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可持续场地倡议(SITES)评价体系在中国城市绿地建设中的研究进展及适用性讨论
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作者 林广思 朱欣 贺肖淇 《广东园林》 2024年第2期2-6,共5页
建设可持续的城市绿地是风景园林行业实现可持续发展的重要途径。然而,中国目前缺乏指导可持续景观建设的标准体系。可持续场地倡议(SITES)体系的提出和引入为国内相关研究提供了新的切入点。以SITES评价体系为研究对象,概述其起源、主... 建设可持续的城市绿地是风景园林行业实现可持续发展的重要途径。然而,中国目前缺乏指导可持续景观建设的标准体系。可持续场地倡议(SITES)体系的提出和引入为国内相关研究提供了新的切入点。以SITES评价体系为研究对象,概述其起源、主要内容等,明确其在城市绿地项目建设中的应用价值,全面总结了SITES评价体系在国内研究与应用方面的进展,同时深入探讨了其在中国城市绿地建设中的适用性和局限性。SITES在关注“场地”尺度、覆盖全生命周期、设置“门槛”条件以及全球统一标准等方面展现了较强的适用性,然而,在实际应用于中国城市绿地项目时存在一定的局限性,包括SITES标准与国内标准规范的不匹配,分值权重的失衡,缺乏政府相关福利政策支持和推广受限制等问题。 展开更多
关键词 城市绿地 可持续景观 可持续场地倡议(siteS) 景观绩效
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What Is the Evidence Supporting the Use of Surgical Face Masks in the Operating Room in Preventing Surgical Site Infection after Clean Surgery? A Systematic Review
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作者 Priscilla O. Aikabeli 《Open Journal of Nursing》 2021年第10期847-870,共24页
<strong>Background:</strong> Facemask is an essential component of the surgical outfit adorned by operating room staff to filter microorganisms by droplets from the oral and nasopharynx of the personnel, t... <strong>Background:</strong> Facemask is an essential component of the surgical outfit adorned by operating room staff to filter microorganisms by droplets from the oral and nasopharynx of the personnel, thereby reducing contamination, protecting the patient’s wound and minimising the risk of Surgical Site Infections (SSI). <strong>Objective: </strong>The objective of this review was to explore the available evidence and provide a better understanding of the effect of a surgical facemask in preventing SSI in clean surgery performed in the operating room. <strong>Data sources: </strong>Key electronic databases related to nursing, allied health, life science, biomedicine and research were searched for published literature on the use of facemask in the operating room. <strong>Methodology:</strong> A systematic review of quantitative research studies of randomised controlled trials was conducted with a meta-analysis of the results. <strong>Results: </strong>No variation in the rate of infection between the two (masked and unmasked) groups. <strong>Conclusion: </strong>The effect of facemask in minimising SSI after clean surgery remains questionable due to the limited results. More comprehensive research is needed. 展开更多
关键词 Operating Room Operating Theatre Facemask clean Surgery Surgical site Infection
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Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO_(2) Reduction 被引量:2
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作者 Kangwang Wang Zhuofeng Hu +8 位作者 Peifeng Yu Alina M.Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期68-84,共17页
We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in... We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in S_(v)–In_(2)S_(3)@2H–MoTe_(2).The X-ray absorption near-edge structure shows that the formation of S_(v)–In_(2)S_(3)@2H–MoTe_(2) adjusts the coordination environment via interface engineering and forms Mo–S polarized sites at the interface.The interfacial dynamics and catalytic behavior are clearly revealed by ultrafast femtosecond transient absorption,time-resolved,and in situ diffuse reflectance–Infrared Fourier transform spectroscopy.A tunable electronic structure through steric interaction of Mo–S bridging bonds induces a 1.7-fold enhancement in S_(v)–In_(2)S_(3)@2H–MoTe_(2)(5)photogenerated carrier concentration relative to pristine S_(v)–In_(2)S_(3).Benefiting from lower carrier transport activation energy,an internal quantum efficiency of 94.01%at 380 nm was used for photocatalytic CO_(2)RR.This study proposes a new strategy to design photocatalyst through bridging sites to adjust the selectivity of photocatalytic CO_(2)RR. 展开更多
关键词 Quantum efficiency Electronic structure Steric interaction Bridging sites CO_(2)reduction
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Experimental investigation on coal pore-fracture variation and fractal characteristics synergistically affected by solvents for improving clean gas extraction 被引量:1
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作者 Feilin Han Sheng Xue +3 位作者 Chunshan Zheng Zhongwei Chen Guofu Li Bingyou Jiang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第3期413-425,共13页
Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal... Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal synergistically affected by solvents have not been fully understood.Ultrasonic testing,nuclear magnetic resonance analysis,liquid phase mass spectrometry was adopted to comprehensively analyze pore-fracture change characteristics of lean coal treated by combined solvent(NMP and CS_(2)).Meanwhile,quantitative characterization of above changing properties was conducted using geometric fractal theory.Relationship model between permeability,fractal dimension and porosity were established.Results indicate that the end face fractures of coal are well developed after CS2and combined solvent treatments,of which,end face box-counting fractal dimensions range from 1.1227 to 1.4767.Maximum decreases in ultrasonic longitudinal wave velocity of coal affected by NMP,CS_(2)and combined solvent are 2.700%,20.521%,22.454%,respectively.Solvent treatments could lead to increasing amount of both mesopores and macropores.Decrease ratio of fractal dimension Dsis 0.259%–2.159%,while permeability increases ratio of NMR ranges from 0.1904 to 6.4486.Meanwhile,combined solvent could dissolve coal polar and non-polar small molecules and expand flow space.Results could provide reference for solvent selection and parameter optimization of permeability-enhancement technology. 展开更多
关键词 clean gas extraction Chemical solvent Experimental investigation Fractal characteristics Pore fracture
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关于*r-clean环
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作者 覃健 应志领 周华 《华东师范大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第2期30-32,共3页
称对合环为*r-clean环是指环中任一元素都可表示为投射子和*-正则元的和.研究了该环的一些扩张性质,并给出了*-阿贝尔的*r-clean环中元素的刻画.
关键词 *r-clean *-clean *-正则环
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A comprehensive review of lunar lava tube base construction and field research on a potential Earth test site 被引量:1
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作者 Yujie Feng Peng-Zhi Pan +3 位作者 Xuhai Tang Zhaofeng Wang Yuxin Li Altaf Hussain 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1201-1216,共16页
The Moon,as the closest celestial body to the Earth,plays a pivotal role in the progression of deep space exploration,and the establishment of research outposts on its surface represents a crucial step in this mission... The Moon,as the closest celestial body to the Earth,plays a pivotal role in the progression of deep space exploration,and the establishment of research outposts on its surface represents a crucial step in this mission.Lunar lava tubes are special underground caves formed by volcanic eruptions and are considered as ideal natural shelters and scientific laboratories for lunar base construction.This paper begins with an in-depth overview of the geological origins,exploration history,and distribution locations of lunar lava tubes.Subsequently,it delves into the presentation of four distinctive advantages and typical concepts for constructing bases within lava tubes,summarizing the ground-based attempts made thus far in lunar lava tube base construction.Field studies conducted on a lava tube in Hainan revealed rock compositions similar to those found during the Apollo missions and clear lava tube structures,making it a promising analog site.Lastly,the challenges and opportunities encountered in the field of geotechnical engineering regarding the establishment of lunar lava tube bases are discussed,encompassing cave exploration technologies,in-situ testing methods,geomechanical properties under lunar extreme environments,base design and structural stability assessment,excavation and reinforcement techniques,and simulated Earth-based lava tube base. 展开更多
关键词 Lunar lava tube Lunar base construction Extraterrestrial cave exploration Earth analog site
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英语强化词Clean的语法化研究
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作者 程美君 张宏国 《现代语言学》 2024年第9期553-560,共8页
本文以英语强化词“clean”为研究对象,进行语法化的历时演变个案研究。研究基于《牛津英语词典》以及美国历史英语语料库中的语料,分析了强化词“clean”的语法化演变路径、演变机制和动因。研究最后得出结论,“clean”经历了实义形容... 本文以英语强化词“clean”为研究对象,进行语法化的历时演变个案研究。研究基于《牛津英语词典》以及美国历史英语语料库中的语料,分析了强化词“clean”的语法化演变路径、演变机制和动因。研究最后得出结论,“clean”经历了实义形容词到低强化副词再到高强化副词的语法化演变路径,主要分为两个阶段;其演变过程中主要体现了隐喻转喻与主观化两大演变机制,动因主要是语义泛化和效率性动因,并且机制和动因充分体现了人类作为语言使用者的主体性特征。该研究在一定程度上丰富了英语强化词语法化的个案研究,具有一定的参考价值和意义。This paper focuses on the English intensifier “clean”, presenting a case study for its grammaticalization. Based on the Old English Dictionary and the Corpus of Historical American English, the study analyzes the evolutionary path, mechanism and motivation of the grammaticalization of “clean”. The study concludes that with two stages, the evolutionary path is from notional adjective to low-intensive functional adverb, and then to high-intensive functional adverb. Metaphor and metonymy as well as subjectivity are the main mechanisms, while semantic generalization and efficiency factor serve as motivations. Both the mechanism and the motivation demonstrate the predominant role of human beings. This study, to some degree, enriches the case study of the grammaticalization of English intensifiers, with some reference value and significance. 展开更多
