The Origin of Mesozoic A-type Granitoids,Fujian Province,Southeast China:Insights from Geochronology,Mineralogy and Geochemistry

The magma sources,origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain.New results reveal that,miarolites from the Qishan and Kuiqi intrusions yield crystallization ages of~101 and~98 Ma,and they have a high formation temperature(~910℃)and low oxygen fugacity value,indicating crystallization condition at low pressure in the upper crust with temperature of 678℃.The Qishan and Kuiqi miarolites are characterized by enrichment in SiO_(2) and high-K alkali,depletion in Ca and Mg,and belong to the high-K weak peraluminous rock series.The samples are enriched in HFSEs(i.e.,Ta,Zr and Hf)and LILEs(i.e.,Ba,P and Sr),depleted in Ba and Sr with the negative anomaly of Eu.In the primitive mantle normalized trace element spider diagram,the samples show a right-inclined‘seagull-type’pattern,combined the ratios of(La/Yb)_(N),10000×Al/Ga,Rb/Nb and Nb/Ta etc.,they were proved to be alkaline A-type granite.Combined the characterize of the trace elements,they were derived from clay-rich source accompanied pelite melting,and subjected to K-feldspar crystallization fractional.The values of ε_(Hf)(t)and tDM2 are distributed in the range of-2.8 to 3.3 with~1.2 Ga,and-6.0 to 4.0 with~1.2 Ga,revealing that they were generated from the Mesoproterozoic Cathaysia basement rocks.The comprehensive research reveals the Kuiqi and Qishan intrusions derived from crust-mantle mixing and partial melting of the crust,respectively,resulting from lithospheric extension generated by the Paleo-Pacific Plate subducted into the European-Asian Plate.

Characteristics of Lightning Activity in Southeast China and its Relation to the Atmospheric Background

Based on the lightning observation data from the Fengyun-4A(FY-4A)Lightning Mapping Imager(FY-4A/LMI)and the Lightning Imaging Sensor(LIS)on the International Space Station(ISS),we extract the“event”type data as the lightning detection results.These observations are then compared with the cloud-to-ground(CG)lightning observation data from the China Meteorological Administration.This study focuses on the characteristics of lightning activity in Southeast China,primarily in Jiangxi Province and its adjacent areas,from April to September,2017–2022.In addition,with the fifth-generation European Centre for Medium-Range Weather Forecasts reanalysis data,we further delved into the potential factors influencing the distribution and variations in lightning activity and their primary related factors.Our findings indicate that the lightning frequency and density of the FY-4A/LMI,ISS-LIS and CG data are higher in southern and central Jiangxi,central Fujian Province,and western and central Guangdong Province,while they tend to be lower in eastern Hunan Province.In general,the high-value areas of lightning density for the FY-4A/LMI are located in inland mountainous areas.The lower the latitude is,the higher the CG lightning density is.High-value areas of the CG lightning density are more likely to be located in eastern Fujian and southeastern Zhejiang Province.However,the high-value areas of lightning density for the ISS-LIS are more dispersed,with a scattered distribution in inland mountainous areas and along the coast of eastern Fujian.Thus,the mountainous terrain is closely related to the high-value areas of the lightning density.The locations of the high-value areas of the lightning density for the FY-4A/LMI correspond well with those for the CG observations,and the seasonal variations are also consistent.In contrast,the distribution of the high-value areas of the lightning density for the ISS-LIS is more dispersed.The positions of the peak frequency of the FY-4A/LMI lightning and CG lightning contrast with local altitudes,primarily located at lower altitudes or near mountainsides.K-index and convective available potential energy(CAPE)can better reflect the local boundary layer conditions,where the lightning density is higher and lightning seasonal variations are apparent.There are strong correlations in the annual variations between the dew-point temperature(Td)and CG lightning frequency,and the monthly variations of the dew-point temperature and CAPE are also strongly correlated with monthly variations of CG lightning,while they are weakly correlated with the lightning frequency for the FY-4A/LMI and ISS-LIS.This result reflects that the CAPE shows a remarkable effect on the CG lightning frequency during seasonal transitions.

