The complex mechanical and damage mechanisms of rocks are intricately tied to their diverse mineral compositions and the formation of pores and cracks under external loads.Numerous rock tests reveal a complex interpla...The complex mechanical and damage mechanisms of rocks are intricately tied to their diverse mineral compositions and the formation of pores and cracks under external loads.Numerous rock tests reveal a complex interplay between the closure of porous defects and the propagation of induced cracks,presenting challenges in accurately representing their mechanical properties,especially under true triaxial stress conditions.This paper proposes a conceptualization of rock at the mesoscopic level as a two-phase composite,consisting of a bonded medium matrix and frictional medium inclusions.The bonded medium is characterized as a mesoscopic elastic material,encompassing various minerals surrounding porous defects.Its mechanical properties are determined using the mixed multi-inclusion method.Transformation of the bonded medium into the frictional medium occurs through crack extension,with its elastoplastic properties defined by the DruckerePrager yield criterion,accounting for hardening,softening,and extension.MorieTanaka and Eshelby’s equivalent inclusion methods are applied to the bonded and frictional media,respectively.The macroscopic mechanical properties of the rock are derived from these mesoscopic media.Consequently,a True Triaxial Macro-Mesoscopic(TTMM)constitutive model is developed.This model effectively captures the competitive effect and accurately describes the stress-deformation characteristics of granite.Utilizing the TTMM model,the strains resulting from porous defect closure and induced crack extension are differentiated,enabling quantitative determination of the associated damage evolution.展开更多
In the classical economic prevalent opinions, economic efficiency is in direct proportion to the level of the market competitiveness and perfect competitive market has the highest efficiency. However, in this paper, i...In the classical economic prevalent opinions, economic efficiency is in direct proportion to the level of the market competitiveness and perfect competitive market has the highest efficiency. However, in this paper, it will be approved the viewpoint that perfect competitive market owns highest efficiency is not existent in practical economy, even on the theoretic level, uncertainty exits. So the perfect objective model the government oolicv should oursue is coexistence of the effective competition and effective monopoly.展开更多
An approach for studying the adsorption and desorption behaviors of single-stranded DNA( ssDNA) molecules on the mica surface by the surface forces apparatus( SFA) is reported,which can be used to characterize the...An approach for studying the adsorption and desorption behaviors of single-stranded DNA( ssDNA) molecules on the mica surface by the surface forces apparatus( SFA) is reported,which can be used to characterize the precise thickness,configuration and mechanical properties of ssDNA layers on the mica surface at a certain buffer solution. The formation of ss DNA layers is first studied by tuning the ssDNA concentrations, and the experimental results indicate that the ss DNA concentration of 100 ng / μL is ideal for forming a ssDNA monolayer structure on the mica surface, and the hardwall value measured to be 1.04 nm under this circumstance is regarded as the thickness of the ssDNA monolayer confined on mica. The desorption behavior of ssDNA molecules from the mica surface is further studied by observing and comparing different shapes of the force-distance curves under certain conditions. It is found that the desorption of ss DNA molecules from the mica surface occurs as the monovalent salts are added into the gap buffer. It is inferred that the competition effect between monovalent and divalent salts can induce the release of ssDNA from substrate.The results also reveal that 10 mmol / L monovalent salts( Na~+)is sufficient for the desorption of ssDNA from mica. This work provides an applicable method to study the binding mechanism of ss DNA molecules on inorganic substrates.展开更多
Grain boundaries(GBs),as extremely anisotropic pinning defects,have a strong impact on vortex motion in type-Ⅱsuperconductors,and further on the macro level dominates the superconductivity for example the critical cu...Grain boundaries(GBs),as extremely anisotropic pinning defects,have a strong impact on vortex motion in type-Ⅱsuperconductors,and further on the macro level dominates the superconductivity for example the critical current density.Many previous studies indicated that mostly GB plays the role of a strong barrier for vortex motion,while an easy-flow channel just under some certain conditions.In order to thoroughly make clear of the questions of what is exactly the role of GB on vortex motion and how it works,in this article we developed a large scale molecular dynamic model and revealed the action of GB on vortex motion