Gas-Phase Deposited Plasmonic Nanoparticles Supported on 3D-Graphene/Nickel Foam for Highly SERS Detection

In this work, we proposed a novel three-dimensional (3D) plasmonic nanostructure based on porous graphene/nickel foam (GNF) and gas-phase deposited Ag nanoparticles (NPs). Ag NPs with high density were directly deposited on the surface of 3D GNF by performing a novel cluster beam deposition approach. In comparison with traditional Ag substrate (SiO2/Ag), such hot-spots enriched 3D nanostructure showed extremely high electromag-netic field enhancement under incident light irradiation which could be used as a sensitive chemical sensor based on surface enhanced Raman scattering (SERS). The experimental results demonstrated that the proposed nanostructure showed superior SERS performance in terms of Raman signal reproducibility and sensitivity for the probe molecules. 3D full-wave simulation showed that the enhanced SERS performance in this 3D hierarchical plasmonic nanostructure was mainly obtained from the hot-spots between Ag NPs and the near-field coupling between Ag NPs and GNF sca olds. This work can provide a novel assembled SERS substrate as a SERS-based chemical sensor in practical applications.

Palladium-Carbon Composite Nanoparticle Films with Enhanced Electrocatalytic Activity for Hydrogen Peroxide Sensors

A nanocomposite electrocatalyst was prepared with the method of cluster beam deposition of palladium nanoparticle thin lms on carbon nanoparticle supporting layers and used as sensitive nonenzyme hydrogen peroxide sensors. An enhancement on the electrocatalytic activity of the palladium nanoparticles toward H2O2 reduction was observed, which was related to the coverage of the carbon nanoparticles. With one monolayer of carbon nanoparticles, the H2O2 detection sensitivity reached the maximum, which was more than twice of that of the pure Pd nanoparticles.

Cryogenically Cooled High-Pressure Hydrogen Cluster Jet Injection into the HL-2A Tokamak

The experimental set-up of SMBI system in HL-2A and the detail structure of the molecular beam valve with cooling trap are shown in Fig.l. The valve used for producing hydrogen cluster jet is a solenoid valve S99 with a nozzle orifice of 0.2 mm diameter. The distance between the nozzle of the valve and the edge plasma is about 1.28 m. A liquid nitrogen cryogenic trap is applied for cooling the valve body and decreasing the working gas temperature. The hydrogen cluster jet used for the experiments is in fact a free jet. For real gases, the adiabatic expansion of gas through a nozzle into vacuum results in substantial cooling in the frame of the moving gas. Atoms or molecules that interact weakly at low temperature can form clusters as a result. Attractive forces between atoms can be hydrogen bonding,

Scaling up of cluster beam deposition technology for catalysis application

Many research works have demonstrated that the combination of atomically precise cluster deposition and theoretical calculations is able to address fundamental aspects of size-effects,cluster-support interactions,and reaction mechanisms of cluster materials.Although the wet chemistry method has been widely used to synthesize nanoparticles,the gas-phase synthesis and size-selected strategy was the only method to prepare supported metal clusters with precise numbers of atoms for a long time.However,the low throughput of the physical synthesis method has severely constrained its wider adoption for catalysis applications.In this review,we introduce the latest progress on three types of cluster source which have the most promising potential for scale-up,including sputtering gas aggregation source,pulsed microplasma cluster source,and matrix assembly cluster source.While the sputtering gas aggregation source is leading ahead with a production rate of~20 mg·h^(-1),the pulsed microplasma source has the smallest physical dimensions which makes it possible to compact multiple such devices into a small volume for multiplied production rate.The matrix assembly source has the shortest development history,but already show an impressive deposition rate of~10 mg·h^(-1).At the end of the review,the possible routes for further throughput scale-up are envisaged.

Design and experimental testing of a gas cluster ion accelerator

A gas cluster ion beam（GCIB） system with cluster energy up to 12 keV has been designed. To facilitate pumping of the nozzle chamber and increased pressure of the gas source up to 10 atm, pulse mode was used for the gas feeding. Argon was employed as the working gas. To separate monomers from clusters, both electromagnet and retarding electrode were utilized. A maximal pulsed cluster current of 90 nA has been achieved. The shape of pulsed ion beam currents has been analyzed in detail at different applied magnetic and retarding electric fields.