The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,su...The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.展开更多
Arc erosion morphologies of Ag/MeO(10) electrical contact materials after 50000 operations under direct current of 19 V and 20 A and resistive load conditions were investigated using scanning electron microscope(SE...Arc erosion morphologies of Ag/MeO(10) electrical contact materials after 50000 operations under direct current of 19 V and 20 A and resistive load conditions were investigated using scanning electron microscope(SEM) and a 3D optical profiler(3DOP). The results indicated that 3DOP could supply clearer and more detailed arc erosion morphology information. Arc erosion resistance of Ag/SnO_2(10) electrical contact material was the best and that of Ag/CuO(10) was the worst. Arc erosion morphology of Ag/MeO(10) electrical contact materials mainly included three different types. Arc erosion morphologies of Ag/ZnO(10) and Ag/SnO_2(10) electrical contact materials were mainly liquid splash and evaporation, and those of Ag/CuO(10) and Ag/CdO(10) were mainly material transfer from anode to cathode. Arc erosion morphology of Ag/SnO_2(6)In_2O_3(4) electrical contact materials included both liquid splash, evaporation and material transfer. In addition, the formation process and mechanism on arc erosion morphology of Ag/MeO(10) electrical contact materials were discussed.展开更多
The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive s...The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive strength of the mortar and concrete with interface component and fiber gradient distributions are obviously improved. The strengthes of the fiber gradient distributed mortar and concrete (FGDM/C) are higher than those of fiber homogeneously distributed mortar and concrete (FHDM/C). To obtain the same strength, therefore, a smaller fiber volume content in FGDM/C is needed than that in FHDM/C. The results also show that the component gradient distribution of the concrete can be obtained by means of multi-layer vibrating formation.展开更多
A brand new direct and adaptive slicing approach is proposed, which canapparently improve the part accuracy and reduce the building time. At least two stages are includedin this operation: getting the crossing contour...A brand new direct and adaptive slicing approach is proposed, which canapparently improve the part accuracy and reduce the building time. At least two stages are includedin this operation: getting the crossing contour of the cutting plane with the solid part anddetermining the layer thickness. Apart from usual SPI algorithm, slicing of the solid model has itsspecial requirements. Enabling the contour line segments of the cross-section as long as possible isone of them, which is for improving manufacturing efficiency and is reached by adaptively adjustingthe step direction and the step size at every crossing point to obtain optimized secant height. Thelayer thickness determination can be divided into two phases: the geometry-based thicknessestimation and the material-based thickness verifying. During the former phase, the geometrytolerance is divided into two parts: a variety of curves are approximated by a circular arc, whichintroduces the first part, and the deviation error between the contour line in LM process and thecircular arc generates the second part. The latter phase is mainly verifying the layer thicknessestimated in the former stage and determining a new one if necessary. In addition, an example usingthis slicing algorithm is also illustrated.展开更多
This paper examines the experimental study on influence of material component to non-linear relation between sediment yield and drainage network development completed in the Lab. The area of flume drainage system is 8...This paper examines the experimental study on influence of material component to non-linear relation between sediment yield and drainage network development completed in the Lab. The area of flume drainage system is 81.2 m2, the longitudinal gradient and cross section slope are from 0.0348 to 0.0775 and from 0.0115 to 0.038, respectively. Different model materials with a medium diameter of 0.021 mm, 0.076 mm and 0.066 mm cover three experiments each. An artificial rainfall equipment is a sprinkler-system composed of 7 downward nozzles, distributed by hexagon type and a given rainfall intensity is 35.56 mm/hr.cm2. Three experiments are designed by process-response principle at the beginning the ψ shaped small network is dug in the flume. Running time spans are 720 m, 1440 minutes and 540 minutes for Runs I, IV and VI, respectively. Three experiments show that the sediment yield processes are characterized by delaying with a vibration. During network development the energy of a drainage system is dissipated by two ways, of which one is increasing the number of channels (rill and gully), and the other one is enlarging the channel length. The fractal dimension of a drainage network is exactly an index of energy dissipation of a drainage morphological system. Change of this index with time is an unsymmetrical concave curve. Comparison of three experiments explains that the vibration and the delaying ratio of sediment yield processes increase with material coarsening, while the number of channel decreases. The length of channel enlarges with material fining. There exists non-linear relationship between fractal dimension and sediment yield with an unsymmetrical hyperbolic curve. The absolute value of delaying ratio of the curve reduces with time running and material fining. It is characterized by substitution of situation to time.展开更多
This paper deals with an analytical model of thermal stresses which originate during a cooling process of an anisotropic solid continuum with uniaxial or triaxial anisotropy. The anisotropic solid continuum consists o...This paper deals with an analytical model of thermal stresses which originate during a cooling process of an anisotropic solid continuum with uniaxial or triaxial anisotropy. The anisotropic solid continuum consists of anisotropic spherical particles periodically distributed in an anisotropic infinite matrix. The particles are or are not embedded in an anisotropic spherical envelope, and the infinite matrix is imaginarily divided into identical cubic cells with central particles. The thermal stresses are thus investigated within the cubic cell. This mulfi-particle-(envelope)-matrix system based on the cell model is applicable to two- and three-component materials of precipitate-matrix and precipitate-envelope-matrix types, respectively. Finally, an analysis of the determination of the thermal stresses in the multi-par- ticle-(envelope)-matrix system which consists of isotropic as well as uniaxial- and/or triaxial-anisotropic components is presented. Additionally, the thermal-stress induced elastic energy density for the anisotropic components is also derived. These analytical models which are valid for isotropic, anisotropic and isotropic-anisotropic multi-particle- (envelope)-matrix systems represent the determination of important material characteristics. This analytical determination includes: (1) the determination of a critical particle radius which defines a limit state regarding the crack initiation in an elastic, elastic-plastic and plastic components; (2) the determination of dimensions and a shape of a crack propagated in a ceramic components; (3) the determination of an energy barrier and micro-/macro-strengthening in a component; and (4) analytical-(experimental)-computational methods of the lifetime prediction. The determination of the thermal stresses in the anisotropic components presented in this paper can be used to determine these material characteristics of real two- and three-component materials with anisotropic components or with anisotropic and isotropic components.展开更多
