Baddeleyite from Large Complex Deposits: Significance for Archean-Paleozoic Plume Processes in the Arctic Region (NE Fennoscandian Shield) Based on U-Pb (ID-TIMS) and LA-ICP-MS Data

Baddeleyite is an important mineral geochronometer. It is valued in the U-Pb (ID-TIMS) geochronology more than zircon because of its magmatic origin, while zircon can be metamorphic, hydrothermal or occur as xenocrysts. Detailed mineralogical (BSE, KL, etc.) research of baddeleyite started in the Fennoscandian Shield in the 1990s. The mineral was first extracted from the Paleozoic Kovdor deposit, the second-biggest baddeleyite deposit in the world after Phalaborwa (2.1 Ga), South Africa. The mineral was successfully introduced into the U-Pb systematics. This study provides new U-Pb and LA-ICP-MS data on Archean Ti-Mgt and BIF deposits, Paleoproterozoic layered PGE intrusions with Pt-Pd and Cu-Ni reefs and Paleozoic complex deposits (baddeleyite, apatite, foscorite ores, etc.) in the NE Fennoscandian Shield. Data on concentrations of REE in baddeleyite and temperature of the U-Pb systematics closure are also provided. It is shown that baddeleyite plays an important role in the geological history of the Earth, in particular, in the break-up of supercontinents.

The chromite deposits associated with ophiolite complexes, Southeastern Desert, Egypt: Petrological and geochemical characteristics and mineralization

The podiform chromitites occur in a well-preserved mantle sequence consisting of lherzolite-harzburgite with abundant lenses of olivine dunite. The podiform chromitite deposits are common as small and irregularly shaped masses in the Southeastern Desert (SED) of Egypt. The podiform chromitites exhibit a wide range of compositions from high Cr to high Al varieties. The Cr of chrome spinel ranges from 0.67 to 0.88 in olivine-dunite, quite similar to that of the high-Cr chromitite, whereas it is around 0.62 in lherzolite-harzburgite. Primary hydrous mineral inclusions, amphibole and phlogopite, in chrome spinel have been reported for the first time from the Pan-African Proterozoic podiform chromitites. On the other hand, petrographic and geochemical evidence suggests that podiform chromitites in the SED of Egypt were formed as a result of crystallization of mafic melts, probably of boninitic composition, the boninitic parental magmas were probably produced by a second stage of melting above a subduction zone. Three types of chromite ores can be distinguished within the SED of Egypt: (a) sulphide-poor podiform ores; (b) brecciated ores; and (c) sulphide-rich ores. Two textural types of inclusions in chromite are distinguished: (1) primary silicate inclusions generally have high Mg-number (>96), Cr and Ni, and are dominated by pargasitic amphibole, forsterite, diopside, enstatite and Na-phlogopite. A diversity of primary and secondary platinum group minerals (PGM) is described from the chromitites, including alloys, sulphides, sulpharsenides and arsenides of Ru, Os, Ir, Rh, Ni, Cu, Fe and Co; (2) in addition to primary PGM and hydrous silicates, the fluids are of low to moderate salinity, sodium-dominated aqueous solutions with complex gas contents. Variable amounts of water, hydrogen, hydrocarbons, carbon dioxides and nitrogen have been determined in inclusion-rich samples. The chondrite-normalized PGE patterns of lherzolite-harzburgite and olivine-dunite have negative Ir and Pt, and positive Pd and Au anomalies. Chromitites are homo-geneous in composition but texturally zoned on a large scale. They carry elevated IPGE, manifested in numerous, primary and secondary PGM phases.

