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Chemical Scissors Tailored Nano‑Tellurium with High‑Entropy Morphology for Efficient Foam‑Hydrogel‑Based Solar Photothermal Evaporators
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作者 Chenyang Xing Zihao Li +4 位作者 Ziao Wang Shaohui Zhang Zhongjian Xie Xi Zhu Zhengchun Peng 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期149-168,共20页
The development of tellurium(Te)-based semiconductor nanomaterials for efficient light-to-heat conversion may offer an effective means of harvesting sunlight to address global energy concerns.However,the nanosized Te(... The development of tellurium(Te)-based semiconductor nanomaterials for efficient light-to-heat conversion may offer an effective means of harvesting sunlight to address global energy concerns.However,the nanosized Te(nano-Te)materials reported to date suffer from a series of drawbacks,including limited light absorption and a lack of surface structures.Herein,we report the preparation of nano-Te by electrochemical exfoliation using an electrolyzable room-temperature ionic liquid.Anions,cations,and their corresponding electrolytic products acting as chemical scissors can precisely intercalate and functionalize bulk Te.The resulting nano-Te has high morphological entropy,rich surface functional groups,and broad light absorption.We also constructed foam hydrogels based on poly(vinyl alcohol)/nano-Te,which achieved an evaporation rate and energy efficiency of 4.11 kg m^(−2)h^(−1)and 128%,respectively,under 1 sun irradiation.Furthermore,the evaporation rate was maintained in the range 2.5-3.0 kg m^(−2)h^(−1)outdoors under 0.5-1.0 sun,providing highly efficient evaporation under low light conditions. 展开更多
关键词 TELLURIUM High entropy Electrochemical modification Solar absorption evaporation rate
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Highly efficient three-dimensional solar evaporator for zero liquid discharge desalination of high-salinity brine
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作者 Meichun Ding Demin Zhao +6 位作者 Panpan Feng Baolei Wang Zhenying Duan Rui Wei Yuxi Zhao Chen-Yang Liu Chenwei Li 《Carbon Energy》 SCIE EI CAS CSCD 2024年第9期52-65,共14页
Solar-driven interfacial evaporation is a promising technology for freshwater production from seawater,but salt accumulation on the evaporator surface hinders its performance and sustainability.In this study,we report... Solar-driven interfacial evaporation is a promising technology for freshwater production from seawater,but salt accumulation on the evaporator surface hinders its performance and sustainability.In this study,we report a simple and green strategy to fabricate a three-dimensional porous graphene spiral roll(3GSR)that enables highly efficient solar evaporation,salt collection,and water production from near-saturated brine with zero liquid discharge(ZLD).The 3GSR design facilitates energy recovery,radial brine transport,and directional salt crystallization,thereby resulting in an ultrahigh evaporation rate of 9.05 kg m^(-2) h^(-1)6 in 25 wt%brine under 1-sun illumina-tion for 48 h continuously.Remarkably,the directional salt crystallization on its outer surface not only enlarges the evaporation area but also achieves an ultrahigh salt collection rate of 2.92 kg m^(-2) h^(-1),thus enabling ZLD desalination.Additionally,3GSR exhibits a record-high water production rate of 3.14 kg m^(-2) h^(-1) in an outdoor test.This innovative solution offers a highly efficient and continuous solar desalination method for water production and ZLD brine treatment,which has great implications for addressing global water scarcity and environmental issues arising from brine disposal. 展开更多
关键词 graphene aerogels graphene composites solar desalination solar-driven interfacial evaporation
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Influence of liquid film shape on evaporation performance of agitated thin film evaporator
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作者 顾鑫强 黄瑶 +1 位作者 邹鲲 彭倚天 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期305-314,共10页