关键词 强化词 clean 语法化 机制 动因
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Asymmetric Zn-N_4 atomic sites embedded hollow fibers as stable Zn anode for high-performance Zn-ion hybrid capacitor
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作者 Yukun Liu Bing Li +5 位作者 Jin Wang Caiyun Li Hongrui Yang Yang Song Sen Zhang Chao Deng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期460-469,I0009,共11页
Zn based electrochemical energy storage systems(EES)have attracted tremendous interests owing to their low cost and high intrinsic safety.Nevertheless,the uncontrolled growth of Zn dendrites and the side reactions of ... Zn based electrochemical energy storage systems(EES)have attracted tremendous interests owing to their low cost and high intrinsic safety.Nevertheless,the uncontrolled growth of Zn dendrites and the side reactions of Zn metal anodes(ZMAs)severely restrict their applications.To address these issues,we design the asymmetric Zn-N_(4) atomic sites embedded hollow fibers(AS-IHF)as the flexible host for stable ZMAs.Through introducing different nitrogen resources in the synthesis,two kinds of coordination,i,e.Zn-N(pyridinic)and Zn-N(pyrrolic),are introduced in the Zn-N_(4) atomic module synchronously.The asymmetric Zn-N_(4) module with regulated micro-environment facilitates the superior zincophilic features and promotes the Zn adsorption.Meanwhile,the highly porous structure of the hollow fiber effectively reduces local current density,homogenize Zn ion flux,and alleviate structure stress.All the advantages endow the high efficiency and good stability for Zn plating/stripping.Both theoretical and experimental results demonstrate the high reversibility,low nucleation overpotential,and dendritefree behavior of the AS-IHF@Zn anode,which afford the high stability in high-rate and long-term cycling.Moreover,the solid-state Zn-ion hybrid capacitor(ZIHC)based on AS-IHF@Zn anode shows the high flexibility,reliability,and superior long-term cycling capability in a wide-range of temperatures(-20-25℃).Therefore,the present work not only gives a new strategy for modulating local environments of single atomic sites,but also propels the development of flexible power sources for diverse electronics. 展开更多
关键词 Asymmetric coordination Single atomic sites Zincophilic sites Dendrite free behavior Zn-ion hybrid capacitor
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d-Orbital steered FeN_(4)moiety through N,S dual-site adjustation for zinc-air flow battery
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作者 Chunzhu Bao Mingwei Tong +1 位作者 Xueli Li Zhonghua Xiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期8-15,共8页
The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in s... The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in synergistically regulating their electronic states and structural porosity for the great device performance.Here,we conquer these issues by exploiting N and S co-doped graphene with COP rich in metal-ligand nitrogen to synergistically construct an effective catalyst for oxygen reduction reaction(ORR).Among them,the N and S co-doped sites with high electronegativity properties alter the number of electron occupations in the d orbital of the iron centre and form electron-transfer bridges,thereby boosting the selectivity of the ORR-catalysed four-electron pathway.Meanwhile,the introduction of COP materials aids the formation of pore interstices in the graphene lamellae,which both adequately expose the active sites and facilitate the transport of reactive substances.Benefiting from the synergistic effect,as-prepared catalyst exhibits excellent half-wave potentials(E_(1/2)=912 mV)and stability(merely 8.8%drop after a long-term durability test of 50000 s).Further,ZAFBs assembled with the N/SG@CO_(2)P catalyst demonstrate exceptional power density(163.8 mW cm^(-2))and continuous charge and discharge for approximately 140 h at 10 mA cm^(-2),outperforming the noble-metal benchmarks. 展开更多
关键词 Nitrogen/sulfurdual sites Metal-coordinated nitrogen sites Covalent organic polymer Oxygen reduction reaction Zn-airflow battery
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Surface activity and cleaning performance of rosin-based quaternary ammonium salt type asymmetric Gemini surfactants