+-Evidence of Porphyry Deposits in the Ntem Complex: A Case Study from Structural and Hydrothermal Alteration Zones Mapping through Landsat-8 OLI, Aeromagnetic and Geological Data Integration in the Yaounde-Sangmelima Region (Southern Cameroon)

A semi-regional study was carried out in the Yaounde-Sangmelima area, a densely vegetated tropical region of southern Cameroon located in the Central Africa Fold Belt (CAFB)/Congo Craton (CC) transition zone. Towards structural lineaments and predictive hydrothermal porphyry deposits mapping, an integrated analysis of Landsat-8 OLI data, aeromagnetic, geological and mineral indices maps was performed. The Remote sensing using False colour composite images involving bands combinations and Crosta method (features oriented principal components analysis) enabled the mapping of the gneisses and schists domains without a clear differentiation between the Yaounde and Mbalmayo schists;despite the reflectance anomalies evidenced NW of Akonolinga, hydrothermal alterations in the study area failed to be detected. Besides, aeromagnetics depicted a moderately fractured northern zone (the CAFB) contrasting with a high densely fractured zone (the CC, known as Ntem complex). The Ntem complex displays signatures of a meta-igneous, an intrusive complex, greenstone relics south of Sangmelima and hydrothermal activity. Indeed, CET porphyry analysis tool detected many porphyry centres. In general, the study revealed many lineaments including contacts, fractures faults zones and strike-slips. The major aeromagnetics structures are SW-NE to WSW-ENE and WNW-ESE to NW-SE while those from Landsat-8 are NE-SW, WNW-ESE, NW-SE, WSW-ENE and NW-ESE to NNW-SSE. Together, these structures depict trans-compressions or trans-tensions corresponding to a broad NE-SW strike-slips channel that affect both the CAFB and the Ntem Complex, and they control the intrusions thus confirming a pervasive hydrothermal activity within the Ntem Complex. The proximity or coincidence of these porphyry centres with some mapped Iron-Gold affiliated mineral indices and porphyry granites indicate the possible occurrence of many hydrothermal ore deposits. These results show the high probability for the Ntem complex to host porphyry deposits so they may serve to boost mineral exploration in the Yaounde-Sangmelima region and in the entire southern Cameroon as well.

断陷湖盆陡坡带扇三角洲—滑塌扇复合扇体的沉积演化及油气地质意义——以中非地区Melut盆地A凹陷白垩系为例

【目的】扇三角洲—深水滑塌扇组成的复合扇体作为断陷盆地陡坡带重要的粗粒沉积体系和油气储层,其展布范围、演化期次、成藏模式等一直是湖盆沉积和成藏研究的热点。【方法】以中非地区Melut盆地A凹陷高精度三维地震和钻测井资料为基础,采用岩心观察、层序划分、地震反射特征与地震属性分析等方法,对扇三角洲—滑塌扇复合扇体的沉积特征与演化规律进行了研究。【结果与结论】发现研究区复合扇体的沉积相类型包括扇三角洲和重力流成因的滑塌扇,滑塌扇具有两类形貌特征,第一类为受坡折控制的线状供源滑塌扇,第二类为受较陡地形坡度控制的单点供源多级滑塌扇。白垩系研究层段刻画出五期扇体,单期复合扇体内部具有退积特征,多期复合扇体具有“先进积、后退积”的垂向演化特征,其中下白垩统Renk组沉积末期复合扇体规模最大,达到148 km^(2)。复合扇体演化主要受幕式构造活动、古地貌和物源供给,以及相对湖平面变化的影响,构造活动强烈、物源供给充足、短轴构造隆升幅度大的时期,复合扇体规模更大,相对湖平面下降初期和上升初期滑塌扇最为发育。提出A凹陷早白垩世和晚白垩世发生沉积格局转换的新认识,明确了断陷期陡坡带扇三角洲-滑塌扇复合扇体的勘探潜力,指导了勘探部署。

