Influence of Lithological Characters of Coal Bearing Formation on Stability of Roof of Coal Seams

Lithology is one of the important factors influencing the stability of roof of coal seams. In order to investigate this, the phenomenon of underground pressure and distribution of pressure were studied by using the local observation and simulation test with similar materials. The observation results show that the distance of initial weighting and periodic weighting of the mudstone roof is shorter than that of sandstone roofs. The sandstone roof with a high strength has a longer distance of initial weighting and periodic weighting, the abutment stress on the working face is big and the height of caving and fracture zone is high. The peak point of abutment stress in the sandstone roof is near to the working face and the pressure bump is inclined to occur. The result is contrary to that in case of the mudstone roof with a low strength. While in the transition zone of nipped sandstone, roof rock-mass is broken and is poor in stability, therefore, it is difficult to hold the roof.

CLAY MINERAL ASSEMBLAGES AND THEIR IMPLICATIONS IN SHIHEZI FORMATION FROM THE HUAIBEI COAL-BEARING STRATA

Clay mineral assemblages in Shihezi Formation of Huaibei coal-bearing strata are determined by X-ray diffraction and Differential Thermal Analyzer, that is restated to the sediment faces and climatic changes in the source area, and to a lesser extent, alterations during burial diagenesis. In the Upper Shihezi Formation, the clay fraction is dominated by kaolinite in northern part of the coal field, which was formed in alluvial sediment environment. But in the South of Huaibei coal field, the clay mineral assemblage consists of mainly illite that reflects the influence of sea water. The predominately kaolinite and sederite composition of the clay fraction in the lower Shihezi Formation sediments documents less relief and gentle erosion of kaolinite rich soils developing under warm source area. In the lower part of Shihezi Formation, some chlorite is detected, which suggests transformation of illite or kaolinite to chlorite under conditions of burial diagenesis.

Identification methods of coal-bearing source rocks for Yacheng Formation in the western deepwater area of South China Sea

Owing to the fact that the coal-beds are with the characteristics of multi-beds, thin single-bed, rapid lateral changes and deep burial, coal-bearing source rocks are difficult to be identified and predicted, especially in the lower exploration deepwater area. In this paper, a new integrative process utilizing geology and geophysics is proposed for better predicting the distribution of coal-bearing source rocks. Coal-beds were identified by the logging responses of“three higher, three lower, and one expand”and carbargilite were recognized by the characteristics of“four higher and one lower”. Based on the above logical decision, coal-beds and carbargilite can be distinguished automatically by cluster analysis of logging curves in verticality. Within the constraints of well-seismic calibration, the coal-beds group also can be detected in horizontality by the integrated representation of“negative phase, higher Q, lower impedance and lower frequency”within the seismic data. However, the distribution of coal-bearing source rocks utilizing geophysical methodology may do not conform to the geological rules of coal accumulation. And then the main geological controlling factors of coal accumulation are comprehensively analyzed as follows：（1） Paleotopography and tectonic subsidence determine the planar range of terrestrial-marine transitional facies markedly;（2） The relative sea level changes affect the accommodation space and shoreline migration, and limit the vertical range of coal-beds. More specifically, the relationship between the accommodation creation rate and the peat accumulation rate is a fundamental control on coal accumulation. The thickest and most widespread coals form where those two factors reached a state of balance;（3） The supply of autochthonous clasts and the distance between deposition places and paleovegetation accumulated area are the critical factor to form abundant coal, which means that if deposition area is close to paleouplift, there would be sufficient organic matters to form abundant source rocks. The results show that the integrated methods can significantly improve prediction accuracy of coal-bearing source rocks, which is suitable for early exploration of western deepwater area of South China Sea.

Ground fissure development regularity and formation mechanism of shallow buried coal seam mining with Karst landform in Jiaozi coal mine: a case study

A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geographical distribution,dynamic development process,and failure mechanism of these ground fissures by employing field monitoring,numerical simulation,and theoretical analysis.The findings demonstrate that ground fissure development has an obvious feature of subregion,and its geographical distribution is significantly affected by topography.Tensile type,open type,and stepped type are three different categories of ground fissure.Ground fissures emerge dynamically as the panel advances,and they typically develop with a distance of less than periodic weighting step distance in advance of panel advancing position.Ground fissures present the dynamic development feature,temporary fissure has the ability of self-healing.The dynamic development process of ground fissure with closed-distance coal seam repeated mining is expounded,and the development scale is a dynamic development stage of“closure→expansion→stabilized”on the basis of the original development scale.From the perspective of topsoil deformation,the computation model considering two points movement vectors towards two directions of the gob and the ground surface is established,the development criterion considering the critical deformation value of topsoil is obtained.The mechanical model of hinged structure of inclined body is proposed to clarify the ground fissure development,and the interaction between slope activity and ground fissure development is expounded.These research results fulfill the gap of ground fissures about development regularity and formation mechanism,and can contribute to ground fissure prevention and treatment with Karst landform.

