Preparation and promising optoelectronic applications of lead halide perovskite patterned structures:A review

Lead halide perovskites have received considerable attention from researchers over the past several years due to their superior optical and optoelectronic properties,because of which they can be a versatile platform for fundamental science research and applications.Patterned structures based on lead halide perovskites have much more novel properties compared with their more commonly seen bulk-,micro-,and nano-crystals,such as improvement in antireflection,light-scattering effects,and light absorption,as a result of their adjustability of spatial distributions.However,there are many challenges yet to be resolved in this field,such as insufficient patterned resolution,imperfect crystal quality,complicated preparation process,and so on.To pave the way to solve these problems,we provide a systematic presentation of current methods for fabricating lead halide perovskite patterned structures,including thermal imprint,use of etching films,two-step vapor-phase growth,template-confined solution growth,and seed-assisted growth.Furthermore,the advantages and disadvantages of these methods are elaborated in detail.In addition,thanks to the extraordinary properties of lead halide perovskite patterned structures,a variety of potential applications in optics and optoelectronics of these structures are described.Lastly,we put forward existing challenges and prospects in this exciting field.

Population structure and distribution pattern of Taxus cuspidata in Muling region of Heilongjiang Province, China

An investigation was conducted on distribution pattern, site condition and population structure of yew Taxus cuspidata Sieb. et Zucc. in Muling Forest Bureau of Heilongjiang Province, China in April, 2005. Results showed that yew is mainly distributed under the main storey of natural mixed forest of conifer and broadleaf, the soil moisture content of the yew site is high （40%-60%）, the pH value of soil is relatively lower （4.7-5.5）, and that the population structure of wild yew is not rational, belonging to the degeneration population, which is one of the reasons leading to the population decline. Although the site conditions of Muling area are suitable for the growth of wild yew, the population of wild yew shows a decline tendency, due to the fact that the middle-sized adult yew trees have been cut, young yews are often grazed by wildlife, and that the trunks of adult yew tend to be hollow.

Spatial pattern analysis for quantification of landscape structure of Tadoba-Andhari Tiger Reserve,Central India

Landscape structure is often regarded as an important factor that governs the distribution and abundance of species. Therefore it is critical to understand the landscapes and their dynamics. Patterns of landscape elements strongly influence the ecological characteristics. This study was designed to document and map the current status of the tropi-cal dry deciduous forest of the Tadoba-Andhari Tiger Reserve （TATR）, Central India, （using IRS P6 LISS IV data） and to describe its landscape structure at three levels of organization viz. landscape, class, and patch. The study area was classified into 10 land cover classes that include 6 vegetation classes. The landscape structure was analyzed using FRAG-STATS using 12 set of indices. The TATR landscapes have a total of 2,307 patches with a mean patch size of 25.67 ha and patch density of 1.7 patches per km2. Amongst all land cover classes, mixed bamboo forest is dominant-it occupied maximum area （77.99%）-while riparian forest is least represented （0.32%）. Mixed forest has maximum number of patches among all vegetation classes. Results have shown that despite being dominant in the area, mixed bamboo forest has low patch density （0.25/100 ha）. Dominance of mixed bamboo forest is attributed to large patch sizes and not to the number of patches. This study has focussed on the approach of integrating satellite forest classification and forest inven-tory data for studying forest landscape patterns.

Population structure and spatial pattern analysis of Quercus aquifolioides on Sejila Mountain,Tibet,China

Understanding population structure provides basic ecological data related to species and ecosystems.Our objective was to understand the mechanisms involved in the maintenance of Quercus aquifolioides populations.Using a 1 ha permanent sample plot data for Q.aquifolioides on Sejila Mountain,Tibet Autonomous Region(Tibet),China,we analyzed the population structure of Q.aquifolioides by combining data for diameter class,static life table and survival curve.Simultaneously,the spatial distribution of Q.aquifolioides was studied using Ripley’s L Function in point pattern analysis.The results showed:(1) Individuals in Q.aquifolioides populations were mainly aggregated in the youngest age classes,that accounted for94.3% of the individuals; the older age classes had much smaller populations.Although the youngest age classes(ClassesⅠ and Ⅱ) had fewer individuals than Class Ⅲ,the total number of individuals in classes Ⅰ and Ⅱ was also greater than in classes Ⅳ to Ⅸ.In terms of tree height,fewsaplings,more medium-sized saplings and few large-sized trees were found.The diameter class structure of Q.aquifolioides populations formed an atypical ‘pyramid’type; the population was expanding,but growth was limited,tending toward a stable population.(2) Mortality of Q.aquifolioides increased continuously with age; life expectancy decreased over time,and the survivorship curve was close to a Deevey I curve.(3) The spatial distribution pattern of Q.aquifolioides varied widely across different developmental stages.Saplings and medium-sized tree showed aggregated distributions at the scales of 0–33 m and 0–29 m,respectively.The aggregation intensities of saplings and medium-sized trees at small scales were significantly stronger than that of large-sized trees.However,large-sized trees showed a random distribution at most scales.(4) No correlation was observed among saplings,medium-and large-sized trees at small scales,while a significant and negative association was observed as the scale increased.Strong competition was found among saplings,medium-and large-sized trees,while no significant association was observed between medium-and largesized trees at all scales.Biotic interactions and local ecological characteristics influenced the spatial distribution pattern of Q.aquifolioides populations most strongly.