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作者 Haoyu Feng Yaoqi Pan +4 位作者 Yijia Zhang Zhuofan Zhang Yunye Huang Linxi Hou Longqiang Xiao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第9期70-80,共11页
Rosin,a renewable and abundant resource,has been extensively processed and chemically modified to endow it with special properties,especially in the surfactant industry.In this study,four rosin-based quaternary ammoni... Rosin,a renewable and abundant resource,has been extensively processed and chemically modified to endow it with special properties,especially in the surfactant industry.In this study,four rosin-based quaternary ammonium asymmetric gemini surfactants(RGS-2-n)with different alkyl chain lengths(n=12,14,16,18)were synthesized using a simple two-step method based on dehydroabietylamine as the raw material.The feasibility of these surfactants for cleaning purposes was comprehensively evaluated,suggesting that the surfactants own high surface activity and good cleaning performance.Furthermore,by successfully introducing the amine group of dehydroabietylamine into the hydrophilic group of the surfactants,we avoided its potential harm to the environment and water pollution.Density functional theory proves rosin-based gemini surfactants with asymmetric structure can further improve cleaning efficiency.Overall,our findings suggests that RGS-2-n surfactants are promising and sustainable candidates for cleaning electric plates,and provide new opportunities for rosin application in the electric industry. 展开更多
关键词 Electronic components Asymmetric gemini surfactants cleaning performance ROSIN
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Comparison of bone artifacts from the Schöningen site in Germany and the Lingjing site in China
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作者 WANG Hua LI Zhanyang Thijs van KOLFSCHOTEN 《人类学学报》 CSSCI CSCD 北大核心 2024年第2期214-232,共19页
Similarities play an important role in the reconstruction of human physical,cultural and technological evolution.The two sites presented in this paper,the Middle Palaeolithic site Lingjing in China Layer 10 and 11 and... Similarities play an important role in the reconstruction of human physical,cultural and technological evolution.The two sites presented in this paper,the Middle Palaeolithic site Lingjing in China Layer 10 and 11 and the Lower Palaeolithic site Schöningen 13Ⅱ-4,the socalled Schöningen Spear Horizon in Germany,show striking similarities.The archaeological record of both sites includes lithic artifacts as well as a very large assemblage of fossil bones.The preservation of the material at both sites is excellent and the faunas encountered at both sites show many similarities.The faunal lists of both sites include a diverse carnivore guild,an elephant species,two different rhinoceros species,two different equids,different cervids and large bovids.Both sites also yielded bone retouchers as well as a unique record of bone hammers that show identical,unusual flaking and percussion damage.These similarities are remarkable if one takes into account the difference in age(ca 200 kaBP)and the geographical distance between the two sites of ca 8000 km.Therefore,we do not assume a close cultural link between the hominin populations active at both sites.The authors assume that the observed similarities show more or less identical,opportunistic hominin behaviour at both sites located in a comparable environment with more or less similar taphonomic conditions. 展开更多
关键词 PALAEOLITHIC open-air sites bone tools Asia EUROPE
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Assessing the Spatial Equality of COVID Testing Sites Maintaining Zero COVID Policy
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作者 Muhammad Sajid Mehmood Gang Li +3 位作者 Shiyan Zhai Yaochen Qin Annan Jin Lan Li 《Journal of Geographic Information System》 2024年第3期183-200,共18页
Rapid and timely testing is essential to minimize the COVID-19 spread. Decision makers and policy planners need to determine the equal distribution and accessibility of testing sites. This study mainly examines the sp... Rapid and timely testing is essential to minimize the COVID-19 spread. Decision makers and policy planners need to determine the equal distribution and accessibility of testing sites. This study mainly examines the spatial equality of COVID-19 testing sites that maintain a zero COVID policy in Guangzhou City. The study has identified the spatial disparities of COVID testing sites, characteristics of testing locations, and accessibility. The study has obtained information on COVID testing sites in Guangzhou City and population data. Point pattern analyses, Euclidian distance and allocation, and network analyses are the main methods