Evaluation of roof cutting by directionally single cracking technique in automatic roadway formation for thick coal seam mining

Automatic roadway formation by roof cutting is a sustainable nonpillar mining method that has the potential to increase coal recovery,reduce roadway excavation and improve mining safety.In this method,roof cutting is the key process for stress relief,which significantly affects the stability of the formed roadway.This paper presents a directionally single cracking(DSC)technique for roof cutting with considerations of rock properties.The mechanism of the DSC technique was investi-gated by explicit finite element analyses.The DSC technique and roof cutting parameters were evaluated by discrete element simulation and field experiment.On this basis,the optimized DSC technique was tested in the field.The results indicate that the DSC technique could effectively control the blast-induced stress distribution and crack propagation in the roof rock,thus,achieve directionally single cracking on the roadway roof.The DsC technique for roof cutting with optimized parameters could effectively reduce the deformation and improve the stability of the formed roadway.Field engineering application verified the feasibility and effectiveness of the evaluated DSC technique for roof cutting.

Experimental Study on Hydrocarbon Formation Due to Reactions Between Carbonates and Water or Water Bearing Minerals in Deep Earth

In order to investigate the mechanism of formation of abiogenetic hydrocarbons at the depth of the Earth, experimental research on reactions between carbonates and water or water bearing minerals was carried out at the pressure of about 1 GPa and the temperature range of 800-1500℃. The reactions took place in an open and nonequilibrium state. Chromatographic analyses of the gas products indicate that in the experiments there were generated CH 4 dominated hydrocarbons, along with some CO 2 and CO. Accordingly, we think there is no essential distinction between free state water and hydroxy in the minerals in the process of hydrocarbon formation. This study indicates that reactions between carbonates and water or water bearing minerals should be an important factor leading to the formation of abiogenetic hydrocarbons at the Earth’s depth.

Ore-bearing Formations and Mineral Resource Prospects of the Peripheral Areas of the Tarim Block

The tectonic development of the Tarim block has experienced four stages, i. e. Earth's core accretion and block formation in the Precambrian, margin splitting, opening-closing and piecing up in the Early Palaeozoic, rift formation and plate unification in the Late Palaeozoic, and basin-mountain coupling and landform shaping in the Meso-Cenozoic, forming six ore-bearing formations and ore deposits of various genetic types in the Tianshan Mountains, Kunlun Mountains and Altun Mountains. In the peripheral areas of Tarim there are four giant intercontinental metallogenic belts passing through, the Central Tianshan and southwestern Tianshan belts in the former USSR and the Qinling-Qilian-Kunlun and Palaeo-Tethys belts in China. According to the macro-analysis on the nearly one thousand known deposits (occurrences) and geophysical-geochemical anomalies, and the information from reconnaissance in some areas, the region has very good prospects for mineral resources. Some of the metallogenic belts may well become the reserve bases for exploration of mineral resources in China.

Ore-Bearing Formations of the Precambrian in South China and Their Prospects

In the Precambrian System of the Yangtze and Cathaysian plates six ore-bearing formations can be identified: the Cu-Pb-Zn-bearing formations in volcanic rocks of marine facies of the Neoarchean-Paleoproterozoic, Cu-Au-bearing formations and Pb-Zn-bearing formations in volcanic rocks of marine facies of the Mesoproterozoic, Pb-Zn-bearing formations in volcaniclastic rock and carbonate rock of the Neoproterozoic, Fe-Mn-bearing formations in the volcaniclastic rock of the Neoproterozoic, and Ni-Cr-serpentine-bearing formations in ophiolite and ultrabasic rock of the Meso- and Neoproterozoic. They were mostly formed in the marginal rift valleys of the Yangtze and Cathaysian plates, where occur stratabound and stratiform ore deposits, thermal deposits and porphyry polymetallic deposits. The six regions with ore-bearing formations have good prospects for ore deposits.