The Structure and Pattern of Urban Network in the Lanzhou-Xining Urban Agglomeration

In this paper,we use factor analysis to evaluate the urban comprehensive quality of each city in the Lanzhou-Xining(Lan-Xi)urban agglomeration.The time distance was obtained by using GIS spatial analysis,and the structure and pattern of the spatial network were analyzed by using the gravity model and social network analysis method.The results show that:1)The scale effect of the Lan-Xi urban agglomeration is gradually emerging,and it is gradually forming the urban agglomeration with Lanzhou and Xining as the core,the Lan-Xi high-speed railway as the axis,and a high-dense connection.2)Lanzhou and Xining are at the core of the Lan-Xi urban agglomeration,which has a strong attraction and spreads to neighboring cities.3)In the network structure of the Lan-Xi urban agglomeration,Lanzhou,Baiyin,Gaolan,Yuzhong,Yongdeng,Dingxi,Lintao,Xining,Ledu,Huangzhong,Ping’an,Minhe and Datong are located in the network core position,which have the superiority position and lead to the entire regional communication enhancement and the regional integration development.4)This urban agglomeration has significant subgroups,eight tertiary subgroups and four secondary subgroup;the tertiary subgroups which compose secondary subgroup have a close connection and mutually influence each other.5)The Lanzhou Metropolitan Area and the Xining Metropolitan Area have an important impact on the surrounding cities,and the peripheral cities are basically controlled by the central city.The Dingxi subgroup,Lintao-Linxia subgroup,Gonghe subgroup have more structural holes than the subgroups within the Lanzhou Metropolitan Area and the Xining Metropolitan Area,so the peripheral cities of these subgroups have relatively less connection with surrounding cities.

Structure and production fluid flow pattern of post-fracturing high-rank coal reservoir in Southern Qinshui Basin

Field geological work, field engineering monitoring, laboratory experiments and numerical simulation were used to study the development characteristics of pore-fracture system and hydraulic fracture of No.3 coal reservoir in Southern Qinshui Basin. Flow patterns of methane and water in pore-fracture system and hydraulic fracture were discussed by using limit method and average method. Based on the structure model and flow pattern of post-fracturing high-rank coal reservoir, flow patterns of methane and water were established. Results show that seepage pattern of methane in pore-fracture system is linked with pore diameter, fracture width, coal bed pressure and flow velocity. While in hydraulic fracture, it is controlled by fracture height, pressure and flow velocity. Seepage pattern of water in pore-fracture system is linked with pore diameter, fracture width and flow velocity. While in hydraulic fracture, it is controlled by fracture height and flow velocity. Pores and fractures in different sizes are linked up by ultramicroscopic fissures, micro-fissures and hydraulic fracture. In post-fracturing high-rank coal reservoir, methane has level-three flow and gets through triple medium to the wellbore; and water passes mainly through double medium to the wellbore which is level-two flow.

Novel mechanical behavior of periodic structure with the pattern transformation

Abstract In periodic cellular structures, novel pattern transformations are triggered by a reversible elastic instability under the axial compression. Based on the deformation-triggered new pattern, periodic cellular structures can achieve special mechanical properties. In this paper, the designed architecture materials which include elastomer matrixes containing empty holes or filled holes with hydrogel material are modeled and simulated to investigate the mechanical property of the periodic materials. By analyzing the relationship between nominal stress and nominal strain of periodic material, and the corresponding deformed patterns, the influence of geometry and shapes of the holes on the mechanical property of architecture material is studied in more details. We hope this study can provide future perspectives for the deformation-triggered periodic structures.

