Carbon nanoparticles（C-dots） were prepared by refluxing the combustion soots of candles and corn stalk in nitric acid.The synthesized C-dots were characterized.The results showed a sharp increase in oxygen content a...Carbon nanoparticles（C-dots） were prepared by refluxing the combustion soots of candles and corn stalk in nitric acid.The synthesized C-dots were characterized.The results showed a sharp increase in oxygen content and a sharp decrease in carbon content after oxidation.The C-dots had-OH and-CO2H groups introduced which made them hydrophilic.However,their difference was also obvious.The C-dots from candle soot had a 10-45 nm broad particle size distribution,and those from corn stalk soot had a 6-18 nm relatively small and narrow size distribution.The C-dots were mainly of sp2 and sp3 carbon structure different from the C-dots of diamond-like structure from candle soot.Interestingly,two kinds of C-dots all exhibited unique photoluminescent properties.The obtained C-dots have potential applications in a broad range of areas.展开更多
Forsterite particles doped with europium ions（Eu^（3＋）） were synthesized via a solution combustion method. The effect of co-dopants on photoluminescence intensity was described. Different percentages of calcium（...Forsterite particles doped with europium ions（Eu^（3＋）） were synthesized via a solution combustion method. The effect of co-dopants on photoluminescence intensity was described. Different percentages of calcium（Ca^（2＋））, zinc（Zn^（2＋））, barium（Ba^（2＋）） and strontium（Sr^（2＋）） were added to the Mg2SiO4：Eu^（3＋）host.The synthesized sample was characterized by X-ray diffraction, transmission electron microscopy,scanning electron microscopy, spectrofluorometer and the FTIR spectroscopy. X-ray diffraction（XRD）results revealed that dominant phase was forsterite in all samples. Additionally, a negligible amount of periclase phase was recognized in the samples. The average size of the synthesized particles was less than 200 nm. The presence of co-dopant led to an enhancement in the photoluminescent property of the synthesized samples. The maximum increase in photoluminescence intensity was obtained by Ba^（2＋）ions as a co-dopant. Condensed films of photoluminescence particles were produced by utilizing electrophoresis technique to deposit particles. The results showed that polyvinyl pyrrolidone was the best surface modifier to raise the mass deposition of the samples on the substrate.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.21465019 and 21266023)the Ningxia Natural Science Founds(NZ13011)+2 种基金the Research Project for Science and Technology of Higher Education of Ningxia Provine of China(NGY2014011)the Science and Technology Planning Project of Jiangsu Entryexit Inspection Quarantine Bureauof China(2016KJ50)the Zhenjiang Social Development Project(SH2014021)
文摘Carbon nanoparticles（C-dots） were prepared by refluxing the combustion soots of candles and corn stalk in nitric acid.The synthesized C-dots were characterized.The results showed a sharp increase in oxygen content and a sharp decrease in carbon content after oxidation.The C-dots had-OH and-CO2H groups introduced which made them hydrophilic.However,their difference was also obvious.The C-dots from candle soot had a 10-45 nm broad particle size distribution,and those from corn stalk soot had a 6-18 nm relatively small and narrow size distribution.The C-dots were mainly of sp2 and sp3 carbon structure different from the C-dots of diamond-like structure from candle soot.Interestingly,two kinds of C-dots all exhibited unique photoluminescent properties.The obtained C-dots have potential applications in a broad range of areas.
文摘Forsterite particles doped with europium ions（Eu^（3＋）） were synthesized via a solution combustion method. The effect of co-dopants on photoluminescence intensity was described. Different percentages of calcium（Ca^（2＋））, zinc（Zn^（2＋））, barium（Ba^（2＋）） and strontium（Sr^（2＋）） were added to the Mg2SiO4：Eu^（3＋）host.The synthesized sample was characterized by X-ray diffraction, transmission electron microscopy,scanning electron microscopy, spectrofluorometer and the FTIR spectroscopy. X-ray diffraction（XRD）results revealed that dominant phase was forsterite in all samples. Additionally, a negligible amount of periclase phase was recognized in the samples. The average size of the synthesized particles was less than 200 nm. The presence of co-dopant led to an enhancement in the photoluminescent property of the synthesized samples. The maximum increase in photoluminescence intensity was obtained by Ba^（2＋）ions as a co-dopant. Condensed films of photoluminescence particles were produced by utilizing electrophoresis technique to deposit particles. The results showed that polyvinyl pyrrolidone was the best surface modifier to raise the mass deposition of the samples on the substrate.