used to achieve the research objectives, and 1183 total COVID testing sites can be recognized in Guangzhou City. Results revealed that spatial disparities could be noticed over the study area. Testing locations of Guangzhou City are highly clustered. The most significant testing sites are located in Haizhu District, which has the third largest population. The highest population density can be identified in Yuexiu District. However, only 94 testing sites are located there. According to all the results, higher disparities can be identified, and a lack of testing sites is located in the north part of the study area. Some people in the northern part have to travel more than 10 km to reach a testing site. Finally, this paper suggests increasing the number of testing sites in the north and south parts of the study area and keeping the same distribution, considering the area, total population, and population density. This kind of research will be helpful to decision-makers in making proper decisions to maintain a zero COVID policy. 展开更多
关键词 COVID-19 Testing sites Spatial Disparities Spatial Equality Guangzhou City ACCESSIBILITY
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Cleaning of two mirrors in the first mirror unit using radiofrequency capacitively coupled plasma
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作者 Chenxue WANG Rong YAN +5 位作者 Yuming LIU Su XU Lei MU Wei ZHENG Rui DING Junling CHEN 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第9期165-171,共7页
First mirror(FM)cleaning,using radio frequency(RF)plasma,has been proposed to recover FM reflectivity in nuclear fusion reactors such as the International Thermonuclear Experimental Reactor(ITER).To investigate the in... First mirror(FM)cleaning,using radio frequency(RF)plasma,has been proposed to recover FM reflectivity in nuclear fusion reactors such as the International Thermonuclear Experimental Reactor(ITER).To investigate the influence of simultaneous cleaning of two mirrors on mirror cleaning efficiency and uniformity,experiments involving single-mirror cleaning and dual-mirror cleaning were conducted using RF capacitively coupled plasma in the laboratory.For the test and simultaneous cleaning of two mirrors,the FM and second mirror(SM),both measuring 110 mm×80 mm,were placed inside the first mirror unit(FMU).They were composed of 16 mirror samples,each with a dimension of 27.5 mm×20 mm.These mirror samples consist of a titanium-zirconium-molybdenum alloy substrate,a 500 nm Mo intermediate layer and a 30 nm Al_(2)O_(3) surface coating as a proxy for Be impurities.The cleaning of a single first mirror(SFM)and the simultaneous cleaning of the FM and SM(DFM and DSM)lasted for 9 h using Ar plasma at a pressure of 1 Pa.The total reflectivity of mirror samples on the DSM did not fully recover and varied with location,with a self-bias of−140 V.With a self-bias of−300 V,the total reflectivity of mirror samples on the SFM and DFM was fully recovered.The energy dispersive spectrometer results demonstrated that the Al_(2)O_(3) coating had been completely removed from these mirror samples.However,the mass loss of each mirror sample on the SFM and DFM before and after cleaning varied depending on its location,with higher mass loss observed for mirror samples located in the corners and lower loss for those in the center.Compared with SM cleaning,the simultaneous cleaning of two mirrors reduced the difference between the highest and lowest mass loss.Furthermore,this mass loss for the mirror samples of the DFM facing the DSM was increased.This indicated that mirror samples cleaned face to face in the FMU simultaneously could influence each other,highlighting the need for special attention in future studies. 展开更多
关键词 first mirror unit dual-mirror cleaning REFLECTIVITY sputtering rate
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Characteristics of Gold Mineralization at the Baguiomo Gold Panning Site, Koudougou Region, Burkina Faso, West Africa
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作者 Pascal Ouiya Aziz Fayçal Tarnagda Martial Eric Fozing 《Open Journal of Geology》 CAS 2024年第1期1-18,共18页