Smooth cutting pattern generation technique for membrane structures using geodesic line on subplane and spline interpolation

Practical techniques for smooth geodesic patterning of membrane structures were investigated.For the geodesic search,adjustment of the subplane of the extracted elements series was proposed,and various spline approximation methods were used to flatten the strip for the generation of a smooth pattern.This search approach is very simple,and the geodesic line could be easily attained by the proposed method without the need for a difficult computation method.Smooth cutting patterning can also be generated by spline approximation without the noise in discrete nodal information.Additionally,the geodesic cutting pattern saved about 21%of the required area for the catenary model due to the reduction of the curvature of the planar pattern seam line.

Migration Networks Pattern of China’s Floating Population from the Perspective of Complex Network

Since China’s reform and opening-up,the growing disparity between urban and rural areas and regions has led to massive migration.With China’s Rural Revitalization Strategy and the industrial transfer from the eastern coastal areas to the inland,the migration direction and pattern of the floating population have undergone certain changes.Using the 2017 China Migrants Dynamic Survey(CMDS),excluding Hong Kong,Macao,and Taiwan regions of China,organized by China’s National Health Commission,the relationship matrix of the floating population is constructed according to the inflow place of the interviewees and their outflow place(the location of the registered residence)in the questionnaire survey.We then apply the complex network model to analyze the migration direction and network pattern of China’s floating population from the city scale.The migration network shows an obvious hierarchical agglomeration.The first-,second-,third-and fourth-tier distribution cities are municipalities directly under the central government,provincial capital cities,major cities in the central and western regions and ordinary cities in all provinces,respectively.The migration trend is from the central and western regions to the eastern coastal areas.The migration network has‘small world’characteristics,forming nine communities.It shows that most node cities in the same community are closely linked and geographically close,indicating that the migration network of floating population is still affected by geographical proximity.Narrowing the urban-rural and regional differences will promote the rational distribution this population.It is necessary to strengthen the reform of the registered residence system,so that the floating population can enjoy urban public services comparable to other populations,and allow migrants to live and work in peace.

Elevational patterns of warming effects on plant community and topsoil properties: focus on subalpine meadows ecosystem

Climate warming profoundly affects plant biodiversity, community productivity, and soil properties in alpine and subalpine grassland ecosystems. However, these effects are poorly understood across elevational gradients in subalpine meadow ecosystems. To reveal the elevational patterns of warming effects on plant biodiversity, community structure, productivity, and soil properties, we conducted a warming experiment using open-top chambers from August 2019 to August 2022 at high(2764 m a. s. l.), medium(2631 m a. s. l.), and low(2544 m a. s. l.) elevational gradients on a subalpine meadow slope of Mount Wutai, Northern China. Our results showed that three years of warming significantly increased topsoil temperature but significantly decreased topsoil moisture at all elevations(P<0.05), and the percentage of increasing temperature and decreasing moisture both gradually raised with elevation lifting. Warming-induced decreasing proportions of soil organic carbon(SOC, by 19.24%), and total nitrogen(TN, by 24.56%) were the greatest at high elevational gradients. Experimental warming did not affect topsoil C: N, p H, NO_(3)^(-)-N, or NH_(4)^(+)-N at the three elevational gradients. Warming significantly increased species richness(P<0.01) and Shannon-Weiner index(P<0.05) at low elevational gradients but significantly decreased belowground biomass(P<0.05) at a depth of 0–10 cm at three elevational gradients. Warming caused significant increases in the aboveground biomass in the three elevational plots. Warming significantly increased the aboveground biomass of graminoids in medium(by 92.47%) and low(by 98.25%) elevational gradients, that of sedges in high(by 72.44%) and medium(by 57.16%) elevational plots, and that of forbs in high(by 75.88%), medium(by 34.38%), and low(by 74.95%) elevational plots. Species richness had significant linear correlations with SOC, TN, and C: N(P<0.05), but significant nonlinear responses to soil temperature and soil moisture in the warmed treatment(P<0.05). The warmed aboveground biomass had a significant nonlinear response to soil temperature and significant linear responses to soil moisture(P<0.05). This study provided evidence that altitude is a factor in sensitivity to climate warming, and these different parameters(e.g., plant species richness, Shannon-Weiner index, soil temperature, soil moisture, SOC, and TN) can be used to measure this sensitivity.