Exploring the Spatiotemporal Changes and Driving Forces of Ecosystem Services of Zhejiang Coasts,China,Under Sustainable Development Goals

Ecosystem services(ESs)refer to the continuous provisioning of ecosystem goods and services that benefit human beings.Over recent decades,rapid urbanization has exerted significant pressure on coastal ecosystems,resulting in biodiversity and habitat loss,environmental pollution,and the depletion of natural resources.In response to these environmental challenges,the Sustainable Development Goals(SDGs)were proposed.Given the pressing need to address these issues,understanding the changes in ESs under the SDGs is crucial for formulating specific ecological strategies.In this study,we first analyzed land use and cover change in the Zhejiang coasts of China during 2000–2020.Then,we investigated the spatiotemporal configuration of ESs by integrating carbon storage(CS),soil retention(SR),habitat quality(HQ)and water yield(WY)using the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model.The driving mechanisms of ESs,which varied by space and time,were also explored using the Geo-detector method.The results revealed that,over the past two decades:1)the Zhejiang coasts have experienced a significant increase of 2783.72 km^(2) in built-up land areas and a continuous decrease in farmland areas due to rapid urbanization;2)owing to higher precipitation,extensive vegetation cover,and reduced anthropogenic disturbances,forests emerge as a crucial land use type for maintaining ecosystem services such as HQ,CS,WY,and SR;3)ESs have generally declined across the entire Zhejiang coasts,with a significant decrease observed in the northern areas and an increase in the southern areas spatially;4)the expansion of built-up land areas emerged as the primary factor affecting ecosystem services,while the vegetation factor has been increasingly significant and is expected to become predominant in the near future.Our study provides insights of understanding of ecosystem service theory and emphasizing the importance of preserving biodiversity for long-term sustainable development,and valuable scientific references to support the ecological management decision-making for local governments.

A novel seed cone of Pinus from the Miocene of coastal Southeast China indicates kinship with Southeast Asian pines

Pinus is an economically and ecologically important genus whose members are dominant components globally in low-latitude mountainous and mid-latitude temperate forests.Pinus species richness is currently concentrated in subtropical mid-low latitudes of the Northern Hemisphere,differing from the latitudinal diversity gradient mostly recognized in woody angiosperms.How the present pattern was developing in Earth's past is still poorly studied,particularly in eastern Asia.Here,a new fossil species,Pinus shengxianica sp.nov.is described based on a fossil seed cone from the Late Miocene Shengxian Formation in Zhejiang,southeast China.A co-occurring cone is recognized as a known fossil species,Pinus speciosa Li.Extensive comparison of extant and fossil members of Pinus suggests P.shengxianica shares a striking cone similarity to Pinus merkusii and Pinus latteri(subsection Pinus)from tropical Southeast Asia in having annular bulges around the umbo on the apophysis.The morphological resemblance indicates these two extant low-latitude pines probably possess a close affinity with the present newly-discovered P.shengxianica and originated from East Asian mid-low latitude ancestors during this generic re-diversification in the Miocene.This scenario is consistent with the evolutionary trajectory reflected by the pine fossil history and molecular data,marking the Miocene as a key period for the origin and evolution of most extant pines globally.The co-occurrences of diverse conifers and broadleaved angiosperms preferring diverse niches demonstrate Late Miocene eastern Zhejiang was one of the hot spots for coniferophyte diversity and hosted a needled-broadleaved mixed forest with complex vegetation structure and an altitudinal zonation.