The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are ... The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are located in the Kwademen-Baguiomo shear zone. This mineralization, located only a few kilometers from the Kwademen gold deposit, is uncharacterized and, together with the latter, could constitute a gold potential capable of being economically exploitable. It is in this sense that this work is carried out with a view to characterizing the gold mineralization of the Baguiomo gold panning site. To carry out this work, we have made direct field measurements, combined with microstructures, and combined all this with data from geochemical rock analysis of the basalts that are the main host formations. Geochemical data show that tholeitic basalts formed from a mantle plume that was emplaced in an oceanic plateau context. Calc-alkaline basalts and andesites are comparable to Paleoproterozoic tholeitic basalts (PTH3), which are slightly enriched in light rare earths. Fertility tests show that these basalts concentrate between 3 and 6 ppb of gold at the time of accretion, which is sufficient for remobilization of this primary gold during the Eburnian orogeny to yield a deposit of around 4 - 5 Moz. Gold mineralization is associated with pyrite crystals when the latter are disseminated in the rock mass, whereas it is associated with hematite in quartz veins concordant with S1 shear deformation. It is mainly the pyrite crystals in the pressure shadows that contain the gold grains, whose development would be synchronous with micro-shear zone reactivation during the first phase of D1<sub>B</sub> deformation. The second phase of D2<sub>B</sub> deformation, which is a crenulation or fracture schistosity, does not significantly affect the shear deformation that controls mineralization. 展开更多
关键词 Kwademen-Baguiomo Shear Zone Gold Panning site Gold Mineralization Eburnian Orogeny
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Ni/ZSM-5 Catalysts for Light Olefin Oligomerization:Effects of Supports and Ni Sites on Activity and Selectivity
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作者 Zuo Qi Liang Ke +5 位作者 Ma Yirong Jia Yangxiao Liao Mingjie Zheng Jiajun Li Ruifeng Li Wenlin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第3期15-23,共9页
A series of Ni/ZSM-5 containing a small amount of Ni was prepared by an ion exchanged method.The impact of the n(SiO_(2))/n(Al_(2)O_(3))ratio on the catalytic activity was studied using the samples 0.09Ni/ZSM-5(60)and... A series of Ni/ZSM-5 containing a small amount of Ni was prepared by an ion exchanged method.The impact of the n(SiO_(2))/n(Al_(2)O_(3))ratio on the catalytic activity was studied using the samples 0.09Ni/ZSM-5(60)and 0.09Ni/ZSM-5(130).To determine the interaction between the Ni species and acid sites on the surface of the catalyst,the catalysts were characterized by N2 adsorption-desorption,X-ray diffraction(XRD),scanning electron microscopy(SEM),and UV-vis spectroscopy.The performance of the catalysts for the catalytic oligomerization of 1-hexene was investigated in detail.The nickel species were found to be uniformly distributed in all the catalysts.It was discovered that the oligomerization activity of the catalyst can be improved using Ni species;however,the contribution of Brønsted acids in oligomerization reactions is greater than that of Ni sites and Lewis acids. 展开更多
关键词 nickel ZEOLITE acid sites OLIGOMERIZATION catalyst
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New steelmaking process based on clean deoxidation technology
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作者 Zhongliang Wang Yanping Bao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第6期1249-1262,共14页
After the converter steelmaking process,a considerable number of ferroalloys are needed to remove dissolved oxygen from the molten steel,but it also forms a lot of oxide inclusions that cannot be completely removed.At... After the converter steelmaking process,a considerable number of ferroalloys are needed to remove dissolved oxygen from the molten steel,but it also forms a lot of oxide inclusions that cannot be completely removed.At the same time,it increases the carbon emis-sions in the steel production process.After years of research,our team have developed a series of clean deoxidation technologies,includ-ing carbon deoxidation,hydrogen deoxidation,and waste plastic deoxidation of molten steel to address the aforementioned issues.In this study,thermodynamic calculations and laboratory experiments were employed to verify that carbon and hydrogen can reduce the total oxygen content in the molten steel melt to below 5×10^(-6) and 10×10^(-6),respectively.An analysis of the deoxidation mechanisms and ef-fects of polyethylene and polypropylene was also conducted.In addition,the applications of carbon deoxidation technology in different steels with the hot-state experiment and industrial production were discussed carefully.The carbon deoxidation experimental results of different steels were as follows:(1)the oxygen content of bearing steel was effectively controlled at 6.3×10^(-6) and the inclusion number density was lowered by 74.73%compared to aluminum deoxidized bearing steel;(2)the oxygen content in gear steel was reduced to 7.7×10^(-6) and a 54.49%reduction of inclusion number density was achieved with almost no inclusions larger than 5μm from the average level of industry gear steels;(3)a total oxygen content of M2 high-speed steel was as low as 3.7×10^(-6).In industrial production practice,car-bon deoxidation technique was applied in the final deoxidation stage for non-aluminum deoxidized bearing steel,and it yielded excellent results that the oxygen content was reduced to below 8×10^(-6) and the oxide inclusions in the steel mainly consist of silicates,along with small amounts of spinel and calcium aluminate. 展开更多