Construction of well logging knowledge graph and intelligent identification method of hydrocarbon-bearing formation

Based on the well logging knowledge graph of hydrocarbon-bearing formation(HBF),a Knowledge-Powered Neural Network Formation Evaluation model(KPNFE)has been proposed.It has the following functions:(1)extracting characteristic parameters describing HBF in multiple dimensions and multiple scales;(2)showing the characteristic parameter-related entities,relationships,and attributes as vectors via graph embedding technique;(3)intelligently identifying HBF;(4)seamlessly integrating expertise into the intelligent computing to establish the assessment system and ranking algorithm for potential pay recommendation.Taking 547 wells encountered the low porosity and low permeability Chang 6 Member of Triassic in the Jiyuan Block of Ordos Basin,NW China as objects,80%of the wells were randomly selected as the training dataset and the remainder as the validation dataset.The KPNFE prediction results on the validation dataset had a coincidence rate of 94.43%with the expert interpretation results and a coincidence rate of 84.38%for all the oil testing layers,which is 13 percentage points higher in accuracy and over 100 times faster than the primary conventional interpretation.In addition,a number of potential pays likely to produce industrial oil were recommended.The KPNFE model effectively inherits,carries forward and improves the expert knowledge,nicely solving the robustness problem in HBF identification.The KPNFE,with good interpretability and high accuracy of computation results,is a powerful technical means for efficient and high-quality well logging re-evaluation of old wells in mature oilfields.

Experimental Study on the Mechanism for the Formation of Sn- bearing Granite in Northern Guangxi

Experimental results have proved that the Xuefengian Sn-bearing biotite granites were formed by remelting and recrystallization of the Proterozoic metamorphic rocks of the Sibao Group at 500× 105-2000× 105 Pa and 750-570℃ and further testified that the F- and B-bear-ing aqueous solution played an important part in decreasing the formation temperature of the rocks. The results tally with the reality of the field geology. The authors have thus brought to light the mechanism for the formation of the Sn-bearing biotite granites and expounded the significance of their formation in the crust dynamics of South China.

Formation Depth of Coesite-Bearing Eclogite,Dabie UHPM Zone,China

The plastic deformation of garnet in coesite bearing eclogite, quartz eclogite and garnet amphibolite of the UHPM complex in Yingshan County in the Dabie Mountains has been studied. The stress generated by the strong tectonic movement was an important component of the total pressure that resulted in the formation of the eclogite in the Dabie UHPM zone. The three dimensional tectonic principal stresses and additional tectonic stress induced hydrostatic pressure [ p s=( σ 1+ σ 2+ σ 3)/3] are reconstructed according to the differential stress and the strain ratio ( α ) of the garnet in the minor coesite bearing eclogite of the Yingshan County. Then the gravity induced hydrostatic pressure ( p g) is calculated following the equation p minus p s, where p is estimated to be 2.8 GPa based on the quartz coesite geobarmeter. Therefore, the thickness of the rock column overlying the coesite bearing eclogite in the Ying shan County is determined ≥32 km. This estimation, significantly different from ≥100 km, the previous one obtained solely based on the weight/specific weight ratio (W/SW), offers a proper explanation for the puzzle that no tracer of the addition of mantle derived material has been found in the Dabie UHPM zone during the process of UHPM, although a number of researchers claim that this process took place at the depth of the mantle (≥100 km). It is concluded that attention should be paid to the additional tectonic stress induced hydrostatic pressure in the study of UHPM zones.

Gold-bearing formations and their evolution in central Inner Mongolia

In central Inner Mongolia, five gold bearing formations (Xiajining, Dongwufenzi, Wulashan, Baiyunebo and Bainaimiao Groups) belong either to volcano sedimentation or clasolite sedimentation. They formed in different tectonic environments such as an Archean rift zone (Xiajining and Dongwufenzi Groups), an Early Proterozoic stable basin (Wulashan Group), a Middle to Late Proterozoic continental rift zone (Baiyunebo Group), and a Paleozoic island arc environment (Bainaimiao Group). Gold contents in the gold bearing formations in the area are higher than those of other gold bearing formations in the North China Craton. However, as most gold bearing formations in the area are limited, there are a few big gold deposits in central Inner Mongolia. Gold contents in all formations were strongly influenced by migmatization and ductile shearing, the former process prompting mobilization, and the latter process resulting in gold enrichment in ductile shear zones. During the development of Archean to Proterozoic gold bearing formations, gold migrated from the mantle to the crust, then through the crust, finally deposited at the earth’s surface.