As urbanization progresses,the demand for high-rise buildings and underground spaces is growing,and the need for firm geotechnical construction materials,efficient excavation methods,accurate testing instruments,and i...As urbanization progresses,the demand for high-rise buildings and underground spaces is growing,and the need for firm geotechnical construction materials,efficient excavation methods,accurate testing instruments,and innovative geotechnical engineering theories and technologies is increasing.By investigating the phenomena of strengthening and toughening in nature,hydrophobic and ice-phobic,friction anisotropy and drilling as well as excavation,etc,researchers have found that organisms have distinctive external morphology and organization.By imitating the external morphology,structural characteristics or movement mechanism of organisms,novel ideas,new principles,and innovative theories can be provided for the innovation and sustainable development of geotechnical engineering.This paper mainly expounds on the bio-inspired application in geotechnical engineering from three perspectives:geo-materials,geotechnical components,and drilling&excavation equipment,and lists typical application cases.In conclusion,this paper presents a summary and prospects of bio-inspired geotechnical engineering,offering fundamental insights for future research.展开更多
The paper deals with analytical models of the elastic energy gradient Wsq representing an energy barrier. The energy barrier is a surface integral of the elastic energy density Wq. The elastic energy density is induce...The paper deals with analytical models of the elastic energy gradient Wsq representing an energy barrier. The energy barrier is a surface integral of the elastic energy density Wq. The elastic energy density is induced by thermal stresses acting in an isotropic spherical particle (q = p) with the radius R and in a cubic cell of an isotropic matrix (q = m). The spherical particle and the matrix are components of a multi-particle-matrix system representing a model system applicable to a real two-component material of a precipitation-matrix type. The multi-particle-matrix system thus consists of periodically distributed isotropic spherical particles and an isotropic infinite matrix. The infinite matrix is imaginarily divided into identical cubic cells with a central spherical particle in each of the cubic cells. The dimension d of the cubic cell then corresponds to an inter-particle distance. The parameters R, d along with the particle volume fraction v = v(R, d) as a function of R, d represent micro- structural characteristics of a real two-component material. The thermal stresses are investigated within the cubic cell, and accordingly are functions of the microstructural charac- teristics. The thermal stresses originate during a cooling pro- cess as a consequence of the difference am - ap in thermal expansion coefficients between the matrix and the particle, am and ap, respectively. The energy barrier Wsq is used for the determination of the thermal-stress induced strengthening aq. The strengthening represents resistance against com- pressive or tensile mechanical loading for am - ap 〉 0 or am - ap 〈 0. respectively.展开更多
The quality of the favoring agents and fragrances degenerated frequently during the storage and transportation process in a cigarette factory in Yunnan Province, causing huge economic losses. In order to ascertain the...The quality of the favoring agents and fragrances degenerated frequently during the storage and transportation process in a cigarette factory in Yunnan Province, causing huge economic losses. In order to ascertain the causes of deterioration, the microbial population, quantity and aroma components of the raw mate- rials were analyzed in the present study. The results showed that a total of 28 bacterial strains and one fungal strain were isolated and identified, belonging to 13 genera. The 29 strains were Bacillus sp. , Microbacterium sp. , Sphingomonas sp. , Leclercia sp. and Acinetobacter sp. isolated from normal ZY material; Bacil- lus sp. , Microbacterium sp. , Sphingomonas sp. , Brevundimonus sp. , Acinetobacter sp. , Agrobacterium sp. , Ralstonia sp. , Acetobacterium sp. , Saccharomyces sp. and Acidovorax sp. isolated from deteriorated ZY material; Agrobacterium sp. , Microbacterium sp. , Burkholderia sp. , Bacillus subtilis strain, Acetobacterium sp. and Leclercia sp. isolated from normal RZ material ; Agrobacterium sp. , Microbacterium sp. , Bacillus subtilis strain, Acetobacterium sp. , Lec/erc/a sp. , Enter- obacter sp. , Acinetobacter sp. and Saccharomyces sp. isolated from deteriorated RZ material. Microbacterium was the dominant genus by number in normal ZY ma- terial, and the population of this genus accounted for 55.6% of the total. In deteriorated ZY material, Acetobacterium, Bacillus and Saccharomyces were dominant genera, as the population of the three genera occupied 75.0% of the total. The total population of microorganisms in the deteriorated ZY material was 90 times of that in normal ZY material. In normal RZ material, the population of each of Microbacterium, Agrobacterium and Bacillus accounted for 25%, while that of each of Leclercia and Burkholderia accounted for 12.5%. In deteriorated RZ material, the population of Bacillus accounted for 65.0% of the total. The total population of the microorganisms in deteriorated RZ material was 29 times of that in normal RZ material, indicating that the deterioration of the materials was caused by microor- ganisms. The contents of aroma components were detected using two-dimensional gas chromatography-mass spectrometry (GC-MS). The results showed that in nor- mal ZY material, the content of β-damascone was higher than that of other aroma components. And normal ZY material had higher contents of benzaldehyde, β-damascone, β-damascone, β-damascone, menthol and benzyl benzoate than deteriorated ZY material, and the differences in the contents of β-ddamascone and β-damascone were most significant between the two materials. In normal RZ material, the content of β-damascone was higher than that of other aroma components. And normal RZ material had higher contents of menthol, ethyl capratc, β-damascone, β-damascone and tabanane C than deteriorated RZ material, and the differ- ences in the contents of ethyl caprate and capric acid were most significant between the two materials. The results revealed that aroma components changed greatly in deteriorated tobacco materials.展开更多