in type-Ⅱsuperconductors.The most significant finding is that the role of GB on vortex motion can be changeable from a barrier to an easy-flow channel,and which is intrinsically determined by the competition effect correlated with its action on vortex between in the GB and no-GB regions.Such the competition effect essentially depends on the attributes of both the GB(described by the GB strength and angleθ)and no-GB pining regions(by the relative disorder strengthα_(p)/α_(v)).Specifically,for a YBa_(2)Cu_(3)O_(7-x)(YBCO)sample,to obtain a clear knowledge of vortex motion in GB region,we visualized the three typical trajectories of vortices during the three vortex movement stages.Further,in order to understand how GB results in the macro current-carrying property,corresponding to the current-voltage relation of the YBCO conductor,we obtained the average velocity v_(y) of vortices varying with their driving force,which is nearly identical with the previous observations.展开更多
The Brenner-LJ potential is adopted to describe the interaction between C36 clusters and diamond surface, and the deposition mechanism of multi-C36 clusters on the diamond surface is also studied by using the method o...The Brenner-LJ potential is adopted to describe the interaction between C36 clusters and diamond surface, and the deposition mechanism of multi-C36 clusters on the diamond surface is also studied by using the method of molecular dynamics simulation. The simulation results show that the competition effects of two interactions, i.e. the interaction between cluster and cluster and the interaction between cluster and crystal plane, are studied, and then the influence of these competition effects on C36 cluster deposition is analysed. The finding is that when an incident energy is appropriately chosen, C36 clusters can be chemically adsorbed and deposited steadily on the diamond surface in the form of single-layer, and in the deposition process the multi-C36 clusters present a phenomenon of energy transmission. The experimental result shows that at a temperature of 300K, in order to deposit C36 clusters into a steady nanostructured single-layered film, the optimal incident energy is between 10 and 18 eV, if the incident energy is larger than 18 eV, the C36 clusters will be deposited into an island nano-structured film.展开更多
Aims Evaluation of the interaction intensity between Masson pine(Pinus massoniana)and broadleaved trees will facilitate selecting tree combinations suitable for reforestation in abandoned sites in subtropical areas.Me...Aims Evaluation of the interaction intensity between Masson pine(Pinus massoniana)and broadleaved trees will facilitate selecting tree combinations suitable for reforestation in abandoned sites in subtropical areas.Methods Pinus massoniana and seven broadleaved trees species were grown either in monoculture or in two-species mixture.Biomass of tree species was measured and inter-specific interactions were estimated using log response ratio.Test of homogeneity of variances was performed to compare the stability of biomass in the monoculture of the broadleaved trees with that in the mixture.Important Findings Our results showed that the direction and intensity of interactions between P.massoniana and the broadleaved trees varied from year to year and the identity of the broadleaved species.Facilitative interactions were found between Camellia oleifera,Rhus chinensis and P.massoniana.Pinus massoniana had competitive effects on Lithocarpus glaber,Cyclobalanopsis glauca and Elaeocarpus japonicus.Significantly negative relations were found between biomass of P.massoniana and the broadleaved trees in the third year of the experiment,and the compensatory effects between P.massoniana and the broadleaved trees may be involved in stability maintenance in the multi-species forests in the subtropical area.The results of homogeneity test of variances also showed that the biomass per pot in the mixture had significantly lower variances than that in the monoculture,suggesting that total biomass is more stable in the mixture than the monoculture.展开更多
The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat ...The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat treatment processes.The relative effect of β grain size and STA(solution treatment and ageing)processing parameters on mechanical properties were quantitatively explored by the application of Taguchi method.These results were further explained via correlating microstructure with the fracture toughness and tensile properties.It was found that large numbers of fine as precipitates and continuous α_(s) played greater roles than other features,resulting in a high strength and very low ductility(<2%)of STA process samples.The β grain size had a negative correlation with fracture toughness.In the samples prepared by BASCA( β anneal slow cooling and ageing)process,improved ductility and fracture toughness were obtained due to a lower density ofα;precipitates,a basket-weave structure and zigzag morphology of α_(GB).For this heat treatment,an increase in prior β grain size had an observable positive effect on fracture toughness.The contradictory effect of β grain size on fracture toughness found in literature was for the first time explained.It was shown that the microstructure obtained from different processes after β solution has complex effect on mechanical properties.This complexity derived from the competition between microstructure features and the overall sum of their effect on fracture toughness and tensile properties.A novel table was proposed to quasi-quantitatively unravel these competitive effects.展开更多