武夷-云开造山带早古生代镁铁-超镁铁质岩富钪风化壳的首次发现及其意义

本文首次报道华南古生代武夷-云开造山带东南缘的兰排镁铁-超镁铁质岩体富钪(Sc)风化壳,初步计算获得区域内钪的潜在资源为524~566 t,为一潜在大型风化壳型钪矿。兰排岩体呈小型岩株侵入到永和闪长质岩体内,主要由橄榄岩、辉石岩和辉长岩组成,辉石岩锆石^(206)Pb/^(238)U年龄为(428.3±2.0)Ma(MSWD=0.92)。镁铁-超镁铁质岩全岩w(TFe_(2)O_(3))为12.1%~18.7%,其中辉石岩钪含量为44×10^(–6)~97×10^(–6),总体高于橄榄岩(20×10^(–6)~89×10^(–6))和辉长岩(28×10^(–6)~48×10^(–6))。兰排这类富钪岩石组合与以往认为富钪的碳酸岩-碱性岩体和阿拉斯加型岩体都存在较大差异,可能代表了一种新的钪成矿母岩类型,推测碰撞后陆内伸展诱发富钪地幔源区熔融可能是富钪母岩浆形成的重要机制。镁铁-超镁铁质岩体上部发育完整的风化壳剖面,可分为全风化层和半风化层。全风化层的上部富集铁(氢)氧化物(磁铁矿、赤铁矿、针铁矿),而中下部以高岭石等黏土矿物为主。半风化层除了包含蒙脱石等黏土矿物,还包括铁钛氧化物及辉石等硅酸盐矿物或相关蚀变矿物。风化壳样品的Sc含量为21×10^(–6)~304×10^(–6),富集程度最高可达相应基岩的3倍以上。其中,钪含量最高的样品主要分布在铁氧化物最富集的全风化层上部,其钪含量多数超过100×10^(–6)。风化壳钪含量与红土化指数(IOL)呈明显的正相关性,表明红土化过程对风化壳钪的富集有显著影响。初步研究认为钪在风化壳红土化过程中经历了活化-迁移-沉淀的多阶段富集过程:1)风化早期钪以类质同象替换的形式赋存在蒙脱石等黏土矿物中;2)风化后期磁铁矿和蒙脱石溶解,钪赋存在以铁(氢)氧化物为主的矿物中,并达到最高程度的富集(Sc>100×10^(–6));3)风化晚期铁(氢)氧化物溶解,一部分钪向下迁移到特定层位。兰排镁铁-超镁铁质岩体富钪风化壳的发现弥补了我国高品位风化壳型钪矿床的空白,丰富了成矿母岩的类型,为华南早古生代成矿作用的理论研究和战略性矿产的找矿勘查提供了一个新的方向。

冀北招兵沟铁磷矿床成矿时代及成因研究

为探讨冀北—辽西地区太古宙变质岩系中铁磷矿床的成因问题,本研究选取招兵沟矿床开展了岩相学、年代学和地球化学研究。野外观察表明,前人描述的条带状铁磷矿石实际上大多为含铁磷矿脉的黑云角闪斜长片麻岩,可见铁磷矿脉切穿片麻理。含铁磷黑云角闪斜长片麻岩中的锆石与矿石矿物铁钛氧化物和磷灰石密切共生。阴极发光图像上显示基性岩浆锆石特征,无/弱环带或斑块状结构,LA-ICP-MS U-Pb定年获得^(206)Pb/^(238)U加权平均年龄为(282±3)Ma(MSWD=0.78),指示铁磷矿化时代为早二叠世,而非传统认为的新太古代。招兵沟含铁磷黑云角闪斜长片麻岩与区域辉石-角闪石岩侵入体形成时代接近,微量元素地球化学特征相似度高,说明成矿母岩为辉石-角闪石岩。招兵沟铁磷成矿与冀北地区沿红石砬—大庙断裂带发育的显生宙阿拉斯加型镁铁-超镁铁质岩浆活动密切相关。综合来看,招兵沟铁磷矿床可能是与基性岩浆活动有关的矿床,而非传统认为的变质型矿床,其他相似矿床的成因也需要进一步研究。

Microfacies and Depositional Environments of Miocene Isolated Carbonate Platforms from Central Luconia, Offshore Sarawak, Malaysia

