8-Hydroxyquinoling aluminum (Alq3) and 11, 11, 12, 12-tetracyano-9, 10-anthraquino dimethane(TCAQ) monolayer films and their heterostructure complex films were prepared by a vacuum deposition method. By means of surfa...8-Hydroxyquinoling aluminum (Alq3) and 11, 11, 12, 12-tetracyano-9, 10-anthraquino dimethane(TCAQ) monolayer films and their heterostructure complex films were prepared by a vacuum deposition method. By means of surface photovoltage spectroscopy (SPS) and electric field-induced surface photovoltage spectroscopy (EFISPS), the band gaps of TCAQ and Alq3 monolayer films and the properties of the Alq3/TCAQ bilayer film were investigated. By analysing the mechanism and the results of the SPS and the EFISPS, a reasonable energy band structure of the Alq3/TCAQ complex film was roughly determined.展开更多
1 Results Various kinds of biodegradable polymer materials have been researched[1]. In our previous papers,cereals such as wheat,buckwheat,glutinous rice and nonglutinous rice were polycondenced with citric acid and p...1 Results Various kinds of biodegradable polymer materials have been researched[1]. In our previous papers,cereals such as wheat,buckwheat,glutinous rice and nonglutinous rice were polycondenced with citric acid and polysilicic acid to prepare copolymer films respectively[2,3].These copolymer fims have relatively good mechanical properties but the water proofness is not so good.Recently,some cereals such as wheat,glutinous rice,nonglutinous rice,kaoliang,millet and maize were reacted with copper chlorid...展开更多
The characteristics of the LB films of Schiff base aluminium(Ⅲ), tris(2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium(Ⅲ)[Al(TA12)_3], were studied. The surface pressure-area(π-A) isotherm of Al(TA12)_3 in...The characteristics of the LB films of Schiff base aluminium(Ⅲ), tris(2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium(Ⅲ)[Al(TA12)_3], were studied. The surface pressure-area(π-A) isotherm of Al(TA12)_3 in the pure water subphase was investigated. The molecular area, 0.48 nm^2, is one-third of the expected value that indicates the formation of an aggregate. The Langmuir-Blodgett(LB) films of Al(TA12)_3 were transferred and characterized. The UV-Vis spectra and the AFM image both confirmed that the J-aggregates formed. The polarized UV-Vis spectra indicated that the complex plane had to be oriented with an angle of about 30° to the substrate surface. The IR spectra suggested that the complexation took place between aluminium ions and the oxygen atoms of the ligand rather than the nitrogen atom.展开更多
A resistive-type relative humidity （RH） sensor based on vanadium complex （VO2（3-f[）） film is reported in this study. Gold electrodes were deposited on the glass substrates in a co-planar structure. A thin film o...A resistive-type relative humidity （RH） sensor based on vanadium complex （VO2（3-f[）） film is reported in this study. Gold electrodes were deposited on the glass substrates in a co-planar structure. A thin film of vanadium complex was coated as a humidity-sensing material on the top of the pre-patterned electrodes. The humidity-sensing principle of the sensor was based on the conductivity change of coated sensing element upon adsorption/desorption of water vapor. The resistance of the humidity sensor measured at 1 kHz decreased linearly with increasing the humidity in the range of 35%-70% RH. The overall resistance of the sensor decreases 11 times. An equivalent circuit for the VO2（3-fl） based resistive-type humidity sensor was developed. The properties of the sensor studied in this work make it beneficial for use in the instruments for environmental monitoring of humidity.展开更多
The surface pressure-area (pi -A) isotherm of Schiff base aluminium (III), tris (2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium (III) (denoted as Al(TAl2)(3)), on pure water subphase was investigated. The m...The surface pressure-area (pi -A) isotherm of Schiff base aluminium (III), tris (2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium (III) (denoted as Al(TAl2)(3)), on pure water subphase was investigated. The molecular area, 0.48 nm(2), is one-third of expected value that indicated the aggregation took place. The Langmuir-Blodgett (LB) films of Al(TAl2), was transferred and characterized. The AFM image confirmed the formation of aggregates.展开更多
A novel method for preparing metalllzed film has been studied.The reduction process and properties of the poly(vinyl alcohol)(PVA)were probed by several analytic means.According to the etudies,a mechanism for the poly...A novel method for preparing metalllzed film has been studied.The reduction process and properties of the poly(vinyl alcohol)(PVA)were probed by several analytic means.According to the etudies,a mechanism for the polymer surface reduction metallization was proposed and proved.展开更多
Infrared spectra of alternating LB films of octadecyl-TCNQ/CuPc are studied. Charge-transfer complexes are formed in LB films and conductance increases about three orders than that of pure CuPc LB films.