Aims Clonal plant species have the potential for high relative performance in heterogeneous environments,and this might increase the com-petitive ability and invasiveness of introduced clonal plant species.It was hypo...Aims Clonal plant species have the potential for high relative performance in heterogeneous environments,and this might increase the com-petitive ability and invasiveness of introduced clonal plant species.It was hypothesized that clonal species whose performance responds more to heterogeneity of a resource have higher competitive ability in habitats where this resource is more heterogeneous and that this relationship is stronger when other resources are less limiting.Methods To test these hypotheses,the perennial clonal herb Alternanthera philoxeroides,which is invasive in China,was grown alone or with each of four clonal perennial,co-occurring herbs native to China,i.e.Alternanthera sessilis,Cynodon dactylon,Hemarthria altissima and Wedelia chinensis.Plants were given homogeneous or het-erogeneous soil substrate crossed with low and high levels of soil moisture.Important Findings Effects of heterogeneity on the accumulation of mass and ramets and on competitive effect and response of A.philoxeroides differed between native species and interacted with effects of soil moisture.A.philoxeroides reduced the final total mass or ramet number of the native species except A.sessilis,and the negative competitive effects on H.altissima and C.dactylon were more pronounced in heterogeneous than in homogeneous soil.Competitive response of A.philoxeroides was more negative to A.sessilis than to the other native species.Across native species,the competitive response of A.philoxeroides was more negative in heterogeneous than in homo-geneous soils at low moisture level,but the reverse was true at high moisture level.Results do not consistently support either hypoth-esis,but do suggest that competitive ability can be partly explained by individual species traits such as size,and that some competi-tive effects and responses are emergent properties of interspecific interactions.展开更多
This paper clearly defines the concepts of the national competitiveness,the national S&T competitiveness,and the national S&T competitiveness structure.It develops an evaluation framework with three dimensions...This paper clearly defines the concepts of the national competitiveness,the national S&T competitiveness,and the national S&T competitiveness structure.It develops an evaluation framework with three dimensions:the national S&T competitive potential,the national S&T competitive strength and the national S&T competitive effectiveness.This paper proposes a structure analysis method and depicts the national S&T competitiveness structure of 35 countries in an empirical research.Apart from the definitions and the structure analysis method,this paper mainly draws the following conclusions:(1)In the one-dimensional national S&T competitiveness structure,the top 5 countries were all developed countries in 2015,while the developing countries generally performed better than developed countries considering the average annual growth rate of the national S&T competitiveness index.The 35 countries are clustered into 4 categories using the two-dimensional structure analysis method.For example,based on the ranking of the national S&T competitive strength index and the national S&T competitive effectiveness index of the 35 countries in 2015,the 35 countries are clustered into four categories:high-strength and higheffectiveness,low-strength and high-effectiveness,low-strength and low-effectiveness,and high-strength and low-effectiveness.(2)To a large extent,there is a significant correlation between the national S&T competitiveness index score and the GDP per capita value.And to a certain extent,there is some correlation between the national S&T competitiveness index score and the GDP value.Moreover,under the background of strength and effectiveness combination,or under the background of strength and potential combination,the national S&T competitiveness structure and GDP or GDP per capita show significant relationship.展开更多
基金funding support from the National Natural Science Foundation of China(Grant No.U1965203)“Dynamic analysis method of complex rock underground engineering in the Hengduan Mountains”project(Grant No.P43419)the Sichuan University Postdoctoral Research Fund(Grant No.2023SCU12123).