The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of ... The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of the liquid film inside the evaporator can significantly affect its evaporation capability.This work explores how change in shape of the liquid films affect the evaporation of the materials with non-Newtonian characteristics,achieved by changing the structure of the scraper.Examining the distribution of circumferential temperature,viscosity,and mass transfer of the flat liquid film shows that the film evaporates rapidly in shear-thinning region.Various wavy liquid films are developed by using shear-thinning theory,emphasizing the flow condition in the thinning area and the factors contributing to the exceptional evaporation capability.Further exploration is conducted on the spread patterns of the wavy liquid film and flat liquid film on the evaporation wall throughout the process.It is noted that breaking the wavy liquid film on the evaporating wall during evaporation is challenging due to its film-forming condition.For which the fundamental causes are demonstrated by acquiring the data regarding the flow rate and temperature of the liquid film.The definitive findings of the analysis reveal a significant improvement in the evaporation capability of the wavy liquid film.This enhancement is attributed to increasing the shear-thinning areas and maintaining the overall shape of the film throughout the entire evaporation process. 展开更多
关键词 liquid film shape shear-thinning fluids flow characteristics evaporative heat transfer
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A Biomass-Based Hydrogel Evaporator Modified Through Dynamic Regulation of Water Molecules:Highly Efficient and Cost-Effective 被引量:1
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作者 Boqiu Luo Jin Wen +5 位作者 Hao Wang Size Zheng Rui Liao Wenjing Chen Omid Mahian Xiaoke Li 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第3期20-30,共11页
Solar-driven hydrogel evaporator used for water purification demonstrates great potential in seawater desalination and domestic sewage treatment.However,much uncertainty still exists about the most efficient design to... Solar-driven hydrogel evaporator used for water purification demonstrates great potential in seawater desalination and domestic sewage treatment.However,much uncertainty still exists about the most efficient design to obtain cost-effective drinkable water.In this paper,a natural rich biomass Nicandra physalodes(Linn.)Gaertn.polysaccharide was introduced into the polyvinyl alcohol network to control the water distribution during evaporation and build a low-cost hybrid hydrogel solar evaporator with a total material cost of$7.95 m^(−2).The mixed evaporator works stably in a long-span acid–base range(pH 1–14)and salinity range(0–320 g kg^(−1)).Its daily water purification capacity can reach 24.4 kg m^(−2)with a water purification capacity of 3.51 kg m^(−2)h^(−1)under sunlight.This paper provides a new possibility for a highly efficient and cost-effective water desalination system with guaranteed water quality by focusing on the dynamic regulation of water molecules at the evaporation interface. 展开更多
关键词 DESALINATION HYDROGELS interfacial evaporation POLYSACCHARIDE solar energy
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Ionization Engineering of Hydrogels Enables Highly Efficient Salt‑Impeded Solar Evaporation and Night‑Time Electricity Harvesting 被引量:2
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作者 Nan He Haonan Wang +3 位作者 Haotian Zhang Bo Jiang Dawei Tang Lin Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期131-146,共16页
Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic ... Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic scale,have been considered the most promising candidate for solar evaporation.However,the simultaneous achievement of high evaporation efficiency and satisfactory tolerance to salt ions in brine remains a challenging scientific bottleneck,restricting the widespread application.Herein,we report ionization engineering,which endows polymer chains of hydrogels with electronegativity for impeding salt ions and activating water molecules,fundamentally overcoming the hydrogel salt-impeded challenge and dramatically expediting water evaporating in brine.The sodium dodecyl benzene sulfonate-modified carbon black is chosen as the solar absorbers.The hydrogel reaches a ground-breaking evaporation rate of 2.9 kg m−2 h−1 in 20 wt%brine with 95.6%efficiency under one sun irradiation,surpassing most of the reported literature.More notably,such a hydrogel-based evaporator enables extracting clean water from oversaturated salt solutions and maintains durability under different high-strength deformation or a 15-day continuous operation.Meantime,on the basis of the cation selectivity induced by the electronegativity,we first propose an all-day system that evaporates during the day and generates salinity-gradient electricity using waste-evaporated brine at night,anticipating pioneer a new opportunity for all-day resource-generating systems in fields of freshwater and electricity. 展开更多
关键词 Solar evaporation Hydrogel evaporators Salt impeding Ionization engineering Cyclic vapor-electricity generation