The paper deals with analytical fracture mechanics to consider elastic thermal stresses acting in an isotropic multi-particle-matrix system. The multi-particle-matrix system consists of periodically distributed spheri...The paper deals with analytical fracture mechanics to consider elastic thermal stresses acting in an isotropic multi-particle-matrix system. The multi-particle-matrix system consists of periodically distributed spherical particles in an infinite matrix. The thermal stresses originate during a cooling process as a consequence of the difference αm - αp in thermal expansion coefficients between the matrix and the particle, αm and αp, respectively. The multi-particle-matrix system thus represents a model system applicable to a real two-component material of a precipitation-matrix type. The infinite matrix is imaginarily divided into identical cubic cells. Each of the cubic cells with the dimension d contains a central spherical particle with the radius R, where d thus corresponds to inter-particle distance. The parameters R, d along with the particle volume fraction v = v(R, d) as a function of R, d represent microstructural characteristics of a twocomponent material. The thermal stresses are investigated within the cubic cell, and accordingly are functions of the microstructural characteristics. The analytical fracture mechanics includes an analytical analysis of the crack initiation and consequently the crack propagation both considered for the spherical particle (q = p) and the cell matrix (q = m). The analytical analysis is based on the determination of the curve integral Wcq of the thermal-stress induced elastic energy density Wq. The crack initiation is represented by the determination of the critical particle radius Rqc = Rqc(V). Formulae for Rqc are valid for any two-component mate- rial of a precipitate-matrix type. The crack propagation for R 〉 Rqc is represented by the determination of the function fq describing a shape of the crack in a plane perpendicular展开更多
Background:The simplest and most convenient food technology is the using of dry composite mixtures.They have a lot of advantages.Dry composite mixtures,which would completely be the basis for the production of persona...Background:The simplest and most convenient food technology is the using of dry composite mixtures.They have a lot of advantages.Dry composite mixtures,which would completely be the basis for the production of personalized food concentrates,are not represented.The development of such dry composite mixtures is actual and of scientific and practical interest.The purpose of this research is the selection and justification of local import-substituting raw materials components for dry composite mixtures used as the basis for the production of food concentrates.As the objects of research,the raw materials components of the starch,fruit and vegetable,industry were selected.The work uses currently accepted standard research methods for organoleptic and physic-chemical parameters of raw materials components.The research was carried out within of the project“Theoretical Substantiation of Production Technology and the Development of Import-Substituting Food Products of Functional Purpose Based on Dry Composite Mixtures”,funded by the Belarusian Republican Foundation for Basic Research.Based on the researches,it was found out that in the composition of dry composite mixtures for the production of food concentrates it is expedient to use the following raw materials:potato starch,extruded corn starch,dried carrots,dried beets,dried topinambur and dried apples in chopped form.展开更多
The grinding characteristics of two or multi-component material of cli nker with limestone, blast furnace slag and fly ash were studied. Investigation was carried out on the particle size distribution, the Blaine fin...The grinding characteristics of two or multi-component material of cli nker with limestone, blast furnace slag and fly ash were studied. Investigation was carried out on the particle size distribution, the Blaine fineness and the s ieve residue of the separate and interground products. The relative contents of clinker and limestone in different size fractions of the interground product wer e examined, and the interaction of two components, which have different grindabi lities, was analyzed. The results show there exists a selective grinding effect during intergrinding, one component can help or hinder the grinding of the other . Making good use of this interaction appropriately not only enhances the grinda bilities of two or multi-component mixtures, which can promote the grinding pro cess of clinker with industrial wastes, but also improves their particle size di stribution and properties.展开更多
The C.oleifera oil processing industry generates large amounts of solid wastes,including C.oleifera shell(COS)and C.oleifera cake(COC).Distinct from generally acknowledged lignocellulosic biomass(corn stover,bamboo,bi...The C.oleifera oil processing industry generates large amounts of solid wastes,including C.oleifera shell(COS)and C.oleifera cake(COC).Distinct from generally acknowledged lignocellulosic biomass(corn stover,bamboo,birch,etc.),Camellia wastes contain diverse bioactive substances in addition to the abundant lignocellulosic components,and thus,the biorefinery utilization of C.oleifera processing byproducts involves complicated processing technologies.This reviewfirst summarizes various technologies for extracting and converting the main components in C.oleifera oil processing byproducts into value-added chemicals and biobased materials,as well as their potential applications.Microwave,ultrasound,and Soxhlet extractions are compared for the extraction of functional bioactive components(tannin,flavonoid,saponin,etc.),while solvothermal conversion and pyrolysis are discussed for the conversion of lignocellulosic components into value-added chemicals.The application areas of these chemicals according to their properties are introduced in detail,including utilizing antioxidant and anti-in-flammatory properties of the bioactive substances for the specific application,as well as drop-in chemicals for the substitution of unrenewable fossil fuel-derived products.In addition to chemical production,biochar fabricated from COS and its applications in thefields of adsorption,supercapacitor,soil remediation and wood composites are comprehensively reviewed and discussed.Finally,based on the compositions and structural characteristics of C.oleifera byproducts,the development of full-component valorization strategies and the expansion of the appli-cationfields are proposed.展开更多
The objective of this paper was to develop a comprehensive evaluation method and index to evaluate the performance of sealants and fillers for cracks in asphalt concrete pavements using the method of principal compone...The objective of this paper was to develop a comprehensive evaluation method and index to evaluate the performance of sealants and fillers for cracks in asphalt concrete pavements using the method of principal component analysis. The performance experiments including cone penetration, softening point, flow, resilience and tension at low temperature respectively were conducted by reference of ASTM D5329 for eight sealants and fillers often used in China. There by a principal component model was developed and weight of every index was calculated. The experimental results show that there are significantly different performances for sealants and fillers often used in China. Principal component analysis is an objective method that evaluates and selects the performance of sealants and fillers for cracks in asphalt concrete pavements.展开更多
The effect of key parameters on fatigue life of common metallic components, e.g. steel, aluminium alloy, has been analysed quantitatively. The influential coverage and degree of these parameters have been investigated...The effect of key parameters on fatigue life of common metallic components, e.g. steel, aluminium alloy, has been analysed quantitatively. The influential coverage and degree of these parameters have been investigated systematically, some phenomena which can′t be discovered with qualitative analysis method have been revealed, a series of valuable conclusions has been obtained, which would be very beneficial to fatigue resistant design and improvement of anti fatigue ability of metallic components.展开更多