文摘The complex mechanical and damage mechanisms of rocks are intricately tied to their diverse mineral compositions and the formation of pores and cracks under external loads.Numerous rock tests reveal a complex interplay between the closure of porous defects and the propagation of induced cracks,presenting challenges in accurately representing their mechanical properties,especially under true triaxial stress conditions.This paper proposes a conceptualization of rock at the mesoscopic level as a two-phase composite,consisting of a bonded medium matrix and frictional medium inclusions.The bonded medium is characterized as a mesoscopic elastic material,encompassing various minerals surrounding porous defects.Its mechanical properties are determined using the mixed multi-inclusion method.Transformation of the bonded medium into the frictional medium occurs through crack extension,with its elastoplastic properties defined by the DruckerePrager yield criterion,accounting for hardening,softening,and extension.MorieTanaka and Eshelby’s equivalent inclusion methods are applied to the bonded and frictional media,respectively.The macroscopic mechanical properties of the rock are derived from these mesoscopic media.Consequently,a True Triaxial Macro-Mesoscopic(TTMM)constitutive model is developed.This model effectively captures the competitive effect and accurately describes the stress-deformation characteristics of granite.Utilizing the TTMM model,the strains resulting from porous defect closure and induced crack extension are differentiated,enabling quantitative determination of the associated damage evolution.
文摘In the classical economic prevalent opinions, economic efficiency is in direct proportion to the level of the market competitiveness and perfect competitive market has the highest efficiency. However, in this paper, it will be approved the viewpoint that perfect competitive market owns highest efficiency is not existent in practical economy, even on the theoretic level, uncertainty exits. So the perfect objective model the government oolicv should oursue is coexistence of the effective competition and effective monopoly.
基金The National Basic Research Program of China(973Program)(No.2011CB707605)the Fundamental Research Funds for the Central Universities(No.2242015K42085)+1 种基金the Scientific Innovation Research of College Graduates in Jiangsu Province(No.KYLX-0100)the Research Start-Up Fund of Southeast University
文摘An approach for studying the adsorption and desorption behaviors of single-stranded DNA( ssDNA) molecules on the mica surface by the surface forces apparatus( SFA) is reported,which can be used to characterize the precise thickness,configuration and mechanical properties of ssDNA layers on the mica surface at a certain buffer solution. The formation of ss DNA layers is first studied by tuning the ssDNA concentrations, and the experimental results indicate that the ss DNA concentration of 100 ng / μL is ideal for forming a ssDNA monolayer structure on the mica surface, and the hardwall value measured to be 1.04 nm under this circumstance is regarded as the thickness of the ssDNA monolayer confined on mica. The desorption behavior of ssDNA molecules from the mica surface is further studied by observing and comparing different shapes of the force-distance curves under certain conditions. It is found that the desorption of ss DNA molecules from the mica surface occurs as the monovalent salts are added into the gap buffer. It is inferred that the competition effect between monovalent and divalent salts can induce the release of ssDNA from substrate.The results also reveal that 10 mmol / L monovalent salts( Na~+)is sufficient for the desorption of ssDNA from mica. This work provides an applicable method to study the binding mechanism of ss DNA molecules on inorganic substrates.
基金Project supported financially by the National Natural Science Foundation of China(Grant No.12072101)the Fundamental Research Funds for the Central Universities,China(Grant No.2018B48714).