Beneficiation of Titanium Oxides From Ilmenite by Self-Reduction of Coal Bearing Pellets

The study on the beneficiation of titanium oxides from Panzhihua ilmenites by reduction of coal bearing pellets was carried out. The iron oxides in pellets were efficiently reduced to metal iron, and titanium oxide slag beneficiated was separated from metal iron. The effect of temperature, flux and coal blending ratio on the reduction and separation was investigated, and rational parameters were determined. A new process for the beneficiation of titanium oxides by rotary hearth furnace （RHF） was proposed.

Organic Geochemical and Petrographic Characteristics of the Coal Measure Source Rocks of Pinghu Formation in the Xihu Sag of the East China Sea Shelf Basin: Implications for Coal Measure Gas Potential

Coal measure source rocks, located in the Xihu Sag of the East China Sea Shelf Basin, were analyzed to define the hydrocarbon generation potential, organic geochemistry/petrology characteristics, and coal preservation conditions. The Pinghu source rocks in the Xihu Sag are mainly gas-prone accompany with condensate oil generation. The coals and shales of the Pinghu Formation are classified from "fair" to "excellent" source rocks with total organic carbon(TOC) contents ranging from 25.2% to 77.2% and 1.29% to 20.9%, respectively. The coals are richer in TOC and S1+S2 than the shales, indicating that the coals have more generation potential per unit mass. Moreover, the kerogen type of the organic matter consists of types Ⅱ-Ⅲ and Ⅲ, which the maturity Ro ranges from 0.59% to 0.83%. Petrographically, the coals and shales are dominated by vitrinite macerals(69.1%–96.8%) with minor proportions of liptinite(2.5%–17.55%) and inertinite(0.2%–6.2%). The correlation between maceral composition and S1+S2 indicates that the main contributor to the generation potential is vitrinite. Therefore, the coals and shales of the Pinghu Formation has good hydrocarbon generation potential, which provided a good foundation for coal measure gas accumulation. Furthermore, coal facies models indicates that the Pinghu coal was deposited in limno-telmatic environment under high water levels, with low tree density(mainly herbaceous) and with low-moderate nutrient supply. Fluctuating water levels and intermittent flooding during the deposition of peat resulted in the inter-layering of coal, shale and sandstone, which potentially providing favorable preservation conditions for coal measure gas.

Pyrite Formation in Organic-rich Clay, Calcitic and Coal-Forming Environments

The early diagenetic characteristics of pyrite formation processes in a Miocene freshwater sequence of mixed sediments （coal fragments in clays, sandstones or shales） alternating with continuous brown coal layers was investigated. Based on abundant minerals, the following main sedimentary environments were distinguished： the illite-montmorillonitic （I-M）, calcitic （Ct） and coal-forming environment （CL）. For these hydrogeochemically differing environments the effects of limiting factors on the pyrite formation process （availability of sulphate and Fe, amount of organic matter and participation of organic sulphur） were assessed by correlation analysis. Significant differences in the effects of these limiting factors in the particular environments were observed. These differences were explained taking in account the different oxidative activity, Fe-complex and surface complex forming properties of humic substances in dependence of pH of environment and the abundance of sorptionally active clay minerals. In environments having a relatively low pH and containing clay minerals （I-M- and CL-environments） the oxidative activity of humic substances （Hs） on pyrite precursors was greatly prevented however pyrite formation depended on reactive Fe availability as the consequence of complex formation. On the contrary, in environments with a relatively high pH, as it was the calcitic, the oxidative activity of Hs was greatly enhanced, thus oxidizing the sulfur precursors of pyrite. The oxidation degree of organic matter was probably also a consequence of the differing activity of the humic electron-acceptors.

Formation mechanism of methane during coal evolution:A density functional theory study

The formation mechanism of methane （CH4） during coal evolution has been investigated by density functional theory （DFT） of quantum chemistry. Thermogenic gas, which is generated during the thermal evolution of medium rank coal, is the main source of coalbed methane （CBM）. Ethylbenzene （A） and 6,7-dimethyl-5,6,7,8-tetrahydro-1-hydroxynaphthalene （B） have been used as model compounds to study the pyrolysis mechanism of highly volatile bituminous coal （R）, according to the similarity of bond orders and bond lengths. All possible paths are designed for each model. It can be concluded that the activation energies for H-assisted paths are lower than others in the process of methane formation; an H radical attacking on β-C to yield CH4 is the dominant path for the formation of CH4 from highly volatile bituminous coal. In addition, the calculated results also reveal that the positions on which H radical attacks and to which intramolecular H migrates have effects on methyl cleavage.

