Carbon decorated Li_(3)V_(2)(PO_(4))_(3) for high-rate lithium-ion batteries:Electrochemical performance and charge compensation mechanism

Fast charging and high-power delivering batteries are highly demanded in mobile electronics,electric vehicles and grid energy storage,but there are full of challenges.The star-material Li_(3)V_(2)(PO_(4))_(3) is demonstrated as a promising high-rate cathode material meeting the above requirements.Herein,we report the carbon decorated Li_(3)V_(2)(PO_(4))_(3) (LVP/C) cathode prepared via a facile method,which displays a remarkable high-rate capability and long-term cycling performance.Briefly,the prepared LVP/C delivers a high discharge capacity of 122 mAh g^(-1)(-93% of the theoretical capacity) at a high rate up to 20 C and a superior capacity retention of 87.1% after 1000 cycles.Importantly,by applying a combination of X-ray absorption spectroscopy and full-range mapping of resonant inelastic X-ray scattering,we clearly elucidate the structural and chemical evolutions of LVP upon various potentials and cycle numbers.We show unambiguous spectroscopic evidences that the evolution of the hybridization strength between V and O in LVP/C as a consequence of lithiation/delithiation is highly reversible both in the bulk and on the surface during the discharge-charge processes even over extended cycles,which should be responsible for the remarkable electrochemical performance of LVP/C.Our present study provides not only an effective synthesis strategy but also deeper insights into the surface and bulk electrochemical reaction mechanism of LVP,which should be beneficial for the further design of high-performance LVP electrode materials.

Ocean ecological compensation mechanism in Liaoning area from the angle of ecological civilization——based on analysis of Dalian's cooperative governance

How to speed up the establishment of marine ecological compensation and the ecological compensation system is inevitable choice from ocean country to marine power.Therefore,construction of marine ecological compensation mechanism is the effective means which incentives marine ecosystem services supply,improves the quality of marine ecology,and promotes the ocean to the green transformation.Combined with Dalian maritime case study in Liaoning Province,three dimensional interactive marine ecological compensation mechanism,the compensation frame work,path and operation mechanism were built up.Suggestions on accelerating the legislation process;perfecting the management system;establishing proper system for both incentive constraint and reward-punishment;increasing the source of Ocean Ecological Compensation funds;accelerating On the study of the Ocean Ecological Compensation Mechanism in Liaoning Area from the Angl-e of Ecological Civilization Based on Case Analysis of Dalian.

Public Policy Supply for Successful Practice of the Xin’anjiang River Ecological Compensation Mechanism

The ecological protection of the inter-provincial river basin of Xin’anjiang River takes the ecological compensation mechanism as the starting point and achieves good results.The success of the mechanism is best reflected in its innovation of public policy supply,which is not only a vivid practice of Xi Jinping’s ecological civilization thought in the new era,but also establishes a model for absorption,transformation and export of policy supply.The effective supply of public policies on ecological environment is the realistic choice for the construction of ecological civilization in the new era.

Initial Exploration on the Ecological Compensation Mechanism of Baiyangdian Watershed

Establishment of the ecological compensation mechanism is one important way for solving a series of issues in Baiyangdian Watershed, including environment pollution, ecological deterioration, unsustained water supplement, rural pollution aggravation and ecological migration. Based on the principles of main functional area, public goods, welfare economics, financial transfer payment and watershed management, we put forward the construction framework of ecological compensation mechanism in Baiyangdian Watershed. Compensation subject is governments at all levels and beneficiary within watershed. Compensation object is governments at all levels, eco-builder and victim within watershed. Compensation way in- dudes government-led and market-oriented and game-negotiation types. Compensation standard includes financial transfer payment, compensation between upstream and downstream of the watershed, rural environmental protection with collections of management fees and subsidies to co-gov- ernance, ecological migration and inter-basin section. The safeguard measures of implementation for ecological compensation mechanism in Baiy- angdian Watershed are setting legal system and status of the ecological compensation, ensuring special usage of the ecological compensation fund, carrying out performance evaluation index system, building social management system of the ecological compensation and promoting the reform of watershed manaQement structure.

Core Issues in Design of Tibetan Grassland Ecological Compensation Mechanism

Scientific grassland ecological compensation mechanism is favorable for improving the grassland ecological environment and promote the sustainable development of animal husbandry. Combined with actual situations of Tibet,this paper discussed core issues in the design of grassland ecological compensation mechanism,including compensation purpose,compensation subject,compensation object,compensation standard,and compensation method. It pointed out that the design of mechanism is a complex and systematic project. Each issue is complex and varied. The government at all levels should be cautious and make scientific treatment,and should not apply a single solution for all issues.