文摘Grain boundaries(GBs),as extremely anisotropic pinning defects,have a strong impact on vortex motion in type-Ⅱsuperconductors,and further on the macro level dominates the superconductivity for example the critical current density.Many previous studies indicated that mostly GB plays the role of a strong barrier for vortex motion,while an easy-flow channel just under some certain conditions.In order to thoroughly make clear of the questions of what is exactly the role of GB on vortex motion and how it works,in this article we developed a large scale molecular dynamic model and revealed the action of GB on vortex motion in type-Ⅱsuperconductors.The most significant finding is that the role of GB on vortex motion can be changeable from a barrier to an easy-flow channel,and which is intrinsically determined by the competition effect correlated with its action on vortex between in the GB and no-GB regions.Such the competition effect essentially depends on the attributes of both the GB(described by the GB strength and angleθ)and no-GB pining regions(by the relative disorder strengthα_(p)/α_(v)).Specifically,for a YBa_(2)Cu_(3)O_(7-x)(YBCO)sample,to obtain a clear knowledge of vortex motion in GB region,we visualized the three typical trajectories of vortices during the three vortex movement stages.Further,in order to understand how GB results in the macro current-carrying property,corresponding to the current-voltage relation of the YBCO conductor,we obtained the average velocity v_(y) of vortices varying with their driving force,which is nearly identical with the previous observations.
基金Project supported by New Century Elitist Supporting Program Foundation by the Ministry of Education of China(Contract No NCET-06-0332)the National Natural Science Foundation of China (Grant No 50405011)
文摘The Brenner-LJ potential is adopted to describe the interaction between C36 clusters and diamond surface, and the deposition mechanism of multi-C36 clusters on the diamond surface is also studied by using the method of molecular dynamics simulation. The simulation results show that the competition effects of two interactions, i.e. the interaction between cluster and cluster and the interaction between cluster and crystal plane, are studied, and then the influence of these competition effects on C36 cluster deposition is analysed. The finding is that when an incident energy is appropriately chosen, C36 clusters can be chemically adsorbed and deposited steadily on the diamond surface in the form of single-layer, and in the deposition process the multi-C36 clusters present a phenomenon of energy transmission. The experimental result shows that at a temperature of 300K, in order to deposit C36 clusters into a steady nanostructured single-layered film, the optimal incident energy is between 10 and 18 eV, if the incident energy is larger than 18 eV, the C36 clusters will be deposited into an island nano-structured film.
基金National Natural Science Foundation of China(30710103907)State Key Basic Research and Development Plan of China(2002CB111505).
文摘Aims Evaluation of the interaction intensity between Masson pine(Pinus massoniana)and broadleaved trees will facilitate selecting tree combinations suitable for reforestation in abandoned sites in subtropical areas.Methods Pinus massoniana and seven broadleaved trees species were grown either in monoculture or in two-species mixture.Biomass of tree species was measured and inter-specific interactions were estimated using log response ratio.Test of homogeneity of variances was performed to compare the stability of biomass in the monoculture of the broadleaved trees with that in the mixture.Important Findings Our results showed that the direction and intensity of interactions between P.massoniana and the broadleaved trees varied from year to year and the identity of the broadleaved species.Facilitative interactions were found between Camellia oleifera,Rhus chinensis and P.massoniana.Pinus massoniana had competitive effects on Lithocarpus glaber,Cyclobalanopsis glauca and Elaeocarpus japonicus.Significantly negative relations were found between biomass of P.massoniana and the broadleaved trees in the third year of the experiment,and the compensatory effects between P.massoniana and the broadleaved trees may be involved in stability maintenance in the multi-species forests in the subtropical area.The results of homogeneity test of variances also showed that the biomass per pot in the mixture had significantly lower variances than that in the monoculture,suggesting that total biomass is more stable in the mixture than the monoculture.
基金the financial support from Baosteel Australia Joint Research Centre(BA16003)ARC Research Hub for Computational Particle Technology(IH140100035)funded by Australian Research Council grant LE0882821。
文摘The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat treatment processes.The relative effect of β grain size and STA(solution treatment and ageing)processing parameters on mechanical properties were quantitatively explored by the application of Taguchi method.These results were further explained via correlating microstructure with the fracture toughness and tensile properties.It was found that large numbers of fine as precipitates and continuous α_(s) played greater roles than other features,resulting in a high strength and very low ductility(<2%)of STA process samples.The β grain size had a negative correlation with fracture toughness.In the samples prepared by BASCA( β anneal slow cooling and ageing)process,improved ductility and fracture toughness were obtained due to a lower density ofα;precipitates,a basket-weave structure and zigzag morphology of α_(GB).For this heat treatment,an increase in prior β grain size had an observable positive effect on fracture toughness.The contradictory effect of β grain size on fracture toughness found in literature was for the first time explained.It was shown that the microstructure obtained from different processes after β solution has complex effect on mechanical properties.This complexity derived from the competition between microstructure features and the overall sum of their effect on fracture toughness and tensile properties.A novel table was proposed to quasi-quantitatively unravel these competitive effects.