Experimental study on the infrared precursor characteristics of gas-bearing coal failure under loading

The stress and gas pressure in deep coal seams are very high,and instability and failure rapidly and intensely occur.It is important to study the infrared precursor characteristics of gas-bearing coal instability and failure.In this paper,a self-developed stress-gas coupling failure infrared experimental system was used to analyse the infrared radiation temperature(IRT)and infrared thermal image precursor characteristics of gas-free coal and gas-bearing coal.The changes in the areas of the infrared temperature anomalous precursor regions and the effect of the gas on the infrared precursors were examined.The results show that high-temperature anomalous precursors arise mainly when the gas-free coal fails under loading,whereas the gas-bearing coal has high-temperature and low-temperature anomalous precursors.The area of the high-temperature anomalous precursor is approximately 30%–40%under gasbearing coal unstable failure,which is lower than the 60%–70%of the gas-free coal.The area of the low-temperature abnormal precursor is approximately 3%–6%,which is higher than the 1%–2%of the gas-free coal.With increasing gas pressure,the area of the high-temperature anomalous precursor gradually decreases,and the area of the low-temperature anomalous precursor gradually increases.The highand low-temperature anomalous precursors of gas-bearing coal are mainly caused by gas desorption,volume expansion,and thermal friction.The presence of gas inhibits the increase in IRT on the coal surface and increases the difficulty of infrared radiation(IR)monitoring and early warning for gas-bearing coal.

Influence of abnormal stress under a residual bearing coal pillar on the stability of a mine entry

Mine entries close to residual bearing coal pillars(RBCPs) will suffer large deformation that may cause rock burst. To better understand the deformation mechanism and develop safe and practical guidelines for entry design, most studies focus on the absolute size of the stress field in and around the pillar. In this paper, we present a new approach to analyze the abnormal stress field close to a RBCP that uses the stress concentration coefficient(SCC), stress gradient(SG), and coefficient of lateral pressure(CLP) to describe the stress state induced by the RBCP. Based on elastic theory and a mathematical model for the abutment stress in the RBCP, an analytical solution for the abnormal stress in the strata below the RBCP was derived and the characteristics of the abnormal stress for a case study of a coal mine in China were analyzed. The results show that the abnormal stress field around the pillar is characterized by four distinct zones: a zone of high SCC, high SG, and CLP less than 1, a zone of high SCC, low SG, and CLP less than 1, a zone of low SCC, SG close to 0, and CLP greater than 1, and a zone of SCC close to 1, SC close to 0, and CLP close to 1. Based on this zoning pattern, a numerical model was established to study the combined effects of the abnormal stress on the stability of the entry. The most stable zone was determined based on a model of the Xinrui coal mine and verified by field measurements at the mine. Our conclusions can be used as guidelines for designing safe entry layouts in similar geological and mining settings.

Formation and emission characteristics of VOCs from a coal-fired power plant

On-site measurements of volatile organic compounds(VOCs)in different streams of flue gas were carried out on a real coal-fired power plant using sampling bags and SUMMA canisters to collect gas samples,filters to collect particle samples.Gas chromatography-flame ionization detector/mass spectrometry and gas chromatography-mass spectrometry was the offline analysis method.We found that the total mass concentration of the tested 102 VOC species at the outlet of wet flue gas desulfuration device was(13456±47)μg·m^(-3),which contained aliphatic hydrocarbons(57.9%),aromatic hydrocarbons(26.8%),halogen-containing species(14.5%),and a small amount of oxygen-containing and nitrogencontaining species.The most abundant species were 1-hexene,n-hexane and 2-methylpentane.The top ten species in terms of mass fraction(with a total mass fraction of 75.3%)were mainly hydrocarbons with a carbon number of 6 or higher and halogenated hydrocarbons with a lower carbon number.The mass concentration of VOC species in the particle phase was significantly lower than that in the gas phase.The change of VOC mass concentrations along the air pollution control devices indicates that conventional pollutant control equipment had a limited effect on VOC reduction.Ozone formation potential calculations showed that aromatic hydrocarbons contributed the highest ozone formation(46.4%)due to their relatively high mass concentrations and MIR(maximum increment reactivity)values.