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Effect of an Internal Heat Exchanger on the Performances of a Double Evaporator Ejector Refrigeration Cycle
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作者 Rachedi Khadraoui Latra Boumaraf Philippe Haberschill 《Fluid Dynamics & Materials Processing》 EI 2023年第5期1115-1128,共14页
A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by... A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by an internal heat exchanger(IHX).The ejector is introduced into the baseline cycle in order to mitigate the throttling process losses and increase the compressor suction pressure.Moreover,the IHX has the structure of a concentric counter-flow type heat exchanger and is intentionally used to ensure that the fluid at the compressor inlet is vapor.To assess accurately the influence of the IHX on the DEERC performance,a mathematical model is derived in the frame of the dominant one-dimensional theory for ejectors.The model also accounts for the friction effect in the ejector mixing section.The equations of this model are solved using an Engineering Equation Solver(EES)for different fluids.These are:R134a as baseline fluid and other environment friendly refrigerants used for comparison,namely,R1234yf,R1234ze,R600,R600a,R290,R717 and R1270.The simulation results show that the DEERC with an IHX can achieve COP(the coefficient of performance)improvements from 5.2 until 10%. 展开更多
关键词 Refrigeration cycle double evaporator EJECTOR IHX performance improvement environment-friendlyrefrigerants
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Efficient desorption and reuse of collector from the flotation concentrate:A case study of scheelite
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作者 Liming Tao Jianjun Wang +6 位作者 Dejin Liao Wenkai Jia Zihan Zhao Wenfang Che Zhongxu Qi Wei Sun Zhiyong Gao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2435-2444,共10页
Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and floatable.In the hydrometallurgy of concentrate,collectors adsor... Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and floatable.In the hydrometallurgy of concentrate,collectors adsorbed on concentrate can damage ion-exchange resin and increase the chemical oxygen demand(COD)value of wastewater.In this work,we proposed a new scheme,i.e.,desorbing the collectors from concentrate in ore dressing plant and reusing them in flotation flowsheet.Lead nitrate and benzohydroxamic acid(Pb-BHA)complex is a common collector in scheelite flotation.In this study,different physical(stirring or ultrasonic waves)and chemical(strong acid or alkali environment)methods for facilitating the desorption of Pb-BHA collector from scheelite concentrate were explored.Single-mineral desorption tests showed that under the condition of pulp pH 13 and ultrasonic treatment for 15 min,the highest desorption rates of Pb and BHA from the scheelite concentrate were 90.48%and 63.75%,respectively.Run-of-mine ore flotation tests revealed that the reuse of desorbed Pb and BHA reduced the collector dosage by 30%for BHA and 25%for Pb.The strong alkali environment broke the chemical bonds between Pb and BHA.The cavitation effect of ultrasonic waves effectively reduced the interaction intensity between Pb-BHA collector and scheelite surfaces.This method combining ultrasonic waves and strong alkali environment can effectively desorb the collectors from concentrate and provide“clean”scheelite concentrate for metallurgic plants;the reuse of desorbed collector in flotation flowsheet can reduce reagent cost for ore dressing plants. 展开更多
关键词 scheelite concentrate collector DESORPTION REUSE FLOTATION
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Performance Evaluation of an Evaporative Cooling Pad for Humidification-Dehumidification Desalination
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作者 Ibtissam El Aouni Hicham Labrim +4 位作者 Elhoussaine Ouabida Ahmed Ait Errouhi Rachid El Bouayadi Driss Zejli Aouatif Saad 《Fluid Dynamics & Materials Processing》 EI 2024年第10期2323-2335,共13页