基金This research was supported by the Fundamental Research Funds for the Central Universities(TD-JC-2013-1)the National Natural Science Foundation of China(31570413,31500331).
文摘Aims Clonal plant species have the potential for high relative performance in heterogeneous environments,and this might increase the com-petitive ability and invasiveness of introduced clonal plant species.It was hypothesized that clonal species whose performance responds more to heterogeneity of a resource have higher competitive ability in habitats where this resource is more heterogeneous and that this relationship is stronger when other resources are less limiting.Methods To test these hypotheses,the perennial clonal herb Alternanthera philoxeroides,which is invasive in China,was grown alone or with each of four clonal perennial,co-occurring herbs native to China,i.e.Alternanthera sessilis,Cynodon dactylon,Hemarthria altissima and Wedelia chinensis.Plants were given homogeneous or het-erogeneous soil substrate crossed with low and high levels of soil moisture.Important Findings Effects of heterogeneity on the accumulation of mass and ramets and on competitive effect and response of A.philoxeroides differed between native species and interacted with effects of soil moisture.A.philoxeroides reduced the final total mass or ramet number of the native species except A.sessilis,and the negative competitive effects on H.altissima and C.dactylon were more pronounced in heterogeneous than in homogeneous soil.Competitive response of A.philoxeroides was more negative to A.sessilis than to the other native species.Across native species,the competitive response of A.philoxeroides was more negative in heterogeneous than in homo-geneous soils at low moisture level,but the reverse was true at high moisture level.Results do not consistently support either hypoth-esis,but do suggest that competitive ability can be partly explained by individual species traits such as size,and that some competi-tive effects and responses are emergent properties of interspecific interactions.
基金supported the Major Project of the National Social Science Fund of China(Grant Number 18ZDA101)the National Natural Science Foundation of China(Grant Number 71874179)+1 种基金the Strategic Research and Decision Support System Construction of Chinese Academy of Sciences(Grant Number GHJ-ZLZX-2020-11)the Youth Innovation Promotion Association of Chinese Academy of Sciences(Grant Number Y201934)
文摘This paper clearly defines the concepts of the national competitiveness,the national S&T competitiveness,and the national S&T competitiveness structure.It develops an evaluation framework with three dimensions:the national S&T competitive potential,the national S&T competitive strength and the national S&T competitive effectiveness.This paper proposes a structure analysis method and depicts the national S&T competitiveness structure of 35 countries in an empirical research.Apart from the definitions and the structure analysis method,this paper mainly draws the following conclusions:(1)In the one-dimensional national S&T competitiveness structure,the top 5 countries were all developed countries in 2015,while the developing countries generally performed better than developed countries considering the average annual growth rate of the national S&T competitiveness index.The 35 countries are clustered into 4 categories using the two-dimensional structure analysis method.For example,based on the ranking of the national S&T competitive strength index and the national S&T competitive effectiveness index of the 35 countries in 2015,the 35 countries are clustered into four categories:high-strength and higheffectiveness,low-strength and high-effectiveness,low-strength and low-effectiveness,and high-strength and low-effectiveness.(2)To a large extent,there is a significant correlation between the national S&T competitiveness index score and the GDP per capita value.And to a certain extent,there is some correlation between the national S&T competitiveness index score and the GDP value.Moreover,under the background of strength and effectiveness combination,or under the background of strength and potential combination,the national S&T competitiveness structure and GDP or GDP per capita show significant relationship.