A series of europium(III) complexes with different chain length, tris [2-m-pyridylmethanamido-5-phenyl- (1,3,4)-oxadiazole] mono [2-(4-n-alkylphenyl)-iminazole (4,5-f)-1,10-phenanthroline] Eu(III) [Eu(PMA)3Nn (n = 6, ...A series of europium(III) complexes with different chain length, tris [2-m-pyridylmethanamido-5-phenyl- (1,3,4)-oxadiazole] mono [2-(4-n-alkylphenyl)-iminazole (4,5-f)-1,10-phenanthroline] Eu(III) [Eu(PMA)3Nn (n = 6, 10, 14,18)] were synthesized. All of these amphiphilic europium(III) complexes could form stable Langmuir film at air/water interface and could be transferred onto hydrophilic quartz and mica substrates by measurement of UV spectra in which the absorbance of the LB films at about 288 nm scales showed the linearity with the number of layers deposited. In order to investigate relation between fluorescence properties and the arrangement of molecular in LB films, surface topography of monolayer films were observed by atomic force microscopy (AFM). Results showed that the emission spectra have Eu(III) characteristic peaks and strong emission strength. It is interesting that the molecular with looser arrangement in LB films has better monochromacity, which illustrated that energy might transferred more easily from ligand to Eu(III) in loosen structure films.展开更多
Tris (thenoyltrifluoroacetonato) mono(9-octadecylamino-4,5-diazafluorene) europium (III) was synthesized. Stable floating monolayer on pure water subphase (18 degrees C, pH 5.6) was obtained with a collapse pressure o...Tris (thenoyltrifluoroacetonato) mono(9-octadecylamino-4,5-diazafluorene) europium (III) was synthesized. Stable floating monolayer on pure water subphase (18 degrees C, pH 5.6) was obtained with a collapse pressure of 40 mN/m and a zero-pressure area of 0.495 nm(2) molecule(-1). The monolayers can be transferred onto hydrophilically treated substrates of quartz, calcium fluoride at a surface pressure of 25 mN/m with a transfer ratio of ca. unity. The films were characterized by UV, IR and fluorescent spectroscopy.展开更多
The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in si...The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in situ. The fluorescence spectra show that the thin film material emits the characteristic narrow band emission of Tb 3+ under the UV excitation.展开更多
In order to analyze the stress and deformation of different permeability of residual oil film in the complex pore, which are affected by the viscous-elasticity of the fluid, the hydrodynamic displacement mechanism is ...In order to analyze the stress and deformation of different permeability of residual oil film in the complex pore, which are affected by the viscous-elasticity of the fluid, the hydrodynamic displacement mechanism is explored from the stand-point of hydrodynamics, that is, the residual oil film displaced by alternating injection of different concentrations of the polymer solution, viscous-elastic fluid flow equation is established in the complex pore by choosing continuity equation, motion equation and the upper convected Maxwell constitutive equation. The flow field is computed by using the method of numerical analysis. Not only the stress and deformation of residual oil film on the different permeability of micro pores, but also the analysis of the flooding mechanism of alternating injection of different concentrations of the polymer solution is got. The results show that the larger the viscous-elasticity of polymer solution is, the bigger the normal deviatoric stress acting on the residual oil film is;the distribution of normal deviatoric stress has the abrupt change. The stronger the viscous-elasticity of the polymer solution is, the bigger the horizontal stress difference acting on the residual oil film is and the more obvious the deformation is;the high-concentration polymer solution is suitable for high-permeability micro pores. Low-concentration polymer solution is suitable for medium and low-permeability micro pores. Alternating injection of polymer solution can improve Volumetric Sweep Efficiency and increase the deformation of residual oil film, which is conducive to enhancing oil recovery.展开更多
The LB film of the title complex was prepared by dropping a benzene solution of the title complex on the surfaceof water subphase at 25±1℃.The film was deposited in Z type on various hydrophilic pretreated subst...The LB film of the title complex was prepared by dropping a benzene solution of the title complex on the surfaceof water subphase at 25±1℃.The film was deposited in Z type on various hydrophilic pretreated substrates ofquartz,CaF;and electronic conductive glass for different purposes.The π-A curve of the film shows that thecross section per molecule is 125;,which indicates that the alkyl chain of the molecule is basically perpendiculalto the surface of the substrate.UV,IR spectra and transmission electronic microscopy of the film were also obtained.展开更多
A new method of the modifying factor for determining the broadband complex permeability of magnetic thin films,was proposed. Based on the measurement technology of shot-end microstrip line and the new modify factor,a ...A new method of the modifying factor for determining the broadband complex permeability of magnetic thin films,was proposed. Based on the measurement technology of shot-end microstrip line and the new modify factor,a series of FeCo-based magnetic thin films deposited on the oxidized silicon substrates and with an in-plane uniaxial anisotropy were measured in the frequency range of 0.5-5 GHz. The results fit well with the Landau-Lifchitz-Gilbert theory in a broad frequency range.展开更多
Formation of copper wiring on a polyimide film by laser irradiation to a stable copper-complex film consisting of glyoxylic acid copper complex and methylamine copper complex in air has been investigated. A stable met...Formation of copper wiring on a polyimide film by laser irradiation to a stable copper-complex film consisting of glyoxylic acid copper complex and methylamine copper complex in air has been investigated. A stable metallic copper on the polyimide film was precipitated even in air. Since this copper was generated only in the laser-irradiated parts, direct patterning of copper wiring was possible. It was also found that copper was precipitated by electroless copper plating on the laser-deposited copper wiring and it was possible to thicken the copper wiring by this precipitation. The resistivity of the copper wiring was almost the same as that of the bulk of metallic copper. The developed method—combining laser irradiation to a copper-complex-coated film and electroless copper plating—enables the high-speed deposition of fine copper wiring on a polyimide film in air by a printing process, indicating an inexpensive and useful process for fabricating copper wiring without high vacuum facility and heat-treatment under inert gas.展开更多
基金Supported by the National Natural Science Foundation of China(No. 59620167).
文摘8-Hydroxyquinoling aluminum (Alq3) and 11, 11, 12, 12-tetracyano-9, 10-anthraquino dimethane(TCAQ) monolayer films and their heterostructure complex films were prepared by a vacuum deposition method. By means of surface photovoltage spectroscopy (SPS) and electric field-induced surface photovoltage spectroscopy (EFISPS), the band gaps of TCAQ and Alq3 monolayer films and the properties of the Alq3/TCAQ bilayer film were investigated. By analysing the mechanism and the results of the SPS and the EFISPS, a reasonable energy band structure of the Alq3/TCAQ complex film was roughly determined.
文摘1 Results Various kinds of biodegradable polymer materials have been researched[1]. In our previous papers,cereals such as wheat,buckwheat,glutinous rice and nonglutinous rice were polycondenced with citric acid and polysilicic acid to prepare copolymer films respectively[2,3].These copolymer fims have relatively good mechanical properties but the water proofness is not so good.Recently,some cereals such as wheat,glutinous rice,nonglutinous rice,kaoliang,millet and maize were reacted with copper chlorid...
基金Supported by the National Natural Science Foundation of China(No. 29973026, 20073016).
文摘The characteristics of the LB films of Schiff base aluminium(Ⅲ), tris(2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium(Ⅲ)[Al(TA12)_3], were studied. The surface pressure-area(π-A) isotherm of Al(TA12)_3 in the pure water subphase was investigated. The molecular area, 0.48 nm^2, is one-third of the expected value that indicates the formation of an aggregate. The Langmuir-Blodgett(LB) films of Al(TA12)_3 were transferred and characterized. The UV-Vis spectra and the AFM image both confirmed that the J-aggregates formed. The polarized UV-Vis spectra indicated that the complex plane had to be oriented with an angle of about 30° to the substrate surface. The IR spectra suggested that the complexation took place between aluminium ions and the oxygen atoms of the ligand rather than the nitrogen atom.
基金support of Ghulam Ishaq Khan Institute of Engineering Sciences and Technology
文摘A resistive-type relative humidity （RH） sensor based on vanadium complex （VO2（3-f[）） film is reported in this study. Gold electrodes were deposited on the glass substrates in a co-planar structure. A thin film of vanadium complex was coated as a humidity-sensing material on the top of the pre-patterned electrodes. The humidity-sensing principle of the sensor was based on the conductivity change of coated sensing element upon adsorption/desorption of water vapor. The resistance of the humidity sensor measured at 1 kHz decreased linearly with increasing the humidity in the range of 35%-70% RH. The overall resistance of the sensor decreases 11 times. An equivalent circuit for the VO2（3-fl） based resistive-type humidity sensor was developed. The properties of the sensor studied in this work make it beneficial for use in the instruments for environmental monitoring of humidity.
基金the NSFC (29973026, 29773017) and Beijing Natural Science Foundation (2992007) for the provision of financial support.
文摘The surface pressure-area (pi -A) isotherm of Schiff base aluminium (III), tris (2-hydroxy-5-nitro-N-dodecyl-benzylideneaminato) aluminium (III) (denoted as Al(TAl2)(3)), on pure water subphase was investigated. The molecular area, 0.48 nm(2), is one-third of expected value that indicated the aggregation took place. The Langmuir-Blodgett (LB) films of Al(TAl2), was transferred and characterized. The AFM image confirmed the formation of aggregates.
基金The project surported by State"863"PlanNational Natural science fund.
文摘A novel method for preparing metalllzed film has been studied.The reduction process and properties of the poly(vinyl alcohol)(PVA)were probed by several analytic means.According to the etudies,a mechanism for the polymer surface reduction metallization was proposed and proved.
文摘Infrared spectra of alternating LB films of octadecyl-TCNQ/CuPc are studied. Charge-transfer complexes are formed in LB films and conductance increases about three orders than that of pure CuPc LB films.
文摘A series of europium(III) complexes with different chain length, tris [2-m-pyridylmethanamido-5-phenyl- (1,3,4)-oxadiazole] mono [2-(4-n-alkylphenyl)-iminazole (4,5-f)-1,10-phenanthroline] Eu(III) [Eu(PMA)3Nn (n = 6, 10, 14,18)] were synthesized. All of these amphiphilic europium(III) complexes could form stable Langmuir film at air/water interface and could be transferred onto hydrophilic quartz and mica substrates by measurement of UV spectra in which the absorbance of the LB films at about 288 nm scales showed the linearity with the number of layers deposited. In order to investigate relation between fluorescence properties and the arrangement of molecular in LB films, surface topography of monolayer films were observed by atomic force microscopy (AFM). Results showed that the emission spectra have Eu(III) characteristic peaks and strong emission strength. It is interesting that the molecular with looser arrangement in LB films has better monochromacity, which illustrated that energy might transferred more easily from ligand to Eu(III) in loosen structure films.
文摘Tris (thenoyltrifluoroacetonato) mono(9-octadecylamino-4,5-diazafluorene) europium (III) was synthesized. Stable floating monolayer on pure water subphase (18 degrees C, pH 5.6) was obtained with a collapse pressure of 40 mN/m and a zero-pressure area of 0.495 nm(2) molecule(-1). The monolayers can be transferred onto hydrophilically treated substrates of quartz, calcium fluoride at a surface pressure of 25 mN/m with a transfer ratio of ca. unity. The films were characterized by UV, IR and fluorescent spectroscopy.
文摘The transparent luminescent thin films of doped terbium complex were obtained by sol gel method. The result indicates that rare earth carboxylates with poor solubility can be homogeneously doped into sol matrix in situ. The fluorescence spectra show that the thin film material emits the characteristic narrow band emission of Tb 3+ under the UV excitation.
文摘In order to analyze the stress and deformation of different permeability of residual oil film in the complex pore, which are affected by the viscous-elasticity of the fluid, the hydrodynamic displacement mechanism is explored from the stand-point of hydrodynamics, that is, the residual oil film displaced by alternating injection of different concentrations of the polymer solution, viscous-elastic fluid flow equation is established in the complex pore by choosing continuity equation, motion equation and the upper convected Maxwell constitutive equation. The flow field is computed by using the method of numerical analysis. Not only the stress and deformation of residual oil film on the different permeability of micro pores, but also the analysis of the flooding mechanism of alternating injection of different concentrations of the polymer solution is got. The results show that the larger the viscous-elasticity of polymer solution is, the bigger the normal deviatoric stress acting on the residual oil film is;the distribution of normal deviatoric stress has the abrupt change. The stronger the viscous-elasticity of the polymer solution is, the bigger the horizontal stress difference acting on the residual oil film is and the more obvious the deformation is;the high-concentration polymer solution is suitable for high-permeability micro pores. Low-concentration polymer solution is suitable for medium and low-permeability micro pores. Alternating injection of polymer solution can improve Volumetric Sweep Efficiency and increase the deformation of residual oil film, which is conducive to enhancing oil recovery.
文摘The LB film of the title complex was prepared by dropping a benzene solution of the title complex on the surfaceof water subphase at 25±1℃.The film was deposited in Z type on various hydrophilic pretreated substrates ofquartz,CaF;and electronic conductive glass for different purposes.The π-A curve of the film shows that thecross section per molecule is 125;,which indicates that the alkyl chain of the molecule is basically perpendiculalto the surface of the substrate.UV,IR spectra and transmission electronic microscopy of the film were also obtained.
基金Project(50771047) supported by the National Natural Science Foundation of ChinaProject(NCET-04-0702) supported by the New Century Excellent Talents in University, ChinaProject(2005ABB002) supported by the Elitist in Natural Science Foundation of Hubei Province
文摘A new method of the modifying factor for determining the broadband complex permeability of magnetic thin films,was proposed. Based on the measurement technology of shot-end microstrip line and the new modify factor,a series of FeCo-based magnetic thin films deposited on the oxidized silicon substrates and with an in-plane uniaxial anisotropy were measured in the frequency range of 0.5-5 GHz. The results fit well with the Landau-Lifchitz-Gilbert theory in a broad frequency range.
文摘Formation of copper wiring on a polyimide film by laser irradiation to a stable copper-complex film consisting of glyoxylic acid copper complex and methylamine copper complex in air has been investigated. A stable metallic copper on the polyimide film was precipitated even in air. Since this copper was generated only in the laser-irradiated parts, direct patterning of copper wiring was possible. It was also found that copper was precipitated by electroless copper plating on the laser-deposited copper wiring and it was possible to thicken the copper wiring by this precipitation. The resistivity of the copper wiring was almost the same as that of the bulk of metallic copper. The developed method—combining laser irradiation to a copper-complex-coated film and electroless copper plating—enables the high-speed deposition of fine copper wiring on a polyimide film in air by a printing process, indicating an inexpensive and useful process for fabricating copper wiring without high vacuum facility and heat-treatment under inert gas.