Perfecting the Market-Oriented Ecological Compensation Mechanism of Ethnic Minority Areas: A Case Study of Gannan Tibetan Autonomous Prefecture

The construction of the market-oriented ecological compensation mechanism in China is complicated system engineering. China's ecological compensation funds are mainly derived from the public finance, lacking market-oriented operation. That not only increases the financial burden of the government, but also leads to the incomprehensive compensation scope. Moreover, China's ecological compensation lacks market mechanism so that it is difficult to set compensation standards and calculate offsets. This paper takes Gannan Tibetan Autonomous Prefecture as an example to analyze the market-oriented ecological compensation system of ethnic minority areas from the perspective of market economy, so as to provide a theoretical basis and a reference point for the establishment of efficient and reasonable ecological compensation mechanism and policies in ethnic minority areas and provide environmental protection for the sustainable development of economy and society of ethnic minority areas.

Ecological compensation mechanism for Beijing-Tianjin-Hebei region based on footprint balance and footprint deficit

Construction of the ecological compensation mechanism is an important approach to put the“Beijing-Tianjin-Hebei Coordinated Development Plan”into practice and improve the ecological environment of the Beijing-Tianjin-Hebei region.This paper constructs an ecological compensation mechanism for the Beijing-Tianjin-Hebei region based on the footprint balance and footprint deficit after clarifying ecological governance objectives.First,this paper proposes to establish a uniform,hierarchical and classified supply mechanism of ecosystem services according to the classification of land resources,water resources and forest resources for the Beijing-Tianjin-Hebei region.Then,the“Authority with Corresponding Responsibility”for the supply of ecosystem services in the Beijing-Tianjin-Hebei region can be realized through a footprint balance and footprint deficit indicator circulation mechanism.Finally,the scientific and rational ecological compensation standard can be guaranteed through establishing the integrated governance mechanism for ecological compensation in the Beijing-Tianjin-Hebei region and improving the“ecological compensation standard”.The results of this paper can provide sound theoretical support for effectively promoting the improvement of ecosystem services and human well-being in the Beijing-Tianjin-Hebei region.

Compensation mechanism for ecological interests of Erhai Lake tourist destination in Dali, Yunnan province

Erhai Lake in Dali,Yunnan province,is the"Mother Lake"of the Bai people.It has superior location advantages,remarkable comprehensive functions and profound historical culture.It is the cradle of Dali’s politics,economy and culture,and also the foundation of the sustainable economic development of the Autonomous Prefecture.After the government put great efforts to govern Erhai Lake,the original interest demand structure of the surrounding residents was broke down,and the problems of interest friction and interest conflict became the practical problems faced by the region.This paper will analyze the compensation mechanism of Erhai Lake’s ecological interests from the aspects of ecological damage,stakeholders,interests,tourism transformation and so on,so as to provide a reference for the transformation and upgrading of national tourism destinations and tourism industry.

Improving the ecological compensation mechanism for drinking water source in Yunnan province

Ecological compensation mechanism for drinking water source is one of the effective economic ways to solve the issues of the shortage of the protection investment and the lack of the driving forces to protect the water quality.The successful cases of compensation mechanism for drinking water source have examined the dilemma of improving the trans-administrative boundary compensation mechanism both in China and Yunnan.The lack of the provincial rules and regulations in Yunnan is the fundamental reason for the local government not willingly to establish the compensation mechanism.On the other hand,the shortage of the compensation funds is the key difficulty for the shareholders to reach an agreement.Formulating the rules and regulations about the construction of the compensation mechanism of drinking water source in Yunnan would be a feasible way to stipulate the local government to set up the compensation mechanism.Meanwhile,designing a complete set of compensation mechanism would make full use of the mechanism to work well to protect the water quality in an economic way.

Auxiliary Service Dynamic Compensation Mechanism Design for Incentivizing Market Participants to Provide Flexibility in China

Because of the rapid growth of new energy and the accompanying considerable uncertainty in the power market,the demand for flexibility in a power sys-tem has risen sharply.In the meantime,the market structure of auxiliary services has changed,resulting in market participants(MPs)benefiting less than expected from providing flexible services.To encourage MPs to provide flexibility,this study proposes a dynamic design framework for an auxiliary service compensation mech-anism.To evaluate the proposed framework,a case study is conducted,examining a peak-shaving service in Liao-ning province in northeast China.First,the operational status and limitations of the typical product,the peak-shaving service,in China’s flexibility auxiliary ser-vices market are analyzed.Then,taking into considera-tion the time value of the flexible products provided by the MPs,a dynamic mechanism for hierarchical compensa-tion of flexibility auxiliary service costs is proposed,and a mathematical model aimed at optimizing the MPs’com-prehensive income is constructed.The results show that,compared with the existing traditional mechanism,the proposed method can effectively guarantee fair remu-neration for the flexibility provider,while easing the tense supply-demand relationship in the flexibility market.Index Terms—Power system flexibility,auxiliary ser-vices market,peak shaving auxiliary service,differenti-ated operation scenario,dynamic hierarchical compensa-tion mechanism.