Alteration of intestinal microbiota is associated with diabetic retinopathy and its severity:Samples collected from southeast coast Chinese

BACKGROUND Current approaches for the therapy of diabetic retinopathy(DR),which was one of leading causes of visual impairment,have their limitations.Animal experiments revealed that restructuring of intestinal microbiota can prevent retinopathy.AIM To explore the relationship between intestinal microbiota and DR among patients in the southeast coast of China,and provide clues for novel ways to prevention and treatment methods of DR.METHODS The fecal samples of non-diabetics(Group C,n=15)and diabetics(Group DM,n=30),including 15 samples with DR(Group DR)and 15 samples without DR(Group D),were analyzed by 16S rRNA sequencing.Intestinal microbiota compositions were compared between Group C and Group DM,Group DR and Group D,as well as patients with proliferative diabetic retinopathy(PDR)(Group PDR,n=8)and patients without PDR(Group NPDR,n=7).Spearman correlation analyses were performed to explore the associations between intestinal microbiota and clinical indicators.RESULTS The alpha and beta diversity did not differ significantly between Group DR and Group D as well as Group PDR and Group NPDR.At the family level,Fusobacteriaceae,Desulfovibrionaceae and Pseudomonadaceae were significantly increased in Group DR than in Group D(P<0.05,respectively).At the genera level,Fusobacterium,Pseudomonas,and Adlercreutzia were increased in Group DR than Group D while Senegalimassilia was decreased(P<0.05,respectively).Pseudomonas was negatively correlated with NK cell count(r=-0.39,P=0.03).Further,the abundance of genera Eubacterium(P<0.01),Peptococcus,Desulfovibrio,Acetanaerobacterium and Negativibacillus(P<0.05,respectively)were higher in Group PDR compared to Group NPDR,while Pseudomonas,Alloprevotella and Tyzzerella(P<0.05,respectively)were lower.Acetanaerobacterium and Desulfovibrio were positively correlated with fasting insulin(r=0.53 and 0.61,respectively,P<0.05),when Negativibacillus was negatively correlated with B cell count(r=-0.67,P<0.01).CONCLUSION Our findings indicated that the alteration of gut microbiota was associated with DR and its severity among patients in the southeast coast of China,probably by multiple mechanisms such as producing short-chain fatty acids,influencing permeability of blood vessels,affecting levels of vascular cell adhesion molecule-1,hypoxia-inducible factor-1,B cell and insulin.Modulating gut microbiota composition might be a novel strategy for prevention of DR,particularly PDR in population above.

Analysis of wave shoaling and shore-breakers on a low tide terrace beach based on in-situ measurements at Xisha Bay on South China coast

Low tide terrace beach is a main beach type along South China coasts with strong tidal actions.How strong tides affect wave transformations on low tide terrace beach still remains unclear.In this study,in-situ measurements are conducted on the low terrace beach at Xisha Bay to provide quantitative descriptions of wave shoaling and shore-breaker phenomena under the tidal effects.It is found that wave breaking is unsaturated on the low tide terrace beach at Xisha Bay.Magnitudes of wave skewness and asymmetry increase as wave shoals and achieve the maximum value at the shore-breaker,and then decrease rapidly.Mean energy dissipation rates of shore-breakers are tide-modulated since the bottom slope changes at the shoreward boundary of wave propagation in a tidal cycle.The remaining wave energy flux at the initialization of the shore-breaker is 1%–12%of offshore wave energy flux,and the energy flux ratio decreases with increasing offshore wave heights.Wave attenuation at shore-breakers can be estimated directly from offshore wave conditions based on findings in this study,favoring designs of seawalls or beach nourishment projects.Field datasets on wave transformations can also be used for verifications of wave numerical models.

Thermodynamics and Microphysical Characteristics of an Extreme Rainfall Event Under the Influence of a Low-level Jet over the South China Coast