关键词 clean deoxidation carbon deoxidation hydrogen deoxidation waste plastics deoxidation
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Hole cleaning evaluation and installation spacing optimization of cuttings bed remover in extended-reach drilling
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作者 Shuo Peng Wen-Jun Huang De-Li Gao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期2005-2022,共18页
In extended-reach or long-horizontal drilling,cuttings usually deposit at the bottom of the annulus.Once cuttings accumulate to a certain thickness,complex problems such as excessive torque and drag,tubing buckling,an... In extended-reach or long-horizontal drilling,cuttings usually deposit at the bottom of the annulus.Once cuttings accumulate to a certain thickness,complex problems such as excessive torque and drag,tubing buckling,and pipe stuck probably occur,which results in a lot of non-productive time and remedial operations.Cuttings bed remover can efficiently destroy deposited cuttings in time through hydraulic and mechanical stirring effects.This paper aims to build a method for hole cleaning evaluation and installation spacing optimization of cuttings bed remover to improve the wellbore cleaning effect.Firstly,a Computational Fluid Dynamics approach with Eulerian—Eulerian multiphase model was utilized to investigate the mechanism of cuttings transportation,and a new type of cuttings bed remover was designed.Next,an evaluation method of hole cleaning effect of remover was established.After that,the effects of several drilling parameters on hole cleaning including flow rate of drilling fluid,rotational speed of drillpipe,rate of penetration,wellbore size,rheological property of drilling fluid,and remover eccentricity on the performance of cuttings bed remover were investigated.The results demonstrate that the new type of remover with streamline blade performs better than conventional removers.The efficiency of hole cleaning is greatly improved by increasing the rotational speed of drillpipe,flow rate of drilling fluid,remover eccentricity,and 6 rpm Fann dial reading for drilling fluid.While higher rate of penetration and large wellbore size result in worse hole cleaning.These findings can serve as an important guide for the structure optimization design of cuttings bed remover and installation spacing of removers. 展开更多
关键词 Extended-reach drlling Drilling hydraulics Cuttings transport Hole cleaning Cuttings bed remover
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An Analysis of the Fragmentation of Observing Time At the Muztagh-Ata Site
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作者 Wen-Bo Gu Jing Xu +5 位作者 Guo-Jie Feng Xuan Zhang Le-Tian Wang Xin-Liang Wang Ali Esamdin Li-Xian Shen 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2024年第3期29-33,共5页
Cloud cover plays a pivotal role in assessing observational conditions for astronomical site-testing.Except for the fraction of observing time,its fragmentation also wields a significant influence on the quality of ni... Cloud cover plays a pivotal role in assessing observational conditions for astronomical site-testing.Except for the fraction of observing time,its fragmentation also wields a significant influence on the quality of nighttime sky clarity.In this article,we introduce the functionΓ∈[0,1],designed to comprehensively capture both the fraction of available observing time and its continuity.Leveraging in situ measurement data gathered at the Muztagh-Ata site between 2017 and 2021,we showcase the effectiveness of our approach.The statistical result illustrates that the Muztagh-Ata site affords approximately 122 nights that were absolutely clear and 205 very good nights annually,corresponding toΓ≥0.9 andΓ≥0.36 respectively. 展开更多
关键词 site testing-atmospheric effects-methods STATISTICAL
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Effects of synthetic site water on bentonite-concrete system for a potential nuclear waste repository
