Lithium metal anode is the most ideal candidate for next-generation energy storage system.However,the uncontrolled dendrite growth,infinite volume expansion,and undesired side reactions lead to serious safety issues a...Lithium metal anode is the most ideal candidate for next-generation energy storage system.However,the uncontrolled dendrite growth,infinite volume expansion,and undesired side reactions lead to serious safety issues and hinder their potential application.Herein,a pre-lithiation strategy is proposed to construct a high-lithiophilic Cu-Li_(2)O matrix on commercial Cu foil.The in situ-generated Li_(2)O promises adequate nucleation sites and strengthens solid electrolyte interphase and lateral lithium deposition.Meanwhile,the existence of 3D matrix reduces the local current density.The synergy effect of Li_(2)O and Cu suppresses the growth of lithium dendrites.As a result,Cu-Li_(2)O matrix reveals an enhanced lithium plating/stripping behavior with Coulombic efficiency of 98.46%after 270 cycles.The symmetrical cell assembled by Li-plated electrodes displays a prolonged lifespan of 1400 h.The work demonstrates a scalable and effective approach for modified current collectors toward stable Li metal anode.展开更多
Nanofluids are a potential alternative to significantly improving the performance of heat transfer applications. In this work, a numerical analysis to examine the eff ect of dispersing copper(Cu), copper oxide(CuO), a...Nanofluids are a potential alternative to significantly improving the performance of heat transfer applications. In this work, a numerical analysis to examine the eff ect of dispersing copper(Cu), copper oxide(CuO), and aluminum(Al2O3) nanoparticles in pure water on the performance of a flat plate solar collector(FPSC) and a numerical model was proposed. The influence of the nanofluid type on the thermal efficiency was critically investigated and discussed. The eff ect of the mass flow rate on the performance was also analyzed and discussed. Based on correlations of the thermophysical properties of nanofluids, a sensitivity analysis was used to analyze the impact of the nanoparticles on the base fluid. The results indicate that the performance of the FPSC with Cu/water nanofluid was better than that of FPSCs using CuO/water or Al2O3/water nanofluids. When the mass flow rate of the nanofluids was 8.0 L/min, the efficiency of the FPSC was much greater than those at the flow rates of 5.0 L/min and 2.0 L/min. Mean enhancements in thermal efficiency of 4.44%, 4.27%, and 4.21% were observed when 2.0 L/min was applied using Cu/water, Cu O/water, and Al2O3/water nanofluids, respectively. Improvements in thermal efficiency of 2.76%, 2.53%, and 2.47% occurred when 8.0 L/min was applied.展开更多
Luminescent solar concentrators (LSCs) with styrene (ST) and methylmethacrylate (MMA) of different percentage as the matrix were prepared by a casting method using ponceau 2R. DSC has been used to compare the thermal ...Luminescent solar concentrators (LSCs) with styrene (ST) and methylmethacrylate (MMA) of different percentage as the matrix were prepared by a casting method using ponceau 2R. DSC has been used to compare the thermal stability of the different LSCs. FTIR spectroscopy shows that appearance of -N=N- for ponceau 2R in all ST/MMA matrixes indicating that the highest stability of this kind of dye in these matrixes. The values of the optical band gap (Eg) have been obtained from direct allowed transition before and after the samples have been exposed to sunlight for 9 weeks. Photodegradation studies revealed that the more photostable dye doped in PMMA matrix than in other matrixes. The results showed that the homo PMMA/ponceau 2R system has the highest fluorescence quantum yield (Qf). Therefore this sample can be selected for field performance of fluorescent solar collectors. The photovoltaic cell coupled with homo PMMA/2R LSC shows a maximum efficiency, 2% compared to the normal one.展开更多
An energy production system consisting of a solar collector, biogas dry reforming reactor and solid oxide fuel cell (SOFC) was assumed to be installed in Kolkata, India. This study aims to understand the impact of cli...An energy production system consisting of a solar collector, biogas dry reforming reactor and solid oxide fuel cell (SOFC) was assumed to be installed in Kolkata, India. This study aims to understand the impact of climate conditions on the performance of solar collectors with different lengths of parabolic trough solar collector (dx) and mass flow rate of heat transfer fluid (m). In addition, this study has evaluated the amount of H2 produced by biogas dry reforming (GH2), the amount of power generated by SOFC (PSOFC) and the maximum number of possible households (N) whose electricity demand could be met by the energy system proposed, considering the performance of solar collector with the different dx and m. As a result, the optimum dx was found to be 4 m. This study revealed that the temperature of heat transfer fluid (Tfb) decreased with the increase in m. Tfb in March, April and May was higher than that in other months, while Tfb from June to December was the lowest. GH2, PSOFC and N in March, April and May were higher than those in other months, irrespective of m. The optimum m was 0.030 kg/s.展开更多
基金supported by the Heilongjiang Province Marine New Energy and Protective Materials Engineering Technology Research Center(002100130630D)Natural Science Foundation of Heilongjiang(LC2018004)+1 种基金China Postdoctoral Science Foundation(2018M630340 and 2019T120254)the Fundamental Research Funds for the Central University.
