Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types...Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.展开更多
Coal sludge is a seriously polluted solid waste,and the rational utilization of its resources has long being an undoubtedly important research topic.This paper mainly studies the coal sludge partial preheating charact...Coal sludge is a seriously polluted solid waste,and the rational utilization of its resources has long being an undoubtedly important research topic.This paper mainly studies the coal sludge partial preheating characteristic,combustion characteristic and the process of migration and conversion of nitrogen with preheating combustion technology.The experimental results indicate that most of the elements in the coal sludge are released during preheating,and the ratio of the fuel-N converted to the N_(2),NH_(3) and HCN are 75.5%,6.74%and 0.64%,respectively.Compared with the coal sludge,the BET surface area and cumulative pore area of preheated char are increased.The surface of preheated char is loose and porous with many fine particles,while raw coal is dense with larger particles.Meantime,the quantity of carbon defect structure,the active sites and the reactivity of preheated char are all increased.In the whole process,the NO_(x) emission is about 156 mg/m3(@6%O2),the ratio of fuel-N converted to NO_(x) was 2.98%,and the combustion efficiency is 96.5%.This experiment results will play a vital role in efficient and clean utilization of coal sludge.展开更多
A test system was designed to study the parameters affecting the volumetric efficiency of a thick-material pump for coal slime.The parameters studied included solid concentration,the slenderness ratio of the suction c...A test system was designed to study the parameters affecting the volumetric efficiency of a thick-material pump for coal slime.The parameters studied included solid concentration,the slenderness ratio of the suction cylinder and the running speed of the hydraulic cylinder.In the experiment the concentrations of coal slime were 75.7%,76.3%,74.4%,73.5%,72.1%and 70.63%;the running speeds were 0.23,0.18,0.13,0.10 and 0.08 m/s;and the slenderness ratios of the suction cylinder were 1.63,2.26,2.88,3.50,4.13,4.78 and 5.38.The results show that the suction volumetric efficiency decreases gradually with an increase in material concentration.The critical concentration value is 72%;below 72%the suction volumetric efficiency is above 90%,otherwise it decreases rapidly.When the solid concentration reaches 76.3%,the suction volumetric efficiency is only 40%.When the running speed of the piston is less than or equal to 0.23 m/s,the suction volumetric efficiency increases with an increase in running speed.展开更多
The combustion of sewage sludge and coal was studied by thermogravimetric analysis.Both differential scanning calorimetric analysis and derivative thermogravimetric profiles showed differences between combustion of se...The combustion of sewage sludge and coal was studied by thermogravimetric analysis.Both differential scanning calorimetric analysis and derivative thermogravimetric profiles showed differences between combustion of sewage sludge and coal,and non-isothermal kinetics analysis method was applied to evaluate the combustion process.Based on Coats-Redfern integral method,some reaction models were tested,the mechanism and kinetics of the combustion reaction were discussed.The results show that the combustion of sewage sludge is mainly in the low temperature stage,meanwhile the ignition temperature and Arrhenius activation energy are lower than that of coal.The combustion of sewage sludge has the advantage over coal in some aspects,thus sewage sludge can partly replace coal used as cement industry fuel.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 51204179, 51204182)the Natural Science Foundation of Jiangsu Province of China (No. BK20141242)the Fundamental Research Funds for the Central Universities of China (No. 2014XT05)
文摘Coal sludge slurry(CSS) is an alternative fuel and a potential competitive method for sludge reduction.Based on the researches of coal water slurry, we studied CSSs by using a wet-grinding process with different types of regional municipal sludge(sludge) in an orthogonal experiment. The sludge type,sludge mixing proportion, dosage of dispersant, and grinding time were tested in this study. The results show that water content and its occurrence characteristics in the sludge have primary hindering influences on slurry ability. The range of fixed-viscosity concentrations with raw wet sludge is from 50.78%to 44.40%(by weight), while the range is from 53.35% to 51.51%(by weight) with dry sludge. All of the CSSs exhibit shear-thinning behaviors with different variation trends, especially the CSSs with more than 15%(by weight) raw wet sludge in it. Adding the same proportion of raw wet sludge increases the thixotropic properties of CSSs and the highest area of thixotropy loop is 3065 Pa/s, while the highest value of dry sludge is 1798 Pa/s. Hydrophilic group plays an important role in adsorbing water and building three-dimension networks with other particles, which is the main reason for CSS properties.Therefore, the mechanism can be used to find the way for making high quality CSS.
基金This study is supported by“Transformational Technologies for Clean Energy and Demonstration”,Institute of Engineering Thermophysics Chinese Academy of Sciences,Grant No.XDA21040100.
文摘Coal sludge is a seriously polluted solid waste,and the rational utilization of its resources has long being an undoubtedly important research topic.This paper mainly studies the coal sludge partial preheating characteristic,combustion characteristic and the process of migration and conversion of nitrogen with preheating combustion technology.The experimental results indicate that most of the elements in the coal sludge are released during preheating,and the ratio of the fuel-N converted to the N_(2),NH_(3) and HCN are 75.5%,6.74%and 0.64%,respectively.Compared with the coal sludge,the BET surface area and cumulative pore area of preheated char are increased.The surface of preheated char is loose and porous with many fine particles,while raw coal is dense with larger particles.Meantime,the quantity of carbon defect structure,the active sites and the reactivity of preheated char are all increased.In the whole process,the NO_(x) emission is about 156 mg/m3(@6%O2),the ratio of fuel-N converted to NO_(x) was 2.98%,and the combustion efficiency is 96.5%.This experiment results will play a vital role in efficient and clean utilization of coal sludge.
基金Projects 02C26211100499 supported by Science and Technology Corporation Innovation Fund of China 20020290011 by the Ph.D Program Fund
文摘A test system was designed to study the parameters affecting the volumetric efficiency of a thick-material pump for coal slime.The parameters studied included solid concentration,the slenderness ratio of the suction cylinder and the running speed of the hydraulic cylinder.In the experiment the concentrations of coal slime were 75.7%,76.3%,74.4%,73.5%,72.1%and 70.63%;the running speeds were 0.23,0.18,0.13,0.10 and 0.08 m/s;and the slenderness ratios of the suction cylinder were 1.63,2.26,2.88,3.50,4.13,4.78 and 5.38.The results show that the suction volumetric efficiency decreases gradually with an increase in material concentration.The critical concentration value is 72%;below 72%the suction volumetric efficiency is above 90%,otherwise it decreases rapidly.When the solid concentration reaches 76.3%,the suction volumetric efficiency is only 40%.When the running speed of the piston is less than or equal to 0.23 m/s,the suction volumetric efficiency increases with an increase in running speed.
文摘The combustion of sewage sludge and coal was studied by thermogravimetric analysis.Both differential scanning calorimetric analysis and derivative thermogravimetric profiles showed differences between combustion of sewage sludge and coal,and non-isothermal kinetics analysis method was applied to evaluate the combustion process.Based on Coats-Redfern integral method,some reaction models were tested,the mechanism and kinetics of the combustion reaction were discussed.The results show that the combustion of sewage sludge is mainly in the low temperature stage,meanwhile the ignition temperature and Arrhenius activation energy are lower than that of coal.The combustion of sewage sludge has the advantage over coal in some aspects,thus sewage sludge can partly replace coal used as cement industry fuel.