In this paper,the data of Automatic Weather Stations(AWSs),ERA5 reanalysis,sounding,wind profile radar,and dual-polarization radar are used to study an extreme rainfall event in the south China Coast on 11 to 12 May 2022 from the aspects of thermodynamics and microphysical characteristics under the influence of low-level jets(LLJs).Results show that:(1)The extreme rainfall event can be divided into two stages:the first stage(S1)from 0000 to 0600 LST on May 12 and the second stage(S2)from 0700 to 1700 LST on the same day.During S1,the rainfall is mainly caused by the upper-level shortwave trough and the boundary layer jet(BLJ),characterized by strong upward motion on the windward side of mountains.In S2,the combined influence of the BLJ and synoptic-system-related low-level jet(SLLJ)increases the vertical wind shear and vertical vorticity,strengthening the rainstorm.In combination with the effect of topography,a warm and humid southwest flow continuously transports water vapor to farther north,resulting in a significant increase in rainfall over the study area(on the terrain’s windward slope).From S1 to S2,the altitude of a divergence center in the upper air decreases obviously.(2)The rainfalls in the two stages are both associated with the mesoscale convergence line(MCL)on the surface,and the wind field from the mesoscale outflow boundary(MOB)in S1 is in the same direction as the environmental winds.Due to a small area of convergence that is left behind the MOB,convection moves eastward quickly and causes a short duration of heavy rainfall.In S2,the convergence along the MOB is enhanced,which strengthens the rainfall and leads to strong outflows,further enhancing the surface convergence near the MOB and forming a positive feedback mechanism.It results in a slow motion of convection and a long duration of heavy rainfall.(3)In terms of microphysics,the center of a strong echo in S1 is higher than in S2.The warm-rain process of the oceanic type characterizes both stages,but the convective intensity in S2 is significantly stronger than that in S1,featuring bigger drop sizes and lower concentrations.It is mainly due to the strengthening of LLJs,which makes small cloud droplets lift to melting levels,enhancing the ice phase process(riming process),producing large amounts of graupel particles and enhancing the melting and collision processes as they fall,resulting in the increase of liquid water content(LWC)and the formation of large raindrops near the surface.

Two new species of Eirenidae from the coast of southeast China

Through the examination of 377 samples collected from the Taiwan Straits, two new species of Eirenidae, i. e. , Eirene octonemalis n. sp. and Eutima krampi n. sp. are described. All type specimens are deposited at the Department of Oceanography, Xiamen University.

Tectono-Sedimentary History of Southeastern Coast Region,China:a Synthesis

According to the ideas and concepts of systems dynamic of continent structure, using previous information related to the study area, combining analyses on orogenic belt, basin and magmatic rock, the present paper synthesizes the tectono - sedimentary development of southeastern coast region, China, with special emphasis on the mountain making, basining and magmatic activity. The tectonic evolution after Late Caledonian orogeny was dominated by alternating rifting and converging, subsiding and uplifting, mountain making and basining in central and southern parts of southeastern China and the adjacent regions to the east and west. Seventeen geologic events , nine events of plate or terrain convergence , and continental crust accretion , as well as eight events of intracontinental rifting and basin faulting , are closely related to the tectonic and sedimentary evolution of the study area . The accompanied intense and frequent sedimentation , folding , faulting , magmatism and ore- forming process allowed huge coal , multimetal and potential petroleum source rocks to form in local depressions throughout the Caledonian to Himalavan time .

Features of Minerogenic Series Related to Continental VolcanicRocks in the Southeastern Coastal Area of China-A Case Study of the Daiyunshan-ShiniushanVolcanic Depression in Fujian

The Daiyunshan-Shiniushan volcanic depression in Fujian Province is situated in a volcanic belt of the southeast coastal area in China along the west Pacific Ocean. A new breakthrough has been made in the exploration of gold and silver ore deposits in recent years. The minerogenic series of the Daiyunshan-Shiniushan volcanic depression is discussed in this paper based on the analysis of major metallogenic types and factors. According to the study of enormous ore deposits and occurrences in the study area, two minerogenic series have been recognized: 1. Late Jurassic Au-Ag-Pb-Zn minerogenic series related to intermediate-acid, acid volcanic formations; 2. nonmetallic minerogenic series (pyrophyllite, alunite pearlite, andalusite, zeolite, corundum and so on) related to intermediate and acid volcanic formations. The division and study of the minerogenic series have revealed metallogenic and time-space distribution characteristics of the ore deposits in the volcanic belt of the southeast coastal area in China, which are of economic importance for metallogenic prognosis.