The Luconia Province-offshore Sarawak-is a key geological unit for understanding the distribution of hydrocarbon resources in Malaysia. Nevertheless, little effort has been made to address the palaeoenvironmental characteristics of the Tertiary carbonates in the key sector of Central Luconia.We study the sedimentology and petrography of core samples from a well in Central Luconia, for which thirteen microfacies have been identified reflecting different depositional settings. This is the first microfacies scheme elaborated for Luconian carbonates. Lithofacies and microfacies distribution are compatible with deposition in a reef complex, originating around a framework reef, within the euphotic zone. Sediments were deposited in environments of backreef, reef crest, and forereef. The fair weather wave base is marked by the presence of coralline red algae, foraminifera, decreasing degree of bioclast fragmentation and other microfacies features. As a result, a depositional-environmental model is constructed, depicting a reef complex built around a framework reef developed on the margin of an isolated platform. In addition, an innovative, preliminary time series analysis of facies, microfacies and depositional environment data reveal the existence of seasonal cycles in the stacking patterns of facies and microfacies.

化学水浴沉积制备高质量Zn(O,S)薄膜及其性能研究

为获得铜铟镓硒薄膜太阳电池中高质量Zn(O,S)无镉缓冲层薄膜,该研究阐述了柠檬酸三钠作为络合剂制备Zn(O,S)薄膜的成膜机理,系统性研究了该体系下各反应参数对薄膜化学水浴沉积的影响。研究表明,柠檬酸三钠的浓度值显著影响反应类型,异质反应更有利于生成高质量薄膜。同时,柠檬酸三钠与金属离子浓度的比值直接影响成膜质量和成膜速率,适合的pH溶液环境有助于提高Zn(O,S)薄膜沉积的质量。此外,通过工艺参数的优化,获得了电学性能接近传统CdS/CIGS太阳电池的Zn(O,S)/CIGS电池器件。

Some Notes on the Lugiin Gol, Mushgai Khudag and Bayan Khoshuu Alkaline Complexes, Southern Mongolia

Volcanic-plutonic alkaline complexes from Lugiin Gol, Mushgai Khudag and Bayan Khoshuu, southern Mongolia (244, 139 and 131 Ma, respectively) occur within grabens in E-W lineaments. They are represented by syenitic rock-types (silica undersaturated to slightly silica oversaturated) potassic rocks and are associated to stockworks of carbonatitic veins, dykes and so on. Geochemical characteristics and isotope systematics point to a veined mantle source particularly enriched in LILE and LREE. The carbonatitic veins show high contents of Ba, Sr, Th and REE and are suitable as potential ore deposits.

Complex formulations, simple techniques: Can 3D printing technology be the Midas touch in pharmaceutical industry?

3 D printing is a method of rapid prototyping and manufacturing in which materials are deposited onto one another in layers to produce a three-dimensional object. Although 3 D printing was developed in the 1980 s and the technology has found widespread industrial applications for production from automotive parts to machine tools,its application in pharmaceutical area is still limited. However,the potential of 3 D printing in the pharmaceutical industry is now being recognized. The ability of 3 D printing to produce medications to exact specifications tailored to the needs of individual patients has indicated the possibility of developing personalized medicines. The technology allows dosage forms to be precisely printed in various shapes,sizes and textures that are difficult to produce using traditional techniques. However,there are various challenges associated with the proper application of3 D printing in the pharmaceutical sector which should be overcome to exploit the scope of this technology. In this review,an overview is provided on the various 3 D printing technologies used in fabrication of complex dosage forms along with their feasibility and limitations.

Cu－An Metallogenic Series Related to Volcanic－Intrusive Complexes in Eastern China