Case study on the mechanics of NPR anchor cable compensation for large deformation tunnel in soft rock in the Transverse Mountain area,China

A study was conducted to analyze the deformation mechanism of strongly weathered quartz schist in the Daliangshan Tunnel,located in the western Transverse Mountain area.A large deformation problem was experienced during the tunnel construction.To mitigate this problem,a support system was designed incorporating negative Poisson ratio(NPR)anchor cables with negative Poisson ratio effect.Physical model experiments,field experiments,and numerical simulation experiments were conducted to investigate the compensation mechanical behavior of NPR anchor cables.The large deformations of soft rocks in the Daliangshan Tunnel are caused by a high ground stress,a high degree of joint fracture development,and a high degree of surrounding rock fragmentation.A compensation mechanics support system combining long and short NPR anchor cables was suggested to provide sufficient counter-support force(approximately 350 kN)for the surrounding rock inside the tunnel.Comparing the NPR anchor cable support system with the original support system used in the Daliangshan tunnel showed that an NPR anchor cable support system,combining cables of 6.3 m and 10.3 m in length,effectively prevented convergence of surrounding rock deformation,and the integrated settlement convergence value remained below 300 mm.This study provides an effective scientific basis for resolving large deformation problems in deeply buried soft rocks in western transverse mountain areas.

A discussion on compensation of forest ecological engineering benefit

On the basis of analysis of the present situation of the ecological benefit compensation in China and foreign countries, this paper discusses the necessity, principle and approach of establishing the compensation mechanism of forest ecological benefit, as well as compensation standard in order to provide scientific basis for further perfecting the compensation mechanism of forest ecological engineering benefit in China. It is suggested that setting up the compensation mechanism of forest ecological benefit can not only provide the steady funds source of managing and protecting forest resources, but resolve radically the dynamic and mechanism problems of commonweal forest ecological engineering construction, which will produce a widespread and profound influence on China forestry and ecological construction.

Compensation for forest ecological services in China

The paper discusses methods to compensate for the costs incurred in the supply of forest ecological services （FES）, i.e. government dominated and market-based instruments as well as progress made so far in China. Factors which constrain the supply of these services and potential policy improvements are presented.

Controlling chaos based on an adaptive nonlinear compensator mechanism

The control problems of chaotic systems are investigated in the presence of parametric uncertainty and persistent external disturbances based on nonlinear control theory. By using a designed nonlinear compensator mechanism, the system deterministic nonlinearity, parametric uncertainty and disturbance effect can be compensated effectively. The renowned chaotic Lorenz system subjected to parametric variations and external disturbances is studied as an illustrative example. From the Lyapunov stability theory, sufficient conditions for choosing control parameters to guarantee chaos control are derived. Several experiments are carried out, including parameter change experiments, set-point change experiments and disturbance experiments. Simulation results indicate that the chaotic motion can be regulated not only to steady states but also to any desired periodic orbits with great immunity to parametric variations and external disturbances.

Mechanism of Ecological Compensating and Carbon Sink Trade in Qinghai-Tibet Plateau

The Tibetan, Han and other ethnic people in Tibetan Autonomous Region labored hard to protect the forests and steppes and produce invisible ecological products. The forests and steppes in Qinghai -Tibet Plateau conserved water and added the Jinsha River. In order to achieve sustainable development, it needs to construct compensating mechanism inter Provinces between the upper Yangtze River and the middle and lower Yangtze River, to implement carbon sink trading, and to assist farmers and herdsmen in the Tibet to get rich as soon as possible.

