrothermal synthesis of zeolitic material from circulating fluidized bed combustion fly ash for the highly efficient removal of lead from aqueous solution

The utilization of coal fly ash derived from circulating fluidized bed combustion(CFBFA)still faces great challenges because of its unique characteristics.In this study,a zeolitic material with Na-P1 zeolite as the main phase was successfully synthesized via a hydrothermal method by using CFBFA as the raw material.The effects of hydrothermal temperature,time,and added CTAB amount on the characterizations of synthesized materials were investigated by XRD,SEM,and XPS.The properties of the optimal zeolitic material and its adsorption performance for Pb^(2+)in aqueous solution were evaluated.The influences of pH,initial concentration,dosage,and temperature on Pb^(2+)adsorption were also examined.Results revealed the following optimal parameters for the synthesis of zeolitic material:NaOH concentration of 2 mol·L^(-1),solid-to-liquid ratio of 1:10 g·ml^(-1),hydrothermal temperature of 110℃,hydrothermal time of 9 h,and CTAB amount of 1 g(per 100 ml solution).The adsorption capacities of the zeolitic material reached 329.67,424.69,and 542.22 mg·g^(-1) when the pH values of aqueous solution were 5,6,and 7,respectively.The Pb^(2+)removal efficiency can reach more than 99%in aqueous solution with the initial concentrations of 100-300 mg·L^(-1) under pH 6 and suitable adsorbent dosage.The adsorption and kinetics of Pb^(2+)on the zeolitic material can be described by Langmuir isotherm and pseudo-second-order kinetic models,respectively.The ion exchange between Pb^(2+)and Na^(+)and chemisorption are the main adsorption mechanism.All these findings imply that the synthesis of low-cost adsorbent for Pb^(2+)removal from weak acid and neutral aqueous solution provides a highly effective method to utilize CFBFA.

Optimization of the Internal Circulating Fluidized Bed Using Computational Fluid Dynamics Technology

The computational fluid dynamics(CFD)technology is analyzed and calculated utilizing the turbulence model and multiphase flow model to explore the performance of internal circulating fluidized beds(ICFB)based on CFD.The three-dimensional simulation method can study the hydrodynamic properties of the ICFB,and the performance of the fluidized bed is optimized.The fluidization performance of the ICFB is improved through the experimental study of the cross-shaped baffle.Then,through the cross-shaped baffle and funnel-shaped baffle placement,the fluidized bed reaches a coupled optimization.The results show that CFD simulation technology can effectively improve the mass transfer efficiency and performance of sewage treatment.The base gap crossshaped baffle can improve the hydraulic conditions of the fluidized bed and reduce the system energy consumption.The cross-shaped baffle and funnel-shaped baffle can perfect the performance of the reactor and effectively strengthen the treatment in the intense aerobic process of industrial sewage.

Numerical simulations and comparative analysis of two- and three-dimensional circulating fluidized bed reactors for CO2 capture

Carbon dioxide(CO2),the main gas emitted from fossil burning,is the primary contributor to global warming.Circulating fluidized bed reactor(CFBR)is proved as an energy-efficient method for post-combustion CO2 capture.The numerical simulation by computational fluid dynamics(CFD)is believed as a promising tool to study CO2 adsorption process in CFBR.Although three-dimensional(3D)simulations were proved to have better predicting performance with the experimental results,two-dimensional(2D)simulations have been widely reported for qualitative and quantitative studies on gas-solid behavior in CFBR for its higher computational efficiency recently.However,the discrepancies between 2D and 3D simulations have rarely been evaluated by detailed study.Considering that the differences between the 2D and 3D simulations will vary substantially with the changes of independent operating conditions,it is beneficial to lower computational costs to clarify the effects of dimensionality on the numerical CO2 adsorption runs under various operating conditions.In this work,the comparative analysis for CO2 adsorption in 2D and 3D simulations was conducted to enlighten the effects of dimensionality on the hydrodynamics and reaction behaviors,in which the separation rate,species distribution and hydrodynamic characteristics were comparatively studied for both model frames.With both accuracy and computational costs considered,the viable suggestions were provided in selecting appropriate model frame for the studies on optimization of operating conditions,which directly affect the capture and energy efficiencies of cyclic CO2 capture process in CFBR.