Current study and prospect of the Old Red Sand along the southeast coast of China

The Old Red Sand is composed of brown-red, red, or orange-yellow semi-cemented and medium-fine sand sediment, mainly dis- tributed along the southeast coast of China. Based on previous studies, this paper summarizes the distribution and forms, sedi- mentary characteristics, formation mechanism, developing age, reddening process and the paleo-environment, suggesting that the Old Red Sand is mainly aeolian sediment of Late Pleistocene Age. The reddening process is mainly the result of decomposition and oxidation of iron-containing minerals caused by hot and humid tropical and sub-tropical climate. In this study, existing prob- lems are discussed and the prospect of further research is presented as well.

Characteristics of the Boundary Layer Structure of Sea Fog on the Coast of Southern China

Using boundary layer data with regard to sea fog observed at the Science Experiment Base for Marine Meteorology at Bohe,Guangdong Province,the structure of the atmospheric boundary layer and the characteristics of the tops of the fog and the clouds were analyzed.In addition,the effects of advection,radiation,and turbulence during sea fog were also investigated.According to the stability definition of saturated,wet air,the gradient of the potential pseudo-equivalent temperature equal to zero was defined as the thermal turbulence interface.There is evidence to suggest that two layers of turbulence exist in sea fog.Thermal turbulence produced by long-wave radiation is prevalent above the thermal turbulence interface,whereas mechanical turbulence aroused by wind shear is predominant below the interface.The height of the thermal turbulence interface was observed between 180 m and 380 m.Three important factors are closely related to the development of the top of the sea fog：（1） the horizontal advection of the water vapor,（2） the long-wave radiation of the fog top,and（3） the movement of the vertical turbulence.Formation,development,and dissipation are the three possible phases of the evolution of the boundary-layer structure during the sea fog season.In addition,the thermal turbulence interface is the most significant turbulence interface during the formation and development periods;it is maintained after sea fog rises into the stratus layer.

Jurassic Intra-plate Basaltic Magmatism in Southeast China:Evidence from Geological and Geochemical Characteristics of the Chebu Gabbroite in Southern Jiangxi Province

Geochemical and isotopic investigations have been carded out on the Chebu gabbroite in southern Jiangxi Province, southeast China and these results are compared with gabbro bodies along the coast of Fujian Province in order to understand their magma sources and tectonic implications. The Chebu intrusion formed at the beginning of the Middle Jurassic （172~4.3 Ma）. These rocks are Ti-rich and Al-poor in major elements, characterized by strong enrichment in large-ion lithophile elements （LILE） and moderate enrichment in high field strength elements （HFSE） and light rare-earth elements CLREE）, without pronounced Nb or Ta anomalies. Age-correlated Sr-Nd isotope ratios show moderately high ranges of （^87Sr/^86Sr）i from 0.7065 to 0.7086 and 0.5124 to 0.5125 of （^143Nd/^144Nd）i. The geochemical characteristics of the Chebu gabbroite suggest that it is notably different from island-arc basalt and similar to intra-plate basaltic rocks. By combining interpretations of its geological and geochemical characteristics and the regional geological development history, the Chebu gabbroitic intrusion is thought to be the product of asthenosphere upwelling and rapid lithosphere extension during a transition of tectonic systems in southeast China. The tectonic environment and source characteristics of the intrusion are different from Cretaceous gabbro bodies along the coast of Fujian Province, The former formed in a tectonic environment of rapid intra-plate lithospheric extension and the source characteristics were of a weakly enriched primitive mantle, whereas the latter originated mainly in a volcanic-magmatic arc extensional tectonic environment and the nature of the source was an enriched mantle with more subduct subducted components.