The Cu - An co - existence ore deposits related to intermediate- acidic volcanic - intrusive complexes are widespread in eastern China. They can be divided into 5 types: (1) sharn type, (2 )porphyry type, (3)vein type, (4 )breccia pipe type and (5)stratabound type. All of those have intimate spatial, temporal and genetic relations formed by the Mesozoic tertonicmatic - hydrothermal activities in certain geological environments. The magmatic and Cu-An metallogenic ager were predominately in Late Mesozoic (179-90 Ma), and in the period of 150-120 Ma the ore-forming Processes reached the Peak. The main geological Settings of Cu-An ore-forming Processes are: (1) continental margins, including the Peripheral depression of the continental Plate, (2) deep fault zones in the continental Plate,(3)continental rift belt. The magmatic activities were under the combined control of basement fault (s )and superficial fault (s ), and mostly formed the continental volcanic basins. The regional Cu-An metallogenic zones occur along the deep fault zones in WNW - EW direction,such as the Tongling metallogenic subzone, or in NE-NNE direction, such as the Dexing metallogenic subzone. Most of Cu- An ore deposits are related to subvolcanic stocks consist of quartz diorite, granodiorite, quartz porphyry, andesite porphyry, trachyte porphyry and other rocks, which belong to the calc- alkaline series and the I - type granitoid. The spatial zoning of matals from the center to periphery of the stocks is: CU (Mo )→ Cu,Au→Cu, Ph, Zn,An →Ph, Zn, Ag →Ph, Ag. There is a typical venical metallic zoning (from surface to 3 000m in depth ) in Yinshan Cu-An-Ph-Zn-Ag ore deposit, northeastern Jianxi Province.

蒙古阿尔泰哈勒赞布勒格泰碱性岩有关的Zr-Nb-Ta-REE矿床地质特征、地球化学与成因初探

哈勒赞布勒格泰稀有稀土矿床产出于蒙古国阿尔泰地区,是一处与碱性杂岩体有关的超大型Zr-Nb-Ta-REE矿床。该杂岩体具有多期次侵位和多岩相的特征,主要由含钠铁闪石和霓石的碱长正长岩、英碱正长岩、碱长花岗岩、蚀变碱长花岗岩和碱长花岗伟晶岩等组成,并被碱性辉长岩和辉绿岩侵入。其中,蚀变碱长花岗岩发生了全岩Zr、Nb、Ta和REE矿化,并具有广泛的热液交代特征。LA-ICP-MS锆石U-Pb测年显示,该杂岩体中的长英质碱性岩和基性碱性岩具有相似的侵位年龄,均为~400Ma,侵入于~463Ma的黑云母正长花岗岩中。主微量元素地球化学研究显示,该杂岩体具有强过碱性的特征。岩浆演化主要受到碱性长石分异的控制,使硅逐渐聚集于晚期粒间熔体之中,并逐渐演化为英碱正长岩和碱长花岗岩。这个过程使岩浆的过碱性特征不断加强,也使钠铁闪石和霓石逐渐富集。杂岩体的岩浆演化经历了一定程度的锆石、富集稀土的磷灰石、独居石和磷钇矿以及富集Nb的异性石的分异,使Zr、Nb、Ta和REE等成矿元素在岩浆的演化过程中没有得到显著的富集,因此岩浆的演化并非是该杂岩体中稀有稀土元素发生矿化的关键因素。在蚀变碱长花岗岩的石英、碱性长石和钠铁闪石中,普遍发育顺着晶格生长的“雪球状”钠长石,是碱性花岗质共结岩浆演化晚期流体发生周期性饱和并释放,造成Ab周期性过饱和而沉淀的结果。流体的周期性过饱和及释放萃取成矿元素并汇聚于蚀变碱长花岗岩,造成其Zr、Nb、Ta和REE等元素与硅含量相似但未发生蚀变的碱长花岗岩相比富集了近10倍,因此这是发生矿化的根本原因。

江西相山矿田铀成矿的特征、演化及启示

寻找富大硬岩型铀矿一直以来面临挑战。据深大断裂-临界水耦合成矿机制等新认识,重新梳理相山矿田火山杂岩铀成矿的主要特征,结合其他富大热液矿床的研究,探索富大热液矿床的共同规律。富大热液矿床多具有以下特征:首先,常有深大断裂与岩浆杂岩隆起组合的“一刀加一饼”的外形,深大断裂这“一刀”具多期次活动特点,因降压、升温、聚水,改变了周边区域的物理化学环境,驱动成岩成矿相关的物质运移、相变等,从而控制着与成矿密切相关的赋矿岩浆杂岩的形成、热液蚀变和铀成矿期次。其次,有3个主要构造层及与其相对应的三阶段式演化。再次,有2个主成矿期,早期高温成矿期(在相山铀矿田是115±0.5 Ma)与岩浆杂岩形成相关,而晚期低温成矿期(在相山铀矿田是98±8 Ma)与控盆断裂活动、盆地脱水相关,2期成矿叠加是富大矿体形成的必要条件。上述富大热液矿床的特征主要体现为具有“一刀加一饼”外形的、由深大断裂与岩浆杂岩隆起组成的构造岩性组合,其形成机制实质上仍是深大断裂多期活动成岩成矿。这些认识可能给中国富大热液铀矿成矿和找矿研究带来一些启示。