With its long-term empirical clinical practice and increasing number of health benefits reported,Chinese Materia Medica(CMM)is gaining increasing global acceptance.Importantly,the identification of chemical constituen...With its long-term empirical clinical practice and increasing number of health benefits reported,Chinese Materia Medica(CMM)is gaining increasing global acceptance.Importantly,the identification of chemical constituents in vitro and exposed forms in vivo is a prerequisite for understanding how CMM formulae prevent and treat diseases.This review systematically summarizes the exciting and magical journey of CMM components from compound formulae to where they fight,the possible structural transformation of CMM components in vitro and in vivo,and their pharmacological contribution.When a decoction is prepared,significant chemical reactions are observed,including degradation and production of polymers and self-assembling supramolecules,leading to the construction of a component library with diverse decoction structures.After ingestion,compounds pass through the intestinal and blood-brain barriers and undergo a more wonderful journey involving the gut microbiota,microbial enzymes,and endogenous drug-metabolizing enzymes(mainly liver enzymes).At this stage,they are modified and assembled into novel and complex compounds,such as newly generated metabolites,conjugates,and self-assembling superamolecules.This review might provide a strategic orientation to explore the active compounds of CMM formulae in vivo.展开更多
In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geo...In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geometrical interpretation of deformation state, the general form of strain energy density function was introduced. Using this function and variational methods the relations between material characteristics were achieved. All considerations are illustrated by a short theoretical example.展开更多
Raw material blending process is an essential part of the cement production process. The main purpose of the process is to guarantee a certain oxide composition for the raw meal at the outlet of the mill by regulating...Raw material blending process is an essential part of the cement production process. The main purpose of the process is to guarantee a certain oxide composition for the raw meal at the outlet of the mill by regulating the four raw materials. But the chemical compositions of raw materials vary from time to time, resulting in difficulties to control the oxide compositions to a predefined value. Therefore, a novel algorithm to estimate the chemical compositions of the raw materials is developed. The paper mainly consists of two parts. In model construction part, a novel constrained least square model is proposed to overcome the deviation introduced by long-term drift of the material components, and the model parameters are estimated with an online strategy. And in validation part, the approach is implemented to two examples including datasets from simulation model and the actual industrial process. The final results show the effectiveness of the proposed method.展开更多
A new microelement method for the analyses of functionally graded structures was proposed. The key of this method is the maneuverable combination of two kinds of elements. Firstly, the macro elements are divided from ...A new microelement method for the analyses of functionally graded structures was proposed. The key of this method is the maneuverable combination of two kinds of elements. Firstly, the macro elements are divided from the functionally graded material structures by the normal finite elements. In order to reflect the functionally graded distributions of materials and the microconstitutions in each macro-element, the microelement method sets up the dense microelements in every macro-element, and translates nodes to the same as the normal finite elements by the degrees of freedom of all microelemental the compatibility conditions. This microelement method can fully reflect the micro constitutions and different components of materials, and its computational elements are the same as the normal finite elements, so it is an effective numerical method for the analyses of the functionally graded material structures. The three-dimensional analyses of functionally graded plates with medium components and different micro net structures are given by using the microelement method in this paper. The differences of the stress contour in the plane of functionally graded plates with different net microstructures are especially given in this paper.展开更多
We used both correlation and covariance-principal component analysis (PCA) to classify the same absorption-reflectance data collected from 13 different polymeric fabric materials that was obtained using Attenuated Tot...We used both correlation and covariance-principal component analysis (PCA) to classify the same absorption-reflectance data collected from 13 different polymeric fabric materials that was obtained using Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR). The application of the two techniques, though similar, yielded results that represent different chemical properties of the polymeric substances. On one hand, correlation-PCA enabled the classification of the fabric materials according to the organic functional groups of their repeating monomer units. On the other hand, covariance-PCA was used to classify the fabric materials primarily according to their origins;natural (animal or plant) or synthetic. Hence besides major chemical functional groups of the repeat units, it appears covariance-PCA is also sensitive to other characteristic chemical (inorganic and/or organic) or biochemical material inclusions that are found in different samples. We therefore recommend the application of both covariance-PCA and correlation-PCA on datasets, whenever applicable, to enable a broader classification of spectroscopic information through data mining and exploration.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52075255,92160301,52175415,52205475,and 92060203)。
文摘The aerospace community widely uses difficult-to-cut materials,such as titanium alloys,high-temperature alloys,metal/ceramic/polymer matrix composites,hard and brittle materials,and geometrically complex components,such as thin-walled structures,microchannels,and complex surfaces.Mechanical machining is the main material removal process for the vast majority of aerospace components.However,many problems exist,including severe and rapid tool wear,low machining efficiency,and poor surface integrity.Nontraditional energy-assisted mechanical machining is a hybrid process that uses nontraditional energies(vibration,laser,electricity,etc)to improve the machinability of local materials and decrease the burden of mechanical machining.This provides a feasible and promising method to improve the material removal rate and surface quality,reduce process forces,and prolong tool life.However,systematic reviews of this technology are lacking with respect to the current research status and development direction.This paper reviews the recent progress in the nontraditional energy-assisted mechanical machining of difficult-to-cut materials and components in the aerospace community.In addition,this paper focuses on the processing principles,material responses under nontraditional energy,resultant forces and temperatures,material removal mechanisms,and applications of these processes,including vibration-,laser-,electric-,magnetic-,chemical-,advanced coolant-,and hybrid nontraditional energy-assisted mechanical machining.Finally,a comprehensive summary of the principles,advantages,and limitations of each hybrid process is provided,and future perspectives on forward design,device development,and sustainability of nontraditional energy-assisted mechanical machining processes are discussed.
