An iron（Ⅱ） coordination polymer, [Fe（Haip）2（H2O）2]n （1, Haip = 5-ammoniumiso- phthalato）, has been hydro/solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, i...An iron（Ⅱ） coordination polymer, [Fe（Haip）2（H2O）2]n （1, Haip = 5-ammoniumiso- phthalato）, has been hydro/solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectrum and magnetic measurement. Compound 1 crystalizes in monoclinic, space group P2/c with a = 6.9874（14）, b = 9.960（2）, c = 12.894（4） A, β = 117.47（2）°, Fe（C8H6NO4）2（H2O）2, Mr = 452.16, V= 796.2（3） A3, Z = 2, Dc = 1.886 g.cm-3, p = 1.017 mm-1, F（000） = 464.0, 2.71〈0〈28.42°, R = 0.0307, wR = 0.0840 and S = 1.005. Single-crystal X-ray diffraction analysis reveals that 1 features an infinite one-dimensional loop-like chain structure and Haip ligand in 1 is of zwitterionic form. Magnetic measurement results show the dominated ferromagnetic interactions among Fe11 atoms.展开更多
Recently, considerable progress has been made in understanding the early universe by loop quantum cosmology. Modesto et al. investigated the loop quantum black hole （LQBH）using improved semiclassical analysis and th...Recently, considerable progress has been made in understanding the early universe by loop quantum cosmology. Modesto et al. investigated the loop quantum black hole （LQBH）using improved semiclassical analysis and they found that the LQBH has two horizons, an event horizon and a Cauchy horizon, just like the Reissner-NordstrSm black hole. This paper focuses on the dynamical evolution of a massless scalar wave in the LQBH background. By investigating the relation between the complex frequencies of the massless scalar field and the LQBH parameters using the numerical method, we find that the polymeric parameter P makes the massless scalar field decay more quickly and makes the ground scalar wave oscillate slowly. However, the polymeric parameter P causes the frequency of the high harmonic massless scalar wave to shift according to its value. We also find that the loop quantum gravity area gap parameter a0 causes the massless scalar field to decay more slowly and makes the period of the massless scalar field wave become longer. In the complex ω plane, the frequency curves move counterclockwise when the polymeric parameter P increases and this spiral effect is more obvious for a higher harmonic scalar wave.展开更多
Based on the analysis for the situation about heat pipe,this paper points out that high efficiency micro heat pipe,high temperaturelarge heat pipe,high efficiency heat pipe reaction equipment and high efficiency heat ...Based on the analysis for the situation about heat pipe,this paper points out that high efficiency micro heat pipe,high temperaturelarge heat pipe,high efficiency heat pipe reaction equipment and high efficiency heat pipe heat exchange equipment are the developing di-rection of the heat pipe,and the complex heat pipe system is a new heat pipe idea that can satisfy the modern large heat pipe heat exchangeequipment and the high efficiency heat pipe heat exchange equipment.A new complex heat pipe system that is called double circulation con-trollable heat pipe system is advanced and several basic structure modes are given in this paper.The working principle and the basic character-istics about this special heat pipe system are also introduced and analyzed.展开更多
基金supported by the Scientific Research Start-up Funds of Shangrao Normal Universitythe Fourth Characteristic Specialty Foundation of University from Ministry of Education(TS11524)the Natural Science Foundation of Jiangxi Province(No.20122BAB203002)
文摘An iron（Ⅱ） coordination polymer, [Fe（Haip）2（H2O）2]n （1, Haip = 5-ammoniumiso- phthalato）, has been hydro/solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectrum and magnetic measurement. Compound 1 crystalizes in monoclinic, space group P2/c with a = 6.9874（14）, b = 9.960（2）, c = 12.894（4） A, β = 117.47（2）°, Fe（C8H6NO4）2（H2O）2, Mr = 452.16, V= 796.2（3） A3, Z = 2, Dc = 1.886 g.cm-3, p = 1.017 mm-1, F（000） = 464.0, 2.71〈0〈28.42°, R = 0.0307, wR = 0.0840 and S = 1.005. Single-crystal X-ray diffraction analysis reveals that 1 features an infinite one-dimensional loop-like chain structure and Haip ligand in 1 is of zwitterionic form. Magnetic measurement results show the dominated ferromagnetic interactions among Fe11 atoms.
基金supported Project supported by the National Natural Science Foundation of China (Grant No. 10873004)the Program for Excellent Talents at Hunan Normal University,China+4 种基金the National Basic Research Program of China (Grant No. 2010CB832803)the Key Program of the National Natural Science Foundation of China (Grant No. 10935013)the Construct Program of the National Key Disciplinethe Program for Changjiang Scholarsthe Innovative Research Team in University,China(Grant No. IRT0964)
文摘Recently, considerable progress has been made in understanding the early universe by loop quantum cosmology. Modesto et al. investigated the loop quantum black hole （LQBH）using improved semiclassical analysis and they found that the LQBH has two horizons, an event horizon and a Cauchy horizon, just like the Reissner-NordstrSm black hole. This paper focuses on the dynamical evolution of a massless scalar wave in the LQBH background. By investigating the relation between the complex frequencies of the massless scalar field and the LQBH parameters using the numerical method, we find that the polymeric parameter P makes the massless scalar field decay more quickly and makes the ground scalar wave oscillate slowly. However, the polymeric parameter P causes the frequency of the high harmonic massless scalar wave to shift according to its value. We also find that the loop quantum gravity area gap parameter a0 causes the massless scalar field to decay more slowly and makes the period of the massless scalar field wave become longer. In the complex ω plane, the frequency curves move counterclockwise when the polymeric parameter P increases and this spiral effect is more obvious for a higher harmonic scalar wave.
文摘Based on the analysis for the situation about heat pipe,this paper points out that high efficiency micro heat pipe,high temperaturelarge heat pipe,high efficiency heat pipe reaction equipment and high efficiency heat pipe heat exchange equipment are the developing di-rection of the heat pipe,and the complex heat pipe system is a new heat pipe idea that can satisfy the modern large heat pipe heat exchangeequipment and the high efficiency heat pipe heat exchange equipment.A new complex heat pipe system that is called double circulation con-trollable heat pipe system is advanced and several basic structure modes are given in this paper.The working principle and the basic character-istics about this special heat pipe system are also introduced and analyzed.