Spatial pattern and compositive structure of forests in Guizhou

Remote-sensing and field data of Guizhou forest resources in 2000 are processed using ArcGIS, with the production of forest resource distribution map, forest age class structure map, and forest canopy distribution map. Analysis of these data shows that: (1) though there are multiple types of forest resources, forest coverage is low (only 25.27%, excluding sparse woodland, shrub and underage-forest); (2) the geographical distribution of forests is quite uneven, mainly in the southeast of the province and in Zunyi prefecture; (3) the zonal evergreen broad-leaved forests have been seriously destroyed, with striking secondary features, i.e., coniferous forest and shrubbery account for the greatest proportion of Guizhou forests; (4) the timber-forest is much larger in area than shelter-forest and economic forest; (5) young-and-middle aged forests are more widely distributed than near-and-over matured forest; and (6) the forest of Guizhou is not enough to effectively protect the environment of karst mountain areas of the province.

AGE STRUCTURE AND SPATIAL PATTERN OF OLD-GROWTH KOREAN PINE FOREST IN XIAOXING'ANLING MOUNTAIN

Spatial pattern of trees, basal stem increment and height were examined in a 5.0 ha mixed deciduous/ Pinus koraiensis forest from October in 1984 to May in 1987. Conclusions arc as following: 1. Analysis of the age-structure of the korcan pine forest shows that it is different from general steady-state forest type. The lack of saplings and individuals in small-diameter class clearly indicates that regeneration is not continuous. Continuous regeneration depends on thinning of the canopy to form a gap. Similar-aged korcan pine seedings grow in these gaps. 2. The horizontal structure of the korcan pine is a mosaic of more or less even-aged groups of trees. The mosaic is a result of korcan pine by regeneration strategy. The aggregations of korcan pine of different ages overlaps to form a continuous population generation. As a results, the population is maintained in steady state.

CRYSTAL STRUCTURE OF A LONG－PERIOD ORDERED PHASE IN Fe－C MARTENSITE AND COMPUTER SIMULATION OF ITS ELECTRON DIFFRACTION PATTERNS

Different structure models of a long-period ordered phase in Fe-C martenstie formed during aging have been checked by computer simulation of electron diffraction(ED) patterns based on these models.The results showed that the simulated ED pattern of γ'-FexC(Ⅱ) model proposed by the present authors is in good agreement with experimentally observed ED pattern.It was also confirmed that the incommensurate superperiod stems from the coexistence of several γ'-Fe_xC(H) phases with different superperiods.The Fe(144)C(24)(Fe6C) model proposed by Uwakweh et al.generated ED patterns remarkably different from the experimental ones.

TOPOLOGY AND VORTEX STRUCTURES OF A CURVING TURBINE CASCADE WITH TIP CLEARANCE (Ⅱ)- TOPOLOGICAL FLOW PATTERN AND VORTEX STRUCTURE IN THE TRANSVERSE SECTION OF A BLADE CASCADE

By means of ink trace visualization of the flows in conventional straight, positively curved and negatively curved cascades with tip clearance, and measurement of the aerodynamic parameters in transverse section, and by appling topology theory, the topological structures and vortex structure in the transverse section of a blade cascade were analyzed. Compared with conventional straight cascade, blade positive curving eliminates the separation line of the upper passage vortex, and leads the secondary vortex to change from close separation to open separation, while blade negative curving effects merely the positions of singular points and the intensities and scales of vortex.

Pattern Structure of Deterministic Displacement in Random Porous Media with Dispersion Effect

A new model — model of random porous media degradation via several fluid displacing, freezing, and thawing cycles is introduced and investigated in this paper. The fluid transport is based on the deterministic method with dispersion effect. The result shows that the topology and the geometry of the porous media have a strong effect on displacement processes. The cluster size of viscous fingering (VF) pattern in percolation cluster increases with the increase of iteration parameter n. When iteration parameter , VF pattern does not change with n. We find that the displacement fluid forms trapping regions in random porous media with dispersion effect. And the trapping regions will expand with the increasing of the iteration parameter n. When r (throat size) and , the peak value of the distribution increases as n increases, where is the normalized distribution of throat sizes after different displacement-damages but before freezing. The peak value of the distribution reaches a maximum when and , where is the normalized distribution of the size of invaded throat. This result is different from invasion percolation. It is found that the sweep efficiency E increases along with the increasing of iteration parameter n and decreases with the network size L, and E has a minimum as L increases to the maximum size of lattice. The VF pattern in percolation cluster has one frozen zone and one active zone.