Model prediction of the operating behavior of a circulating fluidized bed boiler

An improved mathematical model for a circulating fluidized bed (CFB) boiler based on the model developed earlier by the authors was applied to simulate the operation of a 12 MW CFB boiler. The influences of the excess air ratio, primary air ratio, coal particle size distribution, coal properties (ash content and volatile content) and Ca/S ratio on the boiler operation were analyzed. The results showed that the model simulation may be applied to the optimum design and economic operation of the CFB boiler.

基于TF-NGO算法的CFB锅炉床温系统建模研究

床温是循环流化床(CFB)锅炉重要的运行参数之一。针对床温耦合性强、干扰因素多、控制复杂的问题,亟需建立床温的数学模型,以实现床温控制,从而保证CFB锅炉安全、平稳地运行。为此,首先引入了混沌映射、切线飞行(TF)和柯西变异策略改进北方苍鹰优化(NGO)算法,并用实际工况的系统模型测试TF-NGO算法。测试结果表明,TF-NGO算法拥有更快的收敛速度和更高的寻优精度。其次,采集并预处理山西某电厂350 MW超临界CFB锅炉的现场运行数据。最后,采用TF-NGO算法对所建模型的参数进行辨识,并用实际工况数据进行模型验证。辨识和验证结果表明,由TF-NGO算法辨识的床温模型与实际输出拟合度高,能有效反映床温的动态特性,证明所建模型的有效性。该研究为后续对350 MW超临界CFB锅炉床温的优化控制研究奠定了基础。

低负荷下CFB锅炉二次风优化对NO_(x)排放影响的数值模拟

为控制循环流化床(circulating fluidized bed,CFB)锅炉低负荷下NO_(x)的原始排放,以某350 MW超临界CFB锅炉为研究对象,基于计算颗粒流体力学(computational particle fluid dynamics,CPFD)方法对40%负荷下燃烧过程进行数值模拟。分析了不同二次风角度、新增二次风量对NO_(x)排放的影响。结果表明:随着射流角度的减小,炉膛出口NO浓度逐渐降低,CO浓度无明显增加。部分二次风上移后炉膛密相区氧浓度降低,不完全燃烧增加,还原性氛围增强,抑制了NO的生成。当新增风量从10%增加到30%时,NO排放浓度降低了17.2%。但随着比例的进一步提高,炉膛密相区的缺氧环境造成燃烧效率下降,温度大幅降低。因此,在不影响燃烧的前提下可以通过提高新增二次风比例来降低NO的原始排放浓度。

Combustion characteristics of low-quality lignite for different bed material sphericities in a circulating fluidized bed boiler:A numerical study

This study delves into the combustion behavior of various lignite types within a circulating fluidized bed boiler(CFBB),with a primary focus on the impact of different bed material sphericity ratios(0.5,0.7,and 0.9).Utilizing bed material with a sphericity ratio of 0.9 sourced from theÇan power plant and verified through experimentation,the research reveals several key findings.Notably,furnace temperatures tended to rise with higher sphericity ratios,albeit with variations between lignite types,particularly highlighting the complexity of this relationship in the case of GLI-Tunçbilek lignite.Pressure levels in the combustion chamber remained consistent across different sphericity ratios,indicating minimal influence on pressure dynamics.Improved combustion efficiency,especially at the bottom of the boiler,was observed at lower sphericity levels(0.5 and 0.7)forÇan lignite,as reflected in CO_(2) mole fractions.While NO_(x) emissions generally decreased with lower sphericity,the sensitivity to sphericity varied by lignite type,with Ilgın lignite showcasing low NO_(x) but high SO_(2) emissions,underscoring the intricate interplay between lignite properties,sphericity,and emissions.Overall,this study advances our understanding of CFBB combustion dynamics,offering insights valuable for optimizing performance and emissions control,particularly in lignite-based power.

循环流化床锅炉(CFB)系统流程模拟

以某石化项目450 t/h超高压循环流化床锅炉系统为对象,采用Thermoflex软件建模并对其进行变工况分析,通过与锅炉厂提供的实际数据进行对比,验证了该流程模拟的准确性。利用该模型进行了不同煤种工况对系统的影响因素分析,研究结果可为该锅炉系统设计和设备选型提供理论依据,对该项目动力站实际生产运行提供指导。

探讨CFB锅炉结焦事故原因和应对措施

循环流化床锅炉在实际生产中,因锅炉煤炭燃烧、物料流化不良、风帽大面积损坏、操作控制不当等各种原因,导致锅炉出现结焦,严重影响设备安稳运行。通过对锅炉结焦原因和案例分析,进行技术改造和参数优化,加强日常管理,避免了锅炉结焦事故,确保了装置长周期运行。