基金Project(2012QNZT003)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2012M521542)supported by the Postdoctoral Science Foundation of China+1 种基金Project(14JJ3014)supported by the Hunan Provincial Natural Science Foundation of ChinaProject(BSh1202)supported by the Zhejiang Provincial Postdoctoral Scientific Research Foundation of China
文摘Arc erosion morphologies of Ag/MeO(10) electrical contact materials after 50000 operations under direct current of 19 V and 20 A and resistive load conditions were investigated using scanning electron microscope(SEM) and a 3D optical profiler(3DOP). The results indicated that 3DOP could supply clearer and more detailed arc erosion morphology information. Arc erosion resistance of Ag/SnO_2(10) electrical contact material was the best and that of Ag/CuO(10) was the worst. Arc erosion morphology of Ag/MeO(10) electrical contact materials mainly included three different types. Arc erosion morphologies of Ag/ZnO(10) and Ag/SnO_2(10) electrical contact materials were mainly liquid splash and evaporation, and those of Ag/CuO(10) and Ag/CdO(10) were mainly material transfer from anode to cathode. Arc erosion morphology of Ag/SnO_2(6)In_2O_3(4) electrical contact materials included both liquid splash, evaporation and material transfer. In addition, the formation process and mechanism on arc erosion morphology of Ag/MeO(10) electrical contact materials were discussed.
文摘The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive strength of the mortar and concrete with interface component and fiber gradient distributions are obviously improved. The strengthes of the fiber gradient distributed mortar and concrete (FGDM/C) are higher than those of fiber homogeneously distributed mortar and concrete (FHDM/C). To obtain the same strength, therefore, a smaller fiber volume content in FGDM/C is needed than that in FHDM/C. The results also show that the component gradient distribution of the concrete can be obtained by means of multi-layer vibrating formation.
基金This project is supported by National Natural Science Foundation of China (No.59975015, No.50275018) Doctoral Foundation of Ministry of Edu-cation of China (No.1999014102).
文摘A brand new direct and adaptive slicing approach is proposed, which canapparently improve the part accuracy and reduce the building time. At least two stages are includedin this operation: getting the crossing contour of the cutting plane with the solid part anddetermining the layer thickness. Apart from usual SPI algorithm, slicing of the solid model has itsspecial requirements. Enabling the contour line segments of the cross-section as long as possible isone of them, which is for improving manufacturing efficiency and is reached by adaptively adjustingthe step direction and the step size at every crossing point to obtain optimized secant height. Thelayer thickness determination can be divided into two phases: the geometry-based thicknessestimation and the material-based thickness verifying. During the former phase, the geometrytolerance is divided into two parts: a variety of curves are approximated by a circular arc, whichintroduces the first part, and the deviation error between the contour line in LM process and thecircular arc generates the second part. The latter phase is mainly verifying the layer thicknessestimated in the former stage and determining a new one if necessary. In addition, an example usingthis slicing algorithm is also illustrated.
基金Joint project by National Natural Science Foundation of China and Ministry of Water Resources of China, No.59890200 National Na
文摘This paper examines the experimental study on influence of material component to non-linear relation between sediment yield and drainage network development completed in the Lab. The area of flume drainage system is 81.2 m2, the longitudinal gradient and cross section slope are from 0.0348 to 0.0775 and from 0.0115 to 0.038, respectively. Different model materials with a medium diameter of 0.021 mm, 0.076 mm and 0.066 mm cover three experiments each. An artificial rainfall equipment is a sprinkler-system composed of 7 downward nozzles, distributed by hexagon type and a given rainfall intensity is 35.56 mm/hr.cm2. Three experiments are designed by process-response principle at the beginning the ψ shaped small network is dug in the flume. Running time spans are 720 m, 1440 minutes and 540 minutes for Runs I, IV and VI, respectively. Three experiments show that the sediment yield processes are characterized by delaying with a vibration. During network development the energy of a drainage system is dissipated by two ways, of which one is increasing the number of channels (rill and gully), and the other one is enlarging the channel length. The fractal dimension of a drainage network is exactly an index of energy dissipation of a drainage morphological system. Change of this index with time is an unsymmetrical concave curve. Comparison of three experiments explains that the vibration and the delaying ratio of sediment yield processes increase with material coarsening, while the number of channel decreases. The length of channel enlarges with material fining. There exists non-linear relationship between fractal dimension and sediment yield with an unsymmetrical hyperbolic curve. The absolute value of delaying ratio of the curve reduces with time running and material fining. It is characterized by substitution of situation to time.
文摘This paper deals with an analytical model of thermal stresses which originate during a cooling process of an anisotropic solid continuum with uniaxial or triaxial anisotropy. The anisotropic solid continuum consists of anisotropic spherical particles periodically distributed in an anisotropic infinite matrix. The particles are or are not embedded in an anisotropic spherical envelope, and the infinite matrix is imaginarily divided into identical cubic cells with central particles. The thermal stresses are thus investigated within the cubic cell. This mulfi-particle-(envelope)-matrix system based on the cell model is applicable to two- and three-component materials of precipitate-matrix and precipitate-envelope-matrix types, respectively. Finally, an analysis of the determination of the thermal stresses in the multi-par- ticle-(envelope)-matrix system which consists of isotropic as well as uniaxial- and/or triaxial-anisotropic components is presented. Additionally, the thermal-stress induced elastic energy density for the anisotropic components is also derived. These analytical models which are valid for isotropic, anisotropic and isotropic-anisotropic multi-particle- (envelope)-matrix systems represent the determination of important material characteristics. This analytical determination includes: (1) the determination of a critical particle radius which defines a limit state regarding the crack initiation in an elastic, elastic-plastic and plastic components; (2) the determination of dimensions and a shape of a crack propagated in a ceramic components; (3) the determination of an energy barrier and micro-/macro-strengthening in a component; and (4) analytical-(experimental)-computational methods of the lifetime prediction. The determination of the thermal stresses in the anisotropic components presented in this paper can be used to determine these material characteristics of real two- and three-component materials with anisotropic components or with anisotropic and isotropic components.
基金supported by Natural Science Foundation of Chongqing(No.CSTB2022NSCQ-LZX0001)High-end Foreign Expert Introduction Program(No.G2022165004L).
文摘As urbanization progresses,the demand for high-rise buildings and underground spaces is growing,and the need for firm geotechnical construction materials,efficient excavation methods,accurate testing instruments,and innovative geotechnical engineering theories and technologies is increasing.By investigating the phenomena of strengthening and toughening in nature,hydrophobic and ice-phobic,friction anisotropy and drilling as well as excavation,etc,researchers have found that organisms have distinctive external morphology and organization.By imitating the external morphology,structural characteristics or movement mechanism of organisms,novel ideas,new principles,and innovative theories can be provided for the innovation and sustainable development of geotechnical engineering.This paper mainly expounds on the bio-inspired application in geotechnical engineering from three perspectives:geo-materials,geotechnical components,and drilling&excavation equipment,and lists typical application cases.In conclusion,this paper presents a summary and prospects of bio-inspired geotechnical engineering,offering fundamental insights for future research.