北秦岭华阳川地区复杂地形条件下隐伏硬岩型铀矿的地球物理勘查方法

铀资源是十分重要的战略性能源矿产资源。秦岭地区是中国重要的铀矿成矿区,华阳川地区发现的华阳川铀多金属矿位于北秦岭铀成矿带的东段。目前,在华阳川及周边已发现多处铀矿及铀矿化点,铀矿找矿潜力巨大。为解决华阳川地区复杂地形条件下隐伏硬岩型铀矿资源勘探及外围实现找矿突破对地球物理勘查方法技术的需求,在华阳川铀矿区进行了航空伽玛能谱/磁法、航空瞬变电磁/磁法、航空重力/磁法等综合航空地球物理勘查系统不同高度和不同尺度的航空地球物理测量,同时在地面开展了相应的重、磁、放射性测量、不同装置的激电测深及多种电磁测深等地球物理勘查,对这些方法在复杂地形条件下铀矿资源勘查中的有效性和适用性进行了验证,并在外围找矿有利区段开展了示范性勘查工作,在此基础上筛选出了复杂地形条件下隐伏硬岩型铀矿不同勘查阶段的地球物理勘查方法技术组合,为华阳川地区铀矿的找矿突破提供了地球物理勘查方法技术支撑,对其他复杂条件区的隐伏铀矿勘查及其他隐伏金属矿的勘查工作也具有参考价值。

Contrasting Depositional Environment of Iron Formation at Endengue Area, NW Congo Craton, Southern Cameroon: New Insights from Trace and Rare Earth Elements Geochemistry

The Endengue Banded Iron Formation (BIF) is located in the northwestern edge of the Congo craton in Cameroon. Here, we report geochemical data of trace and rare earth elements (REE) of the Endengue BIF samples from the Archean Ntem complex and investigate their environmental setting. Two types of BIF occur at Endengue area, both containing minimal contamination from terrestrial material. Total REE (ΣREE) contents in the Type 1 BIF are extremely low, ranging from 0.34 to 1.83 ppm, similarly to pure chemical sediments while Type 2 BIF displays ΣREE contents ranging from 2.98 to 24.26 ppm. The PAAS-normalized REE + Y patterns of the two BIF types display LREE enrichment relative to HREE and weak positive Eu anomaly, most likely suggesting that the source of iron and siliceous of the Endengue BIFs is mainly from the contribution of low-temperature hydrothermal alteration of the crust. Type 1 BIF shows very low Nd content (<1 ppm) with positive correlation between Nd and Ce/Ce* and positive Ce anomalies which suggests suboxic or anoxic seawater similar to the depositional environment of Elom BIF in Archean Ntem complex. In contrast, Type 2 BIF displays low to moderate Nd contents (1 and 100 ppm with the exception of sample LBR65) with negative correlation between Nd and Ce/Ce* and negative Ce anomalies. These features indicate precipatation of Type 2 BIF from oxic iron-rich solution that changed to oxidized surface by rapid precipitation of the hydrothermal Fe. The Endengue BIFs were deposited in the continental margin ocean in presence of low-temperature hydrothermal fluids mixed with seawater, similar to Paleoproterozoic Kpwa-Atog Boga BIFs within the Nyong group and other Paleoproterozoic Superior-type BIFs worldwide.