Desulfurization characteristics of slaked lime and regulation optimization of circulating fluidized bed flue gas desulfurization process--A combined experimental and numerical simulation study

Circulating fluidized bed flue gas desulfurization(CFB-FGD) process has been widely applied in recent years. However, high cost caused by the use of high-quality slaked lime and difficult operation due to the complex flow field are two issues which have received great attention. Accordingly, a laboratory-scale fluidized bed reactor was constructed to investigate the effects of physical properties and external conditions on desulfurization performance of slaked lime, and the conclusions were tried out in an industrial-scale CFB-FGD tower. After that, a numerical model of the tower was established based on computational particle fluid dynamics(CPFD) and two-film theory. After comparison and validation with actual operation data, the effects of operating parameters on gas-solid distribution and desulfurization characteristics were investigated. The results of experiments and industrial trials showed that the use of slaked lime with a calcium hydroxide content of approximately 80% and particle size greater than 40 μm could significantly reduce the cost of desulfurizer. Simulation results showed that the flow field in the desulfurization tower was skewed under the influence of circulating ash. We obtained optimal operating conditions of 7.5 kg·s^(-1)for the atomized water flow, 70 kg·s^(-1)for circulating ash flow, and 0.56 kg·s^(-1)for slaked lime flow, with desulfurization efficiency reaching 98.19% and the exit flue gas meeting the ultraclean emission and safety requirements. All parameters selected in the simulation were based on engineering examples and had certain application reference significance.

基于ISO-PSO的350 MW超临界CFB锅炉主汽温建模研究

针对火电厂目前主蒸汽温度数学模型不准确、不能有效地反应实际生产过程、辨识结果偏差较大等问题,使用学习因子动态调整及随机惯性权重策略改进的二阶振荡粒子群优化(ISO-PSO)算法进行建模。首先,采用学习因子动态调整、随机惯性权重策略对二阶振荡粒子群算法进行改善。测试结果表明,改进算法拥有更好的收敛速度及寻优精度。其次,处理山西某电厂350 MW超临界循环流化床(CFB)锅炉在300 MW工况下采集到的主蒸汽温度数据。最后,对比ISO-PSO算法和粒子群优化(PSO)算法。辨识结果及验证结果表明,ISO-PSO算法辨识的主蒸汽温度模型与实际输出的拟合度更高,能够更加准确、快速地反映主蒸汽温度的变化。所建立的主蒸汽温度模型可以及时跟踪实际曲线。该研究为后续350 MW超临界CFB锅炉主蒸汽温度优化控制研究奠定了良好的基础。

基于改进差分进化算法的CFB锅炉主蒸汽压力建模

建立准确的主蒸汽压力数学模型对提升循环流化床(CFB)锅炉主蒸汽压力控制系统性能有着实际意义。受现场条件制约,近年来基于数据驱动的闭环建模已趋于实用化。针对模型参数辨识过程寻优速度和精度指标,提出一种引入两个权重系数的改进差分进化(IDE)算法。与传统差分进化算法相比,改进后的算法在模型参数辨识过程中的寻优速度和精度均有提升,辨识所得模型更加准确。该结果证明了改进后算法的稳定性。通过采集山西某电厂350 MW超临界CFB锅炉现场的实际运行数据并进行预处理,将燃料量和汽机阀门开度同时作为输入、主蒸汽压力作为输出,并利用IDE算法寻优得到主蒸汽压力的最佳模型参数。对比结果表明,模型有着更高的拟合度。该研究对350 MW超临界CFB锅炉主蒸汽压力优化控制有一定的指导意义。