基金supported by the Slovak Research and Development Agency under the contracts No.COST-0022-06, No.COST-0042-06,No.APVV-51-061505,No.APVV-0034-07,No. APVV-0171-06by the 6th FP EU NESPA+16 种基金by FP7-REGPOT-2007- 3 DEMATEN 204953(05/08-04/11)by IMPROVING 229625by HANCOC-MNT.ERA-NET 01/09-12/11by NANOSMART Centre of Excellence(01/2007-12/2010) Slovak Academy of Sciencesby the Slovak Grant Agency VEGA(2/7197/27,2/7194/27,2/7195/27, 1/4107/07)by iNTeg-Risk CP-IP 213345-2by European Structural Fund-Center of Excellence(Progressive Materials with Nano-and Submicron-Structure):ITMS NFP code 262200120019by COST Action 536by COST Action 538by OTKA Foundation(No.T043704, T043685,T 048593,T 63609)by HPRT-CT-2000-00037by EC5 Center of Excellence ICAI-CT-2000-70029by OTKA Postdoctoral Research Grant(D38478)by Swedish Research Council(No.621- 2002-4299)by NSF-OTKA-MTA(No.MTA:96 OTKA:049953)by GVOP-3.2.1.-2004-04-0224/3.0by János Bolyai Research Grant. 96/OTKA:049953,OTKA 63609
文摘The paper deals with analytical models of the elastic energy gradient Wsq representing an energy barrier. The energy barrier is a surface integral of the elastic energy density Wq. The elastic energy density is induced by thermal stresses acting in an isotropic spherical particle (q = p) with the radius R and in a cubic cell of an isotropic matrix (q = m). The spherical particle and the matrix are components of a multi-particle-matrix system representing a model system applicable to a real two-component material of a precipitation-matrix type. The multi-particle-matrix system thus consists of periodically distributed isotropic spherical particles and an isotropic infinite matrix. The infinite matrix is imaginarily divided into identical cubic cells with a central spherical particle in each of the cubic cells. The dimension d of the cubic cell then corresponds to an inter-particle distance. The parameters R, d along with the particle volume fraction v = v(R, d) as a function of R, d represent micro- structural characteristics of a real two-component material. The thermal stresses are investigated within the cubic cell, and accordingly are functions of the microstructural charac- teristics. The thermal stresses originate during a cooling pro- cess as a consequence of the difference am - ap in thermal expansion coefficients between the matrix and the particle, am and ap, respectively. The energy barrier Wsq is used for the determination of the thermal-stress induced strengthening aq. The strengthening represents resistance against com- pressive or tensile mechanical loading for am - ap 〉 0 or am - ap 〈 0. respectively.
基金Supported by the Project of the Key Laboratory of Cigarette Flavoring Components Research of China Tobacco Yunnan Industrial Co.,Ltd.(2015539200340278)
文摘The quality of the favoring agents and fragrances degenerated frequently during the storage and transportation process in a cigarette factory in Yunnan Province, causing huge economic losses. In order to ascertain the causes of deterioration, the microbial population, quantity and aroma components of the raw mate- rials were analyzed in the present study. The results showed that a total of 28 bacterial strains and one fungal strain were isolated and identified, belonging to 13 genera. The 29 strains were Bacillus sp. , Microbacterium sp. , Sphingomonas sp. , Leclercia sp. and Acinetobacter sp. isolated from normal ZY material; Bacil- lus sp. , Microbacterium sp. , Sphingomonas sp. , Brevundimonus sp. , Acinetobacter sp. , Agrobacterium sp. , Ralstonia sp. , Acetobacterium sp. , Saccharomyces sp. and Acidovorax sp. isolated from deteriorated ZY material; Agrobacterium sp. , Microbacterium sp. , Burkholderia sp. , Bacillus subtilis strain, Acetobacterium sp. and Leclercia sp. isolated from normal RZ material ; Agrobacterium sp. , Microbacterium sp. , Bacillus subtilis strain, Acetobacterium sp. , Lec/erc/a sp. , Enter- obacter sp. , Acinetobacter sp. and Saccharomyces sp. isolated from deteriorated RZ material. Microbacterium was the dominant genus by number in normal ZY ma- terial, and the population of this genus accounted for 55.6% of the total. In deteriorated ZY material, Acetobacterium, Bacillus and Saccharomyces were dominant genera, as the population of the three genera occupied 75.0% of the total. The total population of microorganisms in the deteriorated ZY material was 90 times of that in normal ZY material. In normal RZ material, the population of each of Microbacterium, Agrobacterium and Bacillus accounted for 25%, while that of each of Leclercia and Burkholderia accounted for 12.5%. In deteriorated RZ material, the population of Bacillus accounted for 65.0% of the total. The total population of the microorganisms in deteriorated RZ material was 29 times of that in normal RZ material, indicating that the deterioration of the materials was caused by microor- ganisms. The contents of aroma components were detected using two-dimensional gas chromatography-mass spectrometry (GC-MS). The results showed that in nor- mal ZY material, the content of β-damascone was higher than that of other aroma components. And normal ZY material had higher contents of benzaldehyde, β-damascone, β-damascone, β-damascone, menthol and benzyl benzoate than deteriorated ZY material, and the differences in the contents of β-ddamascone and β-damascone were most significant between the two materials. In normal RZ material, the content of β-damascone was higher than that of other aroma components. And normal RZ material had higher contents of menthol, ethyl capratc, β-damascone, β-damascone and tabanane C than deteriorated RZ material, and the differ- ences in the contents of ethyl caprate and capric acid were most significant between the two materials. The results revealed that aroma components changed greatly in deteriorated tobacco materials.