Wavelet analysis of coastal-trapped waves along the China coast generated by winter storms in 2008

This study applies the wavelet analysis to the tidal gauge records, alongshore winds, atmospheric temperature and pressure along the China coast in winter 2008. The analysis results show three events of sea level oscillations （SLOs） on the shelf induced by winter storms. The first event occurred from January 9 to 21. The SLO periods were double-peaked at 1.6-5.3 and 7.0-16.0 d with the power densities of 0.04-0.05 and 0.10-0.15 m^2.d, respectively. The second event occurred from February 5 to 18. The SLO period was single-peaked at 2.3-3.5 d with power density of 0.03-0.04 m^2.d. The third event occurred from February 20 to March 8. The SLO periods were double- peaked at 1.5-4.3 and 6.1-8.2 d with the power densities of 0.08-0.11 and 0.02-0.08 me.d, respectively. The SLOs propagated along the coast from Zhejiang in north to Guangdong in south. The phase speeds ranged about 9-29 m/s from Kanmen to Pingtan, 5-11 m/s from Xiamen to Huizhou and 11-22 m/s from Huizhou to Shuidong. The dispersion relation of the SLOs shows their nature of coastal-trapped wave.

Detecting the Origins of Moisture over Southeast China:Seasonal Variation and Heavy Rainfall

To examine the ability of the Hybrid Single-Particle Lagrangian Integrated Trajectory （HYSPLIT） model to detect the origins and paths of moisture supplied to Southeast China, trajectories of air particles released over Southeast China were traced backward during 1 April 2012 to 31 March 2013 and three typical regional persistent heavy rainfall events. The HYSPLIT model provides more insightful information than water vapor flux. Analysis of the specific humidity along the trajectories revealed the origins of moisture and their contributions to the moisture supply in Southeast China. In the boreal summer half year, four key moisture transport paths from the eastern Indian Ocean, central Indian Ocean, South China Sea （SCS）, and western North Pacific （WNP） contribute 10%, 20%, 31%, and 16% of the moisture to Southeast China, respectively. In the winter half year, the contributions of the paths from the WNP and North China double. Examination of heavy rainfall events showed that under tropical storm conditions, all moisture transport routines are rotated cyclonically before reaching Southeast China. The invasion of cold air can trigger heavy rainfall in both the summer and winter half years but plays different roles： it does not contribute to the moisture supply but plays a key role in converging and uplifting the moisture in the summer half year, while it supplies a great amount of moisture in the winter half year as it absorbs abundant moisture in crossing the WNE

Leaching and Redistribution of Nutrients in Surface Layer of Red Soils in Southeast China

The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.

Sustainable Agriculture Evaluation for Red Soil Hill Region of Southeast China

Agricultural sustainability for economic development is important and a complex issue throughout the world; however,it is difficult to synthetically evaluate its use in the policy making process. The objective of this study was to evaluate sustainable agriculture in the red soil hill region of Southeast China through a newly proposed method combining four separate sub-systems: regional population (P), resource (R), environmental (E), and socio-economic (S). This new index system was proposed to appraise synthetically the agricultural sustainability of the red soil hill region from 1988 to 1996 with a two-step method assessing: a) the agricultural sustainability in each province independently and b) the relative sustainability of each province to the whole region. The first step only provided a development trend for each province based on its original situation, while the second step provided additional information on the comparative status of each province in agricultural development to the region as a whole. Higher index scores were found for the economy and resource categories denoting improvement. However, lower scores in the environment category indicated the improvement was achieved at the cost of deteriorating ecological surroundings due to an increasing population that demanded more from the agro-ecosystem and put heavier pressures on it. Results also showed that water and soil losses in this region were the major obstacles encountered in sustainable agriculture development. The assessment results were verified when compared with results from another method. This suggested that the new assessment system was reliable and credible in evaluating agricultural sustainability on a regional scale.

Revision of the Conchostracan Genus Tenuestheria from the Upper Cretaceous Lanxi Formation in Zhejiang and Its Biostratigraphic Significance in Southeast China

The diagnosis of the conchostracan genus Tenuestheria from the Lanxi Formation in Jinhua, Zhejiang Province in Southeast China is revised following an examination of the type species under a scanning electron microscope, which revealed some morphological features on the carapace that had not been recognized previously. The importance of the Tenuestheria Fauna is considered in the context of correlation of six Turonian-Santonian formations in this region of China. The value of the Cenomanian Nemestheria and Turonian Linhaiella faunas in correlating the underlying early Late Cretaceous formations is also noted.