文摘Lithium metal anode is the most ideal candidate for next-generation energy storage system.However,the uncontrolled dendrite growth,infinite volume expansion,and undesired side reactions lead to serious safety issues and hinder their potential application.Herein,a pre-lithiation strategy is proposed to construct a high-lithiophilic Cu-Li_(2)O matrix on commercial Cu foil.The in situ-generated Li_(2)O promises adequate nucleation sites and strengthens solid electrolyte interphase and lateral lithium deposition.Meanwhile,the existence of 3D matrix reduces the local current density.The synergy effect of Li_(2)O and Cu suppresses the growth of lithium dendrites.As a result,Cu-Li_(2)O matrix reveals an enhanced lithium plating/stripping behavior with Coulombic efficiency of 98.46%after 270 cycles.The symmetrical cell assembled by Li-plated electrodes displays a prolonged lifespan of 1400 h.The work demonstrates a scalable and effective approach for modified current collectors toward stable Li metal anode.
文摘Nanofluids are a potential alternative to significantly improving the performance of heat transfer applications. In this work, a numerical analysis to examine the eff ect of dispersing copper(Cu), copper oxide(CuO), and aluminum(Al2O3) nanoparticles in pure water on the performance of a flat plate solar collector(FPSC) and a numerical model was proposed. The influence of the nanofluid type on the thermal efficiency was critically investigated and discussed. The eff ect of the mass flow rate on the performance was also analyzed and discussed. Based on correlations of the thermophysical properties of nanofluids, a sensitivity analysis was used to analyze the impact of the nanoparticles on the base fluid. The results indicate that the performance of the FPSC with Cu/water nanofluid was better than that of FPSCs using CuO/water or Al2O3/water nanofluids. When the mass flow rate of the nanofluids was 8.0 L/min, the efficiency of the FPSC was much greater than those at the flow rates of 5.0 L/min and 2.0 L/min. Mean enhancements in thermal efficiency of 4.44%, 4.27%, and 4.21% were observed when 2.0 L/min was applied using Cu/water, Cu O/water, and Al2O3/water nanofluids, respectively. Improvements in thermal efficiency of 2.76%, 2.53%, and 2.47% occurred when 8.0 L/min was applied.
文摘Luminescent solar concentrators (LSCs) with styrene (ST) and methylmethacrylate (MMA) of different percentage as the matrix were prepared by a casting method using ponceau 2R. DSC has been used to compare the thermal stability of the different LSCs. FTIR spectroscopy shows that appearance of -N=N- for ponceau 2R in all ST/MMA matrixes indicating that the highest stability of this kind of dye in these matrixes. The values of the optical band gap (Eg) have been obtained from direct allowed transition before and after the samples have been exposed to sunlight for 9 weeks. Photodegradation studies revealed that the more photostable dye doped in PMMA matrix than in other matrixes. The results showed that the homo PMMA/ponceau 2R system has the highest fluorescence quantum yield (Qf). Therefore this sample can be selected for field performance of fluorescent solar collectors. The photovoltaic cell coupled with homo PMMA/2R LSC shows a maximum efficiency, 2% compared to the normal one.
文摘An energy production system consisting of a solar collector, biogas dry reforming reactor and solid oxide fuel cell (SOFC) was assumed to be installed in Kolkata, India. This study aims to understand the impact of climate conditions on the performance of solar collectors with different lengths of parabolic trough solar collector (dx) and mass flow rate of heat transfer fluid (m). In addition, this study has evaluated the amount of H2 produced by biogas dry reforming (GH2), the amount of power generated by SOFC (PSOFC) and the maximum number of possible households (N) whose electricity demand could be met by the energy system proposed, considering the performance of solar collector with the different dx and m. As a result, the optimum dx was found to be 4 m. This study revealed that the temperature of heat transfer fluid (Tfb) decreased with the increase in m. Tfb in March, April and May was higher than that in other months, while Tfb from June to December was the lowest. GH2, PSOFC and N in March, April and May were higher than those in other months, irrespective of m. The optimum m was 0.030 kg/s.