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作者 Zhao Sun Yong-Gui Chen +3 位作者 Wei-Min Ye Qiong Wang Dong-Bei Wu Zhen-Yu Yin 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第9期3786-3797,共12页
In high-level nuclear waste(HLW)repositories,concrete and compacted bentonite are designed to be employed as buffer materials,which may raise a problem of interactions between concrete and bentonite.These interactions... In high-level nuclear waste(HLW)repositories,concrete and compacted bentonite are designed to be employed as buffer materials,which may raise a problem of interactions between concrete and bentonite.These interactions would lead to mineralogy transformation and buffer performance decay of bentonite under the near field environment conditions in a repository.A small-scale experimental setup was established to simulate the concrete-bentonite-site water interaction system from a potential nuclear waste repository in China.Three types of mortars were prepared to correspond to the concrete at different degradation states.The results permit the determination of the following:(1)The macroproperties of Gaomiaozi(GMZ)bentonite(e.g.swelling pressure,permeability,the final dry density,and water content of reacted samples);(2)The composition evolution of fluids from the synthetic site water-concrete-bentonite interaction systems;(3)The sample characterization including Fourier transform infrared spectroscopy(FTIR)and X-ray powder diffraction(XRD).Under the infiltration of the synthesis Beishan site water(BSW),the swelling pressure of bentonite decreases slowly with time after reaching its second swelling peak.The flux decreases with time during the infiltrations,and it tends to be stable after more than 120 d.Due to the cation exchange reactions in the BSW-concrete-bentonite systems,the divalent cations(Ca and Mg)were consumed,and the monovalent cations(Na and K)were released.The dissolution of minerals in the bentonite such as albite causes Si increasing in the pore water.It was concluded that the hydro-mechanical property degradation of bentonite takes place when it comes into contact with concrete mortar,even under low-pH groundwater conditions.The soil dispersion,the uneven water content,and the uneven dry density in bentonite samples may partly contribute to the swelling decay of bentonite.Therefore,the direct contact with concrete has an obvious effect on the performance of bentonite. 展开更多
关键词 Mock-up device GMZ bentonite site water-concrete-bentonite system Geochemistry Buffer performance
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Brønsted-acid sites induced photocatalytic cracking of low-polarity polyethylene plastics
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作者 Qianyou Wen Quan Zhang +6 位作者 Zhengzheng Liu Huining Wang Shuya Hao Fan Zhang Lijuan Zhang Qing Han Gengfeng Zheng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期509-515,共7页
Polyolefins such as polyethylene(PE)are one of the largest-scale synthetic plastics and play a key role in modern society.However,polyethylene is extremely inert to chemical recycling owing to its lack of chemical fun... Polyolefins such as polyethylene(PE)are one of the largest-scale synthetic plastics and play a key role in modern society.However,polyethylene is extremely inert to chemical recycling owing to its lack of chemical functionality and low polarity,making it one of the most challenging environmental hazards globally.Herein,we developed a phosphorylated CeO_(2)catalyst by an organophosphate precursor and featured efficient photocatalysis of low-density polyethylene(LDPE)without the acid or alkaline pre-treatment.Compared to pristine CeO_(2),the surface phosphorylation allows to introduce Brønsted acid sites,which facilitate to form carbonium ions on LDPE via protonation.In addition,the suitable band structure of the phosphorylated CeO_(2)catalyst enables efficient photoabsorption and generates reactive oxygen species,leading to the C–C bond cleavage of LDPE.As a result,the phosphorylated CeO_(2)catalyst exhibited an outstanding carbon conversion rate of>94%after 48 h of photocatalysis under 50 mW/cm^(2)of simulated sunlight,with a high CO_(2)product selectivity of>99%.Furthermore,the PE microparticles with sizes larger than 10μm released from LDPE plastic wrap were directly and completely degraded by photocatalysis within 12 h,suggesting an attractive and environmentally benign strategy of utilizing solar energy-based photocatalysis for reducing potential hazards of LDPE plastic trashes. 展开更多
关键词 Photocatalytic cracking POLYETHYLENE Surface phosphorylation Bronsted-acid site Carbon conversion
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