Age and metal source of orogenic gold deposits in Southeast Guizhou Province, China: Constraints from Re-Os and He-Ar isotopic evidence

The orogenic gold deposits in Southeast Guizhou are an important component of the Xuefeng polymetallic ore belt and have significant exploration potential, but geochronology research on these gold deposits is scarce. Therefore, the ore genetic models are poorly constrained and remain unclear. In the present study, two important deposits(Pingqiu and Jinjing) are investigated, including combined Re-Os dating and the He-Ar isotope study of auriferous arsenopyrites. It is found that the arsenopyrites from the Pingqiu gold deposit yielded an isochron age of 400 ± 24 Ma,with an initial ^(187)Os/^(188)Os ratio of 1.24 ± 0.57(MSWD = 0.96). An identical isochron age of 400 ± 11 Ma with an initial ^(187)Os/^(188)Os ratio of 1.55 ± 0.14(MSWD = 0.34) was obtained from the Jinjing deposit. These ages correspond to the regional Caledonian orogeny and are interpreted to represent the age of the main stage ore. Both initial ^(187)Os ratios suggest that the Os was derived from crustal rocks. Combined with previous rare earth element(REE), trace elements, Nd-Sr-S-Pb isotope studies on scheelite, inclusion fluids with other residues of gangue quartz, and sulfides from other gold deposits in the region, it is suggested that the ore metals from Pingqiu and Jinjing were sourced from the Xiajiang Group. The He and Ar isotopes of arsenopyrites are characterized by ~3 He/~4 He ratios ranging from 5.3 × 10^(-4) Ra to 2.5 × 10^(-2) Ra(Ra = 1.4 × 10^(-6), the ~3 He/~4 He ratio of air), 40 Ar=/~4 He ratios from 0.64 × 10^(-2) to 15.39×10^(-2), and ^(40)Ar/^(36)Ar ratios from 633.2 to 6582.0. Those noble gas isotopic compositions of fluid inclusions also support a crustal source origin,evidenced by the Os isotope. Meanwhile, recent noble gas studies suggest that the amount of in situ radiogenic ~4 He generated should not be ignored, even when Th and U are present at levels of only a few ppm in host minerals.

Neoproterozoic Tectonic Setting of Southeast China:New Constraints from SHRIMP U-Pb Zircon Ages and Petrographic Studies on the Mamianshan Group

Precambrian tectonic history of Zhejiaug, Fujian, and Jiangxi provinces of south China is important for understanding the tectonic evolution of South China but its magmatic activity, petrogenesis, stratigraphic sequence of the Mamianshan Group is still strongly controversial. Here we present new sensitive high resolution ion micro-probe （SHRIMP） U-Pb zircon geochronological data for the Mamianshan Group and petrographical data to constrain the tectonic framework of the regions. Our results showed that the SHRIMP U-Pb zircon age of green schists of the Dongyan Formation is 796.5±9.3 Ma, the Daling Formation is 756.2±7.2 Ma, and mica-quartz schist of the Longbeixi Formation is 825.5±9.8 Ma. These data indicate that the Mamianshan Group was formed not in the Mesoproterozoic, but in the Neoproterozoic and its stratigraphic sequences should be composed of Longbeixi, Dongyan, and Daling Formations from the bottom to the top. Rocks from this Group, from Zhejiang, Fujian and Jiangxi provinces, constituted the upper basement of the Cathaysia Block that overlay the lower basement of the Mayuan Group. Detailed petrographic studies demonstrate that the amphibole schists of the Dongyan Formation in the Mamianshan Group were formed within an intra-arc rift setting rather than a continental rift as previously suggested. Rather, this island-arc type formation was developed by collision and/or subduction between various blocks resulting from the breakup of the supercontinent Rodinia at c.850-750 Ma. The Zhuzhou conglomerate, distributed near Dikou Town, Jian＇ou City, Fujian Province and previously considered as evidence of the Mesoproterozoic Dikou movement, is shown here not to be the basal conglomerate above the angular unconformity between the upper and lower basements. Our conclusions have important implications for understanding the Precambrian tectonics of South China.