CFB中基于赤泥催化的N_(2)O/NO_(x)/SO_(2)协同降低技术路线

随着污染物排放标准越发严格,为进一步发挥循环流化床污染物控制成本低的优势,需要明晰各个运行参数和因素对N_(2)O/NO_(x)/SO_(2)排放的影响规律,挖掘N_(2)O/NO_(x)/SO_(2)协同超低排放的可能性。基于“十四五”规划的要求和N_(2)O/NO_(x)/SO_(2)的研究现状,初步形成了一条或实现N_(2)O/NO_(x)/SO_(2)协同降低的技术路线:在保证燃烧效率的前提下,选择合适的床料(如赤泥)在炉内通过催化或反应脱除N_(2)O,通过平衡赤泥中的铝铁比例,实现N_(2)O和NO_(x)的双低排放,同时由于赤泥良好的吸附能力和较强的碱性,可进一步实现SO_(2)的脱除。如必要,通过流态重构或超细石灰石等将剩余的NO_(x)和SO_(2)降至合理水平,或通过SNCR和脱硫塔分别处理剩余的NO_(x)和SO_(2),使其达到排放标准,从而实现N_(2)O/NO_(x)/SO_(2)的协同超低排放。

Modeling of gas-solid flow in a CFB riser based on computational particle fluid dynamics

A three-dimensional model for gas-solid flow in a circulating fluidized bed（CFB） riser was developed based on computational particle fluid dynamics（CPFD）.The model was used to simulate the gas-solid flow behavior inside a circulating fluidized bed riser operating at various superficial gas velocities and solids mass fluxes in two fluidization regimes,a dilute phase transport（DPT） regime and a fast fluidization（FF） regime.The simulation results were evaluated based on comparison with experimental data of solids velocity and holdup,obtained from non-invasive automated radioactive particle tracking and gamma-ray tomography techniques,respectively.The agreement of the predicted solids velocity and holdup with experimental data validated the CPFD model for the CFB riser.The model predicted the main features of the gas-solid flows in the two regimes;the uniform dilute phase in the DPT regime,and the coexistence of the dilute phase in the upper region and the dense phase in the lower region in the FF regime.The clustering and solids back mixing in the FF regime were stronger than those in the DPT regime.

Comparison of Fully 3-D,Simplified 3-D and 2-D Numerical Simulations on a Circulating Fluidized Bed Boiler

Based on the fully three-dimensional(3-D)and two-dimensional(2-D)comprehensive CFD(Computational Fluid Dynamics)combustion models for a circulating fluidized bed boiler,a simplified 3-D computational domain considering the corrections of furnace side wall openings is proposed.It aims to compensate for the deficiencies of the large amount of computation in the fully 3-D model and improve the air and gas flow treatments at the openings in the simplified 2-D model.Three different computational domains,named as the fully 3-D model,simplified 3-D model and 2-D model,were implemented to perform a comparative CFD analysis in an ultra-supercritical circulating fluidized bed boiler including the hydrodynamics,penetration depth of secondary air,temperature and species distribution.The simulation results computed by the simplified3-D model yield better agreement with the fully 3-D simulation results than those of the 2-D model.The simplified 3-D model is recommended as an alternative computational domain for the conventional 2-D model in the numerical simulation of large-scale circulating fluidized bed boiler.

火电厂CFB锅炉的燃烧技术优化对策

火电厂CFB锅炉是近些年被快速推广应用的全新燃烧技术之一,能够实现多次的低温燃烧,同时可以循环应用脱硫剂实施脱硫,从而大大提升脱硫效率(可以达到90%),整体燃烧效率与传统煤粉炉大体相当。近些年我国对绿色环保日益重视,针对氮氧化物的排放制定了更高的标准。虽然CFB锅炉可以一定程度上实现低氮燃烧,但是为了有效满足当今超低污染物排放的要求,需要对其进一步进行技术改造优化。以某发电厂2×300 MW的CFB锅炉为例,阐述其技术优化的内容,同时比对分析锅炉的燃烧效率,结果表明,技术优化后,锅炉的燃烧效率明显提升,同时大大了降低氮氧化物的排放量,对于进一步推动火电厂实现绿色环保发展具有参考意义。

解开CFB锅炉惯性产生之谜:一种全回路动态模型方法

“双碳”目标背景下,循环流化床机组亟需加快变负荷速率,而目前尚缺乏对变负荷过程中惯性生成机理的准确阐释。基于质量平衡、能量平衡、化学反应平衡,并考虑气固流动特性的差异,构建了炉侧全回路动态模型,以描述变负荷过程中流动、传热、燃烧的物理机制。模型应用于一台135 MW循环流化床锅炉机组进行验证,结果表明该模型能较为准确地预测稳态、变负荷工况的运行参数,相对误差不超过3%。探讨了锅炉的固有动态响应特性,揭示了变负荷过程中三大惯性的耦合机制,确立了流动惯性的主导地位,为提出加快变负荷速率的策略奠定基础。