ROLE OF NaCl IN ORE-FORMING OF SAND-SHALE TYPE COPPER DEPOSITS

ＲＯＬＥＯＦＮａＣｌＩＮＯＲＥＦＯＲＭＩＮＧＯＦＳＡＮＤＳＨＡＬＥＴＹＰＥＣＯＰＰＥＲＤＥＰＯＳＩＴＳ①ＴａｎＫａｉｘｕａｎａｎｄＤａｉＴａｇｅｎＣｏｌｅｇｅｏｆＲｅｓｏｕｒｃｅ，ＥｎｖｉｒｏｎｍｅｎｔａｎｄＣｉｖｉｌＥｎｇｉｎｅｒｉｎｇ，Ｃｅｎ...

络合铁脱硫装置硫沉积控制措施探讨

硫沉积现象在络合铁脱硫装置中不可避免,为此需研究络合铁脱硫装置的设备结构、工艺流程设计、工艺参数的设置以及合理的工艺操作,以期有效控制溶液系统中硫沉积的速度,达到延长络合铁脱硫装置平稳运行时间的目的。通过研究络合铁脱硫装置的运行情况、异常处置情况,横向对比同类装置的异常处置情况,制定控制硫磺沉积措施,再通过现场验证,确认控制措施的可靠性和效率。实践证明,硫磺沉积控制措施在某单井络合铁脱硫装置应用后,装置运行平稳,未发生硫磺过量沉积现象,在控制硫磺沉积方面效果显著。研究成果可供同类项目参考借鉴。

华北克拉通东部新房金矿床成矿规律与三维成矿预测

新房金矿床是近年新发现的中型金矿床,矿体主要赋存于新房变质核杂岩的盖层与基底之间的韧性剪切带内,严格受伸展拆离带控制,矿石类型以蚀变岩型为主,石英脉型次之。该矿床目前正在勘探中,深部及外围成矿潜力巨大。通过地质构造调查、地球物理勘查、地球化学勘查和钻探工程等多种三维立体手段,首次建立了新房金矿床三维地质构造模型,并通过地层、岩浆岩、构造与矿体之间的三维空间关系和成矿机制分析,研究成矿规律,建立了三维成矿预测模型,以期对下一步深部勘查提供科学指导。

双还原剂SHP和DMAB对ABS表面化学镀铜的影响

为进一步改善以次磷酸盐作为还原剂的化学镀铜溶液的沉积速率,采用次磷酸钠(SHP)和二甲胺基甲硼烷(DMAB)构成双还原剂用于化学镀铜溶液中,研究了两种还原剂复合添加浓度对聚丙烯腈-丁二烯-苯乙烯共聚物(ABS)表面化学镀铜的影响。利用网格设计法,探讨化学镀铜溶液中两种还原剂复合的适宜浓度配比,通过恒温加热测试,研究两种还原剂的复合添加浓度对化学镀铜溶液稳定性的影响,并采用场发射扫描电子显微镜和X射线能谱分析仪对化学镀铜层的微观形貌和组成进行表征。研究结果表明,在DMAB和SHP的添加浓度分别为0.50 g·L^(-1)和90 g·L^(-1)时,DMAB和SHP具有良好的协同作用,此时化学镀铜溶液的稳定性好,化学镀铜的沉积速率最大,为3.14μm·h^(-1)。化学镀铜层表面铜晶粒排列致密,表面平整,且镀层中铜含量达到97.4%,ABS表面与化学镀铜层之间的粘结强度最高,达到0.95 kN·m^(-1)。

Catalyst Enhanced Chemical Vapor Depositionof Nickel on Polymer Surface

Catalyst enhanced chemical vapor deposition of nickel film on high Tg polymers such as teflon(PTFE), polyimide(PI), and polysulfone(PS) was investigated by hot wall and cold wall CVD, in which Ni(dmg)_2, Ni(acac)_2, Ni(hfac)_2, Ni(TMHD)_2, and Ni(cp)_2 are used as precursors, and palladium complexes are used as catalysts. The films obtained were shiny with silvery color. The Ni was metallic and the purity of Ni was about 92%-95% from XPS analysis. SEM micrographs show that the film had good morphology. The conductivity of the film was about 0.5-4 W·cm^(-1). Ni films had good adhesion with polyimide and polysulfone.