The perfect combination of renewable energy and desalination technologies is the key to meeting water demands in a cost-effective,efficient and environmentally friendly way.The desalination technique by humidification... The perfect combination of renewable energy and desalination technologies is the key to meeting water demands in a cost-effective,efficient and environmentally friendly way.The desalination technique by humidificationdehumidification is non-conventional approach suitable for areas with low infrastructure(such as rural and decentralized regions)since it does not require permanent maintenance.In this study,this technology is implemented by using solar energy as a source of thermal power.A seawater desalination unit is considered,which consists of a chamber with two evaporators(humidifiers),a wetted porous material made of a corrugated cellulose cardboard and a condenser(dehumidifier).The evaporation system is tested with dry bulb temperature and relative air humidity data.The results of numerical simulations indicate that higher inlet air velocities(from 0.75 to 3 m/s)lead to a decrease in theΔT,ΔRH,and effectiveness.With the air remaining within the evaporator for 30 cm,the temperature differential increases to 5.7°C,accompanied by a 39%rise in relative humidity contrast.These changes result in a significant enhancement in humidification efficiency,achieving a remarkable efficiency level of 78%.However,a wettability value of 630 m^(2)/m^(3)leads to a smaller reduction of these parameters.Increasing the pad thickness,particularly to 0.3 m,improves performance by boostingΔT,ΔRH,and effectiveness,especially for pads with a wettability of 630 m^(2)/m^(3),for which superior performances are predicted by the numerical tests. 展开更多
关键词 DESALINATION HUMIDIFICATION DEHUMIDIFICATION porous material solar energy evaporator
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A Study on the Performances of Solar Air Collectors Having a Hemispherical Dimple on the Absorber Plate
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作者 Shuilian Li Fan Zeng Xinli Wei 《Fluid Dynamics & Materials Processing》 EI 2024年第5期939-955,共17页
In order to increase the efficiency of solar air collectors,a new variant with a protrusion is proposed in this study,and its performances are analyzed from two points of view,namely,in terms of optics and thermodynam... In order to increase the efficiency of solar air collectors,a new variant with a protrusion is proposed in this study,and its performances are analyzed from two points of view,namely,in terms of optics and thermodynamics aspects.By comparing and analyzing the light paths of the protrusion and the dimple,it can be concluded that when sunlight shines on the dimple,it is reflected and absorbed multiple times,whereas for the sunlight shining on the protrusion,there is no secondary reflection or absorption of light.When the lighting area and the properties of the surfaces are the same,the absorption rate of the dimple is 10.3 percentage points higher than that of the protrusion.In the range of Reynolds number from 3000 to 11000,numerical simulations about the effects of the relative height(e/Dh=0.033–0.1)and relative spacing(p/e=4.5–8.5)of protrusions on air heat transfer and flow resistance show that,in terms of comprehensive evaluation coefficient(PF),the best relative height is 0.085,when the relative spacing is 5.A correlation of Nu and f with Re,e/Dh and p/e is obtained by linear regression of the results,in order to provide a useful reference for the design and optimization of this kind of solar air collector. 展开更多
关键词 Heat transfer hemispherical protrusion DIMPLE solar air collector CORRELATION
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Revisiting aluminum current collector in lithium-ion batteries:Corrosion and countermeasures
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作者 Shanglin Yang Jinyan Zhong +1 位作者 Songmei Li Bin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期610-634,I0014,共26页
With the large-scale service of lithium-ion batteries(LIBs),their failures have attracted significant attentions.While the decay of active materials is the primary cause for LIB failures,the degradation of auxiliary m... With the large-scale service of lithium-ion batteries(LIBs),their failures have attracted significant attentions.While the decay of active materials is the primary cause for LIB failures,the degradation of auxiliary materials,such as current collector corrosion,should not be disregarded.Therefore,it is necessary to conduct a comprehensive review in this field.In this review,from the perspectives of electrochemistry and materials,we systematically summarize the corrosion behavior of aluminum cathode current collector and propose corresponding countermeasures.Firstly,the corrosion type is clarified based on the properties of passivation layers in different organic electrolyte components.Furthermore,a thoroughgoing analysis is presented to examine the impact of various factors on aluminum corrosion,including lithium salts,organic solvents,water impurities,and operating conditions.Subsequently,strategies for electrolyte and protection layer employed to suppress corrosion are discussed in detail.Lastly and most importantly,we provide insights and recommendations to prevent corrosion of current collectors,facilitate the development of advanced current collectors and the implementation of next-generation high-voltage stable LIBs. 展开更多
关键词 Lithium-ion battery Aluminum current collector CORROSION Electrochemical performance ELECTROLYTE Protective layer
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Heat Transfer Enhancement of the Absorber Tube in a Parabolic Trough Solar Collector through the Insertion of Novel Cylindrical Turbulators
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作者 Yasser Jebbar Fadhil Fluiful Wisam Khudhayer 《Fluid Dynamics & Materials Processing》 EI 2024年第6期1279-1297,共19页
This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1... This study includes an experimental and numerical analysis of the performances of a parabolic trough collector(PTC)with and without cylindrical turbulators.The PTC is designed with dimensions of 2.00 m in length and 1.00 m in width.The related reflector is made of lined sheets of aluminum,and the tubes are made of stainless steel used for the absorption of heat.They have an outer diameter of 0.051 m and a wall thickness of 0.002 m.Water,used as a heat transfer fluid(HTF),flows through the absorber tube at a mass flow rate of 0.7 kg/s.The dimensions of cylindrical turbulators are 0.04 m in length and 0.047 m in diameter.Simulations are performed using the ANSYS Fluent 2020 R2 software.The PTC performance is evaluated by comparing the experimental and numerical outcomes,namely,the outlet temperature,useful heat,and thermal efficiency for a modified tube(MT)(tube with novel cylindrical turbulators)and a plain tube(PT)(tube without novel cylindrical turbulators).According to the results,the experimental outlet temperatures recorded 63.2°C and 50.5°C for the MT and PT,respectively.The heat gain reaches 1137.5 Win the MT and 685.8 Win the PT.Compared to the PT collector,the PTC exhibited a(1.64 times)higher efficiency. 展开更多
关键词 Parabolic trough collector turbulators absorber tube ANSYS thermal efficiency
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Tree‑Inspired Structurally Graded Aerogel with Synergistic Water,Salt,and Thermal Transport for High‑Salinity Solar‑Powered Evaporation
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作者 Xiaomeng Zhao Heng Zhang +3 位作者 Kit‑Ying Chan Xinyue Huang Yunfei Yang Xi Shen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期19-37,共19页
Solar-powered interfacial evaporation is an energy-efficient solution for water scarcity.It requires solar absorbers to facilitate upward water transport and limit the heat to the surface for efficient evaporation.Fur... Solar-powered interfacial evaporation is an energy-efficient solution for water scarcity.It requires solar absorbers to facilitate upward water transport and limit the heat to the surface for efficient evaporation.Furthermore,downward salt ion transport is also desired to prevent salt accumulation.However,achieving simultaneously fast water uptake,downward salt transport,and heat localization is challenging due to highly coupled water,mass,and thermal transport.Here,we develop a structurally graded aerogel inspired by tree transport systems to collectively optimize water,salt,and thermal transport.The arched aerogel features root-like,fan-shaped microchannels for rapid water uptake and downward salt diffusion,and horizontally aligned pores near the surface for heat localization through maximizing solar absorption and minimizing conductive heat loss.These structural characteristics gave rise to consistent evaporation rates of 2.09 kg m^(-2) h^(-1) under one-sun illumination in a 3.5 wt%NaCl solution for 7 days without degradation.Even in a high-salinity solution of 20 wt%NaCl,the evaporation rates maintained stable at 1.94 kg m^(-2) h^(-1) for 8 h without salt crystal formation.This work offers a novel microstructural design to address the complex interplay of water,salt,and thermal transport. 展开更多
关键词 Composite aerogel Graded structure Solar-powered evaporation Thermal insulation Salt rejection
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Current collectors’ effects on the electrochemical performance of LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2) suspension electrodes for lithium slurry battery
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作者 Linshan Peng Yufei Ren +3 位作者 Zhaoqiang Yin Zhitong Wang Xiangkun Wu Lan Zhang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第8期1306-1313,共8页
Take after the advantages of lithium-ion battery (LIB) and redox flow battery (RFB), semi-solid flow battery (SSFB) is a promising electrochemical energy storage device in renewable energy utilization. The flowable sl... Take after the advantages of lithium-ion battery (LIB) and redox flow battery (RFB), semi-solid flow battery (SSFB) is a promising electrochemical energy storage device in renewable energy utilization. The flowable slurry electrode realizes decouple of energy and power density, while it also brings about new challenge to SSFBs, electron transport between active material and the out circuit. In this consideration, three types of current collectors (CCs) are applied to study the resistance and electrochemical performances of slurry cathodes within pouch cells for the first time. It proves that the electronic resistance (Re) between slurry electrode and the CC plays a decisive role in SSFB operation, and it is so large when Al foil is adopted that the cell cannot even work. Contact angle between Ketjen black (KB) slurry without active material (AM) and the CC is a preliminarily sign for the Re, the smaller the angle, the lower the resistance, and the better electrochemical performance of the cell. 展开更多
关键词 Semi-solid flow battery Slurry electrode Current collector Electronic resistance Carbon coated Al
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Rebuilding the theory of isotope fractionation for evaporation of silicate melts under vacuum condition
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作者 Jie Wang Yun Liu 《Acta Geochimica》 EI CAS CSCD 2024年第4期661-676,共16页
Isotope eff ects are pivotal in understanding silicate melt evaporation and planetary accretion processes.Based on the Hertz-Knudsen equation,the current theory often fails to predict observed isotope fractionations o... Isotope eff ects are pivotal in understanding silicate melt evaporation and planetary accretion processes.Based on the Hertz-Knudsen equation,the current theory often fails to predict observed isotope fractionations of laboratory experiments due to its oversimplified assumptions.Here,we point out that the Hertz-Knudsen-equation-based theory is incomplete for silicate melt evaporation cases and can only be used for situations where the vaporized species is identical to the one in the melt.We propose a new model designed for silicate melt evaporation under vacuum.Our model considers multiple steps including mass transfer,chemical reaction,and nucleation.Our derivations reveal a kinetic isotopic fractionation factor(KIFF orα)αour model=[m(^(1)species)/m(^(2)species)]^(0.5),where m(species)is the mass of the reactant of reaction/nucleation-limiting step or species of diffusion-limiting step and superscript 1 and 2 represent light and heavy isotopes,respectively.This model can eff ectively reproduce most reported KIFFs of laboratory experiments for various elements,i.e.,Mg,Si,K,Rb,Fe,Ca,and Ti.And,the KIFF-mixing model referring that an overall rate of evaporation can be determined by two steps jointly can account for the eff ects of low P_(H2)pressure,composition,and temperature.In addition,we find that chemical reactions,diffusion,and nucleation can control the overall rate of evaporation of silicate melts by using the fitting slope in ln(−ln f)versus ln(t).Notably,our model allows for the theoretical calculations of parameters like activation energy(E_(a)),providing a novel approach to studying compositional and environmental eff ects on evaporation processes,and shedding light on the formation and evolution of the proto-solar and Earth-Moon systems. 展开更多
关键词 evaporATION Kinetic isotopic fractionation Chemical kinetics Hertz-Knudsen equation CAIS
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Nitrogen-doped microporous graphite-enhanced copper plasmonic effect for solar evaporation
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作者 Xintao Wu Chengcheng Li +7 位作者 Ziqi Zhang Yang Cao Jieqiong Wang Xinlong Tian Zhongxin Liu Yijun Shen Mingxin Zhang Wei Huang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第3期215-223,共9页
Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Imp... Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Improving photothermal conversion efficiency and reducing water evaporation enthalpy are the two key strategies for the designing of PCMs.The desired PCMs that combine both of these properties remain a challenging task,even with the latest advancements in the field.Herein,we developed copper nanoparticles(NPs)with different conjugated nitrogen-doped microporous carbon coatings(Cu@C–N)as PCMs.The microporous carbon enveloping layer provides a highly efficient pathway for water transport and a nanoconfined environment that protects Cu NPs and facilitates the evaporation of water clusters,reducing the enthalpy of water evaporation.Meanwhile,the conjugated nitrogen nodes form strong metal-organic coordination bonds with the surface of copper NPs,acting as an energy bridge to achieve rapid energy transfer and provide high solar-to-vapor conversion efficiency.The Cu@C–N exhibited up to 89.4%solar-to-vapor conversion efficiency and an evaporation rate of 1.94 kgm^(−2) h^(−1) under one sun irradiation,outperforming conventional PCMs,including carbon-based materials and semiconductor materials.These findings offer an efficient design scheme for high-performance PCMs essential for solar evaporators to address global water scarcity. 展开更多
关键词 NANOCONFINEMENT photothermal conversion materials plasmonic resonance seawater desalination solar evaporation
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Harnessing overlapped temperature-salinity gradient in solar-driven interfacial seawater evaporation for efficient steam and electricity generation
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作者 Peida Li Dongtong He +2 位作者 Jingchang Sun Jieshan Qiu Zhiyu Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期694-700,I0015,共8页
Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity grad... Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold. 展开更多
关键词 Solar-driven interfacial water evaporation Steam generation Electricity generation Seawater
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Variations in evaporation from water surfaces along the margins of the Badain Jaran Desert over nearly 60 years and influencing factors
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作者 Li-juan Wang Zhe Wang +3 位作者 Gao-lei Jiang Zhen-long Nie Jian-mei Shen Sheng-hua Song 《Journal of Groundwater Science and Engineering》 2024年第3期253-263,共11页
Based on meteorological data collected over nearly 60 years(1960-2017)from four national meteorological stations along the margins of the Badain Jaran Desert,this study analyzed the spatiotemporal variations in evapor... Based on meteorological data collected over nearly 60 years(1960-2017)from four national meteorological stations along the margins of the Badain Jaran Desert,this study analyzed the spatiotemporal variations in evaporation from water surfaces and identified the dominant controlling factors.Methods used included linear trend analysis,linear tendency estimation,the departure method,the rank correlation coefficient-based method,and Multiple Linear Regression(MLR).Results indicate notable spatiotemporal differences in evaporation distribution and evolution.Spatially,average annual evaporation exhibited a pronounced altitude effect,decreasing at a rate of about 8.23 mm/m from east to west with increasing altitude.Temporally,annual evaporation showed significant upward trends after 1996 at the northeastern(Guaizi Lake)and western(Dingxin)margins,with rates of 132 mm/10a and 105 mm/10a,respectively.Conversely,along the northwestern(Ejina Banner)and southern(Alxa Right Banner)margins of the desert,an evaporation paradox was observed,with annual evaporation trending downward at rates of 162 mm/10a and 187 mm/10a,respectively,especially after 1987.The dominant factors controlling evaporation varied spatially:Average annual temperature and relative humidity influended the western margin(Dingxin),average annual temperature was the key factor for the northeastern margin(Guaizi Lake),and average wind speed was crucial for the northern(Ejina Banner)and southern(Alxa Right Banner)margins. 展开更多
关键词 evaporation from water surface evaporation paradox Dominant controlling factor Variation trend
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Laser-Constructing 3D Copper Current Collector with Crystalline Orientation Selectivity for Stable Lithium Metal Batteries
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作者 Hui Li Gang Wang +3 位作者 Jin Hu Jun Li Jiaxu Huang Shaolin Xu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第6期129-139,共11页
The practical application of lithium(Li)metal anodes in high-capacity batteries is impeded by the formation of hazardous Li dendrites.To address this challenge,this research presents a novel methodology that combines ... The practical application of lithium(Li)metal anodes in high-capacity batteries is impeded by the formation of hazardous Li dendrites.To address this challenge,this research presents a novel methodology that combines laser ablation and heat treatment to precisely induce controlled grain growth within laser-structured grooves on copper(Cu)current collectors.Specifically,this approach enhances the prevalence of Cu(100)facets within the grooves,effectively lowering the overpotential for Li nucleation and promoting preferential Li deposition.Unlike approaches that modify the entire surface of collectors,our work focuses on selectively enhancing lithiophilicity within the grooves to mitigate the formation of Li dendrites and exhibit exceptional performance metrics.The half-cell with these collectors maintains a remarkable Coulombic efficiency of 97.42%over 350 cycles at 1 mA cm^(−2).The symmetric cell can cycle stably for 1600 h at 0.5 mA cm^(−2).Furthermore,when integrated with LiFePO4 cathodes,the full-cell configuration demonstrates outstanding capacity retention of 92.39%after 400 cycles at a 1C discharge rate.This study introduces a novel technique for fabricating selective lithiophilic three-dimensional(3D)Cu current collectors,thereby enhancing the performance of Li metal batteries.The insights gained from this approach hold promise for enhancing the performance of all laser-processed 3D Cu current collectors by enabling precise lithiophilic modifications within complex structures. 展开更多
关键词 copper current collector heat treatment laser processing lithium metal battery selective crystalline orientation
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The Effects of the Geometry of a Current Collector with an Equal Open Ratio on Output Power of a Direct Methanol Fuel Cell
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作者 Yingli Zhu Jiachi Xie +2 位作者 Mingwei Zhu Jun Zhang Miaomiao Li 《Energy Engineering》 EI 2024年第5期1161-1172,共12页
The open ratio of a current collector has a great impact on direct methanol fuel cell(DMFC)performance.Although a number of studies have investigated the influence of the open ratio of DMFC current collectors,far too ... The open ratio of a current collector has a great impact on direct methanol fuel cell(DMFC)performance.Although a number of studies have investigated the influence of the open ratio of DMFC current collectors,far too little attention has been given to how geometry(including the shape and feature size of the flow field)affects a current collector with an equal open ratio.In this paper,perforated and parallel current collectors with an equal open ratio of 50%and different feature sizes are designed,and the corresponding experimental results are shown to explain the geometry effects on the output power of the DMFC.The results indicate that the optimal feature sizes are between 2 and 2.5 mm for both perforated and parallel flow field in the current collectors with an equal open ratio of 50%.This means that for passive methanol fuel cells,to achieve the highest output power,the optimal feature size of the flow field in both anode and cathode current collectors is between 2 and 2.5 mm under the operating mode of this experiment.The effects of rib and channel position are also investigated,and the results indicate that the optimum pattern depends on the feature sizes of the flow field. 展开更多
关键词 Direct methanol fuel cell GEOMETRY open ratio current collector POSITION
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Thermodynamic Analysis and Optimization of Flat Plate Solar Collector Using TiO_(2)/Water Nanofluid
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作者 Firas F.Qader Falah Z.Mohammed Barhm Mohamad 《Journal of Harbin Institute of Technology(New Series)》 CAS 2024年第4期61-73,共13页
To research solar energy's efficiency and environmental benefits,the thermal efficiency,exergy,and entropy of solar collectors were calculated.The experiment involved two glass-topped collectors,fluid transfer tub... To research solar energy's efficiency and environmental benefits,the thermal efficiency,exergy,and entropy of solar collectors were calculated.The experiment involved two glass-topped collectors,fluid transfer tubes,and aluminum heat-absorbing plates.Glass wool insulation minimized heat loss.A 0.5% TiO_(2)/Water nanofluid was created using a mechanical and ultrasonic stirrer.Results showed that solar radiation increased thermal efficiency until midday,reaching 48.48% for water and 51.23% for the nanofluid.With increasing mass flow rates from 0.0045 kg/s to 0.02 kg/s,thermal efficiency improved from 16.26% to 47.37% for water and from 20.65% to 48.76% for the nanofluid.Filtered water provided 380 W and 395 W of energy in March and April,while the nanofluid increased it to 395 W and 415 W during these months.Mass flow generated energy,and the Reynolds number raised entropy.The noon exergy efficiency for nanofluids was 50%-55%,compared to 30% for water.At noon,the broken exergy measured 877.53 W for the nanofluid and 880.12 W for water.In Kirkuk,Iraq,the 0.5% TiO_(2)/Water nanofluid outperformed water in solar collectors. 展开更多
关键词 ENERGY EXERGY entropy generation NANOFLUID flat plate solar collector
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