The Zn2＋, Ni2＋ and Co3＋ doped Sr14Cu24041 compounds were synthesized by standard solid state method. X-ray diffraction results show that the changes in lattice parameters are very small. Selected area electron diff...The Zn2＋, Ni2＋ and Co3＋ doped Sr14Cu24041 compounds were synthesized by standard solid state method. X-ray diffraction results show that the changes in lattice parameters are very small. Selected area electron diffraction patterns （EDPs） show that the diffraction spots corresponding to the CuO2 chain substructure are extended to streaks along a＊ and b＊ directions for all the samples, while the diffraction spots produced merely by the Cu203 ladder substructure are still very sharp. This means that the periodicities of chains in a＊ and b＊ directions are partially destroyed upon doping ofZn, Ni and Co due to that the initial phase of each chain becomes a random variable. The temperature dependence of magnetic properties was measured for every sample. And the number of dimers in CuO2 chain per formula unit （f.u.） and dimer coupling constant are obtained by fitting the temperature dependence of the magnetic susceptibility. It is found that the degree of initial phase disorder is related to the order degree of magnetic sequence in CuO2 chain. For the un-doped sample, the decoupling of dimers is weak, the magnetic sequence is slightly destroyed, and the streaks in EDP are also very weak, which implies the degree of initial phase disorder in CuO2 chain is very low. When Zn2~ and Ni2＋ ions are doped, the number of dimers per f.u. decreases, and the intensity of diffraction streaks increases in comparison with the corresponding spots. Furthermore, when the high spin magnetic ions Co3＋ are doped, the number of holes in Sr14Cu24041 decreases, the magnetic sequence is destroyed very seriously, and the spots in EDP are extended to streaks almost completely. The phenomenon that the diffraction spots ofCuO2 chain extend to streaks in EDP appears as evidence that the magnetic sequence in the CuO2 chain is destroyed by doping of Zn, Ni, Co.展开更多
Thin films of five vanadium compounds/composite： （1） VO2（3-fl） （3-fl = 3-Hydroxyflavone）, （2） VO（pbd）： （pbd = 1-Phenyl-l, 3-butadione）, （3） VO（dbm）2 （dbm = Dibenzoylmethane）, （4） VPc （Vanadyl Ph...Thin films of five vanadium compounds/composite： （1） VO2（3-fl） （3-fl = 3-Hydroxyflavone）, （2） VO（pbd）： （pbd = 1-Phenyl-l, 3-butadione）, （3） VO（dbm）2 （dbm = Dibenzoylmethane）, （4） VPc （Vanadyl Phthalocyanine） and （5） V2O5-PEPC （V2O5- poly-N-epoxypropylcarbazole composite）, were deposited by the dropcasting method from the solution in benzene. The transmittance-irradiance relationships were investigated and the transmission in the visible spectrum and optical images were obtained as well. It was found that the transmittance of the VO2（3-fl）, VO（pbd）2, VO（dbm）2 and VPc, was practically independent of the irradiance; whereas the transmittance of V2O5-PEPC decreased by 4% for thin and 9% for thick films with an increase of the irradiance.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.10674105 and 50471028)
文摘The Zn2＋, Ni2＋ and Co3＋ doped Sr14Cu24041 compounds were synthesized by standard solid state method. X-ray diffraction results show that the changes in lattice parameters are very small. Selected area electron diffraction patterns （EDPs） show that the diffraction spots corresponding to the CuO2 chain substructure are extended to streaks along a＊ and b＊ directions for all the samples, while the diffraction spots produced merely by the Cu203 ladder substructure are still very sharp. This means that the periodicities of chains in a＊ and b＊ directions are partially destroyed upon doping ofZn, Ni and Co due to that the initial phase of each chain becomes a random variable. The temperature dependence of magnetic properties was measured for every sample. And the number of dimers in CuO2 chain per formula unit （f.u.） and dimer coupling constant are obtained by fitting the temperature dependence of the magnetic susceptibility. It is found that the degree of initial phase disorder is related to the order degree of magnetic sequence in CuO2 chain. For the un-doped sample, the decoupling of dimers is weak, the magnetic sequence is slightly destroyed, and the streaks in EDP are also very weak, which implies the degree of initial phase disorder in CuO2 chain is very low. When Zn2~ and Ni2＋ ions are doped, the number of dimers per f.u. decreases, and the intensity of diffraction streaks increases in comparison with the corresponding spots. Furthermore, when the high spin magnetic ions Co3＋ are doped, the number of holes in Sr14Cu24041 decreases, the magnetic sequence is destroyed very seriously, and the spots in EDP are extended to streaks almost completely. The phenomenon that the diffraction spots ofCuO2 chain extend to streaks in EDP appears as evidence that the magnetic sequence in the CuO2 chain is destroyed by doping of Zn, Ni, Co.
文摘Thin films of five vanadium compounds/composite： （1） VO2（3-fl） （3-fl = 3-Hydroxyflavone）, （2） VO（pbd）： （pbd = 1-Phenyl-l, 3-butadione）, （3） VO（dbm）2 （dbm = Dibenzoylmethane）, （4） VPc （Vanadyl Phthalocyanine） and （5） V2O5-PEPC （V2O5- poly-N-epoxypropylcarbazole composite）, were deposited by the dropcasting method from the solution in benzene. The transmittance-irradiance relationships were investigated and the transmission in the visible spectrum and optical images were obtained as well. It was found that the transmittance of the VO2（3-fl）, VO（pbd）2, VO（dbm）2 and VPc, was practically independent of the irradiance; whereas the transmittance of V2O5-PEPC decreased by 4% for thin and 9% for thick films with an increase of the irradiance.