Disc-Electrospun PCL Nanofiber Formed Micro-patterned Structure Scaffold

Disc-electrospinning using a disc as spinneret and a rotary drum as collector is a novel technology to prepare nanofiber which has been applied in tissue engineering scaffolds.In this study,nanofibrous mats with micro-patterned structure were fabricated via disc-electrospinning.Poly( #-caprolactone)( PCL) was dissolved in trifluoroethanol( TFE) at various concentrations( 2%-7%)( w / v)for electrospinning and the applied voltage ranged from 40 to 70 kV.Scanning electron microscopy( SEM) was employed to observe the morphology of the nanofibrous scaffolds.SEM images illustrated that the nanofibers with beads formed micro-patterned structure such as triangles and other polygons.The average diameter of nanofibers presented various size with the concentration increased from 2% to 7%.The beads on the nanofibers constructed the vertexes of the polygons,while nanofibers bridged between adjacent vertexes.The concentration of solution and applied voltage may be two dominant factors to influence the topological structure of the nanofibrous scaffolds.Cells cultured on the micro-patterned scaffold spread along the edges of the polygons.The scaffold with patterned structure may have a promising application in tissue engineering.

Crystal Structure and Photocatalytic Characteristics of Nanoscate Sb-doped TiO_2 Thin Films

Nanoscale Sb doped titanium dioxide thin films photocatalyst （Ti1-xSbO2） were obtained from dip-coating sol-gel method. The influence of dopant Sb density on the crystal structure and the phase transformation of the thin tilms were characterized by X-ray diffraction （XRD） and Raman spectra. The results of XRD showed that as prepared lilms were not only in anatase state but also in brookite. The crystalline size was estimated to be around 13.3-20 nm. Raman spectra indicated there coexisted other phases and a transformation from brookite to anatase in the samples doped with 0.2% Sb. After doping a proper amount of Sb, the cryst,allization rate and the content of the anatase Ti1-x, SbO2 in the thin films was clearly enhanced because Sb replaced part. of the Ti of TiO2 in the thin films. The anode current density （photocurrent density） and the first order reaction speed constant （k） of t.hin films doped with 0.2% Sb reached 42.49 μA/cm^2 and 0.171 h/cm^2 under 254 nm UV illumination, respectively, which is about 11 times and 2 times that of the non doped TiO2 anode prepared by the same method respectively.

Three-dimensional Evolutionary Models of the Qiongxi Structures,Southwestern Sichuan Basin,China:Evidence from Seismic Interpretation and Geomorphology

Fold terminations are key features in the study of compressional fault-related folds. Such terminations could be due to loss of displacement on the thrust fault or/and forming a lateral or oblique ramp. Thus, high-quality seismic data would help unambiguously define which mechanism should be responsible for the termination of a given fault-related fold. The Qiongxi and Qiongxinan structures in the Sichuan Basin, China are examples of natural fault-propagation folds that possess a northern termination and a structural saddle between them. The folds/fault geometry and along-strike displacement variations are constrained by the industry 3-D seismic volume. We interpret that the plunge of the fold near the northern termination and the structural saddle are due to the loss of displacement along strike. The fault geometry associated with the northern termination changes from a flat-ramp at the crest of the Qiongxinan structure, where displacement is the greatest, to simply a ramp near the northern tip of the Qiongxi structure, without forming a lateral or oblique ramp. In this study, we also use the drainage pattern, embryonic structure preserved in the crest of the Qiongxinan structure and the assumption that displacement along a fault is proportional to the duration of thrusting to propose a model for the lateral propagation of the Qiongxinan and Qiongxi structures. Specifically, we suggest that the structure first initiated as an isolated fault ramp within brittle units. With increased shortening, the fault grows to link with lower detachments in weaker shale units to create a hybridized fault-propagation fold. Our model suggests a possible explanation for the lateral propagation history of the Qiongxinan and Qiongxi structures, and also provides an alternative approach to confirming the activity of the previous Pingluoba structure in the southwestern Sichuan Basin in the late Cenozoic.

A flat-foldable equiangular spiral folding pattern inspired by sunflowers for deployable structures

Flasher origami pattern has been widely utilized to improve the stowage efficiency of deployable structures.Nevertheless,flasher origami cannot be folded fully flat,and they still have great potential for optimization in terms of storage volume and folding creases.In this paper,a flat foldable equiangular spiral folding pattern inspired by the sunflower disk is introduced.Then,a parametric design method for this equiangular spiral crease diagram is introduced in detail.Subsequently,a kinematic model of the equiangular spiral folding pattern is established based on the kinematic equivalence between rigid origami and spherical linkages.A simulation of the developed model demonstrates that the equiangular spiral folding pattern can be folded flat.Using the folded ratio as an evaluation index,the calculated results and experiments show that the equiangular spiral crease pattern can yield fewer creases and improve stowage efficiency in comparison to flasher origami pattern.Equiangular spiral folding pattern can save a considerable amount of space and provide a new approach to spatially deployable structures.