基金supported by the Slovak Research and Development Agency under the contracts No. COST-0022-06, No.COST-0042-06, No. APVV-51-061505, No. APVV-0034-07, No.APVV-0171-06by the 6th FP EU NESPA+17 种基金by FP7-EGPOT-2007-3 DEMATEN 204953 (05/08-04/11)by IMPROVING 229625by HANCOC-MNT.ERA-NET 01/09-12/11by NANOSMART Centre of Excellence (01/2007-12/2010) Slovak Academy of Sciencesby the Slovak Grant Agency VEGA (2/7197/27, 2/7194/27, 2/7195/27,1/4107/07)by iNTeg-Risk CP-IP 213345-2by European Structural Fund-Center of Excellence (Progressive Materials with Nano-and Submicron-Structure): ITMS NFP code 262200120019by COST Action 536by COST Action 538by OTKA Foundation (No. T043704,T043685, T 048593, T 63609)by HPRT-CT-2000-00037by EC5 Center of Excellence ICAI-CT-2000-70029by OTKA Postdoctoral Research Grant (D38478)by Swedish Research Council (No. 621-2002-4299)by NSF-OTKA-MTA (No. MTA: 96 OTKA: 049953)by GVOP-3.2.1.-2004-04-0224/3.0by Janos Bolyai Research Grant.96/OTKA04953, OTKA 63609.
文摘The paper deals with analytical fracture mechanics to consider elastic thermal stresses acting in an isotropic multi-particle-matrix system. The multi-particle-matrix system consists of periodically distributed spherical particles in an infinite matrix. The thermal stresses originate during a cooling process as a consequence of the difference αm - αp in thermal expansion coefficients between the matrix and the particle, αm and αp, respectively. The multi-particle-matrix system thus represents a model system applicable to a real two-component material of a precipitation-matrix type. The infinite matrix is imaginarily divided into identical cubic cells. Each of the cubic cells with the dimension d contains a central spherical particle with the radius R, where d thus corresponds to inter-particle distance. The parameters R, d along with the particle volume fraction v = v(R, d) as a function of R, d represent microstructural characteristics of a twocomponent material. The thermal stresses are investigated within the cubic cell, and accordingly are functions of the microstructural characteristics. The analytical fracture mechanics includes an analytical analysis of the crack initiation and consequently the crack propagation both considered for the spherical particle (q = p) and the cell matrix (q = m). The analytical analysis is based on the determination of the curve integral Wcq of the thermal-stress induced elastic energy density Wq. The crack initiation is represented by the determination of the critical particle radius Rqc = Rqc(V). Formulae for Rqc are valid for any two-component mate- rial of a precipitate-matrix type. The crack propagation for R 〉 Rqc is represented by the determination of the function fq describing a shape of the crack in a plane perpendicular
文摘Background:The simplest and most convenient food technology is the using of dry composite mixtures.They have a lot of advantages.Dry composite mixtures,which would completely be the basis for the production of personalized food concentrates,are not represented.The development of such dry composite mixtures is actual and of scientific and practical interest.The purpose of this research is the selection and justification of local import-substituting raw materials components for dry composite mixtures used as the basis for the production of food concentrates.As the objects of research,the raw materials components of the starch,fruit and vegetable,industry were selected.The work uses currently accepted standard research methods for organoleptic and physic-chemical parameters of raw materials components.The research was carried out within of the project“Theoretical Substantiation of Production Technology and the Development of Import-Substituting Food Products of Functional Purpose Based on Dry Composite Mixtures”,funded by the Belarusian Republican Foundation for Basic Research.Based on the researches,it was found out that in the composition of dry composite mixtures for the production of food concentrates it is expedient to use the following raw materials:potato starch,extruded corn starch,dried carrots,dried beets,dried topinambur and dried apples in chopped form.
基金Funded by Committee on Science and Technology Foundation of Guangdong (C11305)
文摘The grinding characteristics of two or multi-component material of cli nker with limestone, blast furnace slag and fly ash were studied. Investigation was carried out on the particle size distribution, the Blaine fineness and the s ieve residue of the separate and interground products. The relative contents of clinker and limestone in different size fractions of the interground product wer e examined, and the interaction of two components, which have different grindabi lities, was analyzed. The results show there exists a selective grinding effect during intergrinding, one component can help or hinder the grinding of the other . Making good use of this interaction appropriately not only enhances the grinda bilities of two or multi-component mixtures, which can promote the grinding pro cess of clinker with industrial wastes, but also improves their particle size di stribution and properties.
基金The authors acknowledge the financial support from the National Natural Science Foundation of China(Grant No.32201509)Hunan Science and Technology Xiaohe Talent Support Project(2022 TJ-XH 013)+6 种基金Science and Technology Innovation Program of Hunan Province(2022RC1156,2021RC2100)State Key Laboratory of Woody Oil Resource Utilization Common Key Technology Innovation for the Green Transformation of Woody Oil(XLKY202205)State Key Laboratory of Woody Oil Resource Utilization Project(2019XK2002)Key Research and Development Program of the State Forestry and Grassland Administration(GLM[2021]95)Hunan Forestry Outstanding Youth Project(XLK202108-1)Changsha Science and Technology Project(kq2202325,kq2107022)Science and Technology Innovation Leading Talent of Hunan Province(2020RC4026).
文摘The C.oleifera oil processing industry generates large amounts of solid wastes,including C.oleifera shell(COS)and C.oleifera cake(COC).Distinct from generally acknowledged lignocellulosic biomass(corn stover,bamboo,birch,etc.),Camellia wastes contain diverse bioactive substances in addition to the abundant lignocellulosic components,and thus,the biorefinery utilization of C.oleifera processing byproducts involves complicated processing technologies.This reviewfirst summarizes various technologies for extracting and converting the main components in C.oleifera oil processing byproducts into value-added chemicals and biobased materials,as well as their potential applications.Microwave,ultrasound,and Soxhlet extractions are compared for the extraction of functional bioactive components(tannin,flavonoid,saponin,etc.),while solvothermal conversion and pyrolysis are discussed for the conversion of lignocellulosic components into value-added chemicals.The application areas of these chemicals according to their properties are introduced in detail,including utilizing antioxidant and anti-in-flammatory properties of the bioactive substances for the specific application,as well as drop-in chemicals for the substitution of unrenewable fossil fuel-derived products.In addition to chemical production,biochar fabricated from COS and its applications in thefields of adsorption,supercapacitor,soil remediation and wood composites are comprehensively reviewed and discussed.Finally,based on the compositions and structural characteristics of C.oleifera byproducts,the development of full-component valorization strategies and the expansion of the appli-cationfields are proposed.