Intermolecular Vibrational Energy Transfers in Melts and Solutions

Resonant and nonresonant intermolecular vibrational energy transfers in Gdm- SCN/KSCN=1/1, GdmSCN/KS^13CN=1/1 and GdmSCN/KS^13C^15N=1/1 mixed crystals in melts and in aqueous solutions are studied with the two dimensional infrared spectroscopy. The energy transfers in the samples are slower with a larger energy donor/acceptor gap, independent of the Raman spectra. The energy gap dependences of the nonresonant energy transfers cannot be described by the phonon compensation mechanism. Instead, the experi- mental energy gap dependences can be quantitatively described by the dephasing mechanism. Temperature dependences of resonant and nonresonant energy transfer rates in the melts are also consistent with the prediction of the dephasing mechanism. The series of results suggest that the dephasing mechanism can be dominant not only in solutions, but also in melts （pure liquids without solvents）, only if the molecular motions （translations and rotations） are much faster than the nonresonant energy transfer processes.

Adaptive Memory Event-Triggered Observer-Based Control for Nonlinear Multi-Agent Systems Under DoS Attacks

This paper investigates the event-triggered security consensus problem for nonlinear multi-agent systems(MASs)under denial-of-service(Do S)attacks over an undirected graph.A novel adaptive memory observer-based anti-disturbance control scheme is presented to improve the observer accuracy by adding a buffer for the system output measurements.Meanwhile,this control scheme can also provide more reasonable control signals when Do S attacks occur.To save network resources,an adaptive memory event-triggered mechanism(AMETM)is also proposed and Zeno behavior is excluded.It is worth mentioning that the AMETM's updates do not require global information.Then,the observer and controller gains are obtained by using the linear matrix inequality(LMI)technique.Finally,simulation examples show the effectiveness of the proposed control scheme.

Monitoring long-term ecological impacts from release of Fukushima radiation water into ocean

After 10 years of the Fukushima Nuclear Accident,Japan decided to release the nuclear wastewater into the Pacific Ocean on 13 April 2021.It is apparent that Japan has chosen the most cost-efficient way to deal with the contaminated water,however,great opposition and concerns have been raised internationally due to the ecotoxicological features of radioactive materials and their harmful impacts on the environment.Here we an-alyze the ecological impacts caused by the nuclear accident and the potential impacts of releasing the nuclear wastewater into the ocean.Science-based solutions are proposed through a third-party evaluation and strict envi-ronmental assessment,multi-stakeholder public participation,integrated monitoring of the neighboring coastal countries,long-term international collaborative research,and setting up international convention for ecological compensation.

Population response of rodents to control with rodenticides

We summarize theoretical approaches and practice of rodent pest control in Russia and former USSR during last 50 years. We review literature as well as original data to understand mechanisms of rodent populations recovery after chemical control campaigns in urban areas, agricultural lands and natural foci of plague. Laboratory and field experiments indicate that inherent individual variation in behavioural, physiological and life-history traits provides survival of heterogeneous mix of individuals in residual population with increased resistance to poisonous baits and high reproductive potential that leads to fast recovery of a population. In a series of field experiments with various rodent and lagomorph species （Mus musculus, Rattus norvegicus, Meriones unguiculatus, M. meridianus, M. tamariscinus, Ochotona pallasii ） we have shown that patterns of recolonization of depopulated area and mechanisms of population recovery vary among species and depend on species-specific social organization. After control territorial and group-living species demonstrated an increase in mobility and affiliative and marking behaviour and a decrease in intraspecific aggression. The rate of recolonization of treated areas was high due to redistribution of survived individuals and immigration by neighbors. Population recovered to original level due to increased breeding performance and fecundity of both survived residents and immigrants. In contrast, socially-independent species exhibited minor changes in behaviour. Recolonization was mainly due to better survival and recruitment of youngs, so the rate of recolonization was low. Species-specificity of behavioural compensation mechanisms to control should be considered when developing ecologically based rodent management strategies

Experimental Study on Thermal Stress of Concrete with Different Expansive Minerals Using a Temperature Stress Testing Machine

In order to compare the compensation effect of expansive materials with different mineral sources on the temperature stress of concrete,we investigated the temperature stress of concrete when adding calcium sulfoaluminate type expansive materials(CSA)or CaO and calcium sulfoaluminate mixed type expansive materials(HCSA)at different temperatures by temperature-stress testing machine(TSTM)considering the influence of temperature history on the expansion.The experimental results show that the expansion characteristics of the two kinds of expansive materials with different mineral sources significantly vary.When adding expansive materials,the growth rate of compressive stress during the heating stage increases obviously,the maximum compressive stress is higher,while the decline rate of tensile stress in the late cooling stage becomes slow,and finally cracking temperature decreases.It is proved that concrete with HCSA has lower cracking temperatures and better temperature shrinkage compensation effect.Therefore,it is rational to choose HCSA when preparing concrete with high expansion energy to reduce thermal cracking.