In order to study the combustion characteristics of waste tire particle (WTP), pulverized coal (PC) and their mixture, the contents of CO, CO2 and O2 of off-gas during the combustion of WTP, PC and mixture under t...In order to study the combustion characteristics of waste tire particle (WTP), pulverized coal (PC) and their mixture, the contents of CO, CO2 and O2 of off-gas during the combustion of WTP, PC and mixture under the condition of rich oxygen by 0--4% in blast and at 1 250℃ were measured simultaneously using synthetically infrared analyzer, and then the corresponding combustion ratio was calculated and compared. The results showed that the burning rate of WTP reached approximately 57%, which is much higher than that of PC (only about 18%) in the in- itial 650 s in fresh air, and then the increase of combustion rate of PC is faster than that of WTP; the combustion rate of PC improved remarkably with the addition of WTP. Meanwhile, the combustion rates of all these materials improved with the increase of oxygen content.展开更多
Domestic coal stove is widely used in China, especially for countryside during heating period of winter, and polycyclic aromatic hydrocarbons (PAHs) are important in flue gas of the stove. By using dilution tunnel s...Domestic coal stove is widely used in China, especially for countryside during heating period of winter, and polycyclic aromatic hydrocarbons (PAHs) are important in flue gas of the stove. By using dilution tunnel system, samples of both gaseous and particulate phases from domestic coal combustion were collected and 18 PAH species were analyzed by GC-MS. The average emission factors of total 18 PAH species was 171.73 mg/kg, ranging from 140.75 to 229.11 mg/kg for bituminous coals, while was 93.98 mg/kg, ranging from 58.48 to 129.47 mg/kg for anthracite coals. PAHs in gaseous phases occupied 95% of the total of PAHs emission of coal combustion. In particulate phase, 3-ring and 4- ring PAHs were the main components, accounting for 80% of the total particulate PAHs. The total toxicity potency evaluated by benzo[a]pyrene-equivalent carcinogenic power, sum of 7 carcinogenic PAH components and 2,3,7,8-tetrachlorodibenzodioxin had a similar tendency. And as a result, the toxic potential of bituminous coal was higher than that of anthracite coal. Efficient emission control should be conducted to reduce PAH emissions in order to protect ecosystem and human health.展开更多
The combustion properties and grindability of Shenmu low-rank coal(SM)and its four different semi-cokes were studied by the self-designed equipment and Hardgrove method.The four semi-cokes were obtained under the pyro...The combustion properties and grindability of Shenmu low-rank coal(SM)and its four different semi-cokes were studied by the self-designed equipment and Hardgrove method.The four semi-cokes were obtained under the pyrolysis temperature of 400,500,600 and 700℃,named as SM-400,SM-500,SM-600 and SM-700,respectively.The analyses of nitrogen adsorp-tion,Fourier-transform infrared spectroscopy(FTIR)spectra and Raman spectra were carried out to explain the change in combustion ratio and grindability.The result showed that the specific surface area of samples had an essential effect on the combustion ratio of SM-400 and SM-500.Meanwhile,the grindability depended on the strength of coal matrix,and the augment of pore amounts would increase the grindability.The functional groups and graphitization degree of the same sam-ple were identical with the combustion ratio.With the pyrolysis upgrading temperature increasing,the combustion ratio of sample decreased,corresponding to the decrease in the benzene ring and the increase in graphitization degree.In addition,the thermogravimetric analysis was carried out,and the result was compared against what was shown in the data of com-bustion ratio.For pulverized coal injection,the combustion ratio was more intuitive and more accurate than combustibility.展开更多
文摘In order to study the combustion characteristics of waste tire particle (WTP), pulverized coal (PC) and their mixture, the contents of CO, CO2 and O2 of off-gas during the combustion of WTP, PC and mixture under the condition of rich oxygen by 0--4% in blast and at 1 250℃ were measured simultaneously using synthetically infrared analyzer, and then the corresponding combustion ratio was calculated and compared. The results showed that the burning rate of WTP reached approximately 57%, which is much higher than that of PC (only about 18%) in the in- itial 650 s in fresh air, and then the increase of combustion rate of PC is faster than that of WTP; the combustion rate of PC improved remarkably with the addition of WTP. Meanwhile, the combustion rates of all these materials improved with the increase of oxygen content.
基金supported by the Natural Science Foundation of China(No.41275135,41105090)the National High Technology Research and Development Program(863)of China(No.2012AA063506)the Open Foundation of Environmental Simulation and Pollution Control State Key Laboratories(Peking University)
文摘Domestic coal stove is widely used in China, especially for countryside during heating period of winter, and polycyclic aromatic hydrocarbons (PAHs) are important in flue gas of the stove. By using dilution tunnel system, samples of both gaseous and particulate phases from domestic coal combustion were collected and 18 PAH species were analyzed by GC-MS. The average emission factors of total 18 PAH species was 171.73 mg/kg, ranging from 140.75 to 229.11 mg/kg for bituminous coals, while was 93.98 mg/kg, ranging from 58.48 to 129.47 mg/kg for anthracite coals. PAHs in gaseous phases occupied 95% of the total of PAHs emission of coal combustion. In particulate phase, 3-ring and 4- ring PAHs were the main components, accounting for 80% of the total particulate PAHs. The total toxicity potency evaluated by benzo[a]pyrene-equivalent carcinogenic power, sum of 7 carcinogenic PAH components and 2,3,7,8-tetrachlorodibenzodioxin had a similar tendency. And as a result, the toxic potential of bituminous coal was higher than that of anthracite coal. Efficient emission control should be conducted to reduce PAH emissions in order to protect ecosystem and human health.
基金the Natural Sci-ence Foundation for Young Scientists of China(No.51804026)the Fundamental Research Funds for the Central Universities(FRF-AT-18-001).
文摘The combustion properties and grindability of Shenmu low-rank coal(SM)and its four different semi-cokes were studied by the self-designed equipment and Hardgrove method.The four semi-cokes were obtained under the pyrolysis temperature of 400,500,600 and 700℃,named as SM-400,SM-500,SM-600 and SM-700,respectively.The analyses of nitrogen adsorp-tion,Fourier-transform infrared spectroscopy(FTIR)spectra and Raman spectra were carried out to explain the change in combustion ratio and grindability.The result showed that the specific surface area of samples had an essential effect on the combustion ratio of SM-400 and SM-500.Meanwhile,the grindability depended on the strength of coal matrix,and the augment of pore amounts would increase the grindability.The functional groups and graphitization degree of the same sam-ple were identical with the combustion ratio.With the pyrolysis upgrading temperature increasing,the combustion ratio of sample decreased,corresponding to the decrease in the benzene ring and the increase in graphitization degree.In addition,the thermogravimetric analysis was carried out,and the result was compared against what was shown in the data of com-bustion ratio.For pulverized coal injection,the combustion ratio was more intuitive and more accurate than combustibility.