基金Funded by the National Natural Science Foundation of China(Nos.51408287 and 51668038)the Rolls Supported by Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R29)+2 种基金the Distinguished Young Scholars Fund of Gansu Province(1606RJDA318)the Natural Science Foundation of Gansu Province(1506RJZA064)the Excellent Program of Lanzhou Jiaotong University(201606)
文摘The objective of this paper was to develop a comprehensive evaluation method and index to evaluate the performance of sealants and fillers for cracks in asphalt concrete pavements using the method of principal component analysis. The performance experiments including cone penetration, softening point, flow, resilience and tension at low temperature respectively were conducted by reference of ASTM D5329 for eight sealants and fillers often used in China. There by a principal component model was developed and weight of every index was calculated. The experimental results show that there are significantly different performances for sealants and fillers often used in China. Principal component analysis is an objective method that evaluates and selects the performance of sealants and fillers for cracks in asphalt concrete pavements.
基金TheFoundationforScholarsReturnedfromOverseaCNNC! (No .970 48 2 )
文摘The effect of key parameters on fatigue life of common metallic components, e.g. steel, aluminium alloy, has been analysed quantitatively. The influential coverage and degree of these parameters have been investigated systematically, some phenomena which can′t be discovered with qualitative analysis method have been revealed, a series of valuable conclusions has been obtained, which would be very beneficial to fatigue resistant design and improvement of anti fatigue ability of metallic components.
基金supported by the National Natural Science Foundation of China(81873192 and 81202877)Postgraduate Research and Innovation Project of Tianjin(2021YJSB288 and YJSKC-20211004)the Science and Technology Program of Tianjin(Grant No.20ZYJDJC00070)
文摘With its long-term empirical clinical practice and increasing number of health benefits reported,Chinese Materia Medica(CMM)is gaining increasing global acceptance.Importantly,the identification of chemical constituents in vitro and exposed forms in vivo is a prerequisite for understanding how CMM formulae prevent and treat diseases.This review systematically summarizes the exciting and magical journey of CMM components from compound formulae to where they fight,the possible structural transformation of CMM components in vitro and in vivo,and their pharmacological contribution.When a decoction is prepared,significant chemical reactions are observed,including degradation and production of polymers and self-assembling supramolecules,leading to the construction of a component library with diverse decoction structures.After ingestion,compounds pass through the intestinal and blood-brain barriers and undergo a more wonderful journey involving the gut microbiota,microbial enzymes,and endogenous drug-metabolizing enzymes(mainly liver enzymes).At this stage,they are modified and assembled into novel and complex compounds,such as newly generated metabolites,conjugates,and self-assembling superamolecules.This review might provide a strategic orientation to explore the active compounds of CMM formulae in vivo.
文摘In this paper the conception of theoretical determine the relations between material experimental characteristics is presented. On the base of stress-strain relations for nonlinear elastic anisotropic material and geometrical interpretation of deformation state, the general form of strain energy density function was introduced. Using this function and variational methods the relations between material characteristics were achieved. All considerations are illustrated by a short theoretical example.
基金Supported by the National Key R&D Program of China(2016YFB0303401)the National Natural Science Foundation of China(61333010,61503138).
文摘Raw material blending process is an essential part of the cement production process. The main purpose of the process is to guarantee a certain oxide composition for the raw meal at the outlet of the mill by regulating the four raw materials. But the chemical compositions of raw materials vary from time to time, resulting in difficulties to control the oxide compositions to a predefined value. Therefore, a novel algorithm to estimate the chemical compositions of the raw materials is developed. The paper mainly consists of two parts. In model construction part, a novel constrained least square model is proposed to overcome the deviation introduced by long-term drift of the material components, and the model parameters are estimated with an online strategy. And in validation part, the approach is implemented to two examples including datasets from simulation model and the actual industrial process. The final results show the effectiveness of the proposed method.
基金supported by the National Natural Science Foundation of China (No.10432030)the National Youth Science Foundation of China (No.10802091)the Scientific and Technical Foundation of China University of Mining and Technology (No.2007B013)
文摘A new microelement method for the analyses of functionally graded structures was proposed. The key of this method is the maneuverable combination of two kinds of elements. Firstly, the macro elements are divided from the functionally graded material structures by the normal finite elements. In order to reflect the functionally graded distributions of materials and the microconstitutions in each macro-element, the microelement method sets up the dense microelements in every macro-element, and translates nodes to the same as the normal finite elements by the degrees of freedom of all microelemental the compatibility conditions. This microelement method can fully reflect the micro constitutions and different components of materials, and its computational elements are the same as the normal finite elements, so it is an effective numerical method for the analyses of the functionally graded material structures. The three-dimensional analyses of functionally graded plates with medium components and different micro net structures are given by using the microelement method in this paper. The differences of the stress contour in the plane of functionally graded plates with different net microstructures are especially given in this paper.
文摘We used both correlation and covariance-principal component analysis (PCA) to classify the same absorption-reflectance data collected from 13 different polymeric fabric materials that was obtained using Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR). The application of the two techniques, though similar, yielded results that represent different chemical properties of the polymeric substances. On one hand, correlation-PCA enabled the classification of the fabric materials according to the organic functional groups of their repeating monomer units. On the other hand, covariance-PCA was used to classify the fabric materials primarily according to their origins;natural (animal or plant) or synthetic. Hence besides major chemical functional groups of the repeat units, it appears covariance-PCA is also sensitive to other characteristic chemical (inorganic and/or organic) or biochemical material inclusions that are found in different samples. We therefore recommend the application of both covariance-PCA and correlation-PCA on datasets, whenever applicable, to enable a broader classification of spectroscopic